• Title/Summary/Keyword: $T_2O_3$

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Effect of ${Fe_2}{O_3}$ Addition on Mechanical and Optical Properties of t-$ZrO_2$/${Al_2}{O_3}$ Composites (${Fe_2}{O_3}$ 첨가에 따른 t-$ZrO_2$/${Al_2}{O_3}$ 복합체의 기계적 및 광학적 특성)

  • Lee, Deuk-Yong;Kim, Dae-Joon;Lee, Myung-Hyun;Park, Il-Seok;Choi, Hyun
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.354-358
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    • 2000
  • Tetragonal (t)-ZrO2/Al2O3 composites doped with Y2O3, Nb2O5, and Fe2O3 ((Y, Nb, Fe)-TZP/Al2O3) were prepared over the range containing Fe2O3 from 0.1 to 0.5 mol% with 0.1 mol% intervals to evaluate the effect of Fe2O3 addition on chromaticity, hydrothermal stability, and mechanical property of the composites. After autoclaving for 20 h at 18$0^{\circ}C$ under 3.5 MPa water vapor pressure, no tlongrightarrowm phase transformation was observed probably due to the preferential solid solubility of Fe2O3 in Al2O3, the presence of the rigid Al2O3 particles, and the inherent phase stability of (Y, Nb)-TZP. The optimized strength and the fracture toughness of the composite were 700 MPa and 8.5 MPa.m1/2, respectively, when 0.1 mol% Fe2O3 was added. The composites have shown a gradual color change from a slightly white ivory to a pale yellowish brown with increasing the Fe2O3 concentration.

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Effect of EuO$_3$addition on hydrothermal stability of t-ZrO$_2$/Al$_2$O$_3$composites (t-ZrO$_2$/Al$_2$O$_3$복합체 상 안정성에 대한 Eu$_2$O$_3$첨가 효과)

  • 이득용;김대준;최성갑;이명현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.3
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    • pp.233-238
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    • 2000
  • t-$ZrO_2/Al_2O_3$composites having a superior biocompatability and phase stability were prepared by adding 0~4 mol% of $Eu_2O_3$and sintered for 1 h at $1600^{\circ}C$ to evaluate phase stability, chromaticity and mechanical properties of the composites. No tetragonal to monoclinic phase transformation was observed for the composites containing $Eu_2O_3$after heat treatment for 20 h at $180^{\circ}C$ under 3.5 MPa water vapor pressure condition. As $Eu_2O_3$content increased, the color of the composites was changed from a slight white ivory to a light pink. The strength and the fracture toughness of the composites containing $Eu_2O_3$were above 620 MPa and 7.6 MPa.$m^{1/2}$, respectively, when $Eu_2O_3$was added up to 3 mol%.

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Effects of $Cr_2O_3$ Addition in PSS-PZT Piezoelectric Ceramics for Surface Acoustic Wave Filter ($Cr_2O_3$가 탄성 표면파 필터용 PSS-PZT계 압전 세라믹스에 미치는 영향)

  • 홍재일;손은영;박창엽
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.5
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    • pp.502-507
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    • 1992
  • To improve temperature stability, 0.05Pb(SnS11/2TSbS11/2T)OS13T-0.35PbTiOS13T-0.60PbZrOS13T+0.4[wt%]MnO S12T piezoelectic ceramics were manufactured with the addition of CrS12TOS13T by Hot Press method. And the SAW delay line was fabricated and effects of CrS12TOS13T to the propagation characteristics of SAW was investigated, and the SAW filter was fabricated on C4 specimen added by 0.2[wt%] CrS12TOS13T whose propagation characteriatics of surface acoustic wave were the bast and its frequency characteristics was investigated. Electromechancal coupling factor(kS1sTS02T) was 3.11[%] and its temperature coefficient of the center frequency(CS1foT)was -21.27[ppm/$^{\circ}C$] in C4. The 31[MHz]]SAW IF filter of C4 scarcely had diffraction phenomena and therefore it was proper.

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A Study on the Dielectric and Piezoelectric properties of the Pb(SbS11/2TSnS11/2T)OS13T-PbTiOS13T-PbZrOS13T Ceramics (Pb(Sb1/2Sn1/2)O3-PbTiO3-PbZrO3 세라믹스의 유전 및 압전 특성에 관한 연구)

  • 정장호;류기원;이성갑;이영희
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.5
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    • pp.517-524
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    • 1992
  • In this study, 0.10Pb(SbS11/2TSnS11/2T)OS13T-(0.90-x)PbZrOS13T (0.25 x 0.40) ceramics were fabricated by the atmospheric method. The sintering temperature and time were 1250[$^{\circ}C$] and 2[2hr], respectively. The structureal, dielectric and piezoelectric properties with composition of PbTiOS13T were studied. As the results of XRD ans SEM, the crystal structure of a specimen was rhombohedral, lattice constant and average grain size were decreased with increasing the contents of PbTiOS13T. Relative dielectric constant and Curie temperature were increased with increasing the contents of PbTiOS13T, 0.10PSS-0.40PT-0.50PZ specimen had the highest values of 904 and 265[$^{\circ}C$], respectively. In increasing of PbTiOS13T contents form 25[mol%] to 40[mol%], piezoelectric charge constant and electromechanical coupling factors were increased form 114[pC/N] to 142[pC/N], 17[%] to 24[%] and mechanical quality factor were decreased with increasing the contents of PbTiOS13T. In the 0.10PSS-0.40PT-0.50PZ specimens, those values were 14.2[kV/cm] and 9.43[x10S0-6TC/cmS02T], resectively.

Geochemical Characteristics on Geological Groups of Stream Sediment in the Boseong-Hwasun Area, Korea (보성-화순지역 하상퇴적물에 대한 지질집단별 지구화학적 특성)

  • Park, Young-Seog;Kim, Jong-Kyun
    • Journal of the Korean earth science society
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    • v.32 no.7
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    • pp.707-718
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    • 2011
  • We study the natural background and geochemical characteristics on geological groups of stream sediment in the Boseong-Hwasun area. We collected 186ea stream sediment samples along the primary channels and dried them naturally in laboratory. The contents of major, trace and rare earth elements were determined by XRF, ICP-AES and NAA analysis methods. In order to know the natural background and geochemical characteristics of geological groups, we classified the studied area into granitic gneiss (GGn) area and porphyroblastic gneiss (PGn) area. The contents range of major elements for GGn area is $SiO_2$ 45.5-73.09 wt.%, $Al_2O_3$ 12-20.76 wt.%, $Fe_2O_3$(T) 3.72-8.85 wt.%, $K_2O$ 2.38-4.2 wt.%, MgO 0.75-2.77 wt.%, $Na_2O$ 0.78-1.88 wt.%, CaO 0.27-2.1 wt.%, $TiO_2$ 0.56-1.72 wt.%, $P_2O_5$ 0.06-0.73 wt.% and MnO 0.03-0.95 wt.%, and for PGn area it is $SiO_2$ 43.74-70.71 wt.%, $Al_2O_3$ 11.54-25.05 wt.%, $Fe_2O_3$(T) 3.44-13.46 wt.%, $K_2O$ 2.08-3.86 wt.%, MgO 0.65-2.99 wt.%, $Na_2O$ 0.63-1.7 wt.%, CaO 0.35-2.07 wt.%, $TiO_2$ 0.68-4.17 wt.%, $P_2O_5$ 0.1-0.31 wt.% and MnO 0.07-0.33 wt.%. The contents range of hazard elements for GGn area is Cr 41.7-242 ppm, Co 7.6-25.1 ppm, Ni 12-61 ppm, Cu 10-47 ppm, Zn 48.5-412 ppm, Pb 17-215 ppm, and for PGn area, it is Cr 29.6-454 ppm, Co 5.9-53.7 ppm, Ni 8.7-287 ppm, Cu 6.4-134 ppm, Zn 43.6-370 ppm, Pb 15-37 ppm area. There is a good correlation between Cr and MgO and Co among $Al_2O_3$, $Fe_2O_3$(T), MgO and Ni among $Fe_2O_3$(T), CaO, MgO whereas Cu, Zn and Pb have a low correlation for major elements in GGn area. Generally Cr, Co, Ni, and Cu have a good correlation with major elements, but a low correlation with Zn and Pb in PGn area.

Study on Properties of Ag and PbO Doped $YBa_2Cu_3O_x$

  • Son, Dea-Wha;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.593-596
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    • 2003
  • A proposed way to prepare $YBa_2Cu_3O_y$ wires or tapes is that Ag is used as substrate and melting point of $YBa_2Cu_3O_y$ is decreased to lower than the melting point of silver ($961\;^{\circ}C$). Therefore after the deposition of $YBa_2Cu_3O_y$ film on Ag substrate, the heat treatment can be carried out below the Ag melting point. Silver (Ag) and Lead oxide(PbO) were selected to be additives for $YBa_2Cu_3O_y$. Different Ag and PbO contents were added in $YBa_2Cu_3O_y$, the melting points of which were measured by DTA. In order to guarantee that the superconductivity of $YBa_2Cu_3O_y$ was not reduced after Ag and PbO added into $YBa_2Cu_3O_y$, their superconductivities were measured. It is proved that as additives, both Ag and PbO can reduce the melting point of $YBa_2Cu_3O_y$. For Ag doped $YBa_2Cu_3O_y$, $T_c$ is about 93K and ${\Delta}Tc$ is $2{\sim}3K$. For PbO doped $YBa_2Cu_3O_y$, $T_c$ is $88K{\sim}92K$ and ${\Delta}T_c$ is $11{\sim}12K$. When 10 wt% of Ag and 10 wt% PbO were added in $YBa_2Cu_3O_y$, the melting point of the mixture of $YBa_2Cu_3O_y$ (80 wt%), Ag (10 wt%) and PbO (l0 wt%) is $943^{\circ}C$. The transition temperatures ($T_c$) of the sample is 91.8 K.

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Fabrication of Fibrous A12O3-(m-ZrO2)/t-ZrO2 Composites Having 2, 3-Dimensional Array (2,3차원배열을 갖는 섬유상 A12O3-(m-ZrO2)/t-ZrO2 복합재료의 제조)

  • Kim Ki-Hyun;Lee Byong-Taek
    • Korean Journal of Materials Research
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    • v.15 no.9
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    • pp.608-612
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    • 2005
  • Microstructure and mechanical properties of fibrous $A1_2O_3-(m-ZrO_2)/t-ZrO_2$ composite were investigated depending on the dimensional array. By the change of stacking arrangement of fibrous filaments, 2 and 3-dimensional fibrous composites were successfully obtained without bulk defects such as shrinkage cavity and cracks. The maximum mechanical properties were achieved In the 3-dimensional array composite, due to the fine fibrous and dense microstructure control, in which the values of vickers hardness, fracture toughness and bending strength were about 1507 Hv, $7.2MPa{\cdot}m^{1/2}$ and 650 MPa, respectively.

A Study on Ash Fusibility Temperature of Domestic Thermal Coal Implementing Thermo-Mechanical Analysis (TMA를 이용한 국내 발전용 탄의 용융점 변화에 대한 연구)

  • Lee, Soon-Ho;Lim, Ho;Kim, Sang Do;Jeon, Chung-Hwan
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.233-239
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    • 2014
  • The slagging which generated from ash deposition on furnace wall and tube in boiler reduces the heat transfer efficiency and damages to safety of boiler. The slag flow behavior in boiler is affected by melting temperature which is related to ash compositions. In this study, the behavior of slag is researched by using ash fusibility test, called TMA (Thermo-Mechanical Analysis). The technique measures the percentage shrinkage as the function of temperature, T25%, T50%, T75%, T90%. These temperatures indicate different stages of melting. Then, the effect of ash chemical compositions measured from XRF (X-ray Fluorescence Spectrometer) to ash fusion temperatures is discussed. Among the chemical compositions, refractory and fluxing influence on ash fusibility is described. High levels of refractory component and limited amount of fluxing components ($Fe_2O_3$, $K_2O$, CaO) increase overall melting temperatures. High $SiO_2/Al_2O_3$ ratio decrease high melting temperatures (T75%, T90%). Meanwhile, the presence of reasonable levels of fluxing components reduces overall melting temperature. A presence of fluxing component such as $K_2O$ and CaO is found to decrease the T25% values significantly. From this research, it is possible to make a reasonable explanation and prediction of ash fusion characteristic from analysis of TMA results and ash chemical compositions.

Parallel Computation For The Edit Distance Based On The Four-Russians' Algorithm (4-러시안 알고리즘 기반의 편집거리 병렬계산)

  • Kim, Young Ho;Jeong, Ju-Hui;Kang, Dae Woong;Sim, Jeong Seop
    • KIPS Transactions on Computer and Communication Systems
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    • v.2 no.2
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    • pp.67-74
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    • 2013
  • Approximate string matching problems have been studied in diverse fields. Recently, fast approximate string matching algorithms are being used to reduce the time and costs for the next generation sequencing. To measure the amounts of errors between two strings, we use a distance function such as the edit distance. Given two strings X(|X| = m) and Y(|Y| = n) over an alphabet ${\Sigma}$, the edit distance between X and Y is the minimum number of edit operations to convert X into Y. The edit distance between X and Y can be computed using the well-known dynamic programming technique in O(mn) time and space. The edit distance also can be computed using the Four-Russians' algorithm whose preprocessing step runs in $O((3{\mid}{\Sigma}{\mid})^{2t}t^2)$ time and $O((3{\mid}{\Sigma}{\mid})^{2t}t)$ space and the computation step runs in O(mn/t) time and O(mn) space where t represents the size of the block. In this paper, we present a parallelized version of the computation step of the Four-Russians' algorithm. Our algorithm computes the edit distance between X and Y in O(m+n) time using m/t threads. Then we implemented both the sequential version and our parallelized version of the Four-Russians' algorithm using CUDA to compare the execution times. When t = 1 and t = 2, our algorithm runs about 10 times and 3 times faster than the sequential algorithm, respectively.

Effect of Surface Grinding on Low Temperature Degradation of 3Y-TZP (표면 연마가 3Y-TZP의 저온열화에 미치는 영향)

  • 김대준;이홍림;정형진
    • Journal of the Korean Ceramic Society
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    • v.30 no.2
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    • pp.164-168
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    • 1993
  • Grinding of 3mol% Y-TZP enhanced the texturing of t-ZrO2, which is represented by the increased I(002)t/I(200)t peak intensity ratio, and an asymetric broadening of (111)t peak. The degree of texturing and asymetric broadening depended on a seversity of grinding. The asymetric (111)t peak broadening was resulted by the formation of r-ZrO2. When aged at 25$0^{\circ}C$ for 120h, r-ZrO2 transformed to t-ZrO2 due to the relief of stressed surface area and the amount of tlongrightarrowm transformation inversely varied with the I(002)t/I(200)t. The inverse dependence was interpreted by that the degree of texturing determines the magnitude of residual surface stress and the lattice relaxation of t-ZrO2, which causes the low temperature degradation, is retarded as the residual stress becomes greater.

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