• Title/Summary/Keyword: $N_2O$ Flux

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High Temperature Stability of Nitride Ceramic Materials in LiF-NdF3-Nd2O3 Molten Salts System (LiF-NdF3-Nd2O3 용융염에서 질화물계 세라믹재료의 고온안정성)

  • Kwon, Sukcheol;Lee, Young-Jun;Ryu, Hong-Youl;Lee, Go Gi;Jo, Sung Koo;Lee, Jong-Hyeon
    • Korean Journal of Materials Research
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    • v.25 no.12
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    • pp.694-702
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    • 2015
  • Nd-Fe-B permanent magnets have been used in a wide variety of applications because of their high magnetic flux density. So, demand for neodymium has been increasing in worldwide. In this study, an electrowinning process was performed in $LiF-NdF_3-Nd_2O_3$ high temperature molten salts. However, a corrosion resistant material for use in the molten salt must be found for stable operation because of the harsh corrosion environment of the electrowinning process. Therefore, for this paper, boron nitride(BN), aluminum nitride(AlN), and silicon nitride($Si_3N_4$) were selected as protective and structural materials in the high temperature electrolyte. To investigate the characteristics of BN, AlN, and $Si_3N_4$, in molten salts, materials were immersed in the molten salts for 24, 72, 120, and 192 hours. Also, surface condition and stability were investigated by SEM and EDS and corrosion products were calculated by HSC chemistry. As a result, among BN, AlN, and $Si_3N_4$, AlN was found to show the best protective material properties.

Growth and Characteristics of Near-UV LED Structures on Wet-etched Patterned Sapphire Substrate

  • Cheong, Hung-Seob;Hong, Chang-Hee
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.6 no.3
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    • pp.199-205
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    • 2006
  • Patterned sapphire substrates (PSS) were fabricated by a simple wet etching process with $SiO_2$ stripe masks and a mixed solution of $H_2SO_4$ and $H_3PO_4$. GaN layers were epitaxially grown on the PSS under the optimized 2-step growth condition of metalorganic vapor deposition. During the 1st growth step, GaN layers with triangular cross sections were grown on the selected area of the surface of the PSS, and in the 2nd growth step, the GaN layers were laterally grown and coalesced with neighboring GaN layers. The density of threading dislocations on the surface of the coalesced GaN layer was $2{\sim}4\;{\times}\;10^7\;cm^{-2}$ over the entire region. The epitaxial structure of near-UV light emitting diode (LED) was grown over the GaN layers on the PSS. The internal quantum efficiency and the extraction efficiency of the LED structure grown on the PSS were remarkably increased when compared to the conventional LED structure grown on the flat sapphire substrate. The reduction in TD density and the decrease in the number of times of total internal reflections of the light flux are mainly attributed due to high level of scattering on the PSS.

Water Treatment of High Turbid Source by Tubular Ceramic Microfiltration with Periodic Water-back-flushing System

  • Lee, Hyuk-Chan;Park, Jin-Yong
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.12-17
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    • 2007
  • We performed periodic water-back-flushing using permeate water to minimize membrane fouling to enhance permeate flux in tubular ceramic microfiltration system for water treatment of high turbid source. The filtration time (FT) = 2 min with periodic 6 sec water-back-flushing showed the highest value of dimensionless permeate flux ($J/J_o$), and the lowest value of resistance of membrane fouling ($R_f$), and we acquired the highest total permeate volume $(V_T)\;=\;6.805L$. Also in the result of BT effect at fixed FT = 10 min and BT (back-flushing time) = 20 sec showed the lowest value of $R_f$ and the highest value of $J/J_o$, and we could obtain the highest $V_T\;=\;6.660\;L$. Consequently, FT = 2 min and BT = 6 sec could be the optimal condition in water treatment of high turbid source above 10 NTU. However, FT = 10 min and BT = 20 sec was superior to reduce operating costs because of lower back-flushing frequency. Then the average quality of water treated by our tubular ceramic MF system was turbidity of 0.07 NTU, $COD_{Mn}$ of 1.86 mg/L and $NH_3-N$ of 0.007 mg/L.

통신위성 원격측정명령계 RF 링크버짓 개념설계 연구

  • Kim, Joong-Pyo;Koo, Cheol-Hea
    • Aerospace Engineering and Technology
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    • v.1 no.2
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    • pp.45-50
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    • 2002
  • A conceptual design on the link budget of TC&R RF subsystem which transfers command and telemetry data as RF signal between the ground system and the 2005SAT spacecraft is presented in this paper. In order to perform the analysis of the link budget, we divided the analysis process into two processes, i.e., uplink and downlink process. For the uplink the power flux density at the spacecraft and the margin of the command receiver are calculated. In the case of the downlink the downlink EIRP and the margin of C/ No and Eb / No at the ground station are calculated. Through the uplink performance analysis, the power at the command receiver has well efficient margin, and the margin of C/ No and Eb / No is also fully proper for the downlink case.

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Acidification of pig slurry effects on ammonia and nitrous oxide emissions, nitrate leaching, and perennial ryegrass regrowth as estimated by 15N-urea flux

  • Park, Sang Hyun;Lee, Bok Rye;Jung, Kwang Hwa;Kim, Tae Hwan
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.3
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    • pp.457-466
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    • 2018
  • Objective: The present study aimed to assess the nitrogen (N) use efficiency of acidified pig slurry for regrowth yield and its environmental impacts on perennial ryegrass swards. Methods: The pH of digested pig slurry was adjusted to 5.0 or 7.0 by the addition of sulfuric acid and untreated as a control. The pig slurry urea of each treatment was labeled with $^{15}N$ urea and applied at a rate of 200 kg N/ha immediately after cutting. Soil and herbage samples were collected at 7, 14, and 56 d of regrowth. The flux of pig slurry-N to regrowth yield and soil N mineralization were analyzed, and N losses via $NH_3$, $N_2O$ emission and $NO_3{^-}$ leaching were also estimated. Results: The pH level of the applied slurry did not have a significant effect on herbage yield or N content of herbage at the end of regrowth, whereas the amount of N derived from pig slurry urea (NdfSU) was higher in both herbage and soils in pH-controlled plots. The $NH_4{^+}-N$ content and the amount of N derived from slurry urea into soil $NH_4{^+}$ fraction ($NdfSU-NH_4{^+}$) was significantly higher in in the pH 5 plot, whereas $NO_3{^-}$ and $NdfSU-NO_3{^-}$ were lower than in control plots over the entire regrowth period. Nitrification of $NH_4{^+}-N$ was delayed in soil amended with acidified slurry. Compared to non-pH-controlled pig slurry (i.e. control plots), application of acidified slurry reduced $NH_3$ emissions by 78.1%, $N_2O$ emissions by 78.9% and $NO_3{^-}$ leaching by 17.81% over the course of the experiment. Conclusion: Our results suggest that pig slurry acidification may represent an effective means of minimizing hazardous environmental impacts without depressing regrowth yield.

ANALYSIS OF RAYLEIGH-BENARD NATURAL CONVECTION (Rayleigh-Benard 자연대류 유동 해석)

  • Choi, Seok-Ki;Kim, Seong-O
    • Journal of computational fluids engineering
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    • v.13 no.3
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    • pp.62-68
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    • 2008
  • This paper reports briefly on the computational results of a turbulent Rayleigh-Benard convection with the elliptic-blending second-moment closure (EBM). The primary emphasis of the study is placed on an investigation of accuracy and numerical stability of the elliptic-blending second-moment closure for the turbulent Rayleigh-Benard convection. The turbulent heat fluxes in this study are treated by the algebraic flux model with the temperature variance and molecular dissipation rate of turbulent heat flux. The model is applied to the prediction of the turbulent Rayleigh-Benard convection for Rayleigh numbers ranging from Ra=$2{\times}10^6$ to Ra=$10^9$ and the computed results are compared with the previous experimental correlations, T-RANS and LES results. The predicted cell-averaged Nusselt number follows the correlation by Peng et al.(2006) (Nu=$0.162Ra^{0.286}$) in the 'soft' convective turbulence region ($2{\times}10^6{\leq}Ra{\leq}4{\times}10^7$) and it follows the experimental correlation by Niemela et al. (2000) (N=$0.124Ra^{0.309}$) in the 'hard' convective turbulence region ($10^8{\leq}Ra{\leq}10^9$) within 5% accuracy. This results show that the elliptic-blending second-moment closure with an algebraic flux model predicts very accurately the Rayleigh-Benard convection.

Effect of $N_2$-back-flushing Time and TMP in Lake Water Treatment Using Multichannel Ceramic Microfiltration Membranes (다채널 세라믹 정밀여과막으로 호소수 처리시 질소 역세척 시간 및 막간 압력차의 영향)

  • Park, Jin-Yong;Park, Bo-Reum
    • Membrane Journal
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    • v.17 no.2
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    • pp.124-133
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    • 2007
  • In this study, we treated lake water by 2 kinds of multichannel ceramic micro filtration membranes. We could investigate effects of $N_2-back-flushing$ time (BT) and transmembrane pressure (TMP), and find optimal operating conditions. The BT were changed in $10{\sim}60$ sec, TMP in $0.6{\sim}2.0$ bar at fixed filtration time (FT) 8 min, flow rate 2.0 L/min and back-flushing pressure 2.0 bar. Also, the optimal conditions were discussed in the viewpoints of resistance of membrane fouling $(R_f)$, dimensionless permeate flux $(J/J_o)$, permeate flux (J) and total permeate volume $(V_T)$. As result, optimal back-flushing conditions for HC04 ($0.4{\mu}m$ pore size) and HC10 membrane $(1.0{\mu}m)$ were BT=10 sec and BT=20 sec, respectively. Then, higher TMP should increase the driving force, and could produce more VT. Average rejection rates of pollutants were higher than 95.4% for turbidity, $12.7{\sim}20.1%\;for\;COD_{Mn},\;0.0{\sim}6.4%\;for\;NH_3-N,\;1.9{\sim}4.6%$ for T-N and $34.9{\sim}88.4%$ for T-P.

Emission of Green House Gases in the Agricultural Environment -1. The Cropping System and Emission of the Green House Gases-CO2, CH4, N2O)-under Different Cropping System (농작물(農作物) 재배환경(栽培環境)과 지구온난화(地球溫暖化) 원인(原因)가스 발생(發生) -1. 답전전환시(畓田轉換時) 작부체계(作付體系)와 지구온난원인기체(地球溫暖原因氣體) -이산화탄소(二酸化炭素), 메탄, 아산화질소(亞酸化窒素)- 발생(發生))

  • Lee, Sang-Kyu;Suh, Jang-Sun
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.1
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    • pp.49-56
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    • 1993
  • The net flux of global green house gases such as carbon dioxide($CO_2$), methane($CH_4$), and nitrous oxide($N_2O$) emitted from the rotation of paddy-upland soil during growing sesaon under different cropping system was determined. The results obtained were summarized as follows : 1. The net flux of $CO_2$ during the growing season was the highest from continuous cultivation of rice but the lowest from rotation cultivation of rice-soybean. Under the different cropping system the highst emission was from soil of continuous cultivation of rice, but the lowest from converted system. 2. The net emission of methane was the highest from the sold of continuous cultivation of rice, but the flux was remarkably decreased by differing the cropping system. 3. $N_2O$ was emitted greatly from the every two year rotation of potato-chinese cabbage and the next rank was from continuous cultivation of rice, but was decreased notably from rotation cultivation of rice-soybean and potato-chinese cabbage under rotation of paddy-upland cropping system. 4. The ratio of oxygen and carbon dioxide in the soil air was much different with glowing season, the ratio was varied with 4~10 percents for oxygen and 1~22 percents for carbon dioxide. The ratio of carbon dioxide was dozens or hundreds times to that of air, and the variation was very high also. 5. The emission of global green house gases such as carbon dioxide, methane and nitrous oxide was affected by the moisture, temperature and nutrients of soils and the growth period of crops.

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P=Comparative Analysis of Thermal Performance According to Combines of Multi-layer Insulating Curtain (다겹보온커튼의 조합에 따른 열성능의 비교 분석)

  • Jin, B.O.;Kim, H.K.;Ryou, Y.S.;Lee, T.S.;Kim, Y.H.;Oh, S.S.;Moon, J.P.;Kang, G.C.
    • Journal of the Korean Society of Mechanical Technology
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    • v.20 no.6
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    • pp.763-769
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    • 2018
  • In this research, in order to improve the heat retention of greenhouse, comparative analysis of the heat flux of the marketed multi-later insulating curtain was carried out. Experiments is conducted by fabricating a test apparatus for investigating the heat flux characteristics. The multi-later insulating curtain used for the experiment was compared using the P, N, S, U and T company, which are commercially available, and the heat flux due to temperature difference between the experimental apparatus and the outside was compared and analyzed. When the internal temperature of the experimental result is the maximum temperature $60^{\circ}C$, the heat flux of multi-later insulating curtain is T Co.($73.1W/m^2$) > S Co.($119.5W/m^2$) > U Co.($155W/m^2$) > N Co.($163.1W/m^2$) > P Co.($177.7W/m^2$). The heat flux means the quantity of heat passing through the unit time per unit area, and the higher the numerical value, the higher the quantity of heat passing through the multi-layer insulating curtain. This can be determined that high heat fluxes produce low heat resistance. Further, it has been found that the weight of the insulating curtain is largely unrelated to the heat insulating property, and the heat insulating curtain having a thickness containing a high internal air layer is excellent in the heat insulating property. In the future when manufacturing a heat insulating curtain, It is judged that it is desirable to manufacture a combination of heat insulating materials that contain a high internal air layer content and that can maintain the air layer even for long-term use while minimizing the volume.