• Journal of the Korean Institute of Gas
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• v.4 no.2 s.10
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• pp.1-6
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• 2000

In this experiment, we made the plasma reactor which adhere needle electrode in order to treat safely an NOx which was included in the gas. Also we experimently investigated characteristics of equipment and inspected efficiency. As a reaction gas, by using mixture gas of $NO/N_2$ and $N_2/O_2$, we setted up initial NO concentration and gas flow rate was set at 2 ${\iota}$/min. As a reaction characteristics of NOx, when discharge input power was high, NO concentration decreased and when the oxygen concentration increased, the NO decomposition was easy and decomposition energy efficiency was high. Also in case that NO concentration increased, NO decomposition energy efficiency was high but decomposition rate was low. The characteristics of ozone, when discharge input power was high, ozone increased and when $NO/N_2$ concentration increased, the ozone decreased.

• Journal of Environmental Science International
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• v.8 no.1
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• pp.107-113
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• 1999

A new biological nutrient removal system combining $A^2/O$ process with fixed film was developed in this work and the characteristics of denitrification were especially investigated in the combined fixed film reactor(CFFR). Media was added in the anaerobic, anoxic and aerobic reactors, respectively. Tests were made to establish the effluent level of $NO_x-N$, COD, DO and nitrite effects on $NO_x-N$ removal in the CFFR by decreasing hydraulic retention time (HRT) from 10.0 to 3.5 hours and by increasing internal recycle ratio form 0% to 200%. The influent was synthesized to levels similar to the average influent of municipal wastewater treatment plants in Korea. SARAN media with a porosity of 96.3% was packed 40% / 130% / 25% based on its reactor volume, respectively. It was found that COD rarely limited dentrification in the anoxic reactor because of high $C/NO_x/-N$ ratio in the anoxic reactor, while DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent inhibited denitrification in the anoxic reactor. It was proved that the critical points of DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent were 0.15mg/L and 10%, respectively. As the internal recycle ratio increased, DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent increased. Especially, at the condition of internal recycle ratio, 200%, DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent exceeded the critical points of 0.15mg/L and 10%, respectively. Then, denitrification efficiency considerably decreased. Consequently, it was represented that the control of DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent can assure effective denitrification.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.E
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• pp.9-16
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• 1999

This study has been focused on NO conversion for metal-incorporated silicates(Fe-silicate, Mn-silicate, and Fe-Mn-bimetallosilicate) with a similar MFI type. Used metallosilicates were prepared by the rapid crystallization method. Their catalytic performance for the conversion of NO under excess O2(10%) condition with the addition of hydrocarbon of low concentration(1,100ppm n-C8H18) were investigated. As a result, the NO conversion on the Fe-Mn-bimetallosilicate was enhanced compared with on the Fe- or Mn-silicates. Furthermore, the performances for NO concentration on Fe-Mn-bimetallosilicate more increased with an increased in n-C8H18 concentration, a decrease in NO concentration, and an increase in O2 concentration.

• Journal of Environmental Science International
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• v.3 no.4
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• pp.357-365
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• 1994

Air pollution characteristics and the influence of sea breeze on air pollution concentration were studied using the data measured at 7 air quality continuous monitoring stations in Pusan, 1993. Maximum air pollution concentration in Pusan was Gamjeondong for $SO_2$, Sinpyeongdong for TSP, Daeyeondong for $O_3, Kwangbokdong for $NO_2$, Beomcheondong for CO and all substances were under annual ambient air quality standards. Increased rate of concentration for sea breeze was 24.4% for 502, 31.5% for TSP, 8.0% fort $O_3, 26.7% for $NO_2$, 15.7% for CO. Frequencies distribution of $SO_2$, TSP, $O_3$, $NO_2$, and CO concentration for sea breeze moved toward high concentration class.

• Journal of the Korean institute of surface engineering
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• v.52 no.4
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• pp.233-238
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• 2019

The formation behavior of zinc phosphate conversion coating (ZPCC) on SCM430 alloy was investigated in 25 vol.% of 1M ZnO + 170 ml/L solution containing various $Fe(NO_3)_2$ concentrations, using open-circuit potential(OCP), electrochemical impedance spectroscopy(EIS), cyclic polarization(CP) curve and tape peel test. OCP of SCM430 alloy and corrosion current density increased with increasing $Fe(NO_3)_3$ concentration. Resistance of films formed on SCM430 alloy by chemical conversion treatment decreased with increasing $Fe(NO_3)_3$ concentration. Color and adhesion of chemical conversion coatings became darker and worse, respectively, with increasing $Fe(NO_3)_3$ concentration. It is concluded that addition of $Fe(NO_3)_3$ into a zinc phosphating bath leads to faster reaction to form porous surface coatings with poor adhesion and corrosion resistance.

• Journal of ILASS-Korea
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• v.6 no.3
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• pp.1-7
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• 2001

In this study, quantitative measurement of nitric oxide concentration distributions visualization were investigated in the laminar $CH_4/O_2N_2$ nixed flame by Planar laser-induced fluorescence(PLIF). The NO A-X (0,0) vibrational band around 226nm was excited using a XeCl excimer-pumped dye laser. Selecting an appropriate NO transition minimizes interference from Rayleigh scattering and $O_2$ fluorescence. The measurements were taken in $CH_4/O_2N_2$ premixed flame with equivalence ratios varying from $1.0{\sim}1.6$, and a fixed flow rate of 3slpm. NO was found to produce primarily between an inner premixed and an outer nonpremixed flame front, and total NO concentration is raised when equivalence ratios increase. These results suggest that prompt NO is likely to contribute to MO formation in $CH_4/O_2N_2$ premixed flame. Furthermore, this trend was well matched with previous works.

• Korean Journal of Agricultural and Forest Meteorology
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• v.13 no.4
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• pp.165-170
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• 2011

The ambient concentrations of nitrogen dioxide ($NO_2$) at 65 forest areas were measured every month using passive diffusive samplers from 2002 to 2009 and were compared to those at urban areas in order to investigate the characteristics of temporal and spatial distributions of $NO_2$ from the forest and urban areas. The annually averaged concentrations of $NO_2$ gradually decreased for both areas. The average concentration of $NO_2$ in the forest areas was 8.0 ppb, which was lower than that in the urban areas (i.e., 19.4 ppb) and the ecological standard level of the European Union (i.e., 14.6 ppb). The monthly average of $NO_2$ concentration depicted seasonal variations particularly in the urban areas, showing higher concentration in winter and lower concentration in summer. Strong locality of $NO_2$ concentration distribution illustrates that the locations near the metropolitan areas (e.g., Gyeonggi and Chungnam provinces) had the highest concentration during the measurement period. A significant positive correlation between $NO_x$ emissions and $NO_2$ concentration was observed, suggesting that the magnitude and proximity to sources of atmospheric nitrogen oxides would be important controlling factors.

• Journal of Korean Society for Atmospheric Environment
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• v.9 no.1
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• pp.107-115
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• 1993

This study was carried out to find the characteristics of surface ozone concentration data obtained during 1988-1991 by the Korea Ministry of Environment. Seasonal data (spring, summer, autumn and winter) wre obtained in May, August, November and February respectively at Kwanghwamun in Seoul. The pollutants analyzed in this study are $SO_2, TSP, CO, NO, NO_2 and NO_2/NO$. Atmospheric factors such as solar radiation, wind speed, relative humidity, cloud amount and atmospheric temperature are also analyzed. The influence of pollutants and atmospheric factors that affect ozone concentration were analyzed by statistical method. The results are summarized as follows : 1. The ozone concentration varied seasonally. The maximum values were 23 ppb in spring, 33 ppb in summer, 16 ppb in autumn and 13 ppb in winter. So the seasonal ozone value was highest in Summer. 2. Te diurnal concentration of ozone was highest during 2-4 P. M. and was very low in the morning and evening. 3. The maximal correlation coefficients of each season between ozone concentration and the influencing pollutants or atmospheric factors asr as follows ; a. spring, r = 0.44(solar radiation) b. summer, r = -0.59(relative humidity) c. autumn, r = -0.55(relative humidity) d. winter, r = -0.58($NO_2$) 4. The major factor affecting the ozone concentration in spring was solar radiation, Relative humidity was the first affecting factor in summer, autumn and $NO_2$ concentration was dominant in winter.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.4
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• pp.422-434
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• 2016

This study was conducted to understand roles of $NO_x(=NO+NO_2)$ on high $O_3$ episodes at an urban monitoring station in Seoul. Concentrations of NO, $NO_2$, $NO_y$ and $O_3$ were measured intensively at KIST monitoring station which located at urban center in Seoul metropolitan area during May 18~June 13, 2015. Sampling period was planed because high $O_3$ and PM occurred frequently during from late spring to early summer months in Seoul. The experimental site locates in NW from center of Seoul and is surrounded by residential area. Belt highway of the city runs from north to west side nearby experimental site. Vehicle exhaust emissions due to heavy traffic influenced $NO_x$ concentration at the site during northwesterly wind. Specific $NO_2$ concentration was measured by Blue Light photolytic converter, and it was compared to $NO_2$ concentration measured by molybedenum converter. $[NO_2]_{phtolysis}$ was usually lower than $[NO_2]_{molybedenum}$ during the experiment period; however their diurnal variations were very similar. The linear relationship between these $NO_2$ concentrations was found to be $[NO_2]_{phtolysis}$=0.64 $[NO_2]_{molybedenum}$ - 2.6, $r^2$=0.83 during May 16~8, 2015. The difference between $NO_2$ by molybdenum converter and by photolytic converter (${\Delta}NO_2=[NO_2]_{molybedenum}-[NO_2]_{phtolysis}$) accounted for residual $NO_y$ which can represent $NO_z$ (=$NO_y-NO_x$). $O_3$ concentration showed typical daily trend which has maximum at late afternoon and minimum during the night. $O_3$ increased at a rate of 7 ppb/hr since 8 am. and reached the maximum concentration (~80 ppb) at 3 pm.. The diurnal pattern of $O_3$ was inversely related with that of $NO_2$, suggesting that the formation of $O_3$ was the result of photochemical activity of $NO_2$.

• Environmental Analysis Health and Toxicology
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• v.18 no.2
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• pp.69-76
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• 2003

Effects of ambient nitrite, NO$_2$$\^$-/, at 1, 3, 10 and 30 mg/1, on the changes of plasma nitrite/nitrate and on hepatic drug - metabolizing enzyme activity were examined in the juvenile Israeli carp, Cyprinus carpio. When the fish were exposed to 1 and 3 mg/1 NO$_2$$\^$-/, there was an exposure duration-dependent increase in plasma NO$_2$$\^$-/ over the 96-hr period reaching 6∼7 fold excess the ambient concentration. In the fish exposed to 10 mg/1, a plateau concentration of less than 2-fold of the environment was attained in 12 hr. With 30 mg/1, however, the maximal plasma NO$_2$$\^$-/ was 41.25 mg/1 at 12 hr followed by a gradual decline. There was a concentration-dependent increase in methemoglobin (metHb) level in all NO$_2$$\^$-/ -exposed groups and a significant decrease in hematocrit value in 30 mg/l group after 96-hr exposure. Apart from the blunted increase in plasma NO$_2$$\^$-/ with higher NO$_2$$\^$-/ (10 and 30 mg/1) exposure, the ratio of plasma NO$_3$$\^$-/ to NO$_2$$\^$-/ was signifirantly higher in these groups compared to 1 and 3 mg/1. The imbalance in the plasma NO$_3$$\^$-//NO$_2$$\^$-/ at higher NO$_2$$\^$-/ exposure suggests a possible accelerated conversion of NO$_2$$\^$-/ to NO$_3$$\^$-/. Nitrite exposure did not affect the hepatic drug-metabolic activities in juvenile Israeli carp. All these data indicate that disposition of NO$_2$- differ depending upon exposed concentration and that metHb production may not be the exclusive toxic mechanism in carp.