• 전기학회논문지
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• 제61권8호
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• pp.1153-1158
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• 2012

Niobium oxide ($Nb_2O_5$) has a strong chemical coherence and good electrical conductivity. Therefore, this material is helpful to enhance the performance of the dye sensitized solar cells (DSC) by improving the electron mobility. In this study, $Nb_2O_5$ was mixed with $TiO_2$ and this compound was applied to the DSC to improve its performance. As a result, the current density of the DSC using the $Nb_2O_5-TiO_2$ compound on the photoelectrode was increased, because the internal resistance concerned to the electron transfer in the photoelectrode of DSC was decreased. However, large amount of the $Nb_2O_5$ induces the decrease of the efficiency of the DSC because the surface area to attach dye molecules is decreased due to the large particle of $Nb_2O_5$. Therefore, it is important to optimize the mixture ratio of the $Nb_2O_5-TiO_2$ compound for maximizing the performance of the DSC. Finally, the most optimum performance of the DSC was shown in case of the $Nb_2O_5$ concentration of 10 wt% of the $Nb_2O_5-TiO_2$ compound.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.256-259
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• 1996

$(Sr_{1-x}{\cdot}Ca_x)TiO_3+yNb_2O_5$($0.05{\leq}x{\leq}0.2$, 0.004$1350[^{\circ}C]$ in a reducing atmosphere($N_2$ gas). Dielectric propertries were investigated with contents of $Nb_2O_5$. The grain size and dielectric constant increase with increase $Nb_2O_5$, but decrease in $Nb_2O_5$ exceed($Nb_2O_5=0.6[mol%]$). Also, the temperature characteristics of the dielectric loss factor exhibited a stable value within 0.5[%]. The capacitance characteristics appeals a stab]e value in ${\pm}10[%]$.

• 한국세라믹학회지
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• 제19권4호
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• pp.267-274
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• 1982

The sintering behavior and B-H loop properties of $Li_{0.5O4}$ with the addition of $Nb_2O_5$ and $V_2O_5$ have been investigated by observation of microstructures and measurement of semi-static hysteresis loops. The sintering temperature was lowered by the additions of $Nb_2O_5$ and $V_2O_5$ and the effect of $V_2O_5$ addition was greater than that of $Nb_2O_5$. The abnormal grain growth was observed at about 100$0^{\circ}C$(d:4.6g/㎤) and 85$0^{\circ}C$(d:4.5g/㎤) in the specimens with the addition of $Nb_2O_5$ and $V_2O_5$ respectively. The addition of $Nb_2O_5$ retulted in a large and uniform grain size, and the addition of $V_2O_5$ resulted in a uniform grain size but the final density was lower than that of the pure specimen. The squareness was increased and the coercive force was decreased by the addition of $Nb_2O_5$, and the squareness was decreased and the coercive force was increased by the addition of $V_2O_5$. These effects could be explained by a large and uniform grain size, and by a lower final density of specimens with the addition of $Nb_2O_5$ and $V_2O_5$ respectively.

• 한국광물학회지
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• 제15권1호
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• pp.59-68
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• 2002

캐나다 퀘벡 주 오카지역에서 산출되는 네오비움 페롭스카이트(일명 라트라파이트, $Ca_2NbFe^{3+}O_6$)에 대하여 화학분석과 분말 X선 회절 데이터를 이용한 리트벨트 구조분석을 실시하였다. 라트라파이트는 $CaTiO_3-NaNbO_3-Ca_2NbFe^{3+}O_6$의 연속계열 고용체의 성분을 가지며, 화학분석 결과 평균$(Ca_{1.5}Na_{0.4})\;(Nb_{0.1}Ti_{0.6}Fe_{0.4})O_6$ 리트벨트 구조분석 결과 라트라파이트의 구조는 페롭스카이트($CaTiO_3$)의 결정구조와 유사하지만, Ti 이온이 Nb와 $Fe^{3+}$에 의해 치환되면서 상당히 뒤틀리고, $TiO_6$ 팔면체가 페롭스카이트에 비해 서로 기울어져 있는 모습을 보여준다 새롭게 결정된 라트라파이트의 공간군은 Pbnm, 단위포는 a=5.4474(4), b=5.5264(4), c=7.7519(5) ${\AA},\;V=233.4(3){\AA}^3$이다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제55권7호
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• pp.349-353
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• 2006

[ $TiO_2-Nb_2O_5$ ] sol was prepared using sol-gel method. Crystalline properties of gel powder changed from rutile phase to anatase phase with increasing $Nb_2O_5$ additives at $800^{\circ}C$, while they retained rutile phase regardless of $Nb_2O_5$ additives at $900^{\circ}C,\;1,000^{\circ}C$. They retained amorphous phase from $50^{\circ}C\;to\;400^{\circ}C$, retained anatase phase from $500^{\circ}C\;to\;600^{\circ}C$ and had rutile phase over $700^{\circ}C$ at 1mole% $Nb_2O_5$ additive. After $TiO_2-Nb_2O_5$ sol retained low viscosity with normal chain structure for a long time, its viscosity increased fast with network structure. DTA properties of gel powder had endothermic reaction due to evaporation of propanol and water about $78^{\circ}C$, had exothermic reaction due to propanol combustion about $290^{\circ}C$ and had exothermic reaction due to changing of $TiO_2$ phase about $640^{\circ}C$.

• 마이크로전자및패키징학회지
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• 제30권4호
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• pp.79-85
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• 2023

(1-4x)Bi_1.5Zn_1.0Nb_1.5O₇-3xBi₂Zn_2/3Nb_4/3O₇-2xLiZnNbO₄(x=0.03-0.21) 조성의 새로운 저온 동시 소성 세라믹(LTCC) 유전체는 Bi_1.5Zn_1.0Nb_1.5O₇-xLi₂CO₃(x=0.03-0.21) 혼합물을 850℃~920℃에서 4 시간 반응성 액상소결(reactive liquid phase sintering)을 하여 제조하였다. 소결이 진행되는 동안 Li₂CO₃는 Bi_1.5Zn_1.0Nb_1.5O₇과 반응하여 Bi₂Zn_2/3Nb_4/3O₇과 LiZnNbO₄를 생성하였고 얻어진 소결체의 상대 소결밀도는 이론 밀도의 96% 이상이었다. 초기 Li₂CO₃ 함량(x)을 조절하여 최종 소결체내에 존재하는 Bi_1.5Zn_1.0Nb_1.5O₇, Bi₂Zn_2/3Nb_4/3O₇ 및 LiZnNbO₄ 상의 상대적인 함량을 제어함으로써 높은 유전율(ε_r), 낮은 유전손실(tan δ) 및 NP0 특성(TCε ≤ ±30 ppm/℃)의 유전율 온도계수(TCε)를 갖는 유전체를 개발할 수 있었다. Li₂CO₃의 첨가가 x=0.03 mol에서 x=0.15 mol로 증가함에 따라 얻어진 복합체 내의 Bi₂Zn_2/3Nb_4/3O₇와 LiZnNbO₄의 부피 분율은 증가하였고, Bi_1.5Zn_1.0Nb_1.5O₇의 부피 분율은 감소하였다. 그 결과 복합체의 유전율(ε_r)은 148.38에서 126.99로 유전손실(tan δ)은 5.29×10^-4에서 3.31×10^-4로 그리고 유전율 온도계수(TCε)는 -340.35 ppm/℃에서 299.67 ppm/℃로 변화되었다. NP0 특성을 갖는 유전체는 Li₂CO₃의 함량이 x=0.09일 때 얻을 수 있었고, 이 때의 유전율(ε_r)은 143.06, 유전손실(tan δ)값은 4.31×10^-4, 그리고 유전율 온도계수(TCε)값은 -9.98 ppm/℃ 이었다. Ag전극과의 화학적 호환성 실험은 개발된 복합 재료는 Ag 전극과 동시 소성 과정에서 전극과 반응이 없음을 보여주었다.

• 한국결정성장학회지
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• 제5권1호
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• pp.1-10
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• 1995

CZ법을 이용하여 합치용융조성(congruent) $LiNbO_3$ 및 광손상에 큰 저항성을 보이는 $LiNbO_3$ : Mg 단결정에 MgO 첨가량을 2, 5 및 7 mol%로 변화시키면서 육성하여, 보상 방법으로 광손상을 측정하였다. 5 mol% 이상의 MgO 첨가시 광흡수단 및 $OH^-$ 흡수밴드의 특성이 크게 변화함을 관찰함으로써 MgO 첨가량에 일정한 역치(threshold)가 존재함을 확인하였다. $LiNbO_3$ : Mg 단결정에서는 5 mol% 이상의 MgO 첨가시 Mg가 Nb 자리를 차지하여$Mg_{Nb}^{2+}$를 형성함에 따라 광손상에 대한 저항이 크게 향상될 수 있다. 실제로 융액에 5 mol% 이상의 MgO 첨가시)$LiNbO_3$ : Mg 단결정의 광손상 저항이 3배 이상 향상되었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.402-405
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• 2001

The BaTiO$_3$+10wt%Nb$_2$O$_{5}$ ceramics were prepared by conventional mixed oxide method. The structural and dielectric properties of the BaTiO$_3$+10wt%Nb$_2$O$_{5}$ ceramics with the sintering temperature were investigated. Increasing the sintering temperature, the 2$\theta$ value of BaTiO$_3$peaks were shifted to the higher degree and intensity of the BaTiO$_3$and BaNbO$_3$peaks were increased. In the BaTiO$_3$+10wt%Nb$_2$O$_{5}$ ceramics sintered at 135$0^{\circ}C$ and 1375$^{\circ}C$, the grain was fine and uniform. Increasing the sintering temperature, the pore was decreased and the dielectric constant was increased. In the BaTiO$_3$+10wt%Nb$_2$O$_{5}$ ceramics sintered at 1375$^{\circ}C$, the dielectric constant and dielectric loss were 5424, 0.02 respectively.ctively.

• 한국세라믹학회지
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• 제35권8호
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• pp.864-870
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• 1998

The effect of {{{{ {{Nb }_{2 }O }_{5 } }} and CoO addition on the temperature dependence of the {{{{ {BaTiO }_{3 } }}-based ceramic capa-citor has been studied. X7R with moderate temperature dependence has been developed by means of pre-cisely controlled {{{{ {{Nb }_{2 }O }_{5 } }}/CoO ratio. Dielectric constant(K) and dissipation factor(DF) were 3500 and 1.5% respectively. As the content of {{{{ {{Nb }_{2 }O }_{5 } }} was increased the curie temperature(Tc) was shifted to lower tem-perature and the dielectric constant at Tc was decreased. The proper addition of CoO with {{{{ {{Nb }_{2 }O }_{5 } }} improved the temperature dependence of dielectric properties of the {{{{ {BaTiO }_{3 } }}-based ceramic capacitor.

• 한국결정성장학회지
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• 제15권3호
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• pp.120-123
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• 2005

[ $Li_2CO_3-V_2O_5$ ], flux를 사용한 liquid phase epitaxy(LPE) 법을 사용하여 $LiNbO_3$ (001) 기판위에 5 mol% ZnO가 첨가된 $LiNbO_3$, 박막과 2 mol% MgO가 첨가된 $LiNbO_3$, 박막을 성장시켰다. $Zn:LiNbO_3$, 막과 $Mg:LiNbO_3$, 막과의 결정성과 격자 부정합은 x-ray rocking curve(XRC)로 분석되었다. 그리고 다층 박막의 단면에서의 ZnO와 MgO의 분포가 electron probe micro analyzer(EPMA)를 사용하여 관측되었다.