• 대한환경공학회지
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• 제33권5호
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• pp.368-377
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• 2011

소규모의 대기오염 배출원으로부터 질소산화물을 저감하는 방법으로 제안된 패키지형 SCR (selective catalytic reduction) 시스템 내에서 암모니아 농도제어에 관한 연구가 시행되었다. SCR 시스템의 효율은 촉매층의 효율적인 활용에 좌우되며 촉매층의 효율적인 사용은 시스템에 유입되는 배기가스의 유동균일도와 암모니아 농도의 균일도에 의해 좌우된다. 본 연구에서는 주어진 최적의 유동조건에서 SCR 시스템 내에 배치된 AIG 형상과 분사 유량 조정에 따른 암모니아 농도분포를 평가하였다. 기본 유동조건에서 분사구의 각도에 따른 전산해석 결과, 배가스 유동에 대해 동류방향($0^{\circ}$)으로 암모니아를 분사한 경우의 농도분포의 RMS(%) 수치는 약 95.3%, 대향방향인 $120^{\circ}$의 각도를 가지는 경우 90.1%로 파악되어 대향방향으로의 분사가 더 효율적인 것으로 파악되었다. 유동박리영역에서 벗어나도록 분사구의 위치를 변경하고 기초계산에서의 속도분포와 농도분포를 기준으로 환원제 유량을 조정한 결과 RMS(%) 수치를 최대 62.8%까지 하강시키는 효과를 가져왔다. AIG 형상 및 배치구조에 혼합증진의 효과를 정리하였다.

• 한국가스학회지
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• 제23권3호
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• pp.20-26
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• 2019

석탄 화력발전소 등의 대형 연소기기에서 질소산화물을 저감하기 위해 선택적 촉매환원 방법(SCR)의 탈질설비가 널리 쓰이고 있다. 본 연구에서는 SCR 탈질설비에서 암모니아를 공급하는 암모니아 분사 그리드(AIG)에 있는 암모니아와 희석 공기 혼합기에서 암모니아와 희석 공기의 균일한 혼합에 적합한 최적의 혼합기 형상을 도출하는 것을 목적으로 전산유체해석을 통해 수행하였다. 이를 위해 기본 형상의 혼합기(Case 1)에서 유동 특성과 $NH_3$ 농도 분포 특성을 살펴보았다. 기본 형상의 혼합기에서는 희석 공기 주 배관에서 암모니아 주입 배관 입구 반대쪽의 벽면으로 $NH_3$ 분포가 치우치는 것을 확인하였다. 이를 개선하기 위해 암모니아 주입 배관의 상단 구멍 1 개와 측면 구멍 4개를 막은 경우(Case 2)와 암모니아 주입 배관의 상단에 수평 평판을 설치한 경우(Case 3), 수평 평판과 함께 원호 평판을 설치 한 경우(Case 4)의 혼합기 형상에 대하여 유동과 $NH_3$ 농도 분포 특성을 분석하였다. 암모니아 주입 배관 상단에 수평 평판과 원호 평판을 설치한 경우(Case 4)에 혼합기 출구에서 $NH_3$ 분포의 % RMS 값이 가장 작은 값인 4.92%이고 농도 비율($R_{NH3}$) 범위가 -10.82~8.34%로 가장 최적의 $NH_3$ 균일 분포임을 알 수 있었다.

• Asian Journal of Atmospheric Environment
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• 제12권1호
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• pp.59-66
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• 2018

This study aims to evaluate the performance of the Air Quality Model (AQM) for the seasonal and spatial distribution of the $NH_3$ concentration in the atmosphere. To obtain observational data for the model validation, observations based on biweekly sampling have been conducted using passive samplers since April 2015 at multiple monitoring sites in the Tokyo metropolitan area. AQM, built based on WRF/CMAQ, was applied to predict the $NH_3$ concentration observed from April 2015 to March 2016. The simulation domain includes the Kanto region, which is the most densely populated area in Japan. Because the area also contains large amount of livestock, especially in its northern part, the density of the $NH_3$ emissions derived from human activities and agriculture there are estimated to be the highest in Japan. In the model validation, the model overestimated the observed $NH_3$ concentration in the summer season and underestimated it in the winter season. In particular, the overestimation in the summer was remarkable at a rural site (Komae) in Tokyo. It was found that the overestimation at Komae was caused by the transportation of $NH_3$ emitted in the northern part of the Kanto region during the night. It is suggested that the emission input used in this study overestimated the $NH_3$ emission from human sources around the Tokyo suburbs and agricultural sources in the northern part of the Kanto region in the summer season. In addition, the current emission inventories might overestimate the difference of the agricultural $NH_3$ emissions among seasons. Because the overestimation of $NH_3$ in the summer causes an overestimation of $NO_3{^-}$ in $PM_{2.5}$ in the AQM simulation, further investigation is necessary for the seasonal variation in the $NH_3$ emissions.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2010년도 춘계학술대회 논문집
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• pp.621-623
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• 2010

• 한국대기환경학회지
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• 제4권2호
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• pp.57-66
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• 1988

Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul and suspended particulate was collected by Andersen air sampler during this period. The samples were analyzed for 16 components $(SO_n^{2-}, NO_3^-, Cl^-, PO_4^{3-}, NH_4^+, F^-, Al, Fe, K, Cu, Mn, Na, Pb, Mg, Ca, Cd)$. The conclusions are as follwes: 1. Total suspended particulate concentation during the period of sandy dust phenomena was 489 $\mug/m^3$ (ordinary times: 140-125 $mug/m^3$) 2. The water - soluble ion component concentration of suspended particulate during the period of sandy dust phenomena was few and the metal concentration of that was more than that of ordinary times. 3. The cumulative frequency distribution of suspended particulates in logarithmic diagram did not show similar to normal log distribution during the period of sandy dust phenomena. 4. $SO_4^{2-}, NO_3^-, Cl^-, and PO_4^{3-}$ was onsided to coarse particle, and $NH_4^+$ and F to fine particle in the size distribution of water - soluble ion components during the period of sandy dust phenomena. 5. Metal concentration was high and Al, Fe, Cu, Mn, Na, Mg, and Ca was onsided to coarse particle, and K, Pb, and Cd to fine particle in the size distribution of metal components. 6. During the period of sandy dust phenomena the quantity of respirable particle (< 1 $\mum$) was about 3 times and that of metal components were about 2 - 11 times than that of ordinary times. 7. The concentrations of $NO_3^-, Cl^-, NH_4^+$ at ordinary times were 1.1 - 4 time than that of the period of sandy dust phenomena.

• 한국대기환경학회지
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• 제12권4호
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• pp.377-387
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• 1996

This study was carried out to monitor the visibility including measurement and analysis of the various parameters such as particle size distribution, chemical composition, and meteorotical conditions to understand the characteristics and causes of this phenomenon. According to the analysis of intensive sampling, $SO_4^{2-}, NO-3^-, Cl^-, NH_4^+$ ion concentration increased together with the mass concentration around 1 $\mu$m in the case of low visibility. $(NH_4)_2SO_4, NH_4NO_3$, and $NH_4Cl$ were thought to be the major components of fine particles. The statistical analysis showed that the scattering effect of particle was 81.2%, the absorption effect was 14.9%. Therefore, these effects were the major factors to reduce the visibility. In conclusion, the visibility was reduced by the fine particle of sulfate (18.6%), nitrate (14.2%), organic carbon (10.8%), element carbon (25.8%), and residual (24.8%) during this study.

• 한국환경보건학회지
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• 제22권4호
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• pp.55-61
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• 1996

Measurements of the seasonal variations of concentration and size distribution of TSP, $SO_4^{2-}, NO_3^-, Cl^-, NH_4^+, Na^+, K^+, Ca^{2+}$ and $Mg^{2+}$ were made by Andersen air sampler from May 1995 to April 1996 in Seoul. The size distribution of these ions was divided into four patterns. 1) Distribution was concentrated on fine particles over a year such as $NO_3^-$ component, 2) Distribution was predominated in coarse particles fraction over a year such as $Mg^{2+}$ and $Ca^{2+}$ components, 3) Distribution was differerent from various seasons such as $NH_4^+, SO_4^{2-}, Cl^-$ and $K^+$ components, 4) Distribution was bi-modal such as $Na^+$.

• 한국물환경학회지
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• 제37권2호
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• pp.92-102
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• 2021

In this study, the distribution characteristics according to the type of BOD and the effect of nitrogenous oxygen demand (NOD) and algal oxygen demand on BOD in three streams (Bokhacheon, Byeongseongcheon, and Gulpocheon) were evaluated. Although the BOD and NOD concentrations demonstrated a difference in the three streams, the carbonaceous BOD(CBOD)/BOD ratio was 0.75 (p=0.053, one-way ANOVA), and there was no significant difference in the three streams (r2≥0.92, p<0.0001). The NOD concentration of the Bokhacheon with high NH3-N was 1.7±1.3 mg/L, which was the highest among the three streams and showed a significant correlation with BOD. Seasonal variations in NOD in the three streams did not show a significant correlation with changes in NH3-N concentration (r2<0.28, p≥0.1789), and there was no significant difference in NOD even though NH3-N concentration in Gulpocheon was about twice that of Byeongseongcheon (p=0.870, one way ANOVA). The particulate CBOD(PCBOD)/CBOD ratio of the three streams was 0.55~0.64, and about 60% of the biodegradable organic matter was present in the particulate form. When the Chl.a concentration in the stream was more than 7 ㎍/L, the PCBOD tended to increase with the Chl.a concentration (r2=0.61, p=0.003). In the three streams, particulate NOD accounted for 81% of NOD; however, despite the large variation in NH3-N concentration (0.075~3.182 mg/L), there was no significant difference in soluble NOD(SNOD) concentration that ranged from 0.1 to 0.3 mg/L. In this study, the low contribution rate of SNOD to NOD is considered as a result of the removal of nitrifying bacteria along with the particles during the filtration process.

• 한국물환경학회지
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• 제30권5호
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• pp.503-511
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• 2014

The temporal and spatial analyses of total nitrogen (TN) fractionation were conducted in order to understand 1) total nitrogen components in streams and 2) their patterns in rainy and dry seasons. The result showed that the concentration of nitrogen components in stream water was lower in non-urban area and getting higher in urban area. Dissolved total nitrogen (DTN) was 95~97.7% of total nitrogen in streams, and the proportion of dissolved organic nitrogen (DON) and ammonia nitrogen ($NH_3-N$) was higher with increasing urban area. The concentration of total nitrogen and nitrate nitrogen ($NO_3-N$) were highest in winter among four seasons. The result was showed that concentration of $NH_3-N$ was same variation as concentrations of TN and $NO_3-N$ in urban-rural complex and urban areas, except rural areas. During rainy season, concentrations of particulate organic nitrogen (PON) and $NH_3-N$ increased in rural areas and decreased in both urban-rural complex and urban areas. Correlation between total nitrogen components and land uses was positively correlated with site > paddy, and negatively correlated with forest. The variation of total nitrogen concentration was determined by $NO_3-N$ in non-urban areas, by $NO_3-N$ and $NH_3-N$ in urban-rural complex and by $NH_3-N$ in the urban areas.

• 한국해양학회지:바다
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• 제12권1호
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• pp.1-8
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• 2007

유기물 증가에 미치는 환경인자를 중심으로 그 수평분포 특성, 원인, 주요오염원의 영향권에 대하여 검토하기 위해 표층 해수와 표층 퇴적물을 조사하였으며, 그 결과를 요약하면 다음과 같다. 유기물변동에 영향을 미치는 환경인자에 대한 주요 오염원은 크게 섬진강과 동천 등의 담수, 광양시 생활하수, 여수산업단지로 크게 나누어볼 수 있었다. 해수와 퇴적물의 환경인자에 대한 수평분포 특성과 해수의 흐름 등을 고려하여 이들 주요 오염원의 영향권을 구분한 결과, (I) 섬진강 담수의 영향을 많이 받는 해역, (II) 광양시와 동천의 영향이 큰 해역, (III) 여수 산업단지의 영향을 많이 받는 해역으로 나누어졌다. 그리고, 오염원의 영향권 별 수질환경인자의 특성으로는 섬진강 담수의 영향을 많이 받는 해역은 낮은 염분, 높은 농도의 $NO_3-N$과 $SiO_2-Si$, 담수와 생환하수의 영향이 큰 해역은 낮은 염분, 높은 농도의 $NO_3-N,\;NH_4-N,\;SiO_2-Si$, 여수 산업단지의 영향을 많이 받는 해역은 표층해수의 경우 높은 수온, 높은 농도의 $NH_4-N$과 $PO_4-P$, 퇴적물의 경우 높은 농도의 $NH_4-N,\;PO_4-P,\;SiO_2-Si$로 특징 지울 수 있을 것으로 보인다.