• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
• /
• pp.53-59
• /
• 2006

This study is measurement of radicals in gas & light oil diffusion flame focused on burner exit. The goal of this study is to analyse the relationship between flame chemiluminescence($OH^{\ast}$, $CH^{\ast}$, $C_2^{\ast}$) intensities and flame conditions. The investigation performed turbulent diffusion flame of commercial burner in varying the excess air ratio from 1.0 to 1.8. The optical emissions were measured by photomultiplier(PMT) using optical band pass filter and spectrometer system. The effects of excess air ratio and NOx emission characteristics on the radical emission intensities were investigated experimentally.

• 한국산업융합학회 논문집
• /
• 제7권3호
• /
• pp.265-271
• /
• 2004

A light collecting probe named Multi-colored Integrated Receiving Optics (MICRO) is experimentally examined to verify its performance. For these purposes, the time-series signals of MICRO probe is compared with those of electro-static probe and light-guided probe by monitoring, for example. such as OH radical chemiluminescence. CH radical band and droplet Mie scattering In addition, the experiment was conducted by using laminar premixed Bunsen flame, turbulent premixed Bunsen flame and premixed spray flame, respectively. It was confirmed that the performance of MICRO probe was very useful and convenient to obtain the chemiluminescence signals from local regions in turbulent premixed Bunsen flame and premixed spray flame.

• 한국가축번식학회지
• /
• 제15권2호
• /
• pp.149-155
• /
• 1991

본 실험은 H-Y 항원 유전자 크로닝을 위한 기초연구로서 H-Y 항원의 특성을 규명하기 위하여 친화성 크로마토그래피에 의하여 H-Y 항원을 분리·정제하였다. 정소 추출액을 항체가 결합된 column에 결합시킨 뒤 10% acetic acid로 용출시켰다. 용출된 분획을 모아 농축한 후 HPLC와 SDS-PAGE를 실시하여 H-Y 항원의 분자량은 약 6,7000달톤 임을 알 수 있었으며 isoelectric focusing에 의하여 등전점(pI)은 5.0인 것으로 측정되었다. H-Y 항원에 대한 단일클론항체와 표지항원으로는 H-Y 항원-ABEI(aminobutylethyl isoluminol)를 사용하여 H-Y 항원 정량을 위한 화학발광면역분석법을 개발하였다. 항원항체 반응후 빛의 측정은 NaOH 존재하에서 microperoxidase/H2O2를 이용한 산화반응으로 실시하여 10초간 측정한 빛의 양을 적분하였다. H-Y 항원의 농도와 빛의 양과는 역비례하였으며 감도는 11.8ng/tube 정도이었다.

• 한국추진공학회지
• /
• 제22권1호
• /
• pp.28-35
• /
• 2018

전단 동축형 인젝터를 통해 분사된 기체메탄-기체산소 확산화염의 가연한계와 구조분석을 위해 인젝터 리세스와 추진제 공급유량에 따른 연소실험이 수행되었다. 연구 결과, 추진제 운동량 플럭스 비가 증가함에 따라 높은 산화제 레이놀즈 수 구간에서도 안정적인 부착화염이 관찰되었으며, 인젝터 리세스는 화염의 형태와 가연한계에 큰 영향을 미치지 않음을 확인하였다. 자발광 기법을 통해 가시화된 부착화염은 추진제 분사조건이 변함에도 불구하고 항상 일정한 지점에서 최대 OH 라디칼 방사강도를 나타내었으며, 그 강도는 리세스에 의해 심하게 감소함을 확인하였다.

• 대한기계학회논문집B
• /
• 제33권5호
• /
• pp.365-372
• /
• 2009

The influence of combustor pressure on the local reaction characteristics of $CH_4$/air flames was investigated by measurements of local chemiluminescence intensity. Induced flow flames are often applied to the industrial boiler systems and incinerator in order to improve heat transfer and prevent exhaust gas leakage. In order to investigate combustion characteristics in the induced flow pattern, the combustor pressure index($P^*$) was controlled in the range of $0.7{\sim}1.3$ for each equivalence ratio in the present combustion system, where $P^*$ is defined as the ratio of absolute pressure to atmospheric one. Relationship between local reaction intensity and pressure index have been investigated by simultaneous $CH^*$, $C^*_2$ and $OH^*$ intensity measurements. It could be observed that flame length became longer with decreasing $P^*$ from $CH^*$ chemiluminescence intensity of axial direction. The mean value of $C^*_2$ and $CH^*$ chemiluminescence intensities, which indicates reaction intensity in the $CH_4$/air flames, decreased with decreasing pressure index for ${\Phi}{\leq}1$, but increased with decreasing pressure index for ${\Phi}$>1. $C^*_2/CH^*$ intensity ratio, which can be a good marker to demonstrate local equivalence ratio, was almost same for ${\Phi}{\leq}1$ regardless of pressure index change, while they showed high level for lower pressure index for ${\Phi}$>1 conditions.

• 분석과학
• /
• 제21권1호
• /
• pp.20-24
• /
• 2008

본 연구에서는 lucigenin과 $H_2O_2$에 의한 화학발광을 이용하여 vitamin $P_1$을 정량하는 방법에 대하여 연구하였다. 분석의 최적 조건을 구하기 위해서 화학발광에 영향을 미치는 $H_2O_2$의 농도, pH 그리고 lucigenin의 농도를 조사하였다. 이러한 분석 최적조건의 검정곡선에서 직선성이 성립하는 범위는 $7.5{\times}10^{-6}$에서 $5.0{\times}10^{-4}mol/L$이었고, 검정곡선에서 직선성이 성립하는 농도구간에서 구한 검출한계는 $5.7{\times}10^{-7}mol/L$이었다. 최적 vitamin $P_1$의 농도인 $7.5{\times}10^{-5}mol/L$에서의 상대표준편차는 0.75%(n=10), 상관계수(S/N=3)는 0.9984이었다.

• 한국수소및신에너지학회논문집
• /
• 제28권2호
• /
• pp.181-189
• /
• 2017

This paper describes experimental results on combustion characteristics with hydrogen contents of synthetic natural gas (SNG) in low swirl combustor. To investigate the effect of hydrogen contents for premixed SNG flame, stability map, CH chemiluminescence images, flame spectrum analysis and emission performances were measured. In the results, as the hydrogen content was increased, the lean flammable limit was expanded and the flame length was decreased. The hydrogen contents affected the flame liftoff height, and it has different tendency according to the equivalence ratio and flame shape. The change of height and length of flame according to hydrogen contents is caused by the fast burning velocity of hydrogen, which can be confirmed by GRI 3.0 reaction mechanism in PREMIX code. The intensity of $OH^*$, $CH^*$ and $C_2^*$ was confirmed by spectrum analysis of flame. As a result, the $CH^*$ intensity was not significantly different according to hydrogen content. The increase of hydrogen contents influenced positively CO and NOx emission performances.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2011년도 제37회 추계학술대회논문집
• /
• pp.258-262
• /
• 2011

실험용 분젠 연소기를 사용하여 예혼합된 메탄-산소 층류화염전파속도를 연구하였다. 이를 위해 $CH^*$ 자발광 측정기법과 슐리렌 사진술이 사용되었다. 실험결과는 CHEMKIN 3.7을 이용한 수치해석 결과와 비교하였다. 층류화염전파속도를 측정하기 위하여 층류여역 내에서 전체 당량비는 0.5에서 2.0까지 조절하였다. 동축 화염에서 화염전파속도는 각도측정법을 사용하였으며 슐리렌 사진에서는 3.1 m/s로 $CH^*$ 자발광 사진에서는 2.9 m/s로 측정되었다.

• 한국연소학회지
• /
• 제16권3호
• /
• pp.33-40
• /
• 2011

Combustion experiments were conducted at three different fuels ($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the effects of combustor pressure (30 ~ -30 kPa) on combustion charateristics and reaction zone structure. Regardless of the fuels, emission index of CO (EICO) increased with decreasing combustor pressure, and EICO of $C_2H_4$ was mostly affected by changing combustor pressure at subatmospheric pressure. In order to observe reaction zone, $OH^*$, $CH^*$ and ${C_2}^*$ chemiluminescence intensity were measured. The sequence of the chemiluminescence intensity peak position was affected by chemical characteristics of fuels rather than changing combustor pressure. The emission zone thickness of $C_2H_4$ and $C_3H_8$, defined by the full width at half maximum (FWHM) of $CH^*$ intensity profile, were increased with decreasing combustor pressure. however, the thickness of $C_2H_4$ exhibited the opposite tendency due to the characteristics of the fuel as the bond structure.

• 대한기계학회논문집B
• /
• 제33권5호
• /
• pp.343-348
• /
• 2009

The present study has experimentally investigated the effects of $CO_2$ diluted oxygen on the structure of swirl-stabilized flame in a lab-scale combustor. The methane fuel and oxidant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for various amount of carbon dioxide addition to the methane fuel and various swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the hot combustion zone increases at the upstream reaction zone because of an increase in the recirculation flow for an increase in swirl intensity. The hot combustion zone is also increased at the downstream zone by recirculation flow because of an increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensities of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of diluted gas in the reaction zone.