• Title/Summary/Keyword: $P_t$ 임계점

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Prediction of Vapor Pressure of Parahydrogen from the Triple to the Critical Point (삼중점과 임계점간 파라수소의 증기압 예측)

  • Chung, Jaygwan G.
    • Journal of the Korean Chemical Society
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    • v.45 no.4
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    • pp.293-297
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    • 2001
  • The existing vapor pressure measurements reported in the literature for parahydrogen between the triple point and the critical point have been employed to establish the constants and exponent of the following equation in the form of reduced vapor pressure and reduced temperature: ln $lnP_r=2.64-{\frac{2.75}{T_r}}+1.48129lnT_r+0.11T^5_r$Only the normal boiling point ($T_b$= 20.268K), the critical pressure ($P_c$= 1292.81 kPa), and the critical temperature ($T_c$= 32.976K) are necessary to calculate the vapor pressure for an overall average deviation of 0.21% for 153 experimental vapor pressure data.

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Visualization of Doublet Impinging Jet Spray in Supercritical Mixed Hydrocarbon Fluid (초임계 탄화수소계열 혼합유체의 이중 충돌 제트 분무 가시화)

  • Song, Juyeon;Choi, Myeung Hwan;An, Jeongwoo;Koo, Jaye
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.4
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    • pp.53-58
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    • 2021
  • Based on surrogate model, a hydrocarbon mixture was analyzed by visualizing the impinging break up mechanism in subcritical and supercritical conditions. Decane and methylcyclohexane with different critical pressures and temperatures were selected as experimental fluids. The impinging injector was installed inside the chamber, and the spray was visualized through a speed camera in subcritical and supercritical conditions. The injection condition of the mixture and chamber was kept constant at Pr(P/Pc) = 1, and Tr(T/Tc) was increased from 0.48 to 1.02. As Tr increased, the spray angle increased, and the sheet length decreased as the properties of the mixture reached each critical point. In addition, when the mixture approached the near critical point, it was shown that the change in density gradient was largely observed out of the impinging break up mechanism.

Characteristics of Liquid Fuel Jet Injected into Supercritical Environment (초임계 환경으로 분사되는 액체 연료 제트의 분사 거동 특성)

  • An, Jeongwoo;Choi, Myeung Hwan;Lee, Jun;Koo, Jaye
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.50 no.5
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    • pp.333-338
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    • 2022
  • The single jet of decane/methylcyclohexane mixed fuel that is surrogate for kerosene was injected into supercritical environment and visualized using shadowgraph technique. The injection pressure drop of the fuel jet of Tr = 0.484 was kept constant at 0.5 MPa and the experiment was conducted above the critical point of the mixed fuel, and the reduced temperatures of the chamber was changed from 1.00 to 1.23, and the reduced pressures was 1.00 and 1.38. As an index for reducing the density of jets sprayed into the supercritical environment, the brightness intensity of the post-processed jet image was observed with the internal temperature and pressure of the chamber. It was confirmed that the decrease in the brightness intensity of the jet when the temperature inside the chamber increased, and when the pressure inside the chamber was higher at the same temperature, the decrease in the brightness intensity of the jet was delayed. When the pressure inside the chamber is high, it is thought that the change in brightness intensity is delayed due to the increase in the pseudo-critical temperature of the fuel and the increase in the temperature required to reduce the density of the fuel jet.

Exponent Study of the p($2{\times}1$) Phase on an O/W(110) Surface (O/W(110) 표면의 p($2{\times}1$) 구조의 임계지수 연구)

  • 백두현;정석민;정진욱
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.88-95
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    • 1992
  • Abstract-Using a high resolution low energy electron diffraction(HRLEED), we report an exponent study of 2d continuous phase transition from an ordered ~ ( 2 x 1 )ox ygen overlayer on a W(110) surface. Temperature dependence of a (% 0) superlattice diffraction spot, characteristic of the p(2X 1) structure, shows power-law like divergence of the susceptibility and the fluctuation correlation length at T,=708.765 K. By fitting the intensities as well as the line-shapes, we obtained exponents P=0.19* 0.05, y=1.48+ 0.34, v= 1.23i 0.27 and q=0.38+ 0.12. The non-universal character of the exponents are understood in terms of a 2d XY model with cubic anisotropy as suggested previously.

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Detection of B.U.E. by AE signal analysis (AE 신호 분석에 의한 구성인선의 감지)

  • 오민석;원종식;정윤교
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.10a
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    • pp.259-264
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    • 1995
  • Recently, in order to achieve high flexibilty, monitoring and control strategies of a new type have been developed. This paper investigates the fesability of using scoustic emission signal analysis for the detection of built-up edge during machining. Results for maching SM45C steel show that the presence of a built-up edge can significantil affect the generation of acoustic emission in metal cutting. When the cutting speed comes to the conditions conducive to development of built-up edge, it is shown that the slope of curve-fitted AErms signal undergoes a change. The fesability of utilizing AErms in built-up edge sensing is sugested.

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Basic Study on in-Process Monitoring of B.U.E. Using Force Sensor (Force Sensor를 이용한 구성인선의 In-Process 감시에 관한 기초 연구)

  • Won, Jong-Sik;Oh, Min-Seok;Jung, Youn-Gyo
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.7
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    • pp.67-72
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    • 1997
  • Recently, in order to achieve high flexibility of manufacture, monitoring and control strategies of a new type have been developed. Since the generation of built-up edge on the cutting tool damages the surface finish of the workpiece, the monitoring system of built-up edge is an important process monitoring. In this study, the analyzing methods of cutting force signal to detect the built-up edge during cutting process are described. The cutting force signals are analyzed using the mean, standard deviation and mean to standard deviation of this cutting signals. We can obtain the guide to detect the built-up edge during turning process.

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Hall Effect of High $T_{c}$ superconductor $Y_{1}Ba_{2}Cu_{3}O_{7-\delta}$ Thin Film (고온초전도체 $Y_{1}Ba_{2}Cu_{3}O_{7-\delta}$ 박막의 Hall 효과)

  • 허재호;류제천;김형국;김장환
    • Journal of the Korean Magnetics Society
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    • v.4 no.1
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    • pp.44-47
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    • 1994
  • High $T_{c}$ superconducting $Y_{1}Ba_{2}Cu_{3}O_{7-\delta}$ thin film was grown up for c-axis orientation by epitaxial growth method on $LaAlO_{3}$ single crystal substrate. The crystal structures of this thin film were found to be c-axis orientation by X-ray diffraction patterns. Hall effect and resistivity measurements were made by van der Pauw method. Hall resistivity was calculated from the magnetoresistivity by considering thermomagnetic effect. The relation was $pH=p_{s}tan{\alpha}_{n}-QBT\frac{S_s}{K_s}$ The measured Hall resistivity and the calculated one are in good agreement each other.

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The Structural Effects of Acidic Comonomers in pH/Thermal Sensitive Copolymer Based on N-Isopropylacrylamide on Their LCST Behavior (pH/온도 민감성 N-Isopropylacrylamide계 공중합체의 LCST거동에 대한 산성 공단량체의 구조적 영향)

  • 조항규;김병수;노시태
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.186-198
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    • 2001
  • pH/Thermal sensitive copolymers with the various acidic comonomer compositions composed of N-isopropylacrylamide (NIPAAm) with acrylic acid (AAc), 2-acrylamido glycolic acid (AAmGAc), and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) were synthesized by free radial polymerization. In this study, to characterize the effect of different acidic comonomer composition and pH on the lower critical solution temperature (LCST) behaviors of their copolymers. phase transition experiments were performed with a thermo-optical analyzer (TOA). The phase transition temperature (T$^{p}$ ) of aqueous poly(NIPAAm-co-AAc) solution was lowered with increasing the ionization of the acid group in AAc, that is, the ionized state induced the electrostatic repulsion of ionized groups. In contrast, when AAmGAc was introduced into PNIPAAm, T$^{p}$ was little changed at pH 1-3, whereas climbed up significantly from pH 1 to pH 3. In the range of pH 6-10, Tp was lower than that of pH 3-5. This result was considered to be \"Ionic Screen Effect\" and this effect had been also observed in the case of poly(NIPAAm-co-AMPS).-co-AMPS).

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A study on the Relationships among Coaching leadership, Directive leadership, Self-efficacy and Cohesion - Focused on the Marine Corps Soldiers - (코칭 및 지시적 리더십, 자기 효능감과 응집력간의 관계에 관한 연구 - 해병대 소대원을 중심으로 -)

  • Heo, Je-Eun;Lim, Gye-Hwan;Son, Heon-il
    • Convergence Security Journal
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    • v.16 no.3_1
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    • pp.69-75
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    • 2016
  • This study a Empirical research to examine the relationships among Coaching leadership, Directive leadership, Self-Efficacy and Cohesion, On the focus of Marine Corps Soldiers. The data was collected from 370 Soldiers located at Pohang, January 18 to 25, 2016. Descriptive statistics, frequency, t-test, ANOVA, scheffe test, and Pearson correlation analysis were performed using SPSS/WIN 22.0 program. In Cohesiveness, there were significants differences in Age, Branch of Service and Rank. As the result of Pearson' correlation, the relationships between leadership style, Self-efficacy and Cohesion were positive significants. The implications of these findings for effective leradership of Platoon Leader and future research on develop leradership program and curriculum were then discussed.

A study of electrical characteristic of MOSFET device (고에너지 이온주입에 따른 격자 결함 발생 및 거동에 관한 열처리 최적화방안에 관한 연구)

  • Song, Young-Doo;Kwack, Kae-Dal
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1830-1832
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    • 1999
  • 고에너지 이온주입(1)에 기인한 격자 손상 발생 및 열처리에 따라 이들의 회복이 어느정도 가능한지에 대하여 측정 및 분석방법을 통하여 조사하였다. 그리고 본 실험에서는 이온주입시 형성되는 빈자리 결함(Vacancy defect)과 격자간 결함(interstitial defect)의 재결할(recombination)을 이용 점결합(point defect)를 감소 시킬 수 있는 effective RTA조건을 설정하여 well 특성을 개선하고자 하였다. 8inch p-type Si(100)기판에 pad oxide 100A을 형성한 후 NMOS 형성하기 위해 vtn${\sim}$p-well과 PMOS 형성을 위해 vtp$\sim$n-well을 이온주입 하였다. Mev damage anneal은 RTA(2)(Rapid Thermal Anneal)로 $1000\sim1150C$ 온도에서 $15\sim60$초간 spilt 하여 실험후 suprem-4 simulation data를 이용하여 실제 SIMS측정 분석결과를 비교하였으며 이온주입에 의해 발생된 격자손상이 열처리후 damage 정도를 알아보기 위해 T.W(Therma-Wave)을 이용하였으며 열처리후 면저항값은 4-point probe를 사용하였다. 이온주입후 열처리 전,후에 따른 불순물 분포를 SIMS(Secondary ion Mass Spectrometry)를 이용하여 살펴보았다. SIMS 결과로는 열처리 온도 및 시간의 증가에 따라서 dopant확산 및 활성화는 큰차이는 보이지 않고 오히려 감소하는 경향을 볼 수 있으며 또한 접합깊이와 농도가 약간 낮아지는 것을 볼 수 있었다. 결점(defect)을 감소시키기 위해서 diffusivity가 빠른 임계온도영역($1150^{\circ}C$-60sec)에서 RTA를 실시하여 dopant확산을 억제하고 점결점(point defect)의 재결합(recombination)을 이용하여 전위 (dislocation)밀도를 감소시켜 이온주입 Damage 및 면저항을 감소 시켰다. 이와 같은 특성을 process simulation(3)(silvaco)을 통하여 비교검토 하였다.

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