• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.24 no.8
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• pp.678-681
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• 2011

We have investigated the effect of organic thin film on the driving voltage of OLED (organic light emitting diode) by inserting a 5 nm thick 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) or triphenylphosphineoxide ($Ph_3PO$) between tris-(8-hydroxyquinoline)aluminum ($Alq_3$) electron transport layer and 4,4'-bis(2,2'-diphyenylvinyl)-1,1'-biphenyl (DPVBi) emission layer. The device with 5 nm thick $Ph_3PO$ layer exhibited higher maximum current efficiency and lower driving voltage than the device with BCP layer, resulting from better electron injection from $Alq_3$ to DPVBi in the device with $Ph_3PO$ layer.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.9
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• pp.878-882
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• 2006

We have fabricated single organic layer devices of the organolanthanide complex, terbium tris-(1-phenyl-3-methyl-4-(tertiarybutyry)pyrazol-5-one)triphenylphosphine oxide [$(tb-PMP)_{3}Tb-(Ph_{3}PO)$] for the investigation of its light emission and electrical conduction properties. The thickness of ($(tb-PMP)_{3}Tb-(Ph_{3}PO)$) layer was varied to 60, 75, 95 nm. Mg and Ca layers were used for the cathode contact. The electrical conduction in the $(tb-PMP)_{3}Tb-(Ph_{3}PO)$ single layer devices was dominated by the injection of electrons into the organic layer from the cathode. A higher current density at much lower voltages can be attained with Ca cathode because of the enhanced electron injection. The device shows very sharp emission at 548 nm. The FWHM of the strongest emission peak was 12 nm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.04a
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• pp.83-84
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• 2006

ITO/4, 4', 4"-tris (N -3 - methylphenyl - N - phenyl - amino) - triphenylamine, [m-MTDATA] / Terbium Iris - (1 - phenyl - 3 - methyl - 4 - (tertiarybutyryl) - pyrazol - 5 - one) triphenylphosphine oxide [$(tb-PMP)_3Tb-(Ph_3PO)$] / Mg:Ag devices were made to investigate its electrical and light emission properties. The thickness of m-MTOATA layer was varied from 0 to 80 nm. There was a threshold thickness for the sufficient hole injection. The insertion of 20 nm thick m-MTDATA layer between ITO and Tb-complex resulted in the right shift of current-voltage curve because of the insufficient hole injection. The low operating voltage can be obtained above the 40 nm of m-MTDATA layer. The insertion of m-MTDATA induced the increase of the background in the electroluminescence spectrum which was dependent on the current density of the devices.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.3
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• pp.252-256
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• 2009

We have developed low driving voltage white organic light emitting diode with a new electron transport material, triphenylphosphine oxide ($Ph_{3}PO$). The white light emission was realized with a rubrene yellow dopant and blue-emitting DPVBi layer. The new electron transport layer results in a very high current density at low voltage, resulting in a reduction of driving voltage. The device with a new electron transport layer shows a brightness of $1150\;cd/m^2$ at a low driving voltage of 4.3 V.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.412-413
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• 2006

The electrical conduction mechanism of ITO / Terbium tris - (1 - phenyl - 3 - methyl - 4 - (tertiarybutyryl) - pyrazol - 5 - one) triphenylphosphine oxide [$(tb-PMP)_3Tb-(Ph_3PO)$]/Mg/Al devices has been investigated. The calculation of electric field in single layer organic layer between cathode and anode shows the uniform distribution for the electron injection barrier of over 1.4 eV. The measured current-voltage curve shows well matching with the calculated curve based on the tunneling injection of electron under the uniform distribution of electric field.

• The Korean Journal of Ecology
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• v.15 no.4
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• pp.355-363
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• 1992

Nitrate reductase activity(NRA) and induced NRA were compared in 4 species of moss ctenidium molluscum, homalothecium, tortella tortusa and neckera crispa collected from limestone in england. the NRA and dry weight of the c. molluscum were also measured after spraying with acidic deposition adjusted to ph 5.6, 4.6, 3.6 and 2.8 with one of two molar ratios of nitric to sulfuric acid, i.e. 1:0(N alone) and 1:2(1N+2S) for 20 days. All 4 species showed high NR leavels in the upper part of cut shoots and occurred maximum inducation of NRA within 6h. c. molluscum had the highest NRA levels among 4 species. after daily spraying of acidic deposition, NRA of c. molluscum was increased much more largely at ph 6 and ph 3.6 derived from N alone than from 1N+2S. However that was decreased at ph 2.8 derived both from N alone and 1N+2S . Decline of dry weight had occurred at ph 3.6 and 2.8 derived both from N alone and 1N+2S. Whereas substantial fertilization effect was observed at ph 4.6 derived from N alone. the data suggest that c. molluscum are able to utilize nitrate more effectivery than any other species, and NRA induction are more sensitive than growth response to nitrogen content of acidicdeposition in a short- term. however toxic effects was detected at high $NO_3$ supply and low phacidic deposition.

• Proceedings of the Korean Environmental Health Society Conference
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• 2001.11a
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• pp.42-48
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• 2001

A kinetic model was presented to estimate the uptake/release rate constants and thereafter, bioconcentration factor, $k_1$, $k_2$ and BCF (bioconcentration factor), for the uptake of PH by plankton were obtained. Implies that PH(petroleum hydrocarbon) caused no significant influence on the uptake of $N-NO_3$, but significant influence on that of $P-PO_4$. In addition, the application of kinetic model for the bioconcentration of volatile organic toxic compound by organism suggests that the uptake of PH by plankton was an important process for the environmental capacity of PH.

• Journal of Surface Science and Engineering
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• v.15 no.3
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• pp.127-137
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• 1982

In chemical plating of nickel and chromium on steel, studies on various factors affect-ing the plating operations were carried out. The optimum bath compositions and operat-ing conditions were obtained. The structure and properties of the as deposits or deposits after heat treatment were investigated. (1) The most optimum conditions for the chemical nickel and chromium plating were; 〔Ni2+〕/〔H2PO2-〕; 0.5∼0.8, 〔Cr3+〕/〔H2PO2-〕; 0.6∼0.9 PH;5.0∼5.5, temperature; 90∼95$^{\circ}C$ (2) In the case of nickel deposition, the hardness of deposits increased with increasing phosphorous contents. Heat-treating at the temperature range 200$^{\circ}C$ to 600$^{\circ}C$, the maximum hardness of deposits was obtained at 400$^{\circ}C$ and decreased at temperature above 400$^{\circ}C$ due to growth of Ni3P. (3) Corrosion resistance of chemical nickel deposits was improved with increasing of p-hosphorous contents and heat treating temperature.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.147-157
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• 2004

The production of $^{14}C$ occurs in the Moderator(MOD), Primary Heat Transport System (PHTS), Annulus Gas System(AGS) and Fuel in the CANDU reactor. Among the four systems, The MOD system is the largest contributor to $^{14}C$ production(approximately 94.8%). $^{14}C$ is distributed of $^{14}CO_2$, $H_2^{14}CO_3$, $H^{14}{CO_3}^-$ and $^{14}{CO_3}^{2-}$ species as a function of the pH of water. Of these species, $H_2^{14}CO_3$ and $H^{14}{CO_3}^-$ form are predominant because the pH of MOD system is ＞ 5. In this paper, adsorption-desorption characteristics of bicarbonate ion (${HCO_3}^-$) by IRN 150 resin was investigated. ${HCO_3}^-$ ion existed in neutral condition(app. pH 7)was reacted with ion exchange resin (IRN-150) and saturated with it. Then $NaNO_3$ and $Na_3PO_4$ solutions selected as extraction materials were used to make an investigation into feasibility of ${HCO_3}^-$ extraction from resin saturated with ${HCO_3}^-$. Desorption of $CO^{2+}$ and $Cs^+$ ion by $Na^+$ ion was not occurred, and desorption of ${HCO_3}^-$ ion by ${NO_3}^-$ and ${PO_4}^{3-}$ was occurred slowly. Also, the status of ion exchange which is used in Wolsong NPPs and generation of spent resin yearly were surveyed.

• Bulletin of the Korean Chemical Society
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• v.27 no.10
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• pp.1638-1640
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• 2006

A variety of chiral cyanohydrins were readily prepared from aldehydes with TMSCN under the influence of chiral titanium complex formed in situ from $Ti(O^iPr)_4$/TADDOL(I) in the presence of $Ph_3PO$ as additive. The double activation method produces trimethylsilylethers in excellent yield (95%) with moderate enantiomeric excess.