• 제목/요약/키워드: $Li_3V_2(PO_4)_3$

검색결과 36건 처리시간 0.024초

In-situ 스퍼터링을 이용한 마이크로 박막 전지의 제작 및 전지 특성 평가 (Fabrication and Electrochemical Characterization of All Solid State Thin Film Micro-Battery by in-situ sputtering)

  • 전은정;신영화;남상철;조원일;손봉희;윤영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.159-162
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    • 1999
  • All solid state thin film micro-batteries consisting of lithium metal anode, an amorphous LiPON electrolyte and cathode of vanadium oxide have been fabricated and characterized, which were fabricated with cell structure of Li/LiPON/V$_2$O$\sub$5/Pt. The vanadium oxide thin films were formed by d.c. reactive sputtering on Pt current collector. After deposition of vanadium oxide films, in-situ growths of lithium phosphorus oxynitride film were conducted by r.f. sputtering of Li$_3$PO$_4$ target in mixture gas of N$_2$ and O$_2$. The pure metal lithium film was deposited by thermal evaporation on thin film LiPON electrolyte. The cell capacity was about 45${\mu}$Ah/$\textrm{cm}^2$ $\mu\textrm{m}$ after 200 cycle. No appreciable degradation of the cell capacity could be observed after 50 cycles .

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TPD와 P3HT의 블렌드한 다층막 EL 소자의 전기-광학적 특성 (The Electro-optical Propeties of Multilayer EL devices by blending TPD with P3TH as Emitting layer)

  • 김대중;구할본;김형곤;박계춘
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.542-545
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    • 2002
  • High performance organic electroluminescnet(EL) devices which are composed of organic thin multilayer films are fabricated. The basic structure is ITO/Emitting layer/LiF/Al in which have a blended emitting layer. The emitting layer is consisted of a host material(N,N' diphenyl-N,N' (3-methyl phenyl)-l,l'-biphenyl-4,4'diamine)(TPD)) and a guest emitting material(poly(3-hexylthiophehe)(P3HT)). We think that the energy transfer in blending layer occurred from TPD to P3HT. Red emitting multilayer EL devices were fabricated using tris(8-hydroxyqunolinate) aluminum$(Alq_3)$ as electron transport material. The device structure of ITO/blending layer(TPD+P3HT)$/Alq_3$/LiF/Al was employed. In the Voltage-current-luminance characteristics of multilayer device, the device tum on at the 2V and the luminance of $10{\mu}W/cm^2$ obtain at l0V. Red emission peak at 640nm was observed with this device structure. We have presented evidence that the excitation energy migration between a polymeric host and guest has to be explained. And by using multilayer, the red light emitting EL device enhances not only Voltage-current-luminance characteristic but also stability of device.

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지리정보시스템(GIS) 및 Weight of Evidence 기법을 이용한 강릉지역의 퇴적기원의 비금속 광상부존가능성 분석 (Sedimentary type Non-Metallic Mineral Potential Analysis using GIS and Weight of Evidence Model in the Gangreung Area)

  • 이사로;오현주;민경덕
    • Spatial Information Research
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    • 제14권1호
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    • pp.129-150
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    • 2006
  • 본 연구에서는 GIS 및 확률 기법을 이용하여 광상의 위치와 지질, 지화학 및 지구물리 자료들 간의 상관관계를 분석하고, 광상부존가능도(Mineral potential map) 작성 및 검증을 수행하였다. 연구지역은 1:25만 강릉도폭지역 a이며, 구축된 데이터베이스 자료는 1:25만 광상분포도, 지화학도, 지질도, 부우게 중력이상도, 자력이상도이다. 본 연구에 사용된 광상은 퇴적기원의 비금속광상(고령토, 도석, 규석, 운모, 연옥, 석회석, 납석)이다. 원소별 지화학도 작성은 채취된 각 시료 3,595개의 원소별 분석치를 이용하여 IDW 보간법으로 만들었다. 구축된 지화학도는 Al, Alkalinity, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Si, Sr, V, W, Zn, $Cl^-,\;F^-,\;{NO_2}^-,\;{NO_3}^-,\;{PO_4}^{3-},\;{SO_4}^{2-}$, pH, Eh 및 Conductivity로 총 32개이다. 이러한 광상과 관련 요인들 간의 상관관계는 확률기법인 weight of evidence를 적용하여 계산하였고, 이를 바탕으로 광상부존가능도를 작성하였다. 광상부존가능도는 wieght of evidence의 W+와 W- 값을 GIS 중첩분석에 적용하여 작성하였다. 계산된 광상부존가능지수는 기존 광상부존가능성을 정량적으로 설명하고 표현하며 검증할 수 있는 값이다. 각 기법을 이용하여 작성한 광상부존가능도의 검증결과는 85.66%의 정확도를 나타내었다.

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리튬이온전지용 소프트카본 음극 소재의 인산 처리에 대한 연구 (A Study on the H3PO4-Treated Soft Carbon as Anode Materials for Lithium Ion Batteries)

  • 조용남;이은영;박민식;홍기주;이상익;정후영;이종훈;오승모;김영준
    • 전기화학회지
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    • 제15권4호
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    • pp.207-215
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    • 2012
  • 코크스와 인산을 혼합한 뒤 $900^{\circ}C$에서 열처리하여 제조한 소프트카본의 구조적 특성 변화와 리튬이온전지용 음극 소재로서의 전기화학적 특성을 평가하였다. 입자 단면의 EDS 분석으로 phosphorus는 입자 내부에 전체적으로 존재하기는 하나 표면에 편재해 있었으며, $PO_x$(0 < x ${\leq}$ 4)의 결합 형태로 존재하고 있음을 XPS 분석을 통해 확인하였다. 인산 처리한 소프트카본의 방전 용량은 $390mAh\;g^{-1}$ 이상으로 인산을 처리하지 않은 소프트카본($336mAh\;g^{-1}$)보다 증가하였으며, 인산 처리량이 증가함에 따라 방전 용량이 증가하는 경향성을 나타내었다. 방전 용량 증가는 0.5 V vs. Li/$Li^+$ 이상에서 발현되는 용량 증가에 의한 것임을 확인하였고, 인산 처리로 생성된 $PO_x$(0 < x ${\leq}$ 4) 결합에 의해 소프트카본 내부에 생성된 나노 기공에 의한 것임을 충전 종료 전위별 실험을 통해 확인하였다. 또한 인산 2 wt%로 처리한 소프트카본이 가장 우수한 수명 특성을 나타내었다.

표면 부착형 영구자석 동기 전동기를 이용한 20kW급 실험용 전기자동차 파워트레인 개발 (Development of a Powertrain for 20kW Experimental Electric Vehicle Using Surface Mounted Permanent Magnet Synchronous Motor)

  • 박성환;이정주;손종열;이영일
    • 전력전자학회논문지
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    • 제22권3호
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    • pp.240-248
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    • 2017
  • This paper describes the development of a powertrain for a 20 kW experimental electric vehicle using a surface-mounted permanent magnet synchronous motor (SPMSM) and its application to a test vehicle. Two 10 kW SPMSMs are used in the powertrain, and two-level inverters are developed by using IGBTs to derive these motors. To control the SPMSM, a control board based on a TMS320F28335 DSP module, which has fast arithmetic function and floating point operator, is used. We develop a 100 V/40 A battery pack, which includes $32{\times}4$ LiFePO4 battery cells using commercial BMS. A commercial on-board charger with 220 V (AC) input and 100 V (DC) and 18 A output is used to charge the battery pack. The performance of the developed vehicle, such as acceleration availability, maximum speed, and maximum power, is estimated based on vehicle dynamics and verified through experiments.

Production and Characterization of Ethanol- and Protease-Tolerant and Xylooligosaccharides-Producing Endoxylanase from Humicola sp. Ly01

  • Zhou, Junpei;Wu, Qian;Zhang, Rui;Yang, Yuying;Tang, Xianghua;Li, Junjun;Ding, Junmei;Dong, Yanyan;Huang, Zunxi
    • Journal of Microbiology and Biotechnology
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    • 제23권6호
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    • pp.794-801
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    • 2013
  • This paper reports the production and characterization of crude xylanase from the newly isolated Humicola sp. Ly01. The highest (41.8 U/ml) production of the crude xylanase was obtained under the optimized conditions (w/v): 0.5% wheat bran, 0.2% $KH_2PO_4$, and 0.5% peptone; initial pH 7.0; incubation time 72 h; $30^{\circ}C$; and 150 rpm. A considerable amount of the crude xylanase was induced using hulless barley bran or soybean meal as the carbon source, but a small amount of the enzyme was produced when supplementary urea was used as the nitrogen source to wheat bran. The crude xylanase showed apparent optimal cellulase-free xylanase activity at $60^{\circ}C$ and pH 6.0, more than 71.8% of the maximum xylanase activity in 3.0-30.0% (v/v) ethanol and more than 82.3% of the initial xylanase activity after incubation in 3.0-30.0% (v/v) ethanol at $30^{\circ}C$ for 2 h. The crude xylanase was moderately resistant to both acid and neutral protease digestion, and released 7.9 and 10.9 ${\mu}mol/ml$ reducing sugar from xylan in the simulated gastric and intestinal fluids, respectively. The xylooligosaccharides were the main products of the hydrolysis of xylan by the crude xylanase. These properties suggested the potential of the crude enzyme for being applied in the animal feed industry, xylooligosaccharides production, and high-alcohol conditions such as ethanol production and brewing.