• Title/Summary/Keyword: $UCl_3$

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Revisiting Prediction Tools for Daylight Adequacy and Its Potential Improvement

  • Kim, Dong Hyun
    • KIEAE Journal
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    • v.17 no.3
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    • pp.35-44
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    • 2017
  • Purpose: This study questioned the efficiency of daylight factor as a daylight adequacy and investigated a method of how to complement its weakness by considering a direct sunlight component under a clear sky condition. Method: The Snowdon visitor centre cafe was chosen as a case study building and various techniques such as BRE formula, BRE sky protractor, Pilkington dot diagram and mock-upscale model under the artificial sky simulator were used to analyse and compare daylight factor values. An analysis of direct sunlight component under the clear sky condition was carried out by Climate Consultant 5.5, sun path diagram, and the artificial sky simulator. Result: The result of daylight factor analysis differed by the adopted techniques and it was also contradictory to the results on a direct sunlight penetration. The result not only showed the limitation of daylight factor as a metric but also suggested an improvement by combining it with direct sunlight analysis. The techniques used in this study had a merit of being applied in the early design stage and thus be beneficial to many design professions in order for early daylight performance analysis.

ABNORMAL GROWTH PATTERN OF HUMAN FETAL MAXILLA WITH CLEFT LIP AND PALATE (구순구개열 태아의 비정상적인 상악골 성장형태에 대한 연구)

  • Kim, Soung-Min;Kim, Jung-Hwan;Kim, Ji-Hyuck;Park, Young-Wook;Lee, Jong-Ho;Lee, Suk-Keun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.33 no.3
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    • pp.238-246
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    • 2007
  • This study is aimed to elucidate the abnormal growth pattern of human fetal maxilla with cleft lip and palate (CLP). Total 71 fetal maxillae with CLP were obtained from aborted human fetuses. They were examined radiologically for the dimensional changes of maxillary trapezoid (MT) formed by maxillary primary growth centers (MxPGC)(Lee et al., 1992). In palatal radiogram of the CLP maxilla, the MT was traced by the anterior and posterior MxPGCs, and the dimensions of anterior and posterior maxillary widths, maxillary length, and MT length (MTL), and MT area were measured for evaluation of the basic growth pattern of the developing maxilla. The growth of anterior and posterior MxPGCs was severely retarded in the prenatal maxillae with CLPs, showing abnormal shape of MT. Cleft lip subjects without cleft palate also showed arrested growth of MT. Unilateral cleft lipalveolar cleft or cleft palate (UCL-AC/CP) and bilateral cleft lip-alveolar cleft or cleft palate (BCL-AC/CP) showed enhanced abnormal MT pattern. The abnormality of MT was most marked in BCL-AC/CP. It was also observed that the craniofacial malformations other than CLPs produced abnormal MT. In conclusion, the MT growth of prenatal CLP maxilla was severely arrested and resulting in abnormal MT shape on the palatal radiogram. BCL-AC/CP showed more protruded nasal septum than other types of CLPs, while UCL-AC/CP showed severe deviation of the protruded nasal septum towards the non-cleft side. Cleft lip only subjects also showed the abnormal growth of MT. These data suggest that the MT is primarily involved in CLPs, and MT shape could be utilized as a sensitive indicator for the analysis of maxillary malformation in different types of CLPs.

Effect of Cl2 on Electrodeposition Behavior in Electrowinning Process

  • Kim, Si Hyung;Kim, Taek-Jin;Kim, Gha-Young;Shim, Jun-Bo;Paek, Seungwoo;Lee, Sung-Jai
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2017.10a
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    • pp.73-73
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    • 2017
  • Pyroprocessing at KAERI (Korea Atomic Energy Research Institute) consists of pretreatment, electroreduction, electrorefining and electrowinning. SFR (Sodium Fast Reactor) fuel is prepared from the electrowinning process which is composed of LCC (Liquid Cadmium Process) and Cd distillation et al. LCC is an electrochemical process to obtain actinides from spent fuel. In order to recover actinides inert anodes such as carbon material are used, where chlorine gas ($Cl_2$) evolves on the surface of the carbon material. And, stainless steel (SUS) crucible should be installed in large-scale electrowinning system. Therefore, the effect of chlorine on the SUS material needs to be studied. LiCl-KCl-$UCl_3$-$NdCl_3$-$CeCl_3$-$LaCl_3$-$YCl_3$ salt was contained in 2 kinds of electrolytic crucible having an inner diameter of 5cm, made of an insulated alumina and an SUS, respectively. And, three kinds of electrodes such as cathode, anode, reference were used for the electrochemical experiments. Both solid tungsten (W) and LCC were used as cathodes. Cd of 45 g as the cathode material was contained in alumina crucibles for the deposition experiments, where the crucible has an inner diameter of 3 cm. Glassy carbon rod with the diameter of 0.3 cm was employed as an anode, where shroud was not used for the anode. A pyrex tube containing LiCl-KCl-1mol% AgCl and silver (Ag) wire having a diameter of 0.1cm was used as a reference electrode. Electrodeposition experiments were conducted at $500^{\circ}C$ at the current densities of $50{\sim}100mA/cm^2$. In conclusion, Fe ions were produced in the salt during the electrodeposition by the reaction of chlorine evolved from the anode and Fe of the SUS crucible and thereby LCC system using SUS crucible showed very low current efficiencies compared with the system using the insulated alumina crucible. Anode shroud needs to be installed around the glassy carbon not to influence surrounding SUS material.

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A study for the establishment of analysis tool for the visible area of three dimensional space - Based on the Raster operation using 3D game engine - (다시점 가시영역 분석도구설정에 관한 기초연구 - 3D게임엔진을 이용한 래스터 연산방식을 중심으로 -)

  • Kim, Suk-Tae;Jun, Han-Jong
    • Korean Institute of Interior Design Journal
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    • v.16 no.5
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    • pp.38-46
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    • 2007
  • In the late 1970s, the method of quantitative and scientific space structural analysis based on graph theory was introduced to the process of space design, which arranges design and functional elements, as relying heavily on intuition could produce errors due to unverified experiences and prejudices of the designer. As the method of space analysis is complex and hard to express visually and requires repetitive operations, it was discussed theoretically only. However, with the development of computer performance and graphic in recent years, visualization became possible. But the method of visual structural analysis of space is at the level of two dimensions and it is not easy to get accurate data when it is applied to limited three dimensional space such as an interior space. For the visual structural analysis of space, this study presents 4 indices including visibility volume level, pure visibility connection frequency, effective visibility connection frequency, and path visibility connection frequency. This study also presents space division using three dimensional arrangement rather than the existing vector operation method and raytracing algorithm at the lattice constant. Based on this, an analysis tool for the visible regions of three dimensional space that is capable of evaluating at multiple points by using three dimensional game engine and presentation tool that allows the analyzer to interpret the data effectively is made. It is applied to 2 prototype models by displacing Z axis, and the results are compared with UCL Depthmap to verify the validity of data and evaluate its usefulness as a multidimensional, multi-view space analysis tool.

Indian Parents Prefer Vaccinating their Daughters against HPV at Older Ages

  • Madhivanan, Purnima;Srinivas, Vijaya;Marlow, Laura;Mukherjee, Soumyadeep;Narayanappa, Doddaiah;Mysore, Shekar;Arun, Anjali;Krupp, Karl
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.1
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    • pp.107-110
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    • 2014
  • Background: Increasing uptake of human papillomavirus (HPV) vaccine should be a priority in developing countries since they suffer 88% of the world's cervical cancer burden. In many countries studies show that age at vaccination is an important determinate of parental acceptability. This study explores parental preferences on age-to-vaccinate for adolescent school-going girls. Materials and Methods: The sample was selected using a two-stage probability proportional to size cluster sampling methodology. Questionnaires were sent home with a random sample of 800 adolescent girls attending 12 schools in Mysore to be completed by parents. Descriptive statistics including frequencies, percentages and proportions were generated for independent variables and bivariate analyses (Chi square test) were used to assess the relationship between independent and appropriate age-to-vaccinate. Results: HPV vaccination acceptability was high at 71%. While 5.3% of parents felt girls should be vaccinated by 10 years or younger; 38.3% said 11-15 years; 14.8% said 16-18 years; 5.8% suggested over 19 years; and 33% didn't know. Only 2.8% of parents would not vaccinate their daughters. Conclusions: Delaying HPV vaccination until later ages may signifivantly increase uptake of the HPV vaccine in India.

Interaction between UN and CdCl2 in molten LiCl-KCl eutectic. I. Experiment at 773 K

  • Zhitkov, Alexander;Potapov, Alexei;Karimov, Kirill;Shishkin, Vladimir;Dedyukhin, Alexander;Zaykov, Yury
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.123-134
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    • 2020
  • The interaction between UN and CdCl2 in the LiCl-KCl molten eutectic was studied at 773 K. The reaction was controlled by sampling the melt, as well as by analysis of the resulting precipitate. The process was shown to proceed according to several parallel reactions. The summary reaction was determined to have two stages: a fast one and a slow one. The 19-53% UN → UCl3 conversion was obtained for the molar ratio of CdCl2/UN = 1.22-14.9. The rest of UN converts into the precipitate of complex composition (UNCl + U2N3 + U4N7 + UN2). The increase in the CdCl2/UN molar ratio from 1.22 to 14.9 resulted in the decrease in duration of the first "fast" stage of the process from 18 h to 1 h.

LiCl 용융염 전해환원 공정 희토류원소 산화물의 화학적 거동

  • Park, Byeong-Heung;Choe, In-Gyu;Jeong, Myeong-Su;Heo, Jin-Mok
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.11a
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    • pp.346-346
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    • 2009
  • 산화물 형태 사용후핵연료의 효율적 처분 혹은 재활용을 위한 연구 가운데, 고온의 LiCl 용융염 중에서 전해환원하여 금속으로 환원시킨 후, 환원된 금속을 고온의 LiCl-KCl 용융염에서 전해정련하는 연구가 국내외적으로 활발하게 진행되고 있다. 전해환원을 위해 일정 농도 $Li_2O$가 LiCl 용융염에 첨가되며 $Li_2O$ 농도가 높으면 반응 재질의 부식성이 크게 증가하므로 일반적으로 우라늄 산화물은 1wt% 이하의 $Li_2O$ 농도에서 전해환원 된다. 우라늄 산화물의 전해환원 전위는 $Li_2O$의 전해환원 전위 보다 표준 상태를 기준으로 공정온도인 650 $^{\circ}C$ 에서 약 70 mV 정도 낮기 때문에 전해환원 과정에서 $Li_2O$ 의 환원으로 Li 금속이 생성될 가능성이 있으며 우라늄 산화물은 대부분 직접 전해환원 되지만 일부 Li에 의해 화학적으로 환원되기도 한다. 전해환원 공정에서 환원되지 않은 희토류 산화물은 전해정련 공정에서 $UCl_3$와 반응하여 $UO_2$를 생성시켜 공정 효율을 떨어뜨린다. 따라서 전해환원 공정에서 가능하연 최대한 희토류 산화물을 금속으로 환원시키는 조건을 찾아내는 것이 바람직하고 이를 위해서 우선 전해환원 공정에서 희토류 산화물의 화학적 거동의 이해가 요구된다. 본 연구에서 열역학적 검토를 통하여 희토류 산화물의 환원 조건을 조사한 결과 희토류 산화물은 매운 낮은 $Li_2O$ 농도에서 Li에 의해 환원되고, 1wt% 이하의 $Li_2O$ 농도에서는 Sc와 Lu의 산화물이 $Li_2O$와 복합산화물을 형성하고 이들 복합산화물은 Li에 의해 환원되지 않는 것으로 나타났다. 또한 희토류 원소 별로 희토류 원소 산화물의 Li에 의한 환원 조건으로서 평형상태에서의 $Li_2O$ 농도 즉 환원 임계 $Li_2O$ 농도를 실험적으로 측정하였으며 1wt% $Li_2O$ 농도 이하에서 열역학적 해석과 동일하게 Sc와 Lu만이 복합산화물을 형성하여 Li에 의해 직접환원 되지 않는 것으로 관찰되었다.

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Sensitivity Analysis of Initial Pressure and Upper Control Limit on the Pressure Decay Test for Membrane Integrity Evaluation (압력손실시험을 이용한 막 완결성 평가에서 초기압력 및 UCL 도출인자 민감도 분석)

  • Lee, Joohee;Hong, Seungkwan;Hur, Hyunchul;Lee, Kwangjae;Choi, Youngjune
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.793-800
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    • 2008
  • Recently domestic drinking water industry has recognized membrane-based technology as a promising alternative for water treatment. To ensure successful application of membrane processes, the integrity of membrane systems should be maintained. According to US EPA guidance, the pressure decay test based on the bubble point theory is recommended to detect any membrane defection of which size is close to the smallest diameter of Cryptosporidium oocysts, $3{\mu}m$. Proper implementation of the pressure decay test is greatly affected by initial test pressure, and the interpretation of the test results is associated with upper control limit. This study is conducted to investigate various factors affecting determination of initial test prtessure and upper control limit, including membrane-based parameters such as pore shape correction factor, surface tension and contact angle, and system-based parameters, such as volumetric concentration factor and total volume of system. In this paper, three different hollow fibers were used to perform the pressure decay test. With identical initial test pressure applied, their pressure decay tendency were different from each other. This finding can be explained by the micro-structure disparity of those membranes which is verified by FESEM images of those membranes. More specifically, FESEM images revealed that three hollow fibers have asymmetry, deep finger, shallow finger pore shape, respectively. In addition, sensitivity analysis was conducted on five parameters mentioned above to elucidate their relation to determination of initial test pressure and upper control limit. In case of initial pressure calculation, the pore shape correction factor has the highest value of sensitivity. For upper control limit determination, system factors have greater impact compared to membrane-based parameters.

Shoot.Root Growth and Nodule Formation of White Clover as Affected by Removal of Cotyledon and Unifoliolate (자엽 및 단엽 제법에 따른 White Clover 지상부 및 지하부 생장과 근류유형)

  • 강진호;한경수;박진서;이희원
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.14 no.3
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    • pp.177-185
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    • 1994
  • Slow seedling growth rate and nodulation failure of white clover (Trifolium repens L.) has been limited its good establishment to pastures. The experiment was done to determine the effect of removal of cotyledon and unifoliolate on the shoot, root growth, and nodule formation of 4 white clover cultivars for 8 weeks after the treatment. Four white clover cv. Regal (large leaf), Louisiana S-I (medium-large leaf), Grasslands Huia (mediumsmall leaf), and Aberystwyth S184 (small leaf), were grown in IOcm plastic pot containing 2:l:l soi1:sand:peat moss mixture until grown to cotyledon or unifoliolate stage and then removed one (Cl) or two cotyledons (C2) at cotyledon stage, and unifoliolate only (U), unifoliolate and one cotyledon (UCl) or unifoliolate and two cotyledons (UC2) at the unifoliolate stage, and the plants were sampled at 4, 6 and 8 weeks after the treatments. The intact plants had greater shoot and root dry weights, and no. of nodules than removal-treated ones. Removal treatments at cotyledon stage, the dry weight and no. of nodules more decreased in C1 and C2 than that of unifoliolate stage. While the severer cotyledon removal, the more reduction. Although the dry weights and no. of nodules steadily inclined with regrowing period, the former were higher in Regal and La. S-1 than in the others since 6 weeks after removal treatment but the latter was more in S 184 than in the others 8 weeks after removal treatment. Relationship between no. of nodules and shoot or root dry weight was analysed as linear mode while the earlier and severe removal, the steeper slope. It was concluded that severer damage of cotyledon and unifoliolate had detrimental effects on the shoot and root growth, nodule formation, and aftermath establishment of white clover.

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Cloning and Expression of Thermostable Chitosanase Gene from Bacillus sp. KFB-C108

  • Yoon, Ho-Geun;Kim, Hee-Yun;Kim, Hye-Kyung;Kim, Kyung-Hyun;Hwang, Han-Joon;Cho, Hong-Yon
    • Journal of Microbiology and Biotechnology
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    • v.9 no.5
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    • pp.631-636
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    • 1999
  • The thermostable endo-chitosanase gene from the isolated strain Bacillus sp. KFB-C108 was identified on the basis of a phylogenetic analysis of the 16S rRNA gene sequence, and was cloned into plasmid pUCl8 using E. coli $DH5\alpha$ as the host strain. Positive clones carrying recombinant plasmids (pKCHO I and pKCHO II) containing chitosanase activity were selected using the direct activity staining method. Detailed physical maps showed the two plasmid inserts were identical except that the KCHO II insert (2.6 kb) was 1.8 kb smaller than that of the KCHO I. The recombinant plasmids were analyzed to determine the essential region for chitosanase activity, and a 1.3-kb fragment (KCHO-6) was subcloned into pTrc99A using the EcoRI and BamHI sites to construct pTrc99A/KCHO-6(pTrEB13). The resulting plasmid exerted high chitosanase activity upon transformation of E. coli $DH5{\alpha}cells$, overproducing about 20 times more in the cloned cells than in the wild-type cells. The cloned chitosanase protein exhibited the same molecular weight and catalytic activity similar to those of Bacillus sp. KFB-C108. The cloned enzyme was an endo-type that produced a chitosan tetramer as the major reaction product; however, it produced no monomers or dimers.

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