• Title/Summary/Keyword: $MnO_{2}$

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Effect of Re-oxidation on the Electrical Properties of Mutilayered PTC Thermistors (적층 PTC 써미스터의 전기적 특성에 대한 재산화의 영향)

  • Chun, Myoung-Pyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.2
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    • pp.98-103
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    • 2013
  • The alumina substrates that Ni electrode was printed on and the multi-layered PTCR thermistors of which composition is $(Ba_{0.998}Ce_{0.002})TiO_3+0.001MnCO_3+0.05BN$ were fabricated by a thick film process, and the effect of re-oxidation temperature on their resistivities and resistance jumps were investigated, respectively. Ni electroded alumina substrate and the multi-layered PTC thermistor were sintered at $1150^{\circ}C$ for 2 h under $PO_2=10^{-6}$ Pa and then re-oxidized at $600{\sim}850^{\circ}C$ for 20 min. With increasing the re-oxidation temperature, the room temperature resistivity increased and the resistance jump ($LogR_{290}/R_{25}$) decreased, which seems to be related to the oxidation of Ni electrode. The small sized chip PTC thermistor such as 2012 and 3216 exhibits a nonlinear and rectifying behavior in I-V curve but the large sized chip PTC thermistor such as 4532 and 6532 shows a linear and ohmic behavior. Also, the small sized chip PTC thermistor such as 2012 and 3216 is more dependent on the re-oxidation temperature and easy to be oxidized in comparison with the large sized chip PTC thermistor such as 4532 and 6532. So, the re-oxidation conditions of chip PTC thermistor may be determined by considering the chip size.

Evaluation of the Microstructures and Mechanical Properties on Friction Welded A6063 Alloy (마찰접합 된 A6063 합금의 미세조직과 기계적 특성 평가)

  • Kim, Eun-Hye;Cho, Hyung-Hwan;Song, Kuk-Hyun
    • Korean Journal of Materials Research
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    • v.27 no.5
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    • pp.276-280
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    • 2017
  • This study was carried out to evaluate the developed microstructures and mechanical properties of friction welded A6063 alloy. For this work, specimens were prepared at a size of 12 mm ${\O}{\times}80mm$, and friction welding was carried out at a rotation speed of 2,000 RPM, friction pressure of $12kgf/cm^2$ and upset pressure of $25kgf/cm^2$. To perform an analysis of the grain boundary characteristic distributions, such as the grain size, orientation and misorientation angle distributions, the electron back-scattering diffraction method was used. In addition, in order to identify the dispersed intermetallic compounds of the base and welded materials, transmission electron microscopy was used. The experimental results found that the application of friction welding on A6063 led to significant grain refinement of the welded zone relative to that of the base material. Besides this, intermetallic compounds such as AlMnSi and $Al_2Cu$ were found to be dispersed with more refined size relative to that of the base material. This formation retains the mechanical properties of the welds, which results in the fracture aspect at the base material zone. Therefore, based on the developed microstructures and mechanical properties, the application of friction welding on A6063 could be used to obtain a sound weld zone.

Physicochemical Characteristics of Dredged Soils in Reservoirs (저수지 준설대상 토양의 이화학적 특성)

  • 손재권;구자웅;최진규
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.3
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    • pp.96-107
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    • 1997
  • This study was carried out to examine the physicochemical characteristics of dredged soils in reservoirs. Surveys and analyses of basic materials were made on 241 of 2,328 reservoirs in Chonbuk province through 2 years from December 1994 to November 1996. The results of this study are summarized as follows : 1. Soils were classified as 15 types according to physical properties, and some soils contain comparatively high percentage of sand and gravel. Considering only soil textures, useful and economical soils as aggregate are approximately 25% in all, and the other soils are arable for farm planting. 2. The results of chemical analyses of soils showed on the average 5.9 in pH, 1.lmmhos/cm in ECe, 14.6me/l00g in CEC, 460.0ppm in T-N, 119.0ppm in T-P, 264.9ppm in K, 134.2ppm in Na, l,335.0ppm in Ca, 575.9ppm in Mg, 486.Sppm in Fe, 57.7ppm in Mn, 3.3ppm in Cu, 21.9ppm in Zn, 0.49ppm in As, 0.34ppm in Cd, 0.O3ppm in Hg, 1.7% in OM, respectively. 3. General chemical components, heavy metals, organic matter contents were analyzed as similar to tlie mean values of common soils, therefore it was considered to be no significant effects on crop growth in the chemical properties. 4. Accodingly, the physicochemical characteristics of soils ought to be analyzed accurately before dredging for effective using of dredged soils. And it will be more effective, if the dredged soils are used with proper balance among each content of components with considering to the physicochemical properties of common soils.

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Study on the Reduction of NPS Pollution and GHG Emission from Paddies with SRI Methods (SRI 방법을 적용한 논에서의 비점오염원 및 온실가스 저감효과)

  • Park, Woon-Ji;Lee, Su-In;Yun, Dong-Koun;Kim, Gun-Yeob;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.440-440
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    • 2012
  • 본 연구에서는 수질관리 및 기후변화(온실가스 저감) 등에 부응할 수 있는 SRI 벼재배 방법을 국내 논에 적용하여 농업비점오염원과 온실가스 저감효과를 측정하고 비교하여 SRI의 환경개선효과를 평가하고자 하였다. 시험포는 대조구인 상시담수처리구(관행, 재식거리 $30{\times}15cm$)와 SRI 물관리 처리구로 조성하였다. 각 시험포에는 관개배수시설 및 관개량을 측정할 수 있는 수도계량기, 유출량 측정을 위한 플륨 및 수위계 그리고 온실가스(메탄 및 이산화질소)를 측정하기 위한 아크릴재질의 Chamber를 설치하였다. 관행 및 SRI 시험포에 이앙할 모의 재배품종으로 오대벼를 공시하고 모든 시험포의 경우 1주당 3-5본씩 기계이앙을 실시하였으며, 물관리를 제외한 시비와 제초 등의 영농관리는 동일하게 수행하였다. 메탄($CH_4$)과 아산화질소($N_2O$)는 주 2회, 오전 9시 12시에 60 mL 주사기로 주기적으로 시료를 채취하여 GC로 분석하였다. 그리고 관개기간동안 관개량, 강우량 그리고 강우 유출량을 측정하고 수질시료를 채취하여 오염부하를 산정하였다. SRI 시험포의 SS, $COD_{Cr}$, $COD_{Mn}$, BOD, TN, TP의 총 오염부하량은 각각 583 kg/ha, 210.8 kg/ha, 70.1 kg/ha, 30.7 kg/ha, 56.1 kg/ha, 3.55 kg/ha로서 관행 시험포의 오염부하량에 비해 27.1~46.0%의 오염물질 저감 효과를 보였다. 그리고 각 시험포별 온실가스 메탄과 아산화질소의 총 배출량을 지구온난화잠재력(GWP)으로 환산하여 이산화탄소($CO_2$) 기준으로 산정한 결과, 관행은 14.2 톤/ha 그리고 SRI 물관리 처리구 4.0 톤/ha로 관행 대비 SRI 처리구에서 71.8%의 온실가스 감축효과를 나타내었다. 따라서 SRI 벼재배기술은 논 비점오염부하 및 온실가스 저감을 위한 효과적인 최적영농관리방법인 것으로 판단된다.

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Production of Adventitious Ginseng Roots Using Biorectors

  • Yu, Kee-Won;Hahn, Eun-Joo;Paek, Kee-Yoeup
    • Korean Journal of Plant Tissue Culture
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    • v.27 no.4
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    • pp.309-315
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    • 2000
  • Panax ginseng is an important medicinal plant that has been used worldwide for geriatric, tonic, stomachic, and aphrodisiac treatments. Ginsenosides contained in the ginseng root are the main substances having active functions for human body. The price of ginseng is very expensive due to a complex process of cultivation, and the yield of ginseng is limited, which cannot meet the demand of the increasing market. Researchers have applied plant biotechnology to solve the problems but there are still things to be determined towards ginsenoside production by large-scale adventitious root culture. In this experiment, 5 to 20 liter bioreactors were employed to determine optimal conditions for adventitious root culture and ginsenoside production of Panax gineng. Callus was induced from the ginseng root on MS agar medium containing 1.0 mg. $L^{-1}$ 2,4-D and 0.1 mg. $L^{-1}$ kinetin. Then the callus was cultured on MS agar medium supplemented with 2.0 mg. $L^{-1}$ IBA, 0.1 mg. $L^{-1}$ kinetin, and 30 g. $L^{-1}$ to induce adventitious roots. The maximum root growth and ginsenoside production were obtained in 1/2 MS medium. 2.0 mg. $L^{-1}$ naphthalene acetic acid resulted in greater root growth than 2.0 mg $L^{-1}$ indole-3-butyric acid. Ginsenoside content increased with 2.0 mg. $L^{-1}$ benzyl adenin or kinetin. High concentrations of benzyl adenin (above 3.0 mg. $L^{-1}$ ) decreased the adventitious root growth and ginsenoside productivity. N $H_{4}$$^{+}$ inhibited the ginsenoside accumulation, while high concentrations of $K^{+}$, $Mg_{2}$$^{+}$, and $Ca_{2}$$^{+}$ increased it. N $H_{4}$$^{+}$ at 0.5 and 1.0 times of the normal amount in 3/4 SH medium resulted in the greatest biomass increase, but the highest ginsenoside productivity was obtained when N $O_{3}$$^{-}$ was used as the sole nitrogen source in the medium. Most microelements at high concentrations in the medium inhibited the root growth, but high concentrations of MnS $O_4$enhanced the root growth. Root dry weight increased with increasing sucrose concentrations up to 50 g. $L^{-1}$ , but decreased from 70 g $L^{-1}$ Ginsenoside productivity was maximized at the range of 20 to 30 g. $L^{-1}$ sucrose. In the experiment on bioreactor types, cone and balloon types were determined to be favorable for both adventitious root growth and ginsenoside production. Jasmonic acid was effective for increasing ginsenoside contents and Rb group ginsenosides mainly increased. These results could be employed in commercial scale bioreactor cultures of Panax ginseng.x ginseng.

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Geochemical Characteristics of Intertidal Surface Sediments along the Southwestern Coast of Korea (한국 서해남부 조간대 표층 퇴적물의 지화학적 특성)

  • Hwang, Dong-Woon;Ryu, Sang-Ok;Kim, Seong-Gil;Choi, Ok-In;Kim, Seong-Soo;Koh, Byoung-Seol
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.43 no.2
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    • pp.146-158
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    • 2010
  • In order to evaluate the characteristics of sediments and pollution by organic matter and metallic elements in intertidal sediments along the southwestern coast of Korea, we measured various geochemical parameters, including the mean grain size (Mz), water content (WC), ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and metallic elements (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, As), in intertidal surface sediments. The Mz of the surface sediments ranged from 2.1 to 8.3$\phi$, indicating that the surface sediments consist of various sedimentary facies, such as sand, slightly gravelly mud, sandy mud, and silt. The IL and COD in surface sediment ranged from 0.8 to 5.5% (mean $2.9\pm1.2%$) and from 3.9 to $13.8\;mgO_2/g{\cdot}dry$ (mean $8.5\pm2.6\;mgO_2/g{\cdot}dry$), respectively, which were lower than the values for surface sediment in areas near fish and shellfish farms or industrial complexes. No AVS was detected at any sampling station, despite various sedimentary facies. Most of metallic elements in surface sediments showed relatively good positive correlations with Mz and IL, which imply that the concentrations of metallic elements are mainly controlled by grain size and the organic matter content. The concentrations of metallic elements, except As, at some stations were considerably lower than those in the Sediment Quality Guideline (Effect Range Low, ERL) proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Similarly, the geoaccumulation index (Igeo) class indicated that pollution by metallic elements in intertidal surface sediment, except As, was moderate or non-existent. Our results imply that the intertidal surface sediments along the southwestern coast of Korea are not polluted by organic matter and metallic elements and are healthy for benthic organisms.

Geochemistry and Mineralogy of Mine Drainage Water Precipitate and Evaporite Minerals in the Hwasoon Area (화순 폐탄광지역 광산배수와 침전 및 증발잔류광물에 대한 지구화학적 및 광물학적 연구)

  • 박천영;정연중;강지성
    • Economic and Environmental Geology
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    • v.33 no.5
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    • pp.391-404
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    • 2000
  • This study investigated the geochemical characteristics of mine drainage discharged from an abandoned coal mine in the Hwasoon area. Surface water samples were collected from 23 locations along the Hancheon creek. The concentration of Zn and Cu in stream waters was highest at low pH (3.53), whereas the content of TDS and TDI was highest at high pH (7.78) due to the concentration of Ca, $HCO_3$ and $SO_4$. At the upstream site, the Ba, Fe, Mn, Zn, and $SO_4$ contents were relatively high but decreased significantly with the distance from the coal mine. On the contrary, the Na and $NO_3$ contents were low at the upstream site but increased downstream. Yellow precipitate material collected in the Hancheon consisted mainly of iron and LOI. This yellow precipitate was heated from 100 to $900^{\circ}C$ for 1 hour. With increasing temperature, the intensity of hematite peaks were sharply produced in X-ray pattern and the absorption band Fe-O of hematite increased in IR due to dehydration and melting. The yellow to brown precipitate and evaporite materials were collected by a air-dry from the acid mine water at the laboratory. After drying, the concentration of ions in the acid water samples increased progressively in oversaturation with respect to either gypsum, ferrohexahydrite or quenstedetite. The X-ray powder diffraction studies identified that the precipitated and evaporated materials after drying were well crystallized gypsum, ferrohexahydrite and quenstedetite. Diagnostic peaks used for identification of gypsum were the 7.65, 4.28, 3.03, 2.87 and 2.48$\AA$ peaks and those for ferrohexahydrite were the 5.46, 5.12, 4.89, 4.44, 4.05, 3.62, 3.46, 3.40, 3.20, 3.03, 2.94, 2.53, 2.28, 2.07, 1.88 and 1.86${\AA} peaks. The IR spectra with OH-stretching, deformation of $H_2O$and ${SO_4}^{2-}$stretching vibration include the existence of gypsum, ferrohexahydrite and quenstedetite in the precipitated and evaporite materials. In the SEM and EDS analysis for the evaporite material, gypsum with well-crystallized, acicular, and columnar form was distinctly observed.

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Evaluation of the Nutrient Removal Performance of the Pilot-scale KNR (Kwon's Nutrient Removal) System with Dual Sludge for Small Sewage Treatment (소규모 하수처리를 위한 파일럿 규모 이중슬러지 KNR® (Kwon's nutrient removal) 시스템의 영얌염류 제거성능 평가)

  • An, Jin-Young;Kwon, Joong-Chun;Kim, Yun-Hak;Jeng, Yoo-Hoon;Kim, Doo-Eon;Ryu, Sun-Ho;Kim, Byung-Woo
    • Clean Technology
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    • v.12 no.2
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    • pp.67-77
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    • 2006
  • A simple dual sludge process, called as $KNR^{(R)}$ (Kwon's Nutrient Removal) system, was developed for small sewage treatment. It is a hybrid system that consists of an UMBR (Upflow multi-layer bioreactor) as anaerobic and anoxic reactor with suspended denitrifier and a post aerobic biofilm reactor, filled with pellet-like media, with attached nitrifier. To evaluate the stability and performance of this system for small sewage treatment, the pilot-scale $KNR^{(R)}$ plant with a treatment capacity of $50m^3/d$ was practically applied to the actual sewage treatment plant, which was under retrofit construction during pilot plant operation, with a capacity of $50m^3/d$ in a small rural community. The HRTs of a UMBR and a post aerobic biofilm reactor were about 4.7 h and 7.2 h, respectively. The temperature in the reactor varied from $18.1^{\circ}C$ to $28.1^{\circ}C$. The pilot plant showed stable performance even though the pilot plant had been the severe fluctuation of influent flow rate and BOD/N ratio. During a whole period of this study, average concentrations of $COD_{cr}$, $COD_{Mn}$, $BOD_5$, TN, and TP in the final effluent obtained from this system were 11.0 mg/L, 8.8 mg/L, 4.2 mg/L, 3.5 mg/L, 9.8 mg/L, and 0.87/0.17 mg/L (with/without poly aluminium chloride(PAC)), which corresponded to a removal efficiency of 95.3%, 87.6%, 96.3%, 96.5%, 68.2%, and 55.4/90.3%, respectively. Excess sludge production rates were $0.026kg-DS/m^3$-sewage and 0.220 kg-DS/kg-BOD lower 1.9 to 3.8 times than those in activated sludge based system such as $A_2O$ and Bardenpho.

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Biological Control of Anthracnose (Colletotrichum gloeosporioides) in Red Pepper by Bacillus sp. CS-52 (Bacillus sp. CS-52를 이용한 고추 탄저병 (Colletotrichum gloeosporioides) 방제 특성)

  • Kwon, Joung-Ja;Lee, Jung-Bok;Kim, Beam-Soo;Lee, Eun-Ho;Kang, Kyeong-Muk;Shim, Jang-Sub;Joo, Woo-Hong;Jeon, Chun-Pyo;Kwon, Gi-Seok
    • Korean Journal of Microbiology
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    • v.50 no.3
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    • pp.201-209
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    • 2014
  • This study was carried out in order to develop a biological control of anthracnose of red pepper caused by fungal pathogens. In particular, this study focuses on the Colletotrichum species, which includes important fungal pathogens causing a great deal of damage to red pepper. Antagonistic bacteria were isolated from the soil of pepper fields, which were then tested for biocontrol activity against the Colletotrichum gloeosporioides anthracnose pathogen of pepper. Based on the 16S rRNA sequence analysis, the isolated bacterial strain CS-52 was identical to Bacillus sp. The culture broth of Bacillus sp. CS-52 had antifungal activity toward the hyphae and spores of C. gloeosporioides. Moreover, the substances with antifungal activity were optimized when Bacillus sp. CS-52 was grown aerobically in a medium composed of 0.5% glucose, 0.7% $K_2HPO_4$, 0.2% $KH_2PO_4$, 0.3% $NH_4NO_3$, 0.01% $MnSO_4{\cdot}7H_2O$, and 0.15% yeast extract at $30^{\circ}C$. The inhibition of spore formation resulting from cellulase, siderophores, and indole-3-acetic acid (IAA), were produced at 24 h, 48 h, and 72 h, respectively. Bacillus sp. CS-52 also exhibited its potent fungicidal activity against anthracnose in an in vivo test, at a level of 70% when compared to chemical fungicides. These results identified substances with antifungal activity produced by Bacillus sp. CS-52 for the biological control of major plant pathogens in red pepper. Further studies will investigate the synergistic effect promoting better growth and antifungal activity by the formulation of substances with antifungal activity.

Spectrophotometric Determination of Aluminium Ion in Drinking Water by Flow Injection Analysis (흐름주입분석법에 의한 음용수 중 알루미늄 이온의 분광광도법 정량)

  • Choi, Yong-Wook;Jin, Jae-Young
    • Journal of the Korean Chemical Society
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    • v.44 no.5
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    • pp.422-428
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    • 2000
  • Optimum analytical conditions of the aluminium ion were established by flow injection analysis. Eriochrome Cyanine R(ECR) dye reacts with the aluminium ion at pH 6.0 to form a complex that exhibits maximum absorption at 535 nm. Reaction conditions including the mixing and the reaction coil length, the concentration and the pH of the buffer solutio, temperature, and injection loop volume were optimized to intro-duce this reaction into flow injection analysis. The results were as follows. A mixing coil length of 0.5 m and a reaction coil length of 4.0 m, the pH 6.0 and 1M of acetate buffer solution, the ECR concentration of 0.56 mM, the reaction temperature of 40$^{\circ}C$, the injection loop volume of 300${\mu}L$ were chosen as optimum conditions. Under these conditions the detection limit of the aluminiumion was less than 0.05 mg/L and the repeatability was better than 1%. A sampling frequency of 24 times for an hour was achieved. Interfering ions such as $F^-$, HP$O_4^{2-}$, $Fe^{2+}$, $Fe^{3+}$, $Mn^{2+}$, and other anions were tested, interference did not occur up to 1,000mg/L of ion concentration and up to 2,CO0mg/L of sulfate ion con-centration. This method was applied for the determination of aluminium ion in tap water and ground water of Jeonju and the Gochang area. The results showed that the aluminium residual in tap water of the Jeonju area was at a mean of 0.478mg/L and that in tap water of the Gochang area was at a mean of 0.278mg/L. Aluminium ion residual of the tap waters in the Jeonju area was higher level than that in the Gochang area. Aluminium residual in the ground water of the Jeonju area was 0.386 mg/L and was lower compared to 0.564 mg/L for the Gochang area.

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