• Title/Summary/Keyword: $NO_x$ and $SO_x$ removal

Search Result 60, Processing Time 0.029 seconds

Isolated calcific tendinitis at the posterosuperior labrum: a rare case study

  • Suh, Dong-Hwan;Ji, Jong-Hun;Kim, Chang-Yeon
    • Clinics in Shoulder and Elbow
    • /
    • v.23 no.4
    • /
    • pp.194-197
    • /
    • 2020
  • Calcific tendinitis of the shoulder joint, also known as chemical furuncle of the shoulder, causes intense shoulder pain and usually occurs within 1-2 cm from the insertion of the rotator cuff. We experienced a rare case of calcific tendinitis in the posterosuperior labrum of the shoulder joint in a 39-year-old male patient who presented with severe pain and weakness in the right shoulder. Radiographs and magnetic resonance imaging (MRI) findings showed calcific tendinitis in the posterosuperior labrum of the shoulder joint. A 1-week attempt at conservative treatment failed, so the calcified deposit in the posterosuperior labrum was arthroscopically removed. The patient's symptoms were completely relieved, and satisfactory clinical outcomes were achieved. Postoperative follow-up X-ray and MRI showed no recurrence of calcific tendinitis.

Deactivation of $V_2O_5/TiO_2$ catalyst used in Orimulsion Fuel Power Plant for the Reduction of Nox (배연 탈질용 $V_2O_5/TiO_2$ 촉매의 오리멀젼 연소에 의한 비활성화)

  • Lee, In-Young;Lee, Jung-Bin
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.30 no.1
    • /
    • pp.54-60
    • /
    • 2008
  • Deactivation of SCR catalyst applied in Orimusion fuel power plant was investigated to develope the technique for the regeneration of deactivated SCR catalyst and optimize the operation of SCR facility. The characterization study of the catalysts was carried out using XRD, ICP-AES, SEM and EDS. The NO$_X$ removal activity and SO$_2$ oxidation activity of the catalysts were measured. The NO$_X$ conversion of the deactivated catalyst was 5$\sim$10% lower than that of the fresh catalyst and the value of SO$_2$conversion to SO$_3$ over the deactivated catalyst was about 0.59% higher than that of the fresh catalyst. Vanadium(V), Magnesium(Mg) and Sulfur(S) were largely accumulated in the deactivated catalyst. The accumulation of Vanadium(V) and Sulfur(S) is due to the components of the Orimulsion fuel and the accumulation of Magnesium(Mg) is due to MgO that is injected in the boiler to prevent the oxidation of SO$_2$ to SO$_3$. The diffraction line of the TiO$_2$ of the deactivated catalyst was identified as the crystalline peaks of anatase as the fresh catalyst.

Preparation and Properties of Disc Type CuO Catalyst Impregnated Ceramic Filters (디스크형 산화구리 촉매담지 세라믹필터의 제조와 물성)

  • Hong Min-Sun;Moon Su-Ho;Lee Jae-Chun;Lee Dong-Sub;Lim Woo Taik
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.20 no.2
    • /
    • pp.185-193
    • /
    • 2004
  • A catalyst with CuO ceramic filter for simultaneous treatment of dust and HAP was prepared and characterized. Catalytic ceramic filter can not only potentially achieve the substantial savings in energy but provide with effective optimization and integration of process for simultaneous removal of SO$_2$, NO$_{x}$ and particulates from flue gases. Catalytic ceramic filters remove simultaneously particulates on exterior surface of filters and reduce NO to $N_2$ and $H_2O$ by SCR (Selective Catalytic Reduction) process. Preparation of catalyst impregnated ceramic filter with disk shape (Ψ 50) follow the processing of alumino-silicate ceramic filter, support impregnation and catalyst impregnation (copper oxide). Preparation routes of alumino-silicate catalyst carrier suitable for production of catalytic filters practically were studied and developed using the sol-gel and colloidal processing, homogeneous precipitation and impregnation method. Characterization of the catalyst, catalyst carrier catalytic filter materials have been performed the using various techniques such as BET, XRD, TGA, SEM. Combination of the sol-gel and colloidal processing and impregnation method is recommended to prepare catalyst carriers economically for catalytic filter applications.s.

Studies on the Biological Treatment of Waste Water from Acetaldehyde Plant (아세트 알데히드(특수산업) 폐수의 생물학적 처리)

  • 정기택;서승교;송형익;박임동;방광웅
    • Korean Journal of Microbiology
    • /
    • v.25 no.4
    • /
    • pp.333-338
    • /
    • 1987
  • In order to establish the biological treatment system which can be used for treatment of waste aster from acetaldehyde plant, it was investigated optimum nutrient requirements and growth conditions by mixed culture of Micrococcus roseus AW-6, Micrococcus luteus AW-22, Microbacterium lacticum AW-38 and Microbacterium laevaniformans AW-41 as well as the effect of coagulants and neutralization reagents. Also, it was carried out the continuous culture as well as batch culture to treat the waste water by mixed culture of these strains. The COD removal rate was reached to maximum state for 96hrs culture at pH7.0 and $30^{\circ}C$ NaOH as the neutralization reagents was the most effective, but the coagulants had no effect on the COD remonal rate and the optimum dilution times for treatment were 10 fold. The COD removal rate was also increased by supplimenting 200 ppm $NH_{2}NO_{3}$, 50 ppm $KH_{2}PO_{4}$, 15 ppm $CaCl_{2}$ and 1 ppm $MgSO_{4} \cdot 7H_{2}O $ as additional nutrients. The removal rate coefficient $K_{1}$ on the batch culture was $4.5\times 10^{-6}$, and the detention time for BOD removal rate of 85% was approximately 45hrs. The COD of waste water was reduced to 15% of its initial value by the continuous culture. The COD and BOD of the effluents were to be about 60 ppm and 40 ppm, respectively, and final pH was 7.0.

  • PDF

Conformational changes of short, discrete Rouse chain during creep and recovery processes

  • Watanabe, Hiroshi;Inoue, Tadashi
    • Korea-Australia Rheology Journal
    • /
    • v.16 no.2
    • /
    • pp.91-99
    • /
    • 2004
  • For the Rouse chain composed of infinite number of beads (continuous limit), conformational changes during the creep and creep recovery processes was recently analyzed to reveal the interplay among all Rouse eigenmodes under the constant stress condition (Watanabe and Inoue, Rheol. Acta, 2004). For completeness of the analysis of the Rouse model, this paper analyzes the conformational changes of the discrete Rouse chain having a finite number of beads (N = 3 and 4). The analysis demonstrates that the chain of finite N exhibits the affine deformation on imposition/removal of the stress and this deformation gives the instantaneous component of the recoverable compliance, $J_{R}$(0) = 1/(N-l)v $k_{B}$T with v and $k_{B}$ being the chain number density and Boltzmann constant, respectively. (This component vanishes for N\longrightarrow$\infty$.) For N = 2, it is known that the chain has only one internal eigenmode so that the affinely deformed conformation at the onset of the creep process does not change with time t and $J_{R}$(t) coincides with $J_{R}$(0) at any t (no transient increase of $J_{R}$(t)). However, for N$\geq$3, the chain has N-l eigenmodes (N-l$\geq$2), and this coincidence vanishes. For this case, the chain conformation changes with t to the non-affine conformation under steady flow, and this change is governed by the interplay of the Rouse eigenmodes (under the constant stress condition). This conformational change gives the non-instantaneous increase of $J_{R}$(t) with t, as also noted in the continuous limit (N\longrightarrow$\infty$).X>).TEX>).X>).

Clinical investigation of lipoid pneumonia in adults (성인에서 발생한 지방성 폐렴의 임상적 고찰)

  • Hyun, Jae Geun;Rhee, Chong H.
    • Tuberculosis and Respiratory Diseases
    • /
    • v.43 no.6
    • /
    • pp.965-975
    • /
    • 1996
  • Background : Exogenous lipoid pneumonia is caused by inhalation or aspiration of animal, vegetable or mineral oil. Most cases are ascribed to aspiration of oil in laxatives or nose drops Petroleum, another pure hydrocarbon used as a base in various medications, is occasionally involved. Especially animal oil produces severe tissue inflammatory reaction, but most patients present with only abnormal chest X-ray and no specific clinical symptoms or signs. Method: Seven patients, 3 males and 4 females, with exogenous lipoid pneumonia, who was hospitalized or referred to pulmonary division at Samsung Medical Center from December 1994 10 July 1996, were included. They hadn a history of laking shark liver oil(so-called "squalene") for varying period of time. We reviewed clinical, radioloic and pathologic findings. Result: Patients look 7 to 30 capsules of "squalene" a day for at least one month to 5 years. Six cases had chronic disease such as diabetes, hypertension, or cerebrovascular accident. Respiratory symptoms of mild fever, cough and sputum were present in 3 cases and in 3 cases there was no clinical symptoms and signs but abnormal findings by chest X - ray. The major radiologic findings by simple chest X - ray and computed tomography consisted of consolidation, infiltration involving mainly right middle and both lower lobes, and ground-glass opacity. Five of six bronchoscopic examinations demonstrated both lipid droplets floating on the surface of bronchoalveolar lavage fluid and Lipid-laden macrophages in bronchoalveolar lavage fluid or lung tissue. Follow-up chest X -ray showed improvement in 4 cases but no marked interval change in 3 cases after removal of exposure to "squalene". Conclusion: Shark liver oil can induce lipoid pneumonia in adults. In case of high clinical suspicion, confirmation of "squalene" use by careful history taking is required and bronchoscopy is helpful in diagnosis.

  • PDF

Numerical Analysis on Flow Characteristics in the Reactor of an Integrated Adsorption/Catalysis Process with Bag Filters (백필터를 활용한 흡착/촉매 통합공정 시스템의 반응기 내 유동특성 및 체류시간에 대한 수치해석적 연구)

  • Choi, Choeng-Ryul;Koo, Yoon-Seo
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.23 no.2
    • /
    • pp.203-213
    • /
    • 2007
  • Numerical analysis has been performed to understand flow characteristics in the reactor with bag filters in an integrated adsorption/catalytic process which can treat dioxin and $NO_{x}$ together. Computational fluid dynamics technique was employed with Euler-Lagrangian model to consider flue gas and activated carbon particles simultaneously, so that residence time of flue gas and activated carbon particle could be obtained from the numerical analysis directly. The numerical analysis has been performed with different three particle sizes and compared each flow characteristics with particle's size. Fundamental flow patterns of flue gas and activated carbon particles, pressure distribution, residence time of flue gas and activated carbon particles, and distribution of activated carbon have been obtained from the numerical analysis. Flow patterns of flue gas and activated carbon particles in the reactor were very complicated and they moved along very various paths. Therefore, their residence time in the reactor was also various. The results obtained would be effectively used to estimate the removal efficiency in the reactor once the residence time is combined with the reaction equation.

Immobilized Small Sized Manganese Dioxide Sand in the Remediation of Arsenic Contaminated Water

  • Tiwari, Diwakar;Laldawngliana, C.;Lee, Seung-Mok
    • Environmental Engineering Research
    • /
    • v.19 no.1
    • /
    • pp.107-113
    • /
    • 2014
  • Small sized manganese dioxide particles are immobilized onto the surface of sand by the wet impregnation process. The surface morphology of the solid, i.e., immobilized manganese dioxide natural sand (IMNS) is performed by taking scanning electron microscope images and characterized by the X-ray diffraction data. The specific surface area of the solid is obtained, which shows a significant increase in the specific surface area obtained by the immobilization of manganese dioxide. The $pH_{PZC}$ (point of zero charge) is found to be 6.28. Further, the IMNS is assessed in the removal of As(III) and As(V) pollutants from aqueous solutions under the batch and column operations. Batch reactor experiments are conducted for various physicochemical parametric studies, viz. the effect of sorptive pH (pH 2.0-10.0), concentration (1.0-25.0 mg/L), and background electrolyte concentrations (0.0001-0.1 mol/L $NaNO_3$). Further, column experiments are conducted to obtain the efficiency of IMNS under dynamic conditions. The breakthrough data obtained by the column experiments are employed in non-linear fitting to the Thomas equation, so as to estimate the loading capacity of the column for As(III) and As(V).

Treatment Study on the Combustion Gas of Medical Waste (의료폐기물 소각가스 처리에 관한 연구)

  • Lee, Sung-Jin;Seo, Man-Chul
    • Journal of environmental and Sanitary engineering
    • /
    • v.23 no.3
    • /
    • pp.1-8
    • /
    • 2008
  • Currently, medical waste stoker incinerator is widely used in the emission control technology of health-care risk waste and miscellaneous contaminated waste. In the past, wet type control technology was used to remove the major harmful gaseous contaminants of medical waste such as HCl, $NO_x,\;SO_2$, CO, DUST, Dioxin. However, the treatment cost for wastewater was high and it has a disadvantage for frozen system during winter season. Therefore, in order to obtain effective treatment, the dry type control technology was developed and widely used to remove the gaseous contaminants. In this study, pre-coated bag filter using hydrated lime, ($Ca(OH)_2$), was applied to the dry type control system and the optimum dose of hydrated lime was investigated. The treatment results showed that the dust collection rate was approximately 26.7%. Moreover, the HCl removal rate using pre-coated bag filter ($50mg/sm^3\;Ca(OH)_2$) was 13.52%, which was significantly higher than 3.26% obtained from conventional bag filter.

Performance of V2O5-TiO2 Catalyst Prepared by Various Methods for Removal of Hydrogen Sulfide Emitted from Steel Smelting Process (다양한 제조방법으로 제조된 V2O5-TiO2 촉매를 이용한 제련공정에서 발생한 황화수소 제거능 비교)

  • Kim, Moon il
    • Journal of Environmental Science International
    • /
    • v.30 no.6
    • /
    • pp.501-505
    • /
    • 2021
  • V2O5-TiO2 catalysts were prepared by various methods. V2O5-TiO2 were prepared by sol-gel method with different drying conditions (aerogel and xerogel), and V2O5 supported on TiO2 obtained by sol-gel method with precipitation-deposition method and impregnation method. The performance of the V2O5-TiO2 catalysts was investigated for the selective oxidation of hydrogen sulfide in the stream containing both ammonia and excess water. All the catalysts showed good dispersion of vanadium and they had high H2S conversion with no or little production of sulfur dioxide. The V2O5-TiO2 aerogel catalyst prepared by sol-gel method with drying under super critical condition had the highest surface area which led to better catalytic activity compared to those by other synthesis methods.