• Title/Summary/Keyword: $MgH_2$

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Recovery of Mg-Ferrite Powder from Acid Leaching Mg Waste by Hydrothermal Method (산 침출 Mg폐액으로부터 수열법에 의한 Mg-Ferrite 분말회수)

  • 김영순;윤기석;안찬영;이종현;원창환
    • Resources Recycling
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    • v.6 no.4
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    • pp.31-37
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    • 1997
  • The Mg-ferrite powders were recovered from acid leaching Mg waste by hydrothermal method. Recovering conditions ofMg-Ferrite were investigated m this system and the powders prepared were characterized, using X-ray analysis, chemicalanalysis, SEM. TEM, and VSM. In this study, pH of solution and the kind of neutralizer wcre important factors on thecharacteristics of the product. The optimum condition of recovering MgPenite was the mole ratio of Fe" : Mg"=2'1, reactiontemperature : ZOWC, reaction time.lhr, at pH=lZ, and Oi partial pressure af 2000 psi. And the powders ~ccovered have amonodispersed and spherelike shapes with the narrow sue distribulion.ow sue distribulion.

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Selective Oxidation of Hydrogen Sulfide to Elemental Sulfur with Fe/MgO Catalysts in a Slurry Reactor

  • Lee, Eun-Ku;Jung, Kwang-Deog;Joo, Oh-Shim;Shul, Yong-Gun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.281-284
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    • 2005
  • The Fe/MgO catalysts with different Fe loadings (1, 4, 6, 15 and 30 wt% Fe) were prepared by a wet impregnation with iron nitrate as precursor. All of the catalysts were characterized by BET surface analyzer, X-ray diffraction (XRD), temperature-programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS). The maximum removal capacity of $H_2S$ was obtained with 15 wt% Fe/MgO catalyst which had the highest BET surface area among the measured catalysts. XRD of Fe/MgO catalysts showed that well dispersed Fe particles could be present on Fe/MgO with Fe loadings below 15 wt%. The crystallites of bulk $\alpha$-$Fe_2O_3$ became evident on 30 wt% Fe/MgO, which were confirmed by XRD. TPR profiles showed that the reducibility of Fe/MgO was strongly related to the loaded amounts of Fe on MgO support. Therefore, the highest removal efficiency of $H_2S$ in wet oxidation could be ascribed to a good dispersion and high reducibility of Fe/MgO catalyst. XPS studies indicated that the $H_2S$ oxidation with Fe/MgO could proceed via the redox mechanism ($Fe^{3+}\;{\leftrightarrow}\;Fe^{2+}$).

Effect of Al Doping on the Anisotropy of $MgB_2$ Single Crystals (Al 첨가가 $MgB_2$ 단결정의 비등방성에 미치는 영향에 대한 연구)

  • Kang, Byeong-Won;Lee, Hyun-Sook;Park, Min-Seok;Lee, Sung-Ik
    • Progress in Superconductivity
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    • v.9 no.2
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    • pp.183-187
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    • 2008
  • We have studied superconducting properties of $Mg_{1-x}Al_xB_2$ single crystals from reversible magnetization measurements. It was found that the upper critical fields $H_{c2}$ were decreased for both H // c and H // ab as Al is substituted for Mg. As a result, the large anisotropy of $H_{c2}$ observed in pure $MgB_2$, which is considered as one of the characteristics of two-gap superconductor, was decreased with Al doping. On the other hand, the irreversibility fields $H_{irr}$ were increased for x = 0.1 and were significantly decreased for x = 0.2. In contrary to the anisotropy of $H_{c2}$, the anisotropy of $H_{irr}$ was increased as Al concentration increases.

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Effects of Histamine $H_2-Receptor$ Stimulation on $Mg^{2+}$ Efflux in Perfused Guinea Pig Heart

  • Kang, Hyung-Sub;Chang, Sung-Eun;Kang, Chang-Won;Chae, Soo-Wan;Kim, Jin-Sang
    • The Korean Journal of Physiology and Pharmacology
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    • v.2 no.1
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    • pp.49-54
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    • 1998
  • $Mg^{2+}$ is an important regulator of many cardiac functions. However, regulation of intracellular $Mg^{2+}$ activity in the heart is not well characterized. To assess the effect of histamine $H_2$-receptor stimulation on intracellular $Mg^{2+}$ regulation, changes in extracellular $Mg^{2+}$ concentration were examined under a variety of conditions in perfused guinea pig hearts. $Mg^{2+}$ in the cardiac perfusate was measured by atomic absorbance spectrophotometry. The histamine ($10^{-6}$ M) inuced a marked $Mg^{2+}$ efflux from the heart. The $H_2$-receptor antagonists, cimetidine ($10^{-6}$ M), ranitidined ($10^{-5}$ M), but not a H1-receptor antagonist, diphenhydramine ($3{\times}10^{-6}$ M), completely blocked the histamine-induced $Mg^{2+}$ efflux. The $Mg^{2+}$ efflux could also be induced by forskolin ($3{\times}10^{-6}$ M), 8-Cl-cAMP ($2{\times}10^{-4}$ M), permeable cAMP analogue, or dimaprit, ($10^{-5}$ M). However, the carbachol ($10^{-5}$ M) considerably decreased the efflux of $Mg^{2+}$. In the presence of papaverine ($10^{-5}$ M), a phosphodiesterase inhibitor, dimaprit-induced $Mg^{2+}$ efflux was potentiated. These results suggest that a significant $Mg^{2+}$ efflux from perfused guinea pig heart by histamine can be induced by the histamine $H_2$-receptor stimulation and it is suggested that cytosolic cAMP may be linked.

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Production of Nucleotide by Immobilized Cell (고정화 미생물에 의한 뉴크레오타이드 생산)

  • CHO Jung-Il;JUNG Sung-Won
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.2
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    • pp.111-116
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    • 1991
  • The effective p.eduction of 5'-GMP(5'-Guanylic acid) by enzymatic conversion of 5'-XMP(5'-Xanthyic acid) was investigated. The Iyophilized Brevibacterium ammoniagenes ATCC 19216 which were used as the XHP aminase source, was immobilized by entrapping in K-carrageenan, agar, polyacrylamide or Ca-alginate. $3\%$ K-carrageenan was selected as the most suitable matrix. In the production of 5'-GMP using the free cells of 3. ammoniagenes ATCC 19216, the optimum conditions were $42^{\circ}C$, PH 7.0, 100mg/ml glucose, 120mg/ml cell ,8mg/ml $MgSO_4\cdot7H_2O$, 5mg/ml POESA, 5mg/ml phytic acid. Under the conditions, $94.5\%$ of 5'-GMP was converted within 8 hours. In the production of 5'-GMP using the immobilized whole cells of B. ammoniagenes ATCC 19216, the optimum conditions were $37^{\circ}C$, pH 7.5, 50mg/ml glucose, 1mg/ml $KH_2PO_4$, 10mg/ml phytic acid, 60mg/ml cell, 8mg/ml $MgSO_4\;\cdot\;7H_2O$, 5mg/ml POESA. Under the conditions, $64.7\%$ of 5'-GMP was converted within 40 hours.

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Determination of the Levels of Bisphenol A Diglycidyl Ether (BADGE), Bisphenol F Diglycidyl Ether (BFDGE) and Their Reaction Products in Canned Foods Circulated at Korean Markets (캔 제품의 bisphenol A diglycidyl ether (BADGE), bisphenol F diglycidyl ether (BFDGE) 유도체 및 분해산물 분석법)

  • Kim, Hee-Yun;Lee, Jin-Sook;Cho, Min-Ja;Yang, Ji-Yeon;Baek, Ji-Yun;Cheong, So-Young;Choi, Sun-Hee;Kim, Young-Seon;Choi, Jae-Chun
    • Korean Journal of Food Science and Technology
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    • v.42 no.1
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    • pp.8-13
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    • 2010
  • Bisphenol A diglycidyl ether (BADGE) and bisphenol F diglycidyl ether (BFDGE) were obtained by a polymerization reaction of epichlorohydrin (ECH) with bisphenol A (BPA) or bisphenol F (BPF). These compounds are commonly used as monomers or additives such as a polymerization stabilizer and a hydrochloric acid scavenger of epoxy resin, polyvinyl chloride (PVC)-containing organosols and polyester lacquers, that are applied to the internal surface of most canned foods to impart chemical resistance. The unreacted BADGE, BFDGE and their reaction products migrating from epoxy resin, PVC-containing organosol and/or polyester lacquer-based food packaging materials into the foods have recently become an issue of great concern because of increased customer demand for safety. This study was conducted to develop a rapid and sensitive simultaneous analysis method based on HPLC/FLD and HPLC/APCI-mass and to evaluate the concentration of BADGE, BFDGE and their metabolites, BADGE $H_2O$, BADGE $2H_2O$, BADGE HCl, BADGE 2HCl, BADGE HCl $H_2O$, BFDGE $H_2O$, BFDGE $2H_2O$, BFDGE HCl, BFDGE 2HCl and BFDGE HCl $H_2O$ for 133 canned food samples. The method provided a linearity of 0.9997-0.9999, a limit of detection of $0.01-0.13\;{\mu}g/mL$, a limit of quantitation of $0.03-0.44\;{\mu}g/mL$ and a recovery (%) of 85.64-118.18. The number of samples containing BADGE, BFDGE or their metabolites were: 28/133 (21.1%), with levels of 0.400-0.888 mg/kg being observed for aqueous foods (19/133) and 0.093-0.506 mg/kg being observed for oily foods (9/133).

$0.9Pb(Mg_{1/3}Nb_{2/3})O_{3}-0.1PbTiO_{3}$ powder synthesis by sol-gel process (졸-겔법에 의한 $0.9Pb(Mg_{1/3}Nb_{2/3})O_{3}-0.1PbTiO_{3}$ 분말의 합성)

  • 연석주;이진철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.1
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    • pp.27-32
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    • 2001
  • The 0.9PMN-0.1PT powders was prepared by the sol-gel process, and the effect amounts of ${Mg(OC_{2}H_{5})}_2$ and ${Pb(CH_{3}COO)}_2.3H_{2}O$ as starting materials was studied. As a result the percent of perovskite phase of the calcined powders increased with increased calcination temperatures. Maximum of perovskite phase was at $850^{\circ}C$ for 4 hrs. 0.9PMN-0.1PT powder by addition of 5 wt% excess ${Mg(OC_{2}H_{5})}_2$ crystallized to perovskite phase with a ${\fallingdotseq}100%$ yield.

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Fabrication of MgB2 superconducting wires with advanced Mg-Powder-Compaction process

  • Oh, S.H.;Oh, Y.S.;Jang, S.H.;Moon, Y.H.;Chung, K.C.;Kang, S.H.
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.4
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    • pp.14-18
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    • 2021
  • The Mg-Powder-Compaction (MPC) process is proposed to fabricate the MgB2 superconducting wires. Mg powder wall, similar to the Mg metal tube, inside the Nb outer sheath has been made and the stochiometric B powder was inserted into the wall. Even though the very high MgB2 core density of 2.53 g/cm3 is obtained, the superconducting area fraction of MgB2 is not high enough for the applications. In this work, an advanced MPC process was adopted by adding Mg powder into B powder. The Mg powder wall in the initial wire was fabricated by controlling the wall thickness while maintaining a constant density, and the mixture of B and Mg powder was filled into the Mg powder wall with the same filling density. It is found that the reduction in the area of the Mg powder wall proceeds similar to the wire, and the Mg powder wall is well maintained at the final wire diameter, which is advantage for the fabrication of long wires. With the advanced MPC process, as the added Mg is increased the densities of MgB2 core is decreased and the porous structure is formed, it is found that the area fraction of superconducting MgB2 increase up to the 37.7 % with the improved high critical current density (Jc) and the engineering critical current density (Je).

A Continuous Process for Phosphorus Recovery from Swine Slurry with Forming Struvite (양돈액비에서 Struvite 형성으로 연속적 인의 회수기술)

  • Oh I.H.;Lee J.H.;Choi B.H.;Burns R.T.
    • Journal of Animal Environmental Science
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    • v.12 no.2
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    • pp.95-100
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    • 2006
  • This study was carried out to develop a continuous process for recovering phosphorus in swine slurry. Magnesium chloride ($MgCl_2$) was used in the test as a magnesium source and the pH was regulated by adding NaOH and aerating. The results showed that the recovery rate of soluble phosphorus (SP) has increased with the molar ratios increased. In case of pH regulated with NaOH, the recovery rates of SP with molar ratio of 1:1.5 were over 95% from both farms. The removal of ammonia-nitrogen was at levels of $4{\sim}9%$. With aeration treatment, the SP recovery rate was 66% and the removal rate of ammonia-nitrogen was 15%. The treatment of NaOH to increase pH showed better SP recovery efficiency than the aeation treatment. However, in case of ammonia-nitrogen removal, the treatment of aeration showed better results than the NaOH treatment.

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Effects of Carbon, Nitrogen Sources and pH on Direct Somatic Embryogenesis in Liquid Culture of Rehmannia glutinosa Lib. (지황의 액체배양에서 탄소원.질소원 및 pH가 직접 체세포배 형성에 미치는 영향)

  • Chae, Young-Am;Park, Ju-Hyun
    • Korean Journal of Medicinal Crop Science
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    • v.7 no.1
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    • pp.1-6
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    • 1999
  • Basic informations for direct somatic embryo formation in Rehmannja glutinosa Lib. were obtained in 500ml erlenmyer flask. The ratio of ammonium to nitrate nitrogen of 825(mg/l) : 1900(mg/l) was proper condition for somatic embryo formation from stem and petiole explants and 3% sucrose was the most effective carbon source. Full strength MS medium with 2mg/l BA was better than LS medium for somatic embryogenesis. The initial pH 5.7 of medium(full strength MS with 2.0mg/l BA and 0.1mg/l NAA) was good for embryo production. Potassium ion was taken up rapidly within 2 weeks. while $Ca^{++}$ and $Mg^{++}$ ion contents were almost constant during culture period. Sucrose hydrolysis occurred throughout the culture, while glucose and fructose were absorbed simultaneously from the third week of culture.

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