• Title/Summary/Keyword: $NO_x$ & VOC

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PM2.5 Simulations for the Seoul Metropolitan Area: (II) Estimation of Self-Contributions and Emission-to-PM2.5 Conversion Rates for Each Source Category (수도권 초미세먼지 농도모사 : (II) 오염원별, 배출물질별 자체 기여도 및 전환율 산정)

  • Kim, Soontae;Bae, Changhan;Yoo, Chul;Kim, Byeong-Uk;Kim, Hyun Cheol;Moon, Nankyoung
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.4
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    • pp.377-392
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    • 2017
  • A set of BFM (Brute Force Method) simulations with the CMAQ (Community Multiscale Air Quality) model were conducted in order to estimate self-contributions and conversion rates of PPM (Primary $PM_{2.5}$), $NO_x$, $SO_2$, $NH_3$, and VOC emissions to $PM_{2.5}$ concentrations over the SMA (Seoul Metropolitan Area). CAPSS (Clean Air Policy Support System) 2013 EI (emissions inventory) from the NIER (National Institute of Environmental Research) was used for the base and sensitivity simulations. SCCs (Source Classification Codes) in the EI were utilized to group the emissions into area, mobile, and point source categories. PPM and $PM_{2.5}$ precursor emissions from each source category were reduced by 50%. In turn, air quality was simulated with CMAQ during January, April, July, and October in 2014 for the BFM runs. In this study, seasonal variations of SMA $PM_{2.5}$ self-sensitivities to PPM, $SO_2$, and $NH_3$ emissions can be observed even when the seasonal emission rates are almost identical. For example, when the mobile PPM emissions from the SMA were 634 TPM (Tons Per Month) and 603 TPM in January and July, self-contributions of the emissions to monthly mean $PM_{2.5}$ were $2.7{\mu}g/m^3$ and $1.3{\mu}g/m^3$ for the months, respectively. Similarly, while $NH_3$ emissions from area sources were 4,169 TPM and 3,951 TPM in January and July, the self-contributions to monthly mean $PM_{2.5}$ for the months were $2.0{\mu}g/m^3$ and $4.4{\mu}g/m^3$, respectively. Meanwhile, emission-to-$PM_{2.5}$ conversion rates of precursors vary among source categories. For instance, the annual mean conversion rates of the SMA mobile, area, and point sources were 19.3, 10.8, and $6.6{\mu}g/m^3/10^6TPY$ for $SO_2$ emissions while those rates for PPM emissions were 268.6, 207.7, and 181.5 (${\mu}g/m^3/10^6TPY$), respectively, over the region. The results demonstrate that SMA $PM_{2.5}$ responses to the same amount of reduction in precursor emissions differ for source categories and in time (e.g. seasons), which is important when the cost-benefit analysis is conducted during air quality improvement planning. On the other hand, annual mean $PM_{2.5}$ sensitivities to the SMA $NO_x$ emissions remains still negative even after a 50% reduction in emission category which implies that more aggressive $NO_x$ reductions are required for the SMA to overcome '$NO_x$ disbenefit' under the base condition.

Estimation of Vehicle Kilometers Travelled and Air Pollution Emission from Motorcycles (이륜차의 일 주행거리조사와 대기오염 배출량 추정)

  • Jang, Young-Kee;Kim, Jeong;Kim, Pil-Su;Shin, Yong-Il;Kim, Woon-Soo;Choi, Yu-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.48-56
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    • 2010
  • Recently it has reported that the motorcycle is a major source of air pollution in urban area by many studies. But the air pollution emission from motorcycle has been high uncertainty due investigation of a lack of activity data and emission factors in Korea. So in this study, the population of moped and VKT (Vehicle kilometers travelled) of motorcycle are investigated for calculation of the emission from this source categories. As the results, the population of moped is estimated as about 400, 000 and corresponded as 23% of registrated motorcycle which is larger than 50 cc in engine displacement. And it is found that the VKT of moped and motorcycle are investigated as 19.1 km/day and 32.3 km/day. Annual air pollution emission from motorcycle and moped are estimated by investigated VKT and updated emission factors. The nationwide emissions of PM_{10}, CO, $NO_x$, VOC are calculated as 910 ton/yr, 208, 198 ton/yr, 3, 032 ton/yr and 25, 575 ton/yr in 2008. The contribution ratio of CO, VOC emission from these sources are estimated as 29%, 24% in on-road transport sector and it is confirmed that motorcycle and moped are major air pollution sources in urban area.

A Study on the Fail Safety Logic of Smart Air Conditioner using Model based Design (모델 기반 설계 기법을 이용한 지능형 공조 장치의 이중 안전성 로직 연구)

  • Kim, Ji-Ho;Kim, Byeong-Woo
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.12
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    • pp.1372-1378
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    • 2011
  • The smart air condition system is superior to conventional air condition system in the aspect of control accuracy, environmental preservation and it is foundation for intelligent vehicle such as electric vehicle, fuel cell vehicle. In this paper, failure analyses of smart air condition system will be performed and then sensor fusion technique will be proposed for fail safety of smart air condition system. A sensor fusion logic of air condition system by using CO sensor, $CO_2$ sensor and VOC, $NO_x$ sensor will be developed and simulated by fault injection simulation. The fusion technology of smart air condition system is generated in an experiment and a performance analysis is conducted with fusion algorithms. The proposed algorithm adds the error characteristic of each sensor as a conditional probability value, and ensures greater accuracy by performing the track fusion with the sensors with the most reliable performance.

PM2.5 Source Apportionment Analysis to Investigate Contributions of the Major Source Areas in the Southeastern Region of South Korea (동남지역 주요 배출지역의 PM2.5 기여도 분석)

  • Ju, Hyeji;Bae, Changhan;Kim, Byeong-Uk;Kim, Hyun Cheol;Yoo, Chul;Kim, Soontae
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.4
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    • pp.517-533
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    • 2018
  • We utilize the CAMx (Comprehensive Air Quality Model with eXtensions) system and the PSAT (Particulate Source Apportionment Technology) diagnostic tool to determine the $PM_{2.5}$ concentration and to perform its source apportionment in the southeastern region of South Korea. For a year-long simulation, eight local authorities in the region such as Pohang, Daegu, Gyeongju, Ulsan, Busan-Gimhae, Gosung-Changwon, Hadong, and all remaining areas in Gyeongsangnam-do, are selected as source areas based on the emission rates of $NO_x$, $SO_x$, VOC, and primary PM in CAPSS (Clean Air Policy Support System) 2013 emissions inventory. The CAMx-PSAT simulation shows that Pohang has the highest $PM_{2.5}$ self-contribution rate (25%), followed by Hadong (15%) and Busan-Gimhae (14%). With the exception of Pohang, which has intense fugitive dust emissions, other authorities are strongly affected by emissions from their neighboring areas. This may be measured as much as 1 to 2 times higher than that of the self-contribution rate. Based on these estimations, we conclude that the efficiency of emission reduction measures to mitigate $PM_{2.5}$ concentrations in the southeastern region of South Korea can be maximized when the efforts of local or regional emission controls are combined with those from neighboring regions. A comprehensive control policy planning based on the collaboration between neighboring jurisdictional boundaries is required.

A Study on the Change of the Adsorption Process of VOCs in the Materials Prepared from the Intercalation Reaction (층간 삽입반응으로 얻어진 화합물을 이용한 휘발성 유기화합물의 흡착과정 변화에 대한 연구)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.799-806
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    • 2017
  • The potential use of modified clays in the adsorption of vapor phase benzene and toluene was investigated. The modified clays OC-CPC, IOC, and Al-PILC were prepared for comparative purposes and were characterized using infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. It was confirmed the intercalation of the aluminium pillar in IOC and Al-PILC, as well as the introduction of cetylpyridinium. The adsorption studies showed a great affinity of benzene and toluene for OC-CPC due to the hydrophobic character that resulted and also to the increase in the interlaminar distance. IOC showed a lower affinity for the benzene and toluene, followed by Al-PILC. Natual clay had no affinity for benzene and toluene due to its hydrophilic nature. Clay materials having a laminar structure can be chemically modified, changing their physiochemical characteristics, such as interlaminar distance, surface area, pore size, and chemical affinity. In this study, it was focused on obtaining modified clays to be used for the adsorption of volatile organic chemicals.

An Estimation of Age-, Power-, and Type-Specific Emission Inventories for Construction Equipments Using Improved Methodologies and Emission Factors (배출계수 개발 및 배출량 산정 체계 고도화를 통한 건설기계의 연식, 출력 및 기종별 대기오염물질 배출량 산정)

  • Jin, Hyungah;Lee, Taewoo;Park, Hana;Son, Jihwan;Kim, Sangkyun;Hong, Jihyung;Jeon, Sangzin;Kim, Jeongsoo;Choi, Kwangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.6
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    • pp.555-568
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    • 2014
  • The construction equipment is one of the major sources for hazardous air pollutants in Korea, and the its management has been of great concern recently. The objective of this study was to estimate each contribution of emission of construction equipments according to their production year, electric power consumption and type. To achieve this goal, we developed pollutant emission factors for the machineries manufactured after 2009, which are excluded from the present framework of Korean air pollutants inventory, CAPSS. More than 800 data obtained from emission investigations were utilized for the estimation. Compared with the previous estimation, the scheme used this study was modified to incorporate new emission factors as well as to include the corresponding activity data. Such improvement allow us to gain more detailed emission informations which are better characterized by specifications of construction equipments. The total amount of pollutants emitted from construction equipments in 2011 were estimated as 126.8, 7.0, 58.3, and 17.0 kton for $NO_x$, PM, CO, and VOC, respectively. The estimation results indicate that the increase in the emission of equipments is significantly related to their age and power consumption. The emissions of the older ones manufactured from 1992~1996 were estimated to be the contribution ranged from 23.7% to 26.8%, whereas the newer ones (2009~2011) showed the attributions of 11.3~21.5%. In addition, the results show that the emission of each equipment was increased with the increase in the electric power consumption of engine, probably due to their average output power. Among the nine types of machinery compared, excavators and forklifts were investigated to contribute relatively higher emissions in the level of 39.8~44.0% and 32.0~34.2%, respectively.