• Resources Recycling
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• v.30 no.5
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• pp.57-66
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• 2021

In this study, we attempted to separate and recover Cu from low-grade copper ore by a hydrometallurgical process. The leaching sample obtained after crushing and sieving by 0.355 mm of low-grade copper ore contained 1.5% Cu, 4.7% Fe, 1.0% Mn, and 0.3% Zn. The Cu in the oxide ore was very well leached into sulfuric acid and 97% Cu leaching efficiency was achieved at 80℃ and 3 M sulfuric acid (H₂SO₄). From the leaching solution, Cu was separated by solvent extraction from Fe, Mn, and Zn using LIX984N. The separation tendency between Cu and other metals was confirmed through the distribution ratio and separation factor. By plotting the McCabe-Thiele Diagram, the optimum condition for recovering Cu is 5 vol.% LIX984N, 2-stage counter-current solvent extraction, and an O/A ratio of 0.5. Using this method, 99% of the Cu was extracted and a CuSO₄ solution was finally obtained that contained 1.6 g/L Cu after the stripping process using 2 M H₂SO₄.

• Journal of Wetlands Research
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• v.16 no.4
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• pp.379-388
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• 2014

A sewage was treated using a serially combined vertical(VFCW) and horizontal flow double media (sand and zeolite for VFCW and sand and waste oyster-shell for HFCW) reed constructed wetland(HFCW) with intermittent feeding (see Fig. 1). The sewage was fed into the reed constructed wetland for 10 minutes every 6 hours at the hydraulic load of $314L/m^2{\cdot}day$. The summarized results were as follows: pH values in the effluent depended very heavily on oyster-shell height filled in the HFCW. They were maintained at less than pH 6.24 when the height of the oyster-shell layer was 200 mm. Influent DO(oxygen demand) values(average 0.19 mg/L) were increased in the VFCW(average 7.65 mg/L) and decreased again in the HFCW(average 6.49 mg/L). They were higher in the winter than in the summer. The OTR(oxygen transfer rate) was $57.15g\;O_2/m^2{\cdot}day$ in the VFCW and $5.65g\;O_2/m^2{\cdot}day$ in the HFCW. The removal efficiency of $NH_4{^+}$-N was 80.17%(6.01 $NH_4{^+}$-N mg/L in the effluent). It was lower than that in the case where only zeolite was filled in the reed constructed wetland. But it was expected that treated sewage effluent using a double media reed constructed wetland with 300 mm zeolite layer could stably meet the Korean treated sewage effluent standard(20 mg T-N/L). Average removal efficiencies were SS 88.09%, BOD 88.12%, $COD_{Cr}$ 83.11%, $COD_{Mn}$ 85.58%, T-N 57.21%, $NH_4{^+}$-N 80.17%, T-P 86.73%. Nearly, The concentration of $NO_3{^-}$-N in the effluent of the VFCW was decreased in that of the HFCW. More than half of T-N in the effluent was $NO_3{^-}$-N(7.92 mg/L) but the concentration of $NO_2{^-}$-N in the effluent was average 0.90 mg/L. The removal efficiencies of T-P were 93.24%, 86.30% and 55.44% at the height of the oyster-shell-filled constructed wetland of 800 mm, 500 mm and 200 mm, respectively and therefore, they were proportional to oyster-shell height filled in the HFCW.

• KSBB Journal
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• v.22 no.2
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• pp.102-108
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• 2007

A sewage was treated using a vertical flow zeolite-filled reed bed. The sewage from the student dormitory of Changwon National University was fed into the reed bed for 10 minutes every 6 hours at the hydraulic load of $314L/m^3{\cdot}$day. The filtering height of the reed bed was 100 em and the zeolite mixture was filled in the reed bed. The mixture consisted of the same volume of two types of zeolite: 0.5$\sim$1 mm and 1$\sim$3 mm in diameter. Annual average removal efficiency was 88 89.9%, $COD_{Cr}$ 86.1 %, $COD_{Mn}$ 81.2%, T-N 34.0%, $NH_4^+$-N 97.3% and T-P 34.6%. T-N of effluent was mostly $NO_3^-$-N and the concentration of $NO_2^-$-N in effluent was lower than 0.1 mg/L. All removal efficiencies did not show a remarkable seasonal change. The ranking of phosphorous fractions fixed to the zeolite in column test was Ca-P > Fe-P > reductant soluble Fe-P > occluded P > saloid P > AI-P at all depths of the filter. All phosphorous fractions except for AI-P reduced at deeper filter layer, while their content ratios increased at deeper filter layer. Organic matter content was the highest at the highest layer (0$\sim$5 cm from the top of the filter) and only small differences were observed at the deeper filter layer than 5 em from the top. Organic matter content increased at all depths of the filter with the operating time.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.402-402
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• 2015

본 연구에서는 사과재배지에서 발생하는 비점오염물질 유출 및 수질특성을 살펴보고자 2014년 5월부터 9월까지의 총 15회의 강우사상에 대해 유출특성을 분석하고 오염물질별 유량가중평균농도(Event Mean Concentration, EMC) 및 오염부하를 산정하였다. 모니터링 기간동안 3.2~80.3 mm의 강우가 발생하였으며, 조사된 총 15회의 event 중 3회 유출이 발생하였다. 강우강도는 0.39~4.46 mm/hr의 범위로 나타났으며, 선행무강우일수는 0.3~20.1일, 총 유출량은 $2.7{\sim}100.8m^3$, 유출율은 0.02~0.3의 범위로 나타났다. 강우모니터링 결과, EMC는 TOC 7.1~18.7 mg/L(평균 12.0 mg/L), BOD 4.3~7.8 mg/L(평균 5.9 mg/L), COD 16.9~30.2 mg/L(평균 22.3 mg/L), SS 35.6~738.1 mg/L(평균 293.1 mg/L), T-N 2.342~11.043 mg/L(평균 6.563 mg/L) 그리고 T-P 1.563~2.563 mg/L(평균 1.961 mg/L)의 범위로 나타났으며, 각 강우사상에 대한 단위면적당 오염부하는 TOC 0.12~2.4 kg/ha, $BOD_5$ 0.03~1.0kg/ha, $COD_{Mn}$ 0.12~7.1 kg/ha, SS 0.34~173 kg/ha, T-N 0.068~1.478 kg/ha, T-P 0.011~0.601 kg/ha의 범위로 산정되었다. 사과재배지의 경우 대부분 투수지역으로 강우 초기에 지하로 침투하는 양이 많기 때문에 초기세척효과는 크게 발생하지 않는 것으로 나타났으며, 대체적으로 30 mm 이하의 강우에서는 유출이 발생하지 않는 것으로 분석되었다. 하지만, 사과재배지에서 발생하는 비점오염물질의 유출특성은 기상조건 및 영농활동 조건등에 따라 상이하게 나타나기 때문에 강우시 비점오염원 유출특성을 보다 정량적으로 파악하기 위해서는 체계적이고 지속적인 연구가 필요할 것으로 판단된다.

• The Journal of Korean Academy of Prosthodontics
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• v.47 no.2
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• pp.156-163
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• 2009

Statement of problem: Recently, there have been increased esthetic needs for posterior dental restorations. The failure of posterior dental ceramic restoration are possible not only by the characters of the component materials but also by the type of food. Purpose: The research aim was to compare the in vitro fracture resistance of simulated first molar crowns fabricated using 4 dental ceramic systems, full-porcelain-occlusal-surfaced PFG, half-porcelain-occlusal-surfaced PFG, Empress 2, Ice Zirkon and selected Korean foods. Material and methods: Eighty axisymmetric crowns of each system were fabricated to fit a preparation with 1.5- to 2.0-mm occlusal reduction. The center of the occlusal surface on each of 15 specimens per ceramic system was axially loaded to fracture in a Instron 4465, and the maximum load(N) was recorded. Afterwards, selected Korean foods specimens(boiled crab, boiled chicken with bone, boiled beef rib, dried squid, dried anchovy, round candy, walnut shell) were prepared. 15 specimens per each food were placed under the Instron and the maximum fracture loads for them were recorded. The 95% confidence intervals of the characteristic failure load were compared between dental ceramic systems and Korean foods. Afterwards, on the basis of previous results, 14Hz cyclic load was applied on the 4 systems of dental ceramic restorations in MTS. The reults were analyzed by analysis of variance and Post Hoc tests. Results: 95% confidence intervals for mean of fracture load 1. full porcelain occlusal surfaced PFG Crown: 2599.3 to 2809.1 N 2. half porcelain occlusal surfaced PFG Crown: 3689.4 to 3819.8 N 3. Ice Zirkon Crown: 1501.2 to 1867.9 N 4. Empress 2 Crown: 803.2 to 1188.5 N 5. boiled crab: 294.1 to 367.9 N 6. boiled chicken with bone: 357.1 to 408.6 N 7. boiled beef rib: 4077.7 to 4356.0 N 8. dried squid: 147.5 to 190.5 N 9. dried anchovy: 35.6 to 46.5 N 10. round candy: 1900.5 to 2615.8 N 11. walnut shell: 85.7 to 373.1 N under cyclic load(14Hz) in MTS, fracture load and masticatory cycles are: 1. full porcelain occlusal surfaced PFG Crown fractured at 95% confidence intervals of 4796.8-9321.2 cycles under 2224.8 N(round candy)load, no fracture under smaller loads. 2. half porcelain occlusal surfaced PFG Crown fractured at 95% confidence intervals of 881705.1-1143565.7 cycles under 2224.8 N(round candy). no fracture under smaller loads. 3. Ice Zirkon Crown fractured at 95% confidence intervlas of 979993.0-1145773.4 cycles under 382.9 N(boiled chicken with bone). no fracture under smaller loads. 4. Empress 2 Crown fractured at 95% confidence intervals of 564.1-954.7 cycles under 382.9 N(boiled chicken with bone). no fracture under smaller loads. Conclusion: There was a significant difference in fracture resistance between experimental groups. Under single load, Korean foods than can cause fracture to the dental ceramic restorations are boiled beef rib and round candy. Even if there is no fracture under single load, cyclic dynamic load can fracture dental posterior ceramic crowns. Experimental data with 14 Hz dynamic cyclic load are obtained as follows. 1. PFG crown(full porcelain occlusion) was failed after mean 0.03 years under fracture load for round candy(2224.8 N). 2. PFG crown(half porcelain occlusion) was failed after mean 4.1 years under fracture load for round candy(2224.8 N). 3. Ice Zirkon crown was failed after mean 4.3 years under fracture load for boiled chicken with bone(382.9 N). 4. Empress 2 crown was failed after mean 0.003 years under fracture load for boiled chicken with bone(382.9 N).

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.552-552
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• 2016

논의 경우 다양한 영향인자에 의해 비점오염물질이 배출되기 때문에 유출특성을 파악하기가 어렵다. 따라서 본 연구의 목적은 논에서 발생하는 비점오염물질의 유출 특성에 대해 파악하여 추후 효율적인 농업비점오염 관리를 위한 기초자료를 제공하는데 있다. 연구 대상지점으로 춘천시에 위치한 논 1곳(면적: $11,130m^2$)을 선정하였으며. 2014년 5월부터 9월까지 총 11회(9회 유출)의 강우 사상에 대한 오염물질별 오염부하 및 유량가중평균농도(Event Mean Concentration, EMC)를 산정하였다. 모니터링기간 동안 발생된 강우량의 범위는 2.6~95.8 mm로 나타났으며, 선행무강우일수는 0.59~21.2일, 강우강도는 0.33~5.13 mm/hr의 범위로 나타났다. 총 유출량은 $0.16{\sim}497.3m^3$, 유출율은 0.01~0.47(평균 0.24)의 범위로 나타났다. 오염물질별 EMC는 SS 17.1~55.3 mg/L(평균 31.9 mg/L), BOD 1.9~9.7 mg/L(평균 4.2 mg/L), COD 3.6~18.9 mg/L(평균 8.3 mg/L), TOC 3.4~17.4(평균 6.4 mg/L) mg/L, T-N 1.64~7.17 mg/L (평균 3.79 mg/L), T-P 0.16~1.04 mg/L(평균 0.44 mg/L)의 범위로 나타났다. 각 강우사상에 대한 단위면적당 오염부하는 SS 0.005~19.56 kg/ha, $BOD_5$ 0.001~1.70 kg/ha, $COD_{Mn}$ 0.003~3.15 kg/ha, TOC 0.002~1.81 kg/ha, T-N 0.001~0.822 kg/ha, T-P 0.00003~0.115 kg/ha의 범위로 산정되었다. 논의 경우에는 초기유출 발생에 따른 오염부하의 급격한 변화가 없었고, 누적오염부하량비의 그래프도 강우사상의 기울기가 직선에 가깝게 나타났다. 하지만 지속적으로 오염물질을 배출하는 경향과 다양한 조건에 따라 배출양상이 달라지기 때문에 효과적인 관리를 하기 위해서 장기적인 모니터링 연구가 필요할 것으로 사료된다.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.401-401
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• 2015

본 연구에서는 기타재배지(벚나무재배지)에서 발생하는 비점오염물질 유출 및 수질특성을 살펴보고자 2014년 5월부터 9월까지의 총 12회의 강우사상에 대해 유출특성을 분석하고 오염물질별 유량가중평균농도(Event Mean Concentration, EMC) 및 오염부하를 산정하였다. 모니터링 기간동안 2.6~95.8 mm의 강우가 발생하였으며, 조사된 총 12회의 event 중 단 2회 유출이 발생하였다. 강우강도는 0.33~5.28 mm/hr의 범위로 나타났으며, 선행무강우일수는 0.6~21.2일, 총 유출량은 $0.92{\sim}20.75m^3$, 유출율은 0.03~0.18의 범위로 나타났다. 강우모니터링 결과, EMC는 TOC 3.4~10.3 mg/L(평균 6.9 mg/L), BOD 6.3~6.9 mg/L(평균 6.6 mg/L), COD 22.0~28.8 mg/L(평균 25.4 mg/L), SS 101.8~962.8 mg/L(평균 532.3 mg/L), T-N 4.295~11.864 mg/L(평균 8.080 mg/L) 그리고 T-P 1.109~1.582 mg/L(평균 1.346 mg/L)의 범위로 나타났으며, 각 강우사상에 대한 단위면적당 오염부하는 TOC 0.08~0.58 kg/ha, BOD5 0.05~1.07kg/ha, CODMn 0.22~3.76 kg/ha, SS 0.77~164.4 kg/ha, T-N 0.090~0.734 kg/ha, T-P 0.008~0.270 kg/ha의 범위로 산정되었다. 벚나무재배지의 수질 항목간 Pearson 상관계수를 분석한 결과, 항목 중 $COD_{Mn}$가 다른 수질항목과 유의성을 갖고 높은 상관관계가 나타나 초기유출효과 분석을 위한 대표 수질항목으로 선정하였다. 벚나무재배지의 경우 초기유출 발생에 의한 오염부하의 급격한 증가는 나타나지 않았으며, 누적오염부하량비의 그래프에서는 대부분의 강우사상에서 기울기가 직선에 가깝게 나타났다. 기타재배지의 경우 대부분 투수지역으로 초기세척효과가 비교적 작은 것으로 나타났으며, 지속적으로 오염물질을 배출하는 특성을 보이는 것으로 분석되었다.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.3
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• pp.228-232
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• 2006

In this paper, in order to develop low temperature sintering $PbTiO_3$-system piezoelectric ceramics for thickness-vibration-mode piezoelectric transformer, $Pb_{0.76}Ca_{0.24}[(Mn_{1/3}Sb_{2/3})_{0.04}Ti_{0.96}]O_3$ ceramics using $0.25\;wt\%\;CaCO_3$ and $0.2\;wt\%\;Li_{2}CO_3$ as sintering aids were manufactured according to the variation of poling field. The specimens could be sintered at $930\;^{\circ}C$. The piezoelectric properties were investigated according to the poling field. The maximum properties showed at the field of 6.5 kV/mm, which had kt of 0.49, Qmt of 1816, and $d_{33}$ of 81.4 pC/N.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.176-177
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• 2005

In this paper, in order to develop low temperature sintering $PbTiO_3$-system piezoelectric ceramics for thickness-vibration-mode piezoelectric transformer, $Pb_{0.76}Ca_{0.24}[(Mn_{1/3}Sb_{2/3})_{0.04}Ti_{0.96}]O_3$ ceramics using $0.25wt%CaCO_3$ and 0.2wt%$Li_2CO_3$ as sintering aids were manufactured according to the variation of poling field. Specimens could be sintered at the sintering temperature of $930^{\circ}C$. The piezoelectric properties increased according to the increase of poling field and showed the maximum values (kt=0.49, Qmt=1816, and $d_{33}$=81.4pC/N) under 6.5kV/mm.

• Journal of Wetlands Research
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• v.16 no.1
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• pp.51-59
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• 2014

A sewage was treated using serially combined vertical and horizontal flow zeolite-filled reed bed. The sewage from the student dormitory of Changwon National University was fed into the reed bed for 10 minutes every 6 hours at the hydraulic load of 314 $L/m^2{\cdot}day$. The reed bed depth was 100cm and the zeolite mixture was filled in the reed bed. The mixture consisted of the same volume of two types of zeolite ; 0.5~1mm and 1~3mm in diameter. pH value decreased in vertical bed, while it increased in horizontal bed. But DO concentration in the effluent of both beds was higher than that in the influent. Average removal efficiencies of the entire treatment system were 99.22% SS, 95.56% BOD, 91.02% $COD_{Cr}$, 87.78% $COD_{Mn}$, 45.87% T-N, 99.88% $NH{_4}^+-N$ and 71.17% T-P. Most of T-N in the effluent was $NO{_3}^--N$. However, the concentration of $NO{_2}^--N$ in the effluent was lower than 0.04 mg/L. All removal efficiencies did not show a remarkable seasonal change.