• 한국입자에어로졸학회지
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• 제15권3호
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• pp.91-104
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• 2019

In this study, hourly measurements of $PM_{2.5}$ and its major chemical constituents such as organic and elemental carbon (OC and EC), and ionic species were made between January 15 and February 10, 2018 at the air pollution intensive monitering station in Gwangju. In addition, 24-hr integrated $PM_{2.5}$ samples were collected at the same site and analyzed for OC, EC, water-soluble OC (WSOC), humic-like substance (HULIS), and ionic species. Over the whole study period, the organic aerosols (=$1.6{\times}OC$) and $NO_3{^-}$ concentrations contributed 26.6% and 21.0% to $PM_{2.5}$, respectively. OC and EC concentrations were mainly attributed to traffic emissions with some contribution from biomass burning emissions. Moreover, strong correlations of OC with WSOC, HULIS, and $NO_3{^-}$ suggest that some of the organic aerosols were likely formed through atmospheric oxidation processes of hydrocarbon compounds from traffic emissions. For the period between January 18 and 22 when $PM_{2.5}$ pollution episode occurred, concentrations of three secondary ionic species ($=SO{_4}^{2-}+NO_3{^-}+NH_4{^+}$) and organic matter contributed on average 50.8 and 20.1% of $PM_{2.5}$, respectively, with the highest contribution from $NO_3{^-}$. Synoptic charts, air mass backward trajectories, and local meteorological conditions supported that high $PM_{2.5}$ pollution was resulted from long-range transport of haze particles lingering over northeastern China, accumulation of local emissions, and local production of secondary aerosols. During the $PM_{2.5}$ pollution episode, enhanced $SO{_4}^{2-}$ was more due to the long-range transport of aerosol particles from China rather than local secondary production from $SO_2$. Increasing rate in $NO_3{^-}$ was substantially greater than $NO_2$ and $SO{_4}^{2-}$ increasing rates, suggesting that the increased concentration of $NO_3{^-}$ during the pollution episode was attributed to enhanced formation of local $NO_3{^-}$ through heterogenous reactions of $NO_2$, rather than impact by long-range transportation from China.

• Asian Journal of Atmospheric Environment
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• 제11권4호
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• pp.322-329
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• 2017

Perturbation in ambient particulate matter ($PM_1$, $PM_{2.5}$, $PM_{10}$) and black carbon (BC) concentrations was studied during a firecracker bursting episode in Diwali (Festival of Lights) celebrations in Nagpur, India. Firecracker bursting resulted in greater escalation in fine particulates over coarse particulates while $PM_{2.5}$ was found to be dominated by $PM_1$ concentration. On the Diwali day, daily mean concentration of $PM_{2.5}$ and $PM_{10}$ exceeded Indian National Ambient Air Quality Standards by over 1.8 and 1.5 times, respectively, while daily mean BC concentration on the same day was almost two times higher than the previous day. The BC/$PM_1$ ratio reduced remarkably from about 0.26 recorded before fire-cracker bursting activity to about 0.09 during fire-cracker bursting on Diwali night in spite of simultaneous escalation in ambient BC concentration. Such aberration in BC/$PM_1$ was evidently a result of much higher escalation in $PM_1$ than BC in ambient air during firecracker bursting. The study highlighted strong perturbations in ambient $PM_1$, $PM_{2.5}$, $PM_{10}$ concentrations and BC/$PM_1$ during the firecracker bursting episode. Altered atmospheric BC/$PM_1$ ratios could serve as indicators of firecracker-polluted air and similar BC/$PM_1$ ratios in local and regional air masses might be used as diagnostic ratios for firecracker smoke.

• 한국입자에어로졸학회지
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• 제7권2호
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• pp.49-57
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• 2011

서울의 대기오염, 특히 고농도 대기오염 사례는 시민 건강에 매우 부정적일뿐만 아니라, 일반 시민들이 서울시에 대해 느끼는 체감오염도에도 중요한 변수이다. 따라서 이러한 고농도 대기오염 사례의 원인을 규명하는 것은 과학적으로 중요할 뿐만 아니라 사회적으로도 중요한 문제이다. 2005년 7월 22일부터 31일 사이에 고농도 대기오염 사례가 관측되었다. 이 대기오염 사례에 대해 측정소 간의 시계열분석, 에어로졸 성분 분석, 궤적 분석 등의 종합적인 해석을 통해, 대기오염 사례가 국지적인 것이었는지, 외부 영향에 의한 것인지 규명 하였다. 측정 결과를 바탕으로 이 사례를 7월 22~27일(기간 1)과 28~31일(기간 2)의 두 기간으로 구분하였다. 우리나라의 도시대기측정소의 PM10 농도 추이를 분석한 결과, 기간 1에는 춘천의 PM10 농도와 3시간 후에 서울의 PM10 농도가 상관관계가 높았으며, 기간 2에는 중부 지방 전체의 PM10 농도 사이에 상관관계가 높았다. 기간 1에는 풍속이 점차 강해져서 오염물질이 희석되는 경향을 보였으며, 기간 2에는 풍속이 점차 약해져 정체성 특성을 보여 고농도가 계속 유지되었다. 관측한 PM2.5 이온 조성은 기간 1보다는 기간 2에 높았으며, 두 기간 모두, 서울의 평균 농도보다는 매우 높았다. 궤적분석 결과 기간 1에는 시계열 분석 결과와 일치하게, 공기덩어리가 중국에서 북한과 강원도를 거쳐 서울로 이동하였고, 기간 2에는 중국에서 직접 서울로 이동하였다. 현재는 북한의 대기오염물질 배출 정도나 대기오염도에 대한 자료가 부족하여 보다 상세한 분석이 힘들다. 그러나 북한의 영향이 상당할 것으로 보이므로 이에 대한 연구가 필요하다 (Kim et al., 2011). 이 연구 결과는 2005년 7월 하순에 서울에서 발생한 대기오염 에피소드는 외부 영향, 특히 중국 영향에 의한 것임을 보여준다. 그러나 같은 외부 영향이라도 공기의 이동 경로와 풍속에 따라 오염 특성이 달라지는 것을 확인하였다.

• 한국대기환경학회지
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• 제30권5호
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• pp.434-448
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• 2014

The aerosol characteristics between haze episode and Asian dust event were identified in January and March, 2013 in Gwang-ju of Korea to investigate the metal elements, ionic concentrations and carbonaceous particles of $PM_{2.5}$ and $PM_{10}$. In the haze episode, the concentrations were increased 1~3.2 times of ionic species and 1.6~2.7 of metal elements. Especially, the concentration of $NO{_3}{^-}$, $SO{_4}{^2-}$ and $NH{_4}{^+}$ consists of 50 percent in ionic species during haze episode that was higher than Asian dust event. This suggests that secondary aerosols from anthropogenic air pollution were mainly contributed by haze episode. During the Asian dust event, increase of metal concentrations was higher than haze episode because of remarkable increase of Ti, K and Fe originated from soil. The concentrations of carbonaceous particles were increased 2.5 times during haze episode, and 2.4 times of OC and 2.1 times of EC during Asian dust event in $PM_{2.5}$. However, these aerosol mass concentration does not affect the OC/EC ratio. The average equivalence ratios of cations/anions in $PM_{2.5}$ were 0.99 in haze episodes and 0.94 during non-event day. The neutralization factor of $NH_3$ was higher than that of $CaCO_3$. Futhermore, $NH{_4}{^+}$ aerosol was aged due to atmospheric stagnation that might be affected by the haze episode.

• 한국대기환경학회지
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• 제31권3호
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• pp.269-286
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• 2015

24-hr integrated $PM_{2.5}$ measurements were performed between December 2013 and October 2014 at an urban site in Gwangju and the collected samples were analyzed for organic carbon (OC), elemental carbon (EC), ionic species, and elemental species. Objectives of this study were to identify $PM_{2.5}$ pollution episodes, to characterize their chemical components, and to examine their probable origins. Over the course of the study period, average $PM_{2.5}$ concentration was $37.7{\pm}23.6$ $(6.0{\sim}121.5){\mu}g/m^3$. Concentrations of secondary ionic species; $NH_4{^+}$, $NO_3{^-}$, and $SO_4{^{2-}}$ was on average $5.54{\mu}g/m^3$ (0.28~ 20.86), $7.60{\mu}g/m^3$ (0.45~ 33.53), and $9.05{\mu}g/m^3$ (0.50~ 34.98), accounting for 13.7% (4.6~ 22.7), 18.6% (2.9~ 44.8), and 22.9% (4.9~ 55.1) of the $PM_{2.5}$ concentration, respectively. Average OC and EC concentrations were $5.22{\mu}g/m^3$ and $1.54{\mu}g/m^3$, taking possession of 4.6 and 22.2% (as organic mass) of the $PM_{2.5}$, respectively. Frequencies at which 24-hr averaged $PM_{2.5}$ exceeded a 24-hr averaged Korean $PM_{2.5}$ standard of $50{\mu}g/m^3$ (termed as an "episode" in this study) were 30, accounting for 21.3% of total 141 measurements. These pollution episodes were mostly associated with haze phenomenon and weak surface wind speed. It is suggested that secondary formation of aerosol was one important formation mechanism of the episodes. The episodes were associated with enhancements of organic mass, $NO_3{^-}$ and $SO_4{^{2-}}$ in winter, of $NO_3{^-}$ and $SO_4{^{2-}}$ in spring, and of $SO_4{^{2-}}$ in summer. Potential source contribution function results indicate also that $PM_{2.5}$ episodes were likely attributed to local and regional haze pollution transported from northeastern China in winter, to atmospheric processing of local emissions rather than long-range transport of air pollutants in spring, and to the $SO_4{^{2-}}$ driven by photochemistry of $SO_2$ in summer.

• 한국지구과학회지
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• 제28권1호
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• pp.123-135
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• 2007

동아시아에서 광역적인 대기오염 이동과 한반도 유입을 인공위성과 지상 관측을 통해 5개의 사례를 분석하였다. 이 사례들은 주로 중국 대륙의 도시와 산업지대에서 배출된 오염물질들이 황해를 지나 한반도에 상륙 및 통과하는 광역적인 대기오염 이동이다. NOAA인공위성 관측 자료의 분석은 가시영역과 적외선 영역의 3개 채널을 합성하여 영상을 만들고, 황해 위에서 대기오염의 분포와 이동을 구별해 낼 수 있었다. 또한 청원의 배경관측지점에서 대기오염의 지상 관측 자료는 인공위성 관측 자료와 비교하여 검증하는데 매우 가치가 있었다. 특히, 광역적 대기오염의 이동 사례에서는 $PM_{10}$과 $PM_{2.5}$ 농도의 차이가 적으면서, $PM_{2.5}$값이 높게 증가한다. 그러나 황사의 경우는 $PM_{10}$ 농도가 훨씬 높게 관측되어 $PM_{2.5}$와의 차이가 매우 큼이 특징적이다. 2006년 1월 27일의 사례에서는 중국 발원의 광역적 대기오염이 한반도의 중부 및 남서지역으로의 유입을 인공위성뿐 아니라 여러 지상관측소들에서 순차적으로 관측할 수 있었다. 북북서 기류가 제주도 한라산을 넘어서 풍하측 멀리까지 구름을 소산시키고 대기오염을 감소시키며, 카르만 소용돌이를 만들고 있었다.

• 한국환경과학회지
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• 제32권8호
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• pp.521-531
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• 2023

This study analyzed the impact of recirculation on high-concentration PM_2.5 in the coastal area. Through the analysis of observational data, it was observed that the development of sea breeze led to an increase in PM_2.5 and SO₄^2- concentrations. Hysplit backward trajectory analysis confirmed the occurrence of air mass recirculation. Results from WRF and CMAQ numerical simulations indicated that pollutants transported from land to sea during the night were re-transported to the land by daytime sea breeze, leading to high-concentration PM_2.5 in Busan. To quantitatively investigate the recirculation a recirculation factor (RF) was calculated, showing an increase in RF values during high-concentration PM_2.5 episodes. However, the RF values varied slightly depending on the time resolution of meteorological data used for the calculations. This variation was attributed to the terrain characteristics at observation sites. Additionally, during long-range transported days leading to nationwide high-concentration PM_2.5 events, synoptic-scale circulation dominated, resulting in weaker correlation between PM_2.5 concentration and RF values. This study enhances the understanding of the influence of recirculation on air pollution. However, it is important to consider the impact of temporal resolution and terrain characteristics when using RF for evaluating recirculation during episodes of air pollution.

• 대기
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• 제31권3호
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• pp.267-282
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• 2021

Characteristics of carbonaceous components and organic compounds in PM_2.5 over the atmosphere of the Yellow Sea were investigated. PM_2.5 samples were collected onboard the meteorological research vessel, GISANG 1, over the Yellow Sea during the YES-AQ campaign in 2018 and 2019, respectively. The average concentrations of carbonaceous components in this region were 2.59 ± 1.59 ㎍ m^-3 for the OC, 0.24 ± 0.10 ㎍ m^-3 for the EC, 2.14 ± 1.30 ㎍ m^-3 for the WSOC and 1.17 ± 0.94 ㎍ m^-3 for the HULIS-C, respectively. The total concentration of 56 organic compounds (ΣOCs) accounts for 10% of OC. The main group among organic compounds were dicarboxylic acids which account for 57% of ΣOCs, followed by n-alkanoic acids accounting for 34% of ΣOCs. In n-alkanoic acid distribution, hexanoic (C_6:0) and octanoic (C_8:0) acids which are low molecular weight n-alkanoic acids and known as emitted from marine biogenic activities were dominant in this region. Furthermore, non-HULIS-C fraction increased when the air mass originated from the marine region rather than the continental region. When the Asian dust episode was observed, the WISOC concentrations along with the levoglucosan were increased, while the haze episodes caused the increase of WSOC, HULIC-S and DCAs. In this study, we found that the components of carbonaceous and organic aerosols in PM_2.5 over the Yellow Sea were changed with the specific air pollution episodes. It indicates that the physicochemical properties of PM_2.5 can be changed by the air pollution episodes in this region.