• Korean Journal of Materials Research
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• v.9 no.11
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• pp.1148-1152
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• 1999

An organometallic precursor, hfac(hexafluoroacetylacetonate) Cu(I) DMB (3,3-dimethyl- 1-butene) was synthesized, evaluated and compared with other precursors for metal organic chemical vapor deposition of copper thin films. It was found that at $40^{\circ}C$, the vapor pressure was an order of magnitude higher (about 3 torr) than (hfac) Cu vinyltrimethylsilane (VTMS) and films could be deposited at the substrate temperature of 100-$280^{\circ}C$ with deposition rate substantially higher. The copper films contained no detectable impurities as measured by Auger electron spectroscopy and had a resistivity of about 2.0$\mu\Omega$-cm in the deposition temperature range of 150 to $250^{\circ}C$. From the thermal analysis, (hfac)Cu(I)(DMB) is believed to be quite stable and no appreciable amount of precipitation was observed at $65^{\circ}C$ heating for more than a month.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.27 no.2
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• pp.80-88
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• 2017

In this research a time dependent thermal and solutal convection was computationally investigated for the physical vapor transport of the mixture of $Hg_2Cl_2-I_2$ system with for the convective regime from thermal Rayleigh number of $2.16{\times}10^6$ up to $1.7{\times}10^7$ with marching time to a steady state problem. With time marching, the convective cells are decreased for the thermal Rayleigh number of $2.16{\times}10^6$, and increased for the thermal Rayleigh number of $1.7{\times}10^7$. The convective flow structures are found to be essentially time independent on the horizontal orientation of the enclosure with respect to the gravity vector, and on the other hand, time dependent on the vertical orientation of the enclosure with respect to the gravity vector.

• International Journal of Concrete Structures and Materials
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• v.3 no.1
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• pp.15-23
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• 2009

Over about 30% of problems in construction is related to water-leaking, and the loss from this problem can incur as much as three times the cost of initial construction. Thus, water vapor pressure is known to be the primary cause of defective waterproofing. Accordingly, the theories on the relationship between water pressure and temperature as well as damp-proofing volume of concrete and the change in vapor pressure volume were reviewed and analyzed in this study by making test samples after spraying a dampness remover and applying waterproofing materials to the prepared test specimens. The result of measuring water vapor pressure with the surface temperature of the waterproofing (fluid-applied membrane) layer at the experimental temperature setting of about $10^{\circ}C$, which is the annual average temperature of Seoul, indicated that (1) the temperature of the fluid-applied membrane elevated to about $40^{\circ}C$, and the water vapor pressure generated from the fluid-applied membrane was about 0.03 N/mm 2 when the surface temperature of the waterproofing layer was raised to about $80^{\circ}C$. (2) when the temperature of the fluid-applied membrane of the waterproofing layer was raised from $30^{\circ}C$ to $35^{\circ}C$, water vapor pressure of about 0.01 N/mm 2 was generated, and (3) when a thermal source was applied to the fluid-applied membrane (waterproofing) layer, the temperature increased from $35^{\circ}C$ to $40^{\circ}C$, and approximately $0.005\;N/mm^2$ of water vapor pressure was generated.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.2
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• pp.86-91
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• 1996

Water vapor adsorption isotherms were measured for samples of the A horizons of five typical Korean soils. The experimental data were fitted to the BET and Aranovich adsorption equations. The adsorption isotherms studied followed the BET equation for the relative water vapor pressures in 0.03-0.33 range and the Aranovich equation in 0.03-0.6 range. The calculated surface areas were higher for Aranovich than for BET and opposite relations were found for adsorption energies. For the description of the water adsorption on soils, the use of the Aranovich theory is recommended.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.20 no.3
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• pp.125-132
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• 2010

For typical governing dimensionless parameters of Ar = 5, Pr = 1.16, Le = 0.14, Pe = 3.57, Cv = 1.02, $Gr_s=2.65{\times}10^6$, the effects of thermo physical properties such as a molecular weight, a binary diffusivity coefficient, a partial pressure of component B on solutally buoyancy-driven convection (solutal Grashof number $Gr_s=2.65{\times}10^6$) are theoretically investigated for further understanding and insight into an essence of solutal convection occurring in the vapor phase during the physical vapor transport of a $Hg_2Cl_2-N_2$ system. The solutally buoyancy-driven convection is significantly affected by any significant disparity in the molecular weight of the crystal components and the impurity gas of nitrogen. The solutal convection in a vertical orientation is found to be more suppressed than a tenth reduction of gravitational accelerations in a horizontal orientation. For crystal growth parameters under consideration, the greater uniformity in the growth rate is obtained for either solutal convection mode in a vertical orientation or thermal convection mode in horizontal geometry. The growth rate is also found to be first order exponentially decayed for $10{\leq}P_B{\leq}200$ Torr.

• Korean Journal of Materials Research
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• v.7 no.2
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• pp.107-113
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• 1997

$SrBi_{2}Ta_{2}O_{9}(SBT)$ thin films wcre prepared on $Pt/Ti/SiO_{2}/Si$ suhsrrate by pL~snia-enhanced chemical vapor deposition. Sr and Ta huhhling temperatures were kept ,it $120^{\circ}C$ Iron1 X- ray tiiffriict!on. n~icrostruc~ure. and composjrional analysis of SH7' films, respectivels Hi I~ut~t~lmg tempcl.arure was varied SR'I' thin tilrns dcpositcd ar i3i buhbling temperature of $130^{\circ}C$ have dielccrric constanr of 150 anti dissipation factor of 0 02 at IOOkFic. I .eakagc wrrent density of films was ahour $1.0{\times}10^{-8}A/cm^2$ at 20kV/cm. 1.eakage current i11amcrc1istic.s of Sli'l' films nras c.ontrolled by I'oole Frcnkel emission Kenianent polariziit~on and mercivc field oi SR\ulcorner' films annealed at $550^{\circ}C$ were $9{\mu}C/cm^2$ and 70kV/cm, respectively.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.3
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• pp.46-56
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• 1998

The objective of this study was to investigate the relationship between water vapor diffusion properties and the pore structure of paper. Gas-phase molecular diffusivity of water vapor through pores was determined based on the kinetic theory of gas. A mathematical model was derived to characterize the dimensional changes of the pore caused by the fiber-swelling mechanism. A modified-Fickean diffusion model was designed to simulate the water-vapor diffusion phenomena in porous paper web. Structural characterisocs of paper pores including the tortuosity and the shape factor was studied on a theoretical basis of Knudsen flow diffusion. Results are summarized as follows: 1. The theoretical water vapor diffusivity in gas-phase was 0.092$cm^2$ /min, 2. Porosity was inversely proportional to the degree of wet-swelling of paper, 3. Solid-phase water-diffusivity of fiber was 1.2 $ \times 10^{-5}cm^2/min$, 4. Modified diffusion model was fairly consistent to the experimental data (from part I), and 5. The Fickean pore tortuosity, ranging from 1,000 to 2,500, was in inverse proportion to the porosity of paper, and the Knudsen shape factor and length-angle factor for micro-pores in paper were 0.5~3.5 and about 340, respectively.

• Journal of the Korean Solar Energy Society
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• v.22 no.2
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• pp.27-32
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• 2002

The Characteristics of heat transport in the heat pipe with a double vapor path and different kinds of the working fluid were investigated experimentally. The Experiment was carried out with acetone/ethanol. ethanol/ethanol. and in the aluminium container of the double vapor path. Performance measurements can be operated at the high level by 24000 w/m2 heat flux in the 1000mm evaporator. They are each estimated at the high temperature and experimentally reviewed the characteric of the heat rejection. The results shew that they are stably operated under each condition and the fluid was complemented each other at the fluid's experiment and brought about the extention of operating temperature. In this study, The reliable basic data obtained by the teste in the heat pipe with a double vapor path can be used for thermal design, manufacture, and production etc.

• Journal of Environmental Science International
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• v.12 no.4
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• pp.503-510
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• 2003

How to plan the energy system is one of the keys f3r constructing the Environment -Friendly City. for this reason, a great number of surveys for utilizing unused energy have conducted by a planner. In regard to unused energy, the heat from incineration plants classify as a unused energy having high-exergy-energy. From this point of view, It is studied about the plant systems providing heat to district heating & cooling(D.H.C) and producing electric power. It is divided four system models as system I (10K [kgf/cm$^2$) vapor as outlet of boiler, supply far 10K vapor and return to 60$^{\circ}C$ as supply condition of district heating), system II (30 K vapor as outlet of boiler, supply for 5t vapor and return to 60f as supply condition of district heating), system 111 (30 K vapor as outlet of boiler, supply for 85$^{\circ}C$ hot water and return to 60$^{\circ}C$ as supply condition of district heating), system IV (30 K vapor as outlet of boiler, supply for 47$^{\circ}C$ hot water and return to 40t as supply condition of district heating). The results from the upper condition of four system, System II got a proper on economical benefits and system IV calculated as benefiting on energy saving effects, and suggest indifference curve as the total evaluation method of both economical benefits and energy saving.

• Korean Journal of Crystallography
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• v.4 no.2
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• pp.100-104
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• 1993

Reduced glutathione (GSH) plays a vital role in the metabolism of all cells. Glutathions, a tripeptide cowfosed of glutamic acid, cysteane, and gtycina is synthesized by two synthesized reutions. The first is catalyzed by Y-glutamylcysteine synthetase (GSH-I) and the second by glutathione synthetase (GSH-ll). The glutathione biosynthetic pathway of E. coziis mainly controlled by nonallosteric feedback inhibition of GHS-I by GSH. Determination of the three-dimensional structure of GSH-I by X-ray crystallography is necessary in order to understand the structure-function relationship at the molecular level. As the (irst step toward its structure determination, crystallization of 5. coli V-glutamylcystfine synthetase (GSH-I) has been achived using the hanging drop vapor diffusion method and capillaw method. Crystals of GSH-I have been grown from ammonium sulfate solution. The crystals grew at room temperature within 10 days to dimensions of 0.2 m x 0.2 m x 0.2 ml by hanging drop vapor diffusion method and diffracted to about 4 A resolution using synchrotron X-rays. Another crystal, grown by the capillary method to dimensions of 0.25 mm x 0.25 mm x 0.3 mm within 40 days, diffracted to about 4 A resolution using X-rays from a rotating anode.