• 한국환경농학회지
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• 제16권3호
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• pp.259-263
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• 1997

남강수계 농업용수의 수질변화를 구명하기 위하여 1994년에서 1995년까지 매년 4월부터 9월까지 남강수계 7개 지점을 조사한 결과는 다음과 같다. 무기성분 평균치는 pH 7.9, COD 7.3mg/l, $NO_3-N$ 1.2mg/l, $Na^+$ 6.2mg/l, $Cl^-$ 14.8mg/l, EC 0.13dS/m, $PO_4\;^{3-}$ 0.21㎎/l, $K^+$ 2.6mg/l, $Ca^{2+}$ 10.8mg/l,$Mg^{2+}$ 2.9mg/l, $SO_4\;^{2-}$ 10.5mg/l, $Fe^{3+}$ 0.03mg/l and Zn 0.02mg/l였다. 월별 무기성분 평균치는 7월에 COD $8.4{\sim}11.6mg/l$, $NO_3-N$ $1.1{\sim}1.7mg/l$, $Na^+$ $5.4{\sim}13.1$, $Cl^-$ $18.9{\sim}27.9mg/l$로 가장 높게 나타났으며, 조사지역별로는 월아양수장 지점이 COD $8.8{\sim}11.3mg/l$, $NO_3-N$ $1.6{\sim}2.4mg/l$, $Na^+$ $9.0{\sim}10.2mg/l$, $Cl^-$ $21.7{\sim}23.0mg/l$로 가장 높게 나타났다. 무기성분간의 음이온당량과 양이온당량 비율은 월아양수장 지점이 다른 지점보다 높게 나타났다. 주요성분중 EC는 $K^+$, $Ca^{2+}$, $Mg^{2+}$, $Na^+$, $Cl^-$과 $SO_4\;^{2-}$ 함량과 고도의 정의상관이 있었다.

• 말소리와 음성과학
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• 제4권3호
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• pp.31-41
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• 2012

Recent studies have shown that the stop system of Korean is undergoing a sound change in terms of the two acoustic parameters, voice onset time (VOT) and fundamental frequency (f0). Because of a VOT merger of a consonantal opposition and onset-f0 interaction, the relative importance of the two parameters has been changing in Korean where f0 is a primary cue and VOT is a secondary cue in distinguishing lax from aspirated stops in speech production as well as perception. In English, however, VOT is a primary cue and f0 is a secondary cue in contrasting voiced and voiceless stops. This study examines how Korean English learners use the two acoustic parameters of L1 in producing L2 English stops and whether the sound change of acoustic parameters in L1 affects L2 speech production. The data were collected from six adult Korean English learners. Results show that Korean English learners use not only VOT but also f0 to contrast L2 voiced and voiceless stops. However, unlike VOT variations among speakers, the magnitude effect of onset consonants on f0 in L2 English was steady and robust, indicating that f0 also plays an important role in contrasting the [voice] contrast in L2 English. The results suggest that the important role of f0 in contrasting lax and aspirated stops in L1 Korean is transferred to the contrast of voiced and voiceless stops in L2 English. The results imply that, for Korean English learners, f0 rather than VOT will play an important perceptual cue in contrasting voiced and voiceless stops in L2 English.

• Bulletin of the Korean Chemical Society
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• 제27권5호
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• pp.713-717
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• 2006

$S_2O$-donor macrocyclic isomers incorporating a xylyl group in o- ($L^1$), m- ($L^2$) and p-positions ($L^3$) extract no metal ions except silver(I) from aqueous to chloroform phase. And the magnitudes of %Ex for silver(I) are in the order of $L^1$ > $L^2$ > $L^3$. Taking this result into account, $L^1$-$L^3$ were utilized as membrane active components to prepare potentiometric silver(I)-selective electrodes. The proposed macrocycles-based electrodes E1 ($L^1$), E2 ($L^2$) and E3 ($L^3$) exhibited comparable results which show considerable selectivity toward silver(I) over alkali, alkali earth and other transition metal ions. Comparative NMR study on $L^1$-$L^3$ and their complexes with silver(I) in solution was also accomplished. In addition, a unique sandwich-type complex $[Ag(L^1)_2]CIO_4$ was prepared from the assembly reaction of $L^1$ with $AgClO_4$ and structurally characterized by an X-ray diffraction analysis.

• 농약과학회지
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• 제4권1호
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• pp.32-37
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• 2000

인공핵산 분해효소로서 일련의 3,6-bis(6'-methyl-2'-pyridyl)pyridazine, ($L^{1}$)과 3,6-bis-(2'-pyridyl)pyridazine, ($L^{2}$)을 리간드로 한 몇가지 전이금속 착화합물, $1{\sim}8$을 합성하여 X-ray 결정구조를 확인한 다음, 핵산 모델 화합물과의 가수분해 반응성을 위시하여 논잡초에 대한 살초활성과 식물성 병원균에 대한 살균활성 등을 각각 검토하였다. 그 결과, $L^{2}$-Zn 착물, 8이 무촉매시 보다 빠른 가수분해 반응성을 나타내었으며, 살초활성에서는 $L^{2}$-Ni(II) 및 Co(II) 착물인 5와 6이 벼 (ORY, Oryzar sativa L.)에 대한 선택성을 나타내었을 뿐만 아니라, 올챙이고랭이(SCP, Scriptus juncoids)에 높은 살초활성을 보였다. 그리고 살균활성에서는 $L^{1}$-Co(II) 및 Zn(II) 착물인 2와 4를 위시하여 특히, $L^{1}$ 및 $L^{2}$가 도열병균 MAG (Magnaporthe grisea)에 대하여 90%이상의 살균활성을 나타내었다.

• Macromolecular Research
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• 제11권5호
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• pp.322-327
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• 2003

Two kinds of mutually cross-linkable copolymers were prepared to be used as humidity-sensing materials. The humidity-sensitive thin films consist of cross-linked polyelectrolytes of the following component: 4-vinylbenzyl dimethyl 2-(dimethylphosphino)ethyl phosphonium chloride (1)/ bis(2-methoxyethyl)itaconate (2)= 3/l, 2/l, 1/1 and 1/2 and 4-vinylbenzyl chloride (3)/ vinylbenzyl tributyl phosphonium chloride (4)= 3/l, 2/l, 1/1 and 1/2. The humidity sensor prepared from the reaction of 1/2= 2/l with 3/4= 2/l showed an average resistance of 723,36.2 and 2.42 ㏀ at 30, 60 and 90%RH, respectively. Temperature dependence, frequency dependence, and response time were measured and the reliability test such as water durability and long-term stability were also estimated.

• 식품보건융합연구
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• 제4권2호
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• pp.7-11
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• 2018

Salinity is one of the major and increasing problems in irrigated agriculture in Pakistan. Salinity stress negatively affects the growth and yield of plants guar (Cyanoposisa tetragonoloba). This experiment was conducted to evaluate the effects of ($4dSm^{-1}+13.5(mmol\;L^{-1})^{1/2}$, $5dSm^{-1}+25(mmol \;L^{-1})^{1/2}$, $5dSm^{-1}+30(mmol\;L^{-1})^{1/2}$, $10dSm^{-1}+25(mmol\;L^{-1})^{1/2}$ and $10dSm^{-1}+30(mmol \;L^{-1})^{1/2}$) on biomass yield of guar against salinity tolerance. Maximum biomass yield ($54.50gpot^{-1}$) was produced by $4dSm^{-1}+13.5(mmol\;L^{-1})^{1/2}$ treatment. Biomass produce was reduced with the increase of the salts toxicity. Minimum biomass yield ($30.17gpot^{-1}$) was attained under $10dSm^{-1}+30(mmol \;L^{-1})^{1/2}$. $5dSm^{-1}+25(mmol\;L^{-1})^{1/2}$ treatment exhibited improved outcome i.e. the least diminution % over control (18.66). Salinity cum sodicity showed staid effect on the growth reduction from 18.66% to 44.64%. This reduction fissure was impacted by the toxic effect of salinity and sodicity on Guar growth. Salinity- sodicity behaved toxic impact on the growth reduction from 18.66% to 44.64%. Based on the findings, guar (Cyanoposisa tetragonoloba) grows better at $4dSm^{-1}+13.5(mmol \;L^{-1})^{1/2}$ treatment.

• 한국자원식물학회지
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• 제21권2호
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• pp.111-116
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• 2008

노지에 있는 교잡종 블랙베리의 근맹아를 채취하여 1.2% sodium hypochlorite 용액에 침지하여 표면 살균한 후 BA를 첨가한 변형된 ${\times}$ 1, ${\times}$ 1/2 MS 고체배지에서 다경유도를 시도하였다. 4주간 배양하였을 때 BA $1mg{\cdot}L^{-1}$가 첨가된 기본 MS배지에서 고빈도(83.3%)의 다경유도가 이루어 졌으며, 절편체당 신초수는 $0.5mg{\cdot}L^{-1}$ BA를 첨가한 MS 기본배지에서 3.7개로 가장 높게 형성되었다. 또한 12주간 배양하였을 때 4주간 한 경우에 비하여 신초형성율이 4.1배 많은 15.4개가 형성됨을 관찰할 수 있었다. 형성된 신초로부터 뿌리발생은 식물생장조절물질이 첨가되지 않은 MS배지를 1/1, 1/2, 1/4배로 희석하여 신초를 배양하였을 때 특히 1/2 MS 배지에서 95%로 가장 양호하였다. 재생된 식물체는 모래 : 원예용상토 : 버미큘라이트(1:1:1, vol.)혼합토양에서 순화하였을 경우 95%의 생존율을 나타내었다.

• 한국유기농업학회지
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• 제11권3호
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• pp.65-73
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• 2003

제주지역 화산회토 시설재배지에서 유용미생물제를 시용하여 알타리 무의 생육, 수량변화를 알아보기 위하여 미생물제 액비 1,000mg$.$L$^{-1}$ 엽면시비 3회, 2,000mg$.$L$^{-1}$ 엽면시비 3회, 1,000mg$.$L$^{-1}$ 엽면시비 3회 + 미생물발효퇴비 600kg10a 정식전 살포처리후 20, 40, 60일 후 생육조사한 결과는 다음과 같다. 엽장과 엽폭은 무처리에 비해 미생물제제 처리구가 60일후에 유의하게 길어지는 것으로 나타났다. 엽수는 60일 후에 1,000mg$.$L$^{-1}$ 엽면시비 3회+미생물발효퇴비 600kg/10a에서 가장 많았고 다음으로 2,000mg$.$L$^{-1}$ 엽면시비 3회 처리구, 1,000mg$.$L$^{-1}$ 엽면시비 3회 처리 순으로 조사되었다. 엽록소함량치(SPAD reading value)는 60일 후에는 2,000mg$.$L$^{-1}$ 엽면시비 3회 처리구 및 1,000mg$.$L$^{-1}$ 엽면시비 3회+미생물발효퇴비 600kg/10a 처리구가 높은 것으로 나타났다. 지상부생체중은 미생물제제처리구가 무처리구에 비해 높은 경향을 보였다. 근장은 무처리구보다 미생물제제처리구가 길어지는 것으로 나타났다. 근중은 미생물제액비 1,000mg$.$L$^{-1}$ 엽면시비 3회+미생물발효퇴비 600kg/10a 처리구가 220g으로 가장 높은 것으로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제14권5호
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• pp.561-567
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• 1993

The twelve macrocycle (L) complexes of cadmium(II) nitrate have been synthesized: $CdL(NO_3)_2$. All the complexes have been indentified by elemental analysis, electric conductivity measurements, IR and NMR spectroscopic techniques. The molar electric conductivities of the complexes in water and acetonitrile solvent were in the range of 236.8-296.1 $cm^2{\cdot}mol^{-1}{\cdot}ohm^{-1}$ at 25$^{\circ}$C. The characteristic peaks of macrocycles affected from Cd(II) were shifted to lower frequencies as compared with uncomplexed macrocycles. A complex with 1,4,8,11-tetrakis(methylacetato)-1,4,8,11-tetraaza cyclodecane (L4) exhibited two characteristic bands such as strong stretching (1646 $cm^{-1})$, and weaker symmetric stretching band (1384 $cm^{-1})$. NMR studies indicated that all nitrogen donor atoms of macrocycles have greater affinity to cadmium(II) metal ion than do the oxygen atoms. The $^{13}$C-resonance lines of methylene groups neighboring the donor atom such as N and S were shifted to a direction of high magnetic field and the order of chemical shifts were $L_1 < L_2 < L_3 < L_6 < L_4$. Also the chemical shifts values were larger than those of methylene groups bridgeheaded in side-armed groups. This result seems due to not only the strong interaction of Cd(Ⅱ) with nitrogen donors according to the HSAB theory, but weak interaction of Cd(Ⅱ) and COO- ions or sulfur which is enhanced by the flexible methylene spacing group in side-armed groups. Thus, each additional gem-methyl pairs of L_3, L_4\;and\; L_6$ macrocycles relative to $L_1, L_2,\;and\;L_5$ leads to an large enhancement in Cd(II) affinity. ^{13}C$-NMR spectrum of the complex with $L_{12}$ (1,5,9,13-tetracyclothiacyclohexadecane-3,11-diol) reveals the presence of two sets of three resonance lines, and intensities of the each resonance line have the ratio of 1 : 2 : 2. This molecular conformation is predicted as structure of tetragonal complex to be formed by coordinating two sulfur atoms and the other two sulfur atoms which is affected by OH-groups.

• 대한지리학회지
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• 제46권1호
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• pp.1-19
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• 2011

대자율 및 입도 분석, OSL 연대측정, 주원소, 희토류 및 미량원소 분석을 통해 거창 정장리 뢰스-고토양의 물리, 화학적 특징을 파악하였다. 거창 뢰스-고토양 연속층의 입도 특성은 하안단구를 형성하는 하천퇴적층 그리고 중국 뢰스고원과는 차이를 보인다. 뢰스-고토양 층서 가운데 L1과 L1L1은 MIS 2, L1S1은 MIS 3, L1L2는 MIS 4, S1은 MIS 5, L2는 MIS 6에 대비되므로 거창단면이 위치하는 하안단구는 MIS 7에 형성된 것으로 판단된다. 다만 MIS 3 시기에 남부지방이 중부지방보다 더 온난습윤하였을 가능성이 있다. 주원소와 희토류 원소, 미량원소 조성은 거창의 뢰스-고토양이 중국 뢰스고원보다 풍화가 더 많이 진행되었으며 중국 뢰스고원에서 기원하였음을 지시한다. 이것은 한반도의 다른 지역에서 이루어진 연구 결과와 조화된다.