• 제목/요약/키워드: $TiO_2$ nanofiber

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$TiO_2$ 나노파이퍼를 첨가한 염료감응형 태양전지의 전기화학적 특성 (Electrochemical Characteristics of added $TiO_2$ Nanofiber for Dye-Sensitized Solar Cells)

  • ;박경희;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.243-244
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    • 2009
  • The $TiO_2$ nanofiber doped $TiO_2$ electrode area applied to dye-sensitized solar cells(DSSCs). The mixtures of $TiO_2$ nanofiber to $TiO_2$ photoelectrode has larger surface area than $TiO_2$ photoelectrode. In this research added 2.5, 5 and 10wt% $TiO_2$ nanofibers and the optimum condition of 5 wt% $TiO_2$ nanofiber's high surface area contributing the improvement of short-circuit photocurrent. The open-circuit voltage was 0.7V and solar energy conversion efficiency was 5.4%.

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$TiO_2$ 나노파이버를 첨가한 광전극용 $TiO_2$ 페이스트가 염료감응 태양전지의 광전변환 특성에 미치는 영향 (Effect of performance in $TiO_2$ paste for Dye-Sensitized Solar Cells by $TiO_2$ nanofiber)

  • 백형열;이호;김은미;박경희;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.358-359
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    • 2008
  • Solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of $TiO_2$ nanofiber added to the $TiO_2$ paste, on surface morphology, good electric of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increased with $TiO_2$ nanofiber addition up to 7wt% in $TiO_2$ films. Maximum increase upto 15% in the efficiently was observed at 7 wt. % of $TiO_2$ nanofiber in $TiO_2$ electrode.

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AAO Template를 이용한 Au/TiO2 나노섬유 제조 및 응용에 관한 연구 (A Study on the Preparation and Application of Au/TiO2 Nanofiber from AAO Template)

  • 엄선미;박상선;김영덕;김용록;설용건
    • 전기화학회지
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    • 제12권1호
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    • pp.47-53
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    • 2009
  • 본 연구에서는 불순물이 포함된 Al 기판으로부터 두 단계의 양극산화 (anodization) 법에 의해 균일한 나노기공을 갖는 AAO(Anodic Aluminum Oxide)을 제조하였다. 생성된 AAO템플릿 위에 Deposition-Precipitation(DP)방법을 사용하여 수직으로 형성된 $TiO_2$ 나노섬유에 Au를 첨가시켜 2 wt.% $Au/TiO_2$ 나노섬유룰 제조하였다. 두 단계의 양극산화를 통해 규칙적으로 배열된 AAO 기공 형상과 기판 위에 수직으로 배향된 $TiO_2$ 나노섬유의 형상을 SEM을 통해 확인하였다. 또한 $Au/TiO_2$ 나노섬유의 특성은 XRD와 Raman 분석을 통하여 $TiO_2$의 아나타제(anatase)와 루타일(rutile) 결정구조와 $TiO_2$ 나노섬유에 담지된 Au의 존재를 확인하였다. 또한 일산화탄소(CO) 산화반응을 통해 AAO(Anodic Aluminum Oxide)기판 위에 형성된 $TiO_2$와 2 wt% $Au/TiO_2$ 나노섬유의 광촉매적 활성을 비교하였다.

염료감응형 태양전지의 광전기적 특성 개선을 위한 금속산화물 나노파이버의 응용 (Application of Metal Oxide Nanofiber for Improving Photovoltaic Properties of Dye-Sensitized Solar Cells)

  • 동영상;김은미;정상문
    • 청정기술
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    • 제24권3호
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    • pp.249-254
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    • 2018
  • 염료감응형 태양전지의 광전변환효율(${\eta}$) 향상을 위하여 수열합성한 $TiO_2$ 나노입자에 전기방사한 $TiO_2$, $SiO_2$, $ZrO_2$$SnO_2$ 나노파이버를 첨가하여 광전극에 적용하였다. $TiO_2$ 나노파이버를 첨가한 염료감응형 태양전지는 순수한 $TiO_2$ 나노입자에 비해 높은 전류밀도($J_{sc}$)를 나타내었고 이것은 나노파이버 구조로 인하여 염료에서 여기된 전지의 전달 특성이 용이하여 나타난 현상으로 생각된다. 또한 $SiO_2$ 나노파이버를 첨가한 염료감응형 태양전지의 경우, 순수한 $TiO_2$ 나노입자를 이용한 것에 비해 보다 높은 0.67 V의 개방전압($V_{oc}$)을 나타내었고 에너지 변환효율 또한 6.24%로 가장 높게 나타났다.

전기방사법을 이용한 산화티탄 나노섬유의 제조 (Fabrication of Electrospun Titania Nanofiber)

  • 박수일;이득용;이명현;이세종;김배연
    • 한국세라믹학회지
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    • 제42권8호
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    • pp.548-553
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    • 2005
  • $TiO_2$ nanofibers were fabricated by annealing electrospun $TiO_2$/PVP nanofibers for 3 h at $500^{\circ}C$ in air. Size and uniformity of electrospun $TiO_2$ nanofiber diameters were evaluated via XRD and SEM by varying electric field, PVP concentration, Ti tetraisopropoxide concentration and precursor flow rate. Experimental results revealed that the effect of PVP concentration on size and uniformity of electrospun $TiO_2$ nanofiber diameters was most profound, however, the other effects were relatively small. Uniform fibers with no beads were observed for the electrospun anatase titania nanofibers with a diameter of 170 nm.

에너지 전환 소자용 $TiO_{2}/CNT$ 하이브리드 나노 섬유 전극 (Ti02/CNT Hybrid Nanofiber Electrode for Energy Conversion Devices)

  • 서재섭;김주용;진형준;강민성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.323-325
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    • 2007
  • $TiO_{2}$ electrode electrospun directly onto the substrate was developed for energy conversion device. To enhance energy conversion efficiency of dye-sensitized solar cell, electrodes should have higher surface area to absorb more dyes and higher conductivity to reduce recombination of generated electrons. $TiO_{2}$ nanofibers with higher surface areas were fabricated by annealing electrospun $TiO_{2}/PVP$ nanofibers at $500^{\circ}C$ for 3 hrs in air. it was revealed that $TiO_{2}$ nanofiber electrodes is hybrid with MWNT showed higher conductivity than $TiO_{2}$ semiconductor electrode possibly due to band gap change.

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코어-쉘 구조를 갖는 BaTiO3@Fe 나노섬유의 합성 및 전자파 흡수 특성 (Synthesis and Electromagnetic Wave Absorbing Property of BaTiO3@Fe Nanofibers with Core-Shell Structure)

  • 이영인;장대환;성기훈;이규만;좌용호
    • 한국분말재료학회지
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    • 제23권1호
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    • pp.38-42
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    • 2016
  • $BaTiO_3$-coated Fe nanofibers are synthesized via a three-step process. ${\alpha}-Fe_2O_3$ nanofibers with an average diameter of approximately 200 nm are first prepared using an electrospinning process followed by a calcination step. The $BaTiO_3$ coating layer on the nanofiber is formed by a sol-gel process, and a thermal reduction process is then applied to the core-shell nanofiber to selectively reduce the ${\alpha}-Fe_2O_3$ to Fe. The thickness of the $BaTiO_3$ shell is controlled by varying the reaction time. To evaluate the electromagnetic (EM) wave-absorbing abilities of the $BaTiO_3@Fe$ nanofiber, epoxy-based composites containing the nanofibers are fabricated. The composites show excellent EM wave absorption properties where the power loss increases to the high frequency region without any degradation. Our results demonstrate that the $BaTiO_3@Fe$ nanofibers obtained in this work are attractive candidates for electromagnetic wave absorption applications.

Development of photocatalytic PVA/$TiO_2$ nanofiber membrane by electrospinning and its application for Air Filtration

  • Linh, Nguyen Thuy Ba;Lee, Byong-Taek
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2010년도 춘계학술발표대회
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    • pp.38.1-38.1
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    • 2010
  • Nanofibers have a large potential in air filtration applications. In this work, we have developed a photocatalytic polyvinyl alcohol PVA/$TiO_2$ nanofibers membrane for the treatment of air filtration by using electrospinning method. PVA were electrospun into nanofibrous membranes and $TiO_2$ nanoparticles were loaded in PVA nanofibers in various contents from 10% (w/w) to 50% (w/w). The UV-Vis spectra were conducted for testing the existence of $TiO_2$ nanoparticles in PVA fibers. SEM analysis indicated that $TiO_2$ nanoparticles were loaded on the surface of PVA fibers and dispersed linearly along the fiber direction, which originated from the effect of polarization and orientation caused by high electric field. X-ray diffraction (XRD) was used to determine the crystalline of the membrane. Tensile strength was measured to evaluate the physical properties of the membrane. Therefore, our work suggested that PVA/$TiO_2$ nanofiber membrane has a potential application in air filtration area.

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전기방사를 이용한 Poly(vinyl alcohol)/Pullulan/TiO2 나노부직포의 제조 (Electrospinning Fabrication of Poly(vinyl alcohol)/Pullulan/TiO2 Nanofibers)

  • 양성백;최우석;현재민;신재천;최진현;염정현
    • 한국염색가공학회지
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    • 제26권3호
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    • pp.195-200
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    • 2014
  • Poly(vinyl alcohol)(PVA)/pullulan/titanium dioxide($TiO_2$) composite nanofibers were produced at different $TiO_2$ concentrations(1 and 3 wt.%) using the electrospinning method. The parameters of electrospinning including polymer contents, voltage and tip-to-collector distance(TCD) were optimized for fabrication process. The study showed that the best condition to make PVA/pullulan nanofiber and effect of $TiO_2$ nanoparticles. The PVA/pullulan/$TiO_2$ nanofibers were characterized by scanning electron microscope(SEM), transmission electron microscope(TEM), Thermogravimetric analysis (TGA) and X-ray diffraction(XRD).