• Title/Summary/Keyword: $Ti^+$

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A study of mechanical properties and development of intelligent composite using TiNiCo shape memory alloy (TiNiCo 형상기억복합재료의 기계적특성에 관한 연구)

  • 박영철;한근조;박동성
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.04a
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    • pp.465-469
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    • 1997
  • In this paper, shape memory compsites are made by powder metallurgy. And then, an self-strengthening effect of the composites by shape memory effect above inverse transformation temperature A/sab f/ of TiNi alloy discussed. Moreover, TiNiCo/Al composite is made by using TiNiCo alloy as fiber. And it is discused aboutaffection of Co in the shape memory composite. The results of the intelligent properties of TiNi/Ai-radical shape memory composite, using SMA, by powder metallurgy are the tensile strength of TiNiCo wire is much higher than that of TiNi wire. and the strength of TiNiCo/Al composite is generally higher than that TiNi/Al composite.

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Tool Geometry for Improving Tool-Life in Turning of STS 304 (STS 304의 선삭에서 공구수명 향상을 위한 공구형상)

  • 이재우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.581-584
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    • 2003
  • The austenitic STS 304 stainless steel was turned to clarify the effects of tool geometry on the tool wear. The wear of TiN-TiCN-TiC-TiAlN coated tungsten carbide tool was the smallest, exhibiting larger wear in the order of Si-Al-O-N ceramic, TiN coated tungsten carbide, TiN-TiCN-TiN coated tungsten carbide, TiC-TiN cermet and M20 tungsten carbide tools at the same cutting conditions. The S-type tool of M20 with large approach angle showed the longest tool life of all tools used in this tests due to preventing the groove wear of the side cutting edge. The wear of the S-type tool with the rake angle of 15$^{\circ}$became smaller than with that of -5$^{\circ}$, but the tool with the nose radius of 0.8mm did not perform much better with increasing the rake angle.

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Spectrochemical Determination of Impurities in Barium Titanate and Strontium Titanate Single Crystals (Barium Titanate 및 Strontium Titanate 單結晶中의 不純物의 分光化學分析)

  • Jae-young Hwang
    • Journal of the Korean Chemical Society
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    • v.7 no.4
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    • pp.254-256
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    • 1963
  • A spectrochemical analysis was made to compare the major impurities in $BaTiO_3$ single crystals grown from $KF-BaTiO_3$ system and $TiO_2-BaTiO_3$ system respectively. The present technique was also extended, without any modifications, to the analysis of $SrTiO_3$ crystal.

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Tool-Wear Characteristics in Turning of STS 304 (STS 304 선삭시의 공구마멸 특성)

  • 이재우
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.10
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    • pp.56-64
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    • 2003
  • The effect of tool geometry on the tool wear in turning the austenitic stainless steel, STS 304 was investigated. The wear of TiN-TiCN-TiC-TiAlN coated tungsten carbide tool was the smallest, showing larger wear in the order of Si-Al-O-N ceramic, TiN coated tungsten carbide, TiN- TiCN- TiN coated tungsten carbide, TiC-TiN cermet and M20 tungsten carbide tools at the same cutting conditions. The S-type tool of M20 with the larger side cutting edge angle showed the smallest tool wear in all tests due to preventing the groove wear of the side cutting edge. The wear of the S-type tool with the rake angle of $15^{\circ}$ became smaller than with that of $-5^{\circ}$, but the tool with the nose radius of 0.8mm did not perform much better with increasing the rake angle.

비대칭 마그네트론 스퍼터링 장치에 의한 Ti 나노금속 함량에 따른 탄소박막의 물리적, 전기적 특성

  • Park, Yong-Seop;Lee, Jong-Deok;Hwang, Hyeon-Seok;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.444-444
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    • 2012
  • 본 연구에서는 흑연(graphite)과 티타늄(titanum; Ti) 타겟이 양쪽에 부착되어 있는 비대칭 마그네트론 스퍼터링 장치를 이용하여 Ti가 도핑되어진 탄소(a-C:Ti) 박막을 증착하였다. 흑연 타겟의 파워는 고정하고 Ti 타겟 파워를 증가시켜 탄소 박막내에 Ti의 함량을 증가시켰으며, Ti 금속 함량에 따른 탄소박막의 경도와 마찰계수, 표면의 거칠기, 접촉각 등의 물리적 특성과 비저항 등 전기적 특성을 고찰하였으며, XPS와 라만등을 이용하여 a-C:Ti 박막의 구조적 특성을 고찰하여 Ti 금속 함량에 따른 구조적 특성과 물리적 특성, 전기적 특성과의 관계를 규명하였다.

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Deposition Behaviors of Ti-Si-N Thin Films by RF Plasma-Enhanced Chemical Vapor Deposition. (RF-PECVD법에 의한 Ti-Si-N 박막의 증착거동)

  • 이응안;이윤복;김광호
    • Journal of the Korean institute of surface engineering
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    • v.35 no.4
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    • pp.211-217
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    • 2002
  • Ti-Si-N films were deposited onto WC-Co substrate by a RF-PECVD technique. The deposition behaviors of Ti-Si-N films were investigated by varying the deposition temperature, RF power, and reaction gas ratio (Mx). Ti-Si-N films deposited at 500, 180W, and Mx 60% had a maximum hardness value of 38GPa. The microstructure of films with a maximum hardness was revealed to be a nanocomposite of TiN crystallites penetrated by amorphous silicon nitride phase by HRTEM analyses. The microstructure of maximum hardness with Si content (10 at.%) was revealed to be a nanocomposite of TiN crystallites penetrated by amorphous silicon nitride phase, but to have partly aligned structure of TiN and some inhomogeniety in distribution. and At above 10 at.% Si content, TiN crystallite became finer and more isotropic also thickness of amorphous silicon nitride phase increased at microstructure.

The electric properties of TiN made by reactively magnetron sputtering (반응성 마그네트론 스퍼터링으로 제작한 TiN의 전기적 특성)

  • 김종진;신인철;이상미;김홍배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.75-78
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    • 1996
  • The deposition condition Gf TiN films as electrode was studied by sheet resistance, TiN depositon Thickness X-ray diffraction. TiN was made by reactively DC magnetron sputtering with varying $N_2$/Ar mixture gas and substrate temperature. After finding The deposition condition of TiN films, The samples with the structure of Cu/Ta$_2$O$_{5}$, TiN/Ta$_2$O$_{5}$Si, Cu/TiN/Ta$_2$O$_{5}$ Si were prepared and were measured I-V, C-V. As a results, it was found that when TiN was deposited in an $N_2$a results, it was found that when TiN was deposited in an $N_2$atmosphere its Sheet resistance is lower n than n V$_2$Ar mixtureixture

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Effect of $BaTiO_3$ Dispersion on the Properties of Cast Tapes in Processing of Multilayer Ceramic Capacitor(MLCC) (적층 세라믹콘덴서 제조공정에서 $BaTiO_3$의 분산이 테이프캐스팅 성형체의 물성에 미치는 영향)

  • 김봉호;김병관;김명호;백운규
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.214-222
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    • 1996
  • The effect of physicochemical properties of organic solvent and dispersant among organic solvent dispersant binder and plasticizer which are used as processing additives in MLCC fabrication process on the dispersion of BaTiO3 was studied. The steric and electrostatic stabilization mechanisms in dispersion of BaTiO3 in organic media were evaluated respectively. The sttability of BaTiO3 achieved bysteric stabilization was dependent on the fraction of surface coverage of dispersant adsorption on BaTiO3. The electrostatic repulsive forces of BaTiO3 particles dispersed in orgainc media was found to be appreciabley great and dependent mainly on the kinds of organic solvent used. The mechanism affecting the stability of BaTiO3 was studied by the method of rheologi-cal behaviors of BaTiO3 suspension.

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Studies on Preparation of $TiO_2$Powder with High Purity and Fine Particle -A Study of Fine Particle(III)- (고순도.미립 $TiO_2$분말 제조에 관한 연구 -미립화 연구(III)-)

  • 최병현;허혜경;지미정;정경원;김무경
    • Journal of the Korean Ceramic Society
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    • v.37 no.10
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    • pp.944-948
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    • 2000
  • TiCl$_4$, 물 및 propanol의 혼합용액으로부터 가수분해하여 미립의 TiO$_2$분말을 제조할 때 HPC 첨가와 HPC 존재하에서 TiCl$_4$mole 농도 및 유기용매 처리를 했을 때 입자크기, 응집성 및 형태 등을 관찰하였다. HPC는 TiO$_2$합성시 steric dispersant로 작용하여 응집을 적게 하는 경향을 나타내었고 HPC를 첨가한 상태에서 TiCl$_4$의 mole 농도 변화는 입자크기에 크게 영향을 주었는데 TiCl$_4$mole 농도가 증가함에 따라 입자크기는 증가하였다. 또한 유기용제 처리는 분산 효과가 있었다.

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Influence of Carbon Vacancies on CO Chemisorption on TiC(001): A Theoretical Study

  • Kang, Dae-Bok
    • Journal of the Korean Chemical Society
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    • v.61 no.1
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    • pp.7-11
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    • 2017
  • The extended $H{\ddot{u}}ckel$ method is employed to analyze the interaction of carbon monoxide with the TiC(001) surfaces, both perfect and containing carbon vacancies. CO exhibits a similar ${\sigma}$-donation interaction for both $Ti_{25}C_{25}$ and $Ti_{25}C_{23}$ clusters, as deduced from the fact that the populations of the CO $5{\sigma}$ orbital are identical upon adsorption, but it bonds more strongly with the $Ti_{25}C_{23}$ than with the $Ti_{25}C_{25}$ because the metal d electron density in $Ti_{25}C_{23}$ provides ${\pi}$ back-bonding interactions with CO that are absent in $Ti_{25}C_{25}$. This work suggests that a difference in reactivity toward CO of stoichiometric TiC and TiC with carbon defects is connected with the occupancy of $2{\pi}^*$ orbitals that leads to a significant weakening of the C-O bond.