• Title/Summary/Keyword: $PVF_2$

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Comparison of sample storage containers for the analysis of volatile organic compounds (VOC) (휘발성유기물(VOC) 분석을 위한 시료보관 용기의 비교)

  • Kim, Seokyung;Kim, Dalho
    • Analytical Science and Technology
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    • v.35 no.3
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    • pp.116-123
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    • 2022
  • Polymer bags, metallic canisters, and glass bottles have been used as containers for analyzing the volatile organic compounds (VOCs) in air. In this study, various sampling containers were compared to investigate the short-term stability of VOCs, that is, from the time they are sampled to the time they are analyzed. Polyvinyl fluoride (PVF), polypropylene (PP), polyester aluminum (PE-Al) bags, canisters, and glass bottles were used as sample containers. A 100 nmol/mol standard gas mixture of benzene, toluene, ethylbenzene, m-xylene, styrene, and o-xylene was used for the VOC comparison. Changes in the concentrations of samples stored for 10~20 day in each container were measured using a thermal desorption-gas chromatograph-flame ionization detector (TD-GC-FID). As a result, VOCs stored in a canister and two kinds of amber glass bottles have shown immaterial decreases in concentration in one week, and more than 80 % of the initial concentration was maintained for two weeks. In the case of polymer bags, the concentration of all VOCs, except benzene and toluene, were remarkably decreased below 70% of the initial concentration in one day. Particularly, ethylbenzene, xylene, and styrene have shown dramatic decreases in concentration below 30 % of the initial concentration in all polymer bags in one day.

The Effect of Ion Contribution to the Dielectric Properties of $\beta$-PVDF Thin Film Fabricated by Vapor Deposition Method (진공증착법으로 제조된 $\beta$-PVDF 박막의 유전 특성에 미치는 이온의 영향)

  • 박수홍;김종택;이덕출
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.11
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    • pp.1007-1013
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    • 1998
  • In this paper, the dielectric properties of fabricated Polyvinylidene fluoride(PVDF, $PVF_2$) thin film with substrate temperature from 30 to at vapor deposition. The dielectric properties of PVDF thin film had been studied in the frequency range from 10Hz to 4MHz at measuring temperature between 20 and $100^{/circ}C$. The anomalous increasing in dielectric constant and dielectric loss at low frequencies and high temperature was described for PVDF thin film containing ion impurities. In particularly, ion mobility of fabricated PVDF thin film at substrate temperature at $30^{/circ}C$ decrease from $2\times10^{-5}\;to\;3.07$\times10^{-7}cm^2/V.s$ On the other hand, ion density increase abruptly from 1.49\times$$10^{13}$ to $1.5\times$10^{16}$cm^{-3}$ In spite of decreasing of ion mobility, dielectric constants and dielectric loss for PVDF thin film increase rapidly with decreasing frequency and high temperature. It was concluded that the dielectric constants and dielectric loss was related to ion density than to ion mobility at low frequency and high temperatures.

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Design and Implementation of the Parallel Multimedia File System on Fast Ethernet (Fast Ethernet 환경에서 병렬 멀티미디어 파일 시스템의 설계와 구현)

  • Park, Seong-Ho;Kim, Gwang-Mun;Jeong, Gi-Dong
    • The KIPS Transactions:PartB
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    • v.8B no.1
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    • pp.89-97
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    • 2001
  • 대용량 멀티미디어 미디어 서버를 구성함에 있어 I/O 병목현상을 극복하기 위하여 저장 서버들과 제어 서버로 구성되어진 2계층 분산 클러스터 서버구조가 많이 사용된다. 2 계층 분산 클러스터 서버는 부하 균등, 대역폭 관리 및 저장 서버의 관리 측면에서 유리한 반면, 저장 서버와 제어 서버간의 통신 오버헤드를 발생시킨다. 이러한 오버헤드를 줄이기 위해서는 저장 서버에서 읽은 미디어 데이터를 제어 서버를 거치지 않고 직접 클라이언트에 전송할 수 있어야 한다. 그리고, 저장 용량을 확장하거나 손상된 디스크를 교체하는 경우를 대비하여 분산 클러스터 서버는 다양한 성능의 이기종 디스크를 지원하여야 한다. 또한, I/O 장치와 운영체제가 빠르게 발전됨에 따라 미디어 서버는 새로운 I/O 장치 및 운영체제 등에 쉽게 이식될 수 있어야 하고, 응용 소프트웨어 개발자가 시스템의 환경에 따라 블록크기, 데이터 배치정책, 사본 정책 등을 유연하게 조절할 수 있어야 한다. 본 논문에서 위에서 언급한 멀티미디어 서버의 요구를 고려하여 Fast Ethernet 환경에서 병렬 멀티미디어 파일 시스템(PMFS : Parallel Multimedia File System)을 설계 및 구현하고 실험을 통해 PVFS(Parallel Virtual File System)와 성능을 비교 분석하였다. 이 실험의 결과에 따르면 PMFS는 멀티미디어 데이터에 대하여 PVFS보다 3%∼15%의 향상된 성능을 보였다.

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Comparison of Two Experimental Approaches to Test Temporal Storability of Reduced Sulfur Compounds in Whole Sampling Method (환원황화합물에 대한 용기채취법의 비교 연구)

  • Jo, Sang-Hee;Kim, Ki-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.3
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    • pp.306-315
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    • 2012
  • In this study, storage stability of reduced sulfur compounds ($H_2S$, $CH_3SH$, DMS, $CS_2$, and DMDS) and $SO_2$ in sampling bags was investigated in terms of two contrasting storage approaches between forward (F) and reverse (R) direction. The samples for the F method were prepared at the same time and analyzed sequentially through time. In contrast, those of reverse (R) method were prepared sequentially in advance and analyzed all at once upon the preparation of the last sample. In addition, relative performance between two different bag materials (PVF and PEA) was also assessed by using 100 ppb standard. The response factors (RF) of gaseous RSC samples were determined by gas chromatography/pulsed flame photometric detector (GC/PFPD) combined with air server (AS)/thermal desorber (TD) system at storage intervals of 0, 1, and 3 days. There is no statistical difference in all RSCs between two storage methods. However, the results of relative recovery indicated 2.58~12.8% differences in compound type between the two storage methods. Moreover, loss rates and storage stability of $H_2S$ and $SO_2$ were considerably affected by bag materials than any other variables. Therefore, some considerations about storage methods (or bag material types) for sulfur compounds are needed if stored by sampling bag method.

A Study on the Piezoelectric Sensor Response Characteristic of PVDF Organic Thin Film by Vapor Deposition Method (진공증착법으로 제조된 PVDF 유기박막의 압전 센서 응답 특성에 관한 연구)

  • Park, Soo-Hong
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.448-454
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    • 2008
  • The purpose of this paper is to discuss the fabrication of $\beta$-PVDF($\beta$-Polyvinylidene fluoride, ${\beta}-PVF_2$) organic thin films through the vapor deposition method and to investigate the piezoelectric properties of the organic thin films produced. Vapor deposition was performed under the following conditions : the temperature of evaporator, the applied electric field and the pressure of reaction chamber were $270^{\circ}C$, 142.4 kV/cm and $2.0{\times}10^{-5}Torr$, respectively. The results showed that the amount of $\beta$-form PVDF increased from 72 % to 95.5 % with an increase in the substrate temperature. In the case of a sensor response characteristic by varying the force moment from $1.372{\times}10^{-5}N{\cdot}m$ to $39.2{\times}10^{-5}N{\cdot}m$, the output voltage increased from 1.39V to 7.04V.

A Study on the Ultrasonic Response Characteristic of PVDF Organic Thin Film by Physical Vapor Deposition Method (진공증착법으로 제조된 PVDF 유기박막의 초음파 응답 특성에 관한 연구)

  • Park, Soo-Hong
    • Journal of the Korean Vacuum Society
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    • v.18 no.3
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    • pp.221-228
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    • 2009
  • The purpose of this paper is to discuss the fabrication of $\beta$-PVDF($\beta$-Polyvinylidene fluoride, $\beta$-PVF2) organic thin films through the vapor deposition method and to investigate the ultrasonic response properties of the organic thin films produced. Vapor deposition was performed under the following conditions : the temperature of evaporator, the applied electric field and the pressure of reaction chamber were $270^{\circ}C$, 142.4 kV/cm and $2.0{\times}10^{-5}\;Torr$, respectively. The results showed that the degree of crystallinity increased from 47% to 67.8% with an increase in the substrate temperature. In the case of a sensor response characteristic by varying the distance from 1cm to 100cm, the output voltage decreased from 0.615V to 0.4V.

Fuzzy Logic based Next Hop Node Selection Method for Energy Efficient PVFS in WSN (무선 센서 네트워크에서 확률적 투표 기반 여과 기법의 에너지 효율성을 위한 퍼지 로직 시스템 기반의 다음 이웃 노드 선택 기법)

  • Lee, Jae Kwan;Nam, Su Man;Cho, Tae Ho
    • Journal of the Korea Society for Simulation
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    • v.23 no.2
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    • pp.65-72
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    • 2014
  • Sensor nodes are easily compromised by attacker when which are divided in open environment. The attacker may inject false report and false vote attack through compromised sensor node. These attacks interrupt to transmission legitimate report or the energy of sensor node is exhausted. PVFS are proposed by Li and Wu for countermeasure in two attacks. The scheme use inefficiency to energy of sensor node as fixed report threshold and verification node. In this paper, our propose the next neighbor node selection scheme based on fuzzy logic system for energy improvement of PVFS. The parameter of fuzzy logic system are energy, hops, verification success count, CH select high the next neighbor node among neighbor nodes of two as deduction based on fuzzy logic system. In the experimental, our proposed scheme was improvement to energy of about 9% compare to PVFS.

A Study on the Electrical Characteristic of Organic Thin Film by Physical Vapor Deposition Method (진공증착법을 이용한 유기 박막의 전기적 특성에 관한 연구)

  • Park, Su-Hong
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.57 no.2
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    • pp.140-145
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    • 2008
  • The purpose of this paper is to discuss the fabrication of $\beta$-PVDF($\beta$-Polyvinylidene fluoride, ${\beta}-PVF_2$) organic thin films using the vapor deposition method. Vapor deposition was performed under the following conditions: the temperature of evaporator, the applied electric field, and the pressure of reaction chamber were $270^{\circ}C$, 142.4 kV/cm, and $2.0{\times}10^{-5}\;Torr$, respectively. The molecular structure of the evaporated organic thin films were evaluated by a FT-IR. The results showed that the characteristic absorption peaks of $\beta$-form crystal increase from 72% to 95.5% with an increase in the substrate temperature. In the analysis of the electric characteristics, the abnormal increases in the relative dielectric constant and the dielectric loss factor in the regions of low frequency and high temperature are known to be caused by inclusion of impurity carriers in the PVDF organic thin films. In order to analyze quantitatively the abnormalities in the conductivity mechanism caused by ionic impurities, the product of the ion density and the mobility that affect the electrical property in polymeric insulators is analyzed. In the case of a specimen produced by varying the substrate temperature from $30^{\circ}C$ to $105^{\circ}C$, the product of mobility and the ion density decreased from $4.626{\times}10^8$ to $8.47{\times}10^7/V{\cdot}cm{\cdot}s$. This result suggests that the higher the substrate temperature is maintained, the better excluded the impurities are, and the more electrically stable material can be obtained.

Clinical Analysis of Reoperations on Prosthetic Valve Failur (인공심장판막 실패에 대한 재치환술의 임상적 고찰)

  • Choi, B.C.;Yoo, H.K.;Ahn, W.S.;Hur, Y.;Kim, B.Y.;;Yoo, H.S.
    • Journal of Chest Surgery
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    • v.24 no.7
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    • pp.663-668
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    • 1991
  • To evaluate risks, complications and mortality of reoperations on heart valve prosthesis, we reviewed clinical records of 53 patients who underwent reoperation because of prosthetic valve failure[PVF], from Jan 1959 through Jun. 1991. They had undergone 48 mitral, 10 aortic valve rereplacement Primary tissue failure was the main cause of reoperation : it occurred in 51 valves at a mean postoperative interval of 58 months. Calcification and collagen disruption of prosthesis were main causes of primary tissue failure in macro and micropathology, In 3 failing mechanical prostheses, paravalvular leak was in 2 cases, another one case had the thrombi at the hinge portion. If conditions such as emergency operation with or without endocarditis, thromboembolism and advanced NYHA functional class are prevented, we think that reoperative valve replacement has similar morbidity and mortality to initial valve replacement surgery. But our sturdy represents higher mortality [22.6%] because of late surgical intervention failing the prevention of conditions leading to myocardial damage. In conclusion if the tearing, calcification, and a new murmur were detected the early reoperation should be considered to increase late survival.

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Photovoltaic Application in System Formwork Operations of High-rise Building Construction (초고층 시스템거푸집 공사의 태양광에너지 활용 방안 연구)

  • Kim, Tae-Hoon;Lee, Myung-Do;Lee, Ung-Kyun;Cho, Hun-Hee;Kang, Kyung-In
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.2
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    • pp.116-126
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    • 2011
  • Recently, eco-friendly energy has been employed in diverse fields of industry in order to reduce environmental pollution and secure a new growth engine. In particular, practical applications of photovoltaic energy, such as building integrated photovoltaic systems, have been implemented to the construction industry based on the extensive interest in photovoltaic power as an unlimited and sustainable energy. While the construction of a high-rise building requires large amounts of energy, methods of reducing energy consumption in the construction phase have rarely been studied. Based on this motivation, the research proposes a photovoltaic based formwork system (PVFS), and then performs a design and feasibility analysis for its application to the construction of a high-rise building. Using a case study, the research implements various analyses, including area, position, and total allowable weight required by PVFS, and evaluates the influences of PVFS on the construction processes, as well as its economic feasibility. The proposed PVFS can be adopted to a real-world project in the near future, depending on the advancement of technology and economic feasibility. The results of this research will contribute to establishing a construction environment that promotes a reduction of energy consumption by using eco-friendly energy in the construction phase.