• 제목/요약/키워드: $N_2$ conversion

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$Ca^{2+}$ Effect on the Conversion of ACC to Ethylene in Mungvean(Vigna radiata) Hypocothls (녹두(Vigna radiata)의 하배축에서 ACC의 에틸렌 전환에 미치는 $Ca^{2+}$의 효과)

  • 서효원
    • Journal of Plant Biology
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    • v.36 no.3
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    • pp.233-239
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    • 1993
  • Effect of Ca2+ on the conversion of 1-aminocycloprophane-1-carboxylic acid (ACC) to ethylene was studied with 2.5 day-old mung bean hypocotyl segments. The conversion of ACC in these tissues was inhibited by plasmolysis and sulfosuccinimidyl (hydroxyphenyl) propionate (sulfo-SHPP). The ACC induced ethylene production in HC (high calcium)-tissue grown on the Ca2+ added medium was greater than that in N (normal)-tissue. HC-tissue had a lower inhibition rate of ACC conversion by EGTA and Ca2+ -channel blockers than N-tissue. The rates of the ACC conversion by both kinds of tissues were stimulated by the Ca2+ ionophore A23187. From these results, we suggests a mechanism for the stimulative effect of Ca2+ on the conversion of ACC to ethylene as follows; in some tissues where ACC conversion is linked with plasma membrane, Ca2+ may be transported from apoplast through Ca2+ -channel into the cytoplasm ad stimulate ACC-oxidase activity.

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A study on γ-Al2O3 Catalyst for N2O Decomposition (N2O 분해를 위한 γ-Al2O3 촉매에 관한 연구)

  • Eun-Han Lee;Tae-Woo Kim;Segi Byun;Doo-Won Seo;Hyo-Jung Hwang;Jueun Baek;Eui-Soon Jeong;Hansung Kim;Shin-Kun Ryi
    • Clean Technology
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    • v.29 no.2
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    • pp.126-134
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    • 2023
  • Direct catalytic decomposition is a promising method for controlling the emission of nitrous oxide (N2O) from the semiconductor and display industries. In this study, a γ-Al2O3 catalyst was developed to reduce N2O emissions by a catalytic decomposition reaction. The γ-Al2O3 catalyst was prepared by an extrusion method using boehmite powder, and a N2O decomposition test was performed using a catalyst reactor that was approximately 25.4 mm (1 in) in diameter packed with approximately 5 mm of catalysts. The N2O decomposition tests were carried out with approximately 1% N2O at 550 to 750 ℃, an ambient pressure, and a GHSV=1800-2000 h-1. To confirm the N2O decomposition properties and the effect of O2 and steam on the N2O decomposition, nitrogen, air, and air and steam were used as atmospheric gases. The catalytic decomposition tests showed that the 1% N2O had almost completely disappeared at 700 ℃ in an N2 atmosphere. However, air and steam decreased the conversion rate drastically. The long term stability test carried out under an N2 atmosphere at 700 ℃ for 350 h showed that the N2O conversion rate remained very stable, confirming no catalytic activity changes. From the results of the N2O decomposition tests and long-term stability test, it is expected that the prepared γ-Al2O3 catalyst can be used to reduce N2O emissions from several industries including the semiconductor, display, and nitric acid manufacturing industry.

Biomass Conversion Efficiencies of Fish Pond Fertilization and Feed Supplementation

  • Mahboob, Shahid;Sheri, A.N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.2
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    • pp.192-195
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    • 1998
  • Biomass conversion efficiencies (B.C.E) of six fish species viz, Catla catla, Labeo, rohita, Cirrhina mrigala, Hypophthalmicthys molitrix, Ctenopharyngodon idella and Cyprinus carpio cultured under artificial feed (T1), broiler manure (T2), buffalo manure (T3), N:P:K (25:25:0) (T4) and control pond (T5) have been determined for the period of one year. The overall biomass conversion efficiencies under the influence of T2, T3, and T4 were statistically similar. However, the best (0.40) efficiency was determined under feed supplement-ation (T1).

Changes of Soil Nitrogen Supply and Production of Upland Forage Crops by Cattle Manure during Conversion from Paddy to Upland Condition in Paddy Field (논의 밭전환 연차간 우분시용에 의한 질소공급 및 밭사료 작물의 생산력 변화)

  • Seo Jong-Ho;Kim Sok-Oong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.6
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    • pp.387-393
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    • 2005
  • The effect of cattle manure with the rates of 2 and 4 ton $l0a^{-1}$ for winter rye and summer corn cultivation, respectively, on the dry matter (DM) yield and nitrogen (N) uptake were investigated during successive three­year conversion period from paddy to upland condition in paddy field. The changes in soil properties and soil N sup­plying capacity during repetitive manure application were a1so examined. Growth and DM yield of upland forage crops, especially. winter rye were hindered highly by poor soil condition in the first year after conversion from paddy to upland condition, so apparent recovery of cattle manure N by crops was very low in the first conversion year. But, DM yield and N uptake of upland forage crops were increased linearly by accumulative input of cattle manure along with mineral N enrichment in soil, which also increased apparent recovery of cattle manure-No It seemed that those increases were mainly due to the improvement of soil properties such as soil mineral N, soil organic matter (soil carbon), potentially mineralizable N and bulk density by accumulative input of cattle manure rather than the increase of soil N supply according to accumulative conversion period from paddy to upland condition. It was derived that conversion period from paddy to upland condition over 2 years is needed to obtain proper DM yield in paddy field and accumulative inputs of cattle manure during the conversion period is more influential to the continuous increment of DM yield and N uptake of upland crop as well as of potential N supplying capacity of soil.

Stress analysis of the CR lens using the chrome conversion (Chrome 변환을 이용한 CR 렌즈의 미세응력 시각화)

  • Kim, Yong-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.10 no.1
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    • pp.9-15
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    • 2005
  • The polariscope to measure the microscopic stress in CR lens consists of light source polarizer, model, polarizer, CCD, computer, chrome conversion orderly and the principal-stressed difference, (${\sigma}_1-{\sigma}_2$) and the fringe order n were measured by analyzing two components of light wave $E_1$ and $E_2$ following each polarizer's steps. The two-dimensional model could be determined from the fact that the optical axes of sample concide with the principal-stress directions. The bi-refringence acted to a light wave and the phase retardation were in proportion to the principal-stressed difference(${\sigma}_1-{\sigma}_2$) and the intensity of final light wave was proportioned to $sin2({\Delta}/2)$ and when ${\Delta}/2=n{\pi}$ (n=0, 1, 2, ${\ldots}$) the extinction occurs. Photoelastic's image by microscopic stress could analyzed using chrome conversion, and the image showed clearly.

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A Novel Binary-to-Residue Conversion Algorithm for Moduli ($2^n$ - 1, $2^n$, $2^n + 2^{\alpha}$)

  • Syuto, Makoto;Satake, Eriko;Tanno, Koichi;Ishizuka, Okihiko
    • Proceedings of the IEEK Conference
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    • 2002.07a
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    • pp.662-665
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    • 2002
  • This paper describes a novel converter to implement high-speed binary-to-residue conversion for moduli 2$^{n}$ - 1, 2$^{n}$ , 2$^{n}$ +2$^{\alpha}$/($\alpha$$\in${0,1,…,n-1}) without using look-up table. In our implementation, the high-speed converter can be achieved, because of the modulo addition time is independent of the word length of operands by using the Signed-Digit (SD) adders inside the modulo adders. For a LSI implementation of residue SD number system with ordinary binary system, the proposed binary-to-residue converter is the efficient circuit.cient circuit.

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An experimental study on $NO-NO_2$ conversion characteristics and oxidation of soot by corona discharge (코로나방전에 의한 $NO_2$ 전환특성 및 soot 산화에 관한 연구)

  • Park, Yong-Seong;Chun, Kwang-Min;Park, Kwang-Seo;Lee, Jong-Hyun;Cho, Seong-Woo
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.179-184
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    • 2001
  • The characteristics of $NO-NO_2$ conversion and soot oxidation by corona discharge are investigated experimentally. The discharge current decreases with the increase of oxygen concentration and it increases more sharply for anode corona than for cathode corona as discharge voltage increases after corona onset voltage. $NO-NO_2$ conversion increases with the energy density of corona discharge and the addition of $O_2$ in a base $N_2$ gas. Soot oxidation occurs at approximately $480^{\circ}C$ in a mixture of 21% $O_2$, base $N_2$ gas, and enhances as temperature increases. The initiation temperature of soot oxidation advances greatly to about $280^{\circ}C$ with the addition of 300ppm $NO_2$, which is generated from the conversion of NO to $NO_2$ by corona discharge. CO is generated at higher temperature by about $50{\sim}100^{\circ}C$ than $CO_2$ in the process of soot oxidation.

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Partial oxidation of n-butane over ceria-promoted nickel/calcium hydroxyapatite (세리아가 첨가된 니켈/칼슘 하이드록시 아파타이트 촉매 상의 부탄 부분산화 연구)

  • Kwak, Jung-Hun;Lee, Sang-Yup;Kim, Mi-So;Nam, Suk-Woo;Lim, Tae-Hoon;Hong, Seong-Ahn;Yoon, Ki-June
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.89-92
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    • 2007
  • Partail oxidation(POX) of n-butane was investigated in this research by employing ceria-promoted Ni/calcium hydroxyapatite catalysts ($Ce_xNi_{2.5}Ca_{10}(OH)_2(PO_4)_6$ ; x = $0.1{\sim}0.3$) which had recently been reported to exhibit good catalytic performance in POX of methane and propane. The experiments were carried out with changing ceria content, $O_2/n-C_4H_{10}$ ratio and temperature. As the $O_2/n-C_4H_{10}$ feed ratio increased up to 2.75, n-$C_4H_{10}$ conversion and $H_2$ yield increased and the selectivity of methane and other hydrocarbons decreased. But with $O_2/n-C_4H_{10}$ = 3.0, $n-C_4H_{10}$ conversion and $H_2$ yield decreased. This is considered due to that too much oxygen may inhibit the reduction of Ni or induce the oxidation of Ni, which results in poor catalytic activity. The optimum $O_2/n-C_4H_{10}$ ratio lay between 2.50 and 2.75. $Ce_{0.1}Ni_{2.5}Ca_{10}(OH)_2(PO_4)_6$ showed the highest $n-C_4H_{10}$ conversion and $H-2$ yield on the whole. In durability tests, higher hydrogen yield and better catalyst stability were obtained with the $O_2/n-C_4H_{10}$ ratio of 2.75 than with the ratio of 2.5.

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The effect of thickness and translucency of polymer-infiltrated ceramic-network material on degree of conversion of resin cements

  • Barutcigil, Kubilay;Buyukkaplan, Ulviye Sebnem
    • The Journal of Advanced Prosthodontics
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    • v.12 no.2
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    • pp.61-66
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    • 2020
  • PURPOSE. The aim of the present study was to determine the degree of conversion of light- and dual-cured resin cements used in the cementation of all-ceramic restorations under different thicknesses of translucent (T) and high-translucent (HT) polymer-infiltrated ceramic-network (PICN) material. MATERIALS AND METHODS. T and HT PICN blocks were prepared at 0.5, 1.0, 1.5, and 2.0 mm thicknesses (n=80). Resin cement samples were prepared with a diameter of 6 mm and a thickness of 100 ㎛. Light-cured resin cement was polymerized for 30 seconds, and dual-cure resin cement was polymerized for 20 seconds (n=180). Fourier transform infrared spectroscopy (FTIR) was used for degree of conversion measurements. The obtained data were analyzed with ANOVA and Tukey HSD, and independent t-test. RESULTS. As a result of FTIR analysis, the degree of conversion of the light-cured resin cement prepared under 1.5- and 2.0-mm-thick T and HT ceramics was found to be lower than that of the control group. Regarding the degree of conversion of the dual-cured resin cement group, there was no significant difference from the control group. CONCLUSION. Within the limitation of present study, it can be concluded that using of dual cure resin cement can be suggested for cementation of PICN material, especially for thicknesses of 1.5 mm and above.

Synthesis and Characterization of Gallium Nitride Powders from a Gallium(III) Sulfate Salt in Flowing Ammonia

  • Jung, Woo-Sik
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1058-1061
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    • 2003
  • Gallium Nitride (GaN) powders were synthesized by calcining a gallium(III) sulfate salt in flowing ammonia in the temperature range 500-1100$^{\circ}C$. The process of conversion of the salt to GaN was monitored by X-Ray Diffraction (XRD). The salt decomposed to ${\gamma}$-Ga$_2$O$_3$ and then converted to GaN without ${\gamma}$-${\beta}$Ga$_2$O$_3$ phase transition. Variations in XRD patterns and weight loss of samples with temperature indicate that the conversion of ${\gamma}$-Ga$_2$O$_3$ to GaN does not proceed through Ga$_2$O but stepwise via amorphous gallium oxynitride (GaO$\_$x/N$\_$y/) as intermediates. Room-temperature photoluminescence spectra of GaN powders obtained showed the emission peak at 363 nm and no yellow band.