• Title/Summary/Keyword: $SrSO_4$

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Thermal Release of LiCl Waste Salt from Pyroprocessing (파이로프로세싱 발생 LiCl염폐기물의 열발생)

  • Kim, Jeong-Guk;Kim, Kwang-Rag;Kim, In-Tae;Ahn, Do-Hee;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.2
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    • pp.73-78
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    • 2009
  • The decay heat of Cs and Sr contained in a LiCl waste salt, generated from an electrolytic reduction process in pyroprocessing of spent nuclear fuel, has been calculated. The calculation has been carried out under some assumptions that most of the LiCl waste is purified and recycled to main process, and the residual is fabricated to make a waste form. As a result, the decay heat from daughter nuclides such as Ba and Y seems to be maximum 4.6 times higher than that from their parent nuclides such as Cs and Sr. The thermal release from Cs and Sr in the LiCl waste is the maximum around the first one month, so an cooling system operation for some time at the beginning would be suggested to control a rapid increase in the temperature of the LiCl waste salt.

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Element Dispersion and Wallrock Alteration of TA26 Seamount, Tonga Arc (통가열도 TA26 해저산의 모암변질과 원소분산)

  • Yoo, Bong-Chul;Choi, Hun-Soo;Koh, Sang-Mo
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.359-372
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    • 2011
  • TA26 seamount, which is located at south part of Tonga arc, occurs widely hydrothermal plume and is area that sampled hostrock, hydrothermal ore and hydrothermal alteration rock for this study. Hostrocks are basalt and basaltic andesite. Altered rocks by hydrothermal solution consists of plagioclase, pyroxene, pyrite, ilmenite, amorphous silica, barite, smectite, iron sulfates, Fe-Si sulfates and Fe silicates. Gains and losses of major, trace and rare earth elements during wallrock alteration suggest that $K_2O$(+0.04~+0.45 g), $SiO_2$(-6.52~+10.56 g), $H_2O$(-0.03~+6.04 g), $SO_4$(-0.46~+17.54 g), S(-0.46~+13.45 g), total S(-0.51~+16.93 g), Ba(-7.60~+185078.62 g), Sr(-36.18~+3033.08 g), Ag(+54.83 g), Au(+1467.49 g), As(-5.80~+1030.80 g), Cd(+249.78 g), Cu(-100.57~+1357.85 g), Pb(+4.91~+532.65 g), Sb(-0.32~+66.59 g), V(-113.58~+102.94 g) and Zn(-49.56~+14989.92 g) elements are enriched from hydrothermal solution. Therefore, gained(enriched) elements(($K_2O$, $H_2O$, $SO_4$, S, total S, Ba, Sr, Ag, Au, As, Cd, Cu, Pb, Sb, V, Zn) represent a potentially tools for exploration of sea-floor hydrothermal deposits from the Tonga arc.

Effect of Simultaneous K and Ca Application to Paddy Soil on the Uptake of Radiocaesium and Radiostrontium by Rice (논토양에 대한 K와 Ca의 동시처리가 벼의 Radiocaesium과 Radiostrontium 흡수에 미치는 영향)

  • Choi, Yong-Ho;Lim, Kwang-Muk;Jun, In;Keum, Dong-Kwon;Kim, In-Gyu
    • Journal of Radiation Protection and Research
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    • v.37 no.2
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    • pp.90-95
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    • 2012
  • A radio-tracer experiment was performed in a greenhouse to investigate the effectiveness of the simultaneous application of K and Ca as a countermeasure for reducing the radiocaesium and radiostrontium uptake by rice. Paddy soil (loam of pH 6.5) in soil boxes was spiked with $^{137}Cs$ and $^{85}Sr$, and treated with K and Ca in the forms of KCl and $Ca(OH)_2$, respectively, at agrochemical grades before transplanting. For the seeds of the control plants, soil-to-plant transfer factors (TF, $m^2\;kg^{-1}-dry$) of $^{137}Cs$ and $^{85}Sr$ were $7.4{\times}10^{-5}$ and $2.1{\times}10^{-4}$, respectively, whereas the corresponding values for the straws were $2.6{\times}10^{-4}$ and $2.2{\times}10^{-2}$, respectively. The TF values of $^{137}Cs$ and $^{85}Sr$ kept decreasing as the level of the simultaneous application of K and Ca (K/Ca, $g\;m^{-2}$) increased up to 33.6/322 and 48.0/460, respectively. The maximum rate of the decrease was around 60% for both radionuclides. Nearly 60% reduction in the TF value of $^{85}Sr$ was observed even at the dosage of 33.6/322, which was considered the optimum dosage based on crop productivity as well as reduction in the radiocaesium and radiostrontium uptake by rice. The optimum dosage may depend on various factors so further experiments need to be made for many different conditions.

Fabrication of Luminescent Hydroxyapatite Microspheres for Drug Loading and Release

  • Park, So Yeon;Kwon, Seung Lee;Baek, Mi Yeon;Yoo, Jin Sun;Kim, Min-Cheol;Jung, Hyun Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.360.1-360.1
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    • 2016
  • Hydroxyapatite (Ca10(PO4)6(OH)2, HAP) particles have attracted a great deal of attention in biomedical fields due to their good biocompatibility, bioactivity and fairly broad applications as drug delivery, dental implant, bone cement, and etc. Thus, many researchers have made an effort to add new functionalities such as luminescence, drug delivery, and bone regeneration properties up to HAP powders by controlling their nanostructure as well as composition. In this research, the mesoporous strontium substituted HAP (Sr-HAP) microspheres were synthesized using a hydrothermal method. In this synthesis, aspartic acid monomers were utilized to form microsphere by controlling surface energy of HAP particles and Sr ions were substituted into Ca ion sites, which induced luminescence property in HAP powders. Moreover, the change in the amount of Sr substitution was found to influence the particle size, morphology, and concurrently surface area, which led to changing drug loading as well as drug release property. The amount of Sr influences the morphology, luminescent properties, particle size, surface area cell viability and drug loading property, which are investigated by SEM, TEM, XRD, FTIR, BET, XPS and in vitro test such as MTT assay and drug release test. In particular, the multifunctional Sr-HAP with molar ratios of 0.25 (Sr/(Ca+Sr)) possessed the strongest luminescent property as well as the superior drug loading and sustained release properties that were correspondent with large surface area and pore size. Our study indicates that the fabricated multifunctional Sr-HAP microspheres are quite useful for bone regeneration and drug delivery.

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Curie Temperature and Tunable Dielectric Properties of Barium Strontium Titanate Thick Films (티탄산 바륨 스트론튬 (BaxSr1-xTiO3) 후막의 상전이온도와 가변 유전특성)

  • Jeon, So-Hyun;Kim, In-Sung;Min, Bok-Ki;Song, Jae-Sung;Yoon, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.421-426
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    • 2006
  • [ $(BaSr)TiO_3$ ] thick films were prepared by tape casting method, using $BaTiO_3\;and\;SrTiO_3$ powder slurry in order to investigate dielectric properties i.e. dielectric constant, ${\varepsilon}_r$, Curie temperature, $T_c$. Grain growth within $(BaSr)TiO_3$ thick films was observed with increasing weight ratio of $BaTiO_3$. This observation can be explained by phenomena of substitution of $Sr^{2+}$ ion for $Bi^{2+}$ ion in the $BaTiO_3$ system. Also, the Curie temperature in $(BaSr)TiO_3$ thick films was shifted to lower temperature range with increasing $ SrTiO_3$. Furthermore, Curie temperature having maximum dielectric constant was in the range of $-40^{\circ}C\;to\;30^{\circ}C$, and hence sharper phase transformation occurred at Curie temperature. There occurred decrease in tunability and k-factor of $(Ba_{0.6}Sr_{0.4})TiO_3$ calculated from the dielectric constant, ${\varepsilon}_r$ above Curie temperature. In addition, above the $60^{\circ}C$, phase fixation was observed. This means that internal stress relief occurred with increasing $90^{\circ}$ domains.

Protective Effect of Sanguisorba officinalis L. Root on Amyloid ${\beta}$ Protein (25-35)-induced Neuronal Cell Damage in Cultured Rat Cortical Neuron

  • Ban, Ju-Yeon;Cho, Soon-Ock;Jeon, So-Young;Song, Kyung-Sik;Bae, Ki-Hwan;Seong, Yeon-Hee
    • Korean Journal of Medicinal Crop Science
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    • v.13 no.5
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    • pp.219-226
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    • 2005
  • Sanguisorbae radix (SR) from Sanguisorba officinalis L. (Losaceae) is widely used in Korea and China due to its various pharmacological activity. The present study aims to investigate the effect of the methanol extract of SR on amyloid ${\beta}$ Protein(25-35) $(A{\beta}\;(25-35))$, a synthetic 25-35 amyloid peptide, -induced neurotoxicity using cultured rat cortical neurons. SR, over a concentration range of $10-50\;{\mu}g/ml$, inhibited the $A{\beta}$ (25-35) $(10\;{\mu}M)-induced$ neuronal cell death, as assessed by a 3-[4,5-dimethylthiazole-2-yl]-2,5-diphenyl-tetrazolium bromide (MTT) assay and the number of apoptotic nuclei, evidenced by Hoechst 33342 staining. Pretreatment of SR $(50\;{\mu}g/ml)$ inhibited $10\;{\mu}M\;A{\beta}$ (25-35)-induced} elevation of cytosolic calcium concentration $([Ca^{2+}]c)$, which was measured by a fluorescent dye, fluo-4 AM. SR $(10\;and\;50\;{\mu}g/ml)$ inhibited glutamate release into medium induced by $10\;{\mu}M\;A{\beta}(25-35)$, which was measured by HPLC, and generation of reactive oxygen species. These results suggest that SR prevents $A{\beta}$ (25-35)-induced neuronal cell damage in vitro.

The Study on Microstructure and Magnetic Properties of Ferrite with Various Fe Contents in $Mg_{1.9-2x}Mn_{0.05}Fe_{4x}O_{4+${\gamma}$}+2_{wt%} Al_2O_3$ ($Mg_{1.9-2x}Mn_{0.05}Fe_{4x}O_{4+${\gamma}$}+2_{wt%} Al_2O_3$ 조성내 Fe량 변화에 따른 페라이트의 미세구조 및 자기적 특성 연구)

  • 김성재;정명득;강대석
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.235-240
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    • 1994
  • The electric and magnetic properties of Mg1.9-2xMn0.05Fe4xO4+${\gamma}$+2wt% Al2O3, and its microstructure have been investigated as a function of ferrite composition (x=0.45, 0.5, 0.55). The microstructure turned out to be independent on the ferrite composition. The resistivity was decreased with increasing Fe contents, whereas the Curie temperature decreased. Saturation magnetization was varied from 1741 to 2022 G with composition, and squareness ratio (SR), coercive force (BHc) were decreased and increased with increasing Fe contents respectively, so the sample which SR and BHc were 0.97 Oe and 1.49 Oe can be attainable at x=0.45.

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The Sr and Pb Isotopic and Geochemical Properties of the Atmospheric Bulk Deposition of Jeonju, Gunsan, and Namweon Areas (전주, 군산, 남원지역 강수의 Sr, Pb동위원소 지화학)

  • Jeon Seo-Ryeong;Chung Jae-il
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.463-479
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    • 2005
  • The Sr and Pb isotopic ratios and chemical composition were measured for atmospheric bulk deposition samples collected in the Jeonju, Gunsan and Namweon areas over a period of one year. Acidity of deposition ranged pH $4\~7$ with little higher in dry season, and around pH 5.0 in rainy season. The EC and TDS of rainy season was low showing dilution effect, and increased during dry season. Sulfate $(SO_4)\;and\;NO_3$ are atmospheric aerosols largely of anthropogenic origin in winter. Sodium was concentrated in winter deposition, Ca was concentrated in spring to summer deposition. Namweon has lower EC and TDS than those of other, and Jeonju has higher. Namweon was concentrated in $HCO_3$ and Cunsan was concentrated in Cl. Aluminium, Cu, and Zn show good correlation index with TDS, indicating of their origin atmospheric. $^{87}Sr/^{86}Sr$ ratios of bulk deposition ranged from 0.7109 to 0.7128. The isotopic variations are correlated with mixing of isotopic compositions of local soils, road deposit and biogenic aerosol. In order to constrain further the origin of aerosols in rainwater, it will be necessary to collect additional Sr isotopic data for aerosols. Lead isotope ratios for all areas were similar and belonged to Pb isotope ratios of Seoul's aerosols, but little different with Beijing's aerosols. It showing that Pb in the Korea mainly derived from the gasoline combustion, not exclusively from the Beijing.

Fabrication of High Tc Superconductor Using Thermal pyrolysis Method (열분해법 의한 초전도선재 합성)

  • Lee, Sang-Heon;Choi, Young
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1337-1338
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    • 2006
  • BiSrCaCuO was prepared by the thermal pyrolysis method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $90^{\circ}C$ and calcination at $840^{\circ}C-920^{\circ}C$ for 4h, the high Tc phase was cleary observed. In this paper, the establishment of fabrication condition and additive effects of second elements were examined so as to improve the related properties to the practical use of BiSrCaCuO superconductor, and we reported the production of the BiSrCaCuO high Tc superconductor by the pyrolysis method.

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Enhancement of Spatial Resolution to Local Area for High Resolution Satellite Imagery (고해상도 위성영상을 위한 국소영역 공간해상도 향상 기법)

  • Kang, Ji-Yun;Kim, Ihn-Cheol;Kim, Jea-Hee;Park, Jong Won
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.4
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    • pp.137-143
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    • 2013
  • The high resolution satellite images are used in many fields such as weather observation, remote sensing, military facilities monitoring, cultural properties protection etc. Although satellite images are obtained in same satellite imaging system, the satellite images are degraded depending on the condition of hardware(optical device, satellite operation altitude, image sensor, etc.). Due to the fact that changing the hardware of satellite imaging system is impossible for resolution enhancement of these degraded satellite after launching a satellite, therefore the method of resolution enhancement with satellite images is necessary. In this paper the resolution is enhances by using a Super Resolution(SR) algorithm. The SR algorithm is an algorithm to enhance the resolution of an image by uniting many low resolution images, so an output image has higher resolution than using other interpolation methods. But It is difficult to obtain many images of the same area. Therefore, to solve this problem, we applied SR after by applying the affine and projection transform. As a results, we found that the images applied SR after affine and projection transform have higher resolution than the images only applied SR.