• Title/Summary/Keyword: $H_2O$ addition

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AKARI/IRC spectroscopic survey for interstellar ice study

  • Kim, Jaeyeong;Lee, Jeong-Eun;Kim, Il-Seok;Aikawa, Yuri;Jeong, Woong-Seob;Lee, Ho-Gyu;Noble, Jennifer A.;Dunham, Michael M.
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.41.3-41.3
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    • 2019
  • Ices in interstellar environments are well traced mostly by their absorption features in the near- to mid-infrared spectrum. The infrared camera (IRC) aboard AKARI provides us the near-infrared spectroscopic data which cover $2.5-5.0{\mu}m$ with a spectral resolution of R ~ 120. Our AKARI spectroscopic survey of young stellar objects (YSOs), including low-luminosity protostars and background stars, revealed the absorption features of $H_2O$, $CO_2$, CO, and XCN ice components. We present near-infrared spectra of the observed targets and compare their ice abundances with those previously derived from various YSOs and the background stars behind dense molecular clouds and cores. In addition, we suggest possible science cases for SPHEREx, NASA's new near-infrared space observatory, based on the results from our AKARI IRC spectroscopic study.

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Characteristics of MOCVD Cobalt on ALD Tantalum Nitride Layer Using $H_2/NH_3$ Gas as a Reactant

  • Park, Jae-Hyeong;Han, Dong-Seok;Mun, Dae-Yong;Yun, Don-Gyu;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.377-377
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    • 2012
  • Microprocessor technology now relies on copper for most of its electrical interconnections. Because of the high diffusivity of copper, Atomic layer deposition (ALD) $TaN_x$ is used as a diffusion barrier to prevent copper diffusion into the Si or $SiO_2$. Another problem with copper is that it has weak adhesion to most materials. Strong adhesion to copper is an essential characteristic for the new barrier layer because copper films prepared by electroplating peel off easily in the damascene process. Thus adhesion-enhancing layer of cobalt is placed between the $TaN_x$ and the copper. Because, cobalt has strong adhesion to the copper layer and possible seedless electro-plating of copper. Until now, metal film has generally been deposited by physical vapor deposition. However, one draw-back of this method is poor step coverage in applications of ultralarge-scale integration metallization technology. Metal organic chemical vapor deposition (MOCVD) is a good approach to address this problem. In addition, the MOCVD method has several advantages, such as conformal coverage, uniform deposition over large substrate areas and less substrate damage. For this reasons, cobalt films have been studied using MOCVD and various metal-organic precursors. In this study, we used $C_{12}H_{10}O_6(Co)_2$ (dicobalt hexacarbonyl tert-butylacetylene, CCTBA) as a cobalt precursor because of its high vapor pressure and volatility, a liquid state and its excellent thermal stability under normal conditions. Furthermore, the cobalt film was also deposited at various $H_2/NH_3$ gas ratio(1, 1:1,2,6,8) producing pure cobalt thin films with excellent conformality. Compared to MOCVD cobalt using $H_2$ gas as a reactant, the cobalt thin film deposited by MOCVD using $H_2$ with $NH_3$ showed a low roughness, a low resistivity, and a low carbon impurity. It was found that Co/$TaN_x$ film can achieve a low resistivity of $90{\mu}{\Omega}-cm$, a low root-mean-square roughness of 0.97 nm at a growth temperature of $150^{\circ}C$ and a low carbon impurity of 4~6% carbon concentration.

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Enzymatic Desugarization of Egg White for Drying with Glucose Oxidase (Glucose Oxidase에 의(依)한 건조용(乾燥用) 난백(卵白)의 효소적(酵素的) 탈당(脫糖))

  • Song, Kwang Taek;Oh, Hong Rock;Kwon, Soon Ki;Lee, Bong Duck
    • Korean Journal of Agricultural Science
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    • v.11 no.2
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    • pp.223-232
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    • 1984
  • The influences of some factors involved in removing glucose from egg white by the glucose oxidase system be fore drying were investigated. And the properties between foams prepared from raw and enzyme-treat ed egg white was compared. The results obtained we re summarized as follows; 1. The dianisidine method was found to be suitable for the measurement of egg white glucose in the range up to 100ug/ml. 2. The optimal pH of glucose oxidase activity on glucose was found to be a bout 5.0, and thats activity was most stable in the pH range of about 4.0~5.0 when that enzyme was treat ed for 30 minute at $50^{\circ}C$. 3. The optimal temperature for glucose oxidase reaction on glucose was found to be about $20^{\circ}C$, and that enzyme activity was s table up to $50^{\circ}C$. 4. The removing rate of glucose from egg white with glucose oxidase was influenced by the enzyme concentration, pH and oxygen addition, and the react ion time of the desugarization was about 10 hour sunder the conditions of 0.5% hydrogen peroxide, pH 7.0 and $26^{\circ}C$. 5. All of the each egg white treated with glucose oxidase, glucose oxidase+pancreatin, glucose oxidase+trypsin showed highly foaming ability than that of natural egg white(control), but thats foam stability, on the contrary, was reversed.

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Mechanisms of Immobilization and Leaching Characteristics of Arsenic in the Waste Rocks and Tailings of the Abandoned Mine Areas (폐광산 지역 폐광석 및 광미에서 비소의 고정 메커니즘과 용출특성)

  • Kang Min-Mu;Lee Pyeong-Koo
    • Economic and Environmental Geology
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    • v.38 no.5 s.174
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    • pp.499-512
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    • 2005
  • EPMA determined that Fe(Mn)-(oxy)hydroxides and well-crystallized Fe-(oxy)hydroxides and could contain a small amount of As $(0.3-11.0\;wt.\%\;and\;2.1-7.4\;wt.\%\;respectively)$. Amorphous crystalline Fe-(oxy) hydroxide assemblages were identified as the richest in As with $28-36\;wt.\%$. On the ternary $As_2O_5-SO_3-Fe_2O_3$ diagram, these materials were interpreted here as 'scorodite-like'. Dissolved As was attenuated by the adsorption on Fe-(oxy) hydroxides and Fe(Mn)-(oxy) hydroxides and/or the formation of an amorphous Fe-As phase (maybe scorodite: $FeAsO_4\cdot2H_2O$). Leaching tests were performed in order to find out leaching characteristics of As and Fe under acidic conditions. At the initial pHs 3 and 5, As contents dissolved from tailings of the cheongyang mine significantly increased after 7 days due to the oxidation of As-bearing secondary minerals (up to ca. $2.4\%$ of total), while As of Seobo mine-tailing samples was rarely released (ca. $0.0-0.1\%$ of total). Dissolution experiments at an initial pH 1 liberated a higher amount of As (ca. $1.1-4.2\%$ of total for Seobo tailings, $1.5-14.4\%$ of total for Cheongyang tailings). In addition, good correlation between As and Fe in leached solutions with tailings was observed. The kinetic problems could be the important factor which leads to increasing concentrations of As in the runoff water. Release of As from Cheongyang tailings can potentially pose adverse impact to surface and groundwater qualities in the surrounding environment, while precipitation of secondary minerals and the adsorption of As are efficient mechanisms for decreasing the mobilities of As in the surface environment of Seobo mine area.

Protective effect of ethanolic extract of antler-shaped Ganoderma lingzhi against oxidative stress in PC12 neuronal cell line (PC12 신경세포주에서 녹각영지버섯 주정 추출물의 산화 스트레스 개선 효과)

  • Kim, Hyung Don;Lee, Eun Young;Park, Jeong-Yong;Seo, Kyung Hye;Lee, Kang-Hyo;Choi, Jehun;Han, Jae-Gu;Cho, Jae-Han;Lee, Seung Eun
    • Journal of Mushroom
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    • v.16 no.3
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    • pp.213-217
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    • 2018
  • This study was carried out to identify medicinal mushrooms with protective effects against oxidative stress in PC12 neuronal cell line, followed by evaluation of their antioxidant property. Extracts of medicinal mushrooms, including Ganoderma lucidum extract (GLE), antler-shaped Ganoderma lingzhi extract (AGLE), Hericium erinaceus extract (HEE), and Sanghuangporus baumii extract (SBE), were screened for cytotoxicity using MTT assay. None of the extracts up to $10{\mu}g/ml$ concentration affected cell viability. These extracts were further checked for their protective effect against oxidative stress-induced reactive oxygen species (ROS) production. Exposure to $50{\mu}M$ $H_2O_2$ induced ROS generation in PC12 cells, which was inhibited only by treatment with AGLE. In addition, inhibition of $H_2O_2-induced$ ROS generation by AGLE was found to be in a dose-dependent manner (2.5, 5, and $10{\mu}g/ml$). Microscopic examination of DCF fluorescence for detection of ROS showed a similar pattern. Further, antioxidant activity of AGLE was determined by ABTS radical cation assay, and its $IC_{50}$ was found to be $46.90{\pm}0.31{\mu}g/ml$. Taken together, these results suggest that AGLE may help to alleviate oxidative stress in PC12 neuronal cells.

Effects of Dietary Enterococcus faecium SF68 on Growth Performance, Nutrient Digestibility, Blood Characteristics and Faecal Noxious Gas Content in Finishing Pigs

  • Chen, Y.J.;Min, B.J.;Cho, J.H.;Kwon, O.S.;Son, K.S.;Kim, I.H.;Kim, S.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.3
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    • pp.406-411
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    • 2006
  • The objective of this study was to investigate the effects of feeding probiotic (Enterococcus faecium SF68, EF) on growth performance, nutrient digestibility, blood characteristics and faecal noxious gas content in finishing pigs. A total of eighty [($Landrace{\times}Yorkshire$)${\times}Duroc$] pigs with an initial BW of $50.47{\pm}2.13kg$ were used in this 8-week experiment. Pigs were allotted to four treatments (4 replicates per treatment and 5 pigs per pen) according to a randomized complete block design. Dietary treatments were: 1) CON (control; basal diet), 2) CTC (control diet+0.1% antibiotic, chlortetracycline), 3) EF1 (control diet+0.1% probiotic, EF) and 4) EF2 (control diet+0.2% probiotic, EF). During weeks 0-4, ADG was not affected by the addition of antibiotic or EF (p>0.05). In weeks 4-8, ADG tended to increase in CTC and EF treatments compared to CON treatment (p<0.10). ADFI and gain/feed were not affected in each 4-week period and the entire experimental period (p>0.05). Digestibilities of DM and N were higher in EF supplemented treatments than in CON and CTC treatments (p<0.05). Blood characteristics of WBC, RBC and lymphocyte were not affected in pigs given diets containing EF (p>0.05). Supplementation of EF in the diet decreased faecal ammonia nitrogen ($NH_3$-N) and hydrogen sulphide ($H_2S$) concentrations (p<0.05). Faecal acetic acid concentration tended to decrease (p<0.10) while propionic acid and butyric acid concentrations were significantly lower on diets with EF supplementation than on the diet containing antibiotic (p<0.05). In conclusion, dietary supplementation of EF can increase nutrient digestibility and decrease faecal $NH_3$-N, $H_2S$ and volatile fatty acid (VFA) concentrations in finishing pigs.

Inhibitory Substance Produced by Aspergillus sp. on the Snake Proteinase - Culture Conditions for the Production of Inhibitor - (Aspergillus 속 균주가 생성하는 사독 proteinase에 대한 저해물질- 저해물질의 생산조건 -)

  • Nam Joo Hyun;Jung Hwn Seu
    • Microbiology and Biotechnology Letters
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    • v.15 no.2
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    • pp.135-139
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    • 1987
  • Aspergillus sp. MK-24 was cultured at 3$0^{\circ}C$ in the medium consisting of 2% glucose, 0.2% NaNO$_3$, 0.02% $K_2$HPO$_4$, 0.02% MgSO$_4$ 7$H_2O$, 0.02% KCl, and at initial pH of 5.0. The production of the inhibitor on venom proteinase reached to the maximum in 7 days. Sodium nitrate or potassium nitrate as a nitrogen source was favorable. The production of inhibitor was not affected by the addition of most of the inorganic salt used but depressed by lead, zinc, cobalt, mercuric or silver salts.

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Nitrogen and Phosphorus Removal Efficiency of Aluminum Usage in DEPHANOX Process (DEPHANOX 공정 내 알루미늄 첨가에 따른 질소 및 인 제거 효율 평가)

  • Lee, Beom;Park, Noh-Back;Tian, Dong-Jie;Heo, Tae-Young;Jun, Hang-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.5
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    • pp.295-303
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    • 2012
  • Removal of total nitrogen (T-N) and total phosphorus (T-P) was evaluated in a DEPHANOX process by adding Al(III) to the separator to maintain T-P in the final effluent below 0.2 mg/L. pH in each reactor was maintained 7~8 after addition of Al(III) to the levels of 5, 10, 15 mg/L. The removal efficiency of COD and T-N decreased at higher Al(III) dose, but T-P removal efficiency increased from 76.28 to 84.02, 94.66% at Al(III) dose of 5, 10, 15 mg/L, respectively. T-P in effluent showed 0.17 mg/L at Al(III) dose of 15 mg/L. Minimum 15 mg/L of Al(III) was required to maitain T-P below 0.2 mg/L in the final effluent.

The Hydraulic Characteristics of Liquid Shotcrete Accelerators within Cement System (시멘트 계에서 액상 숏크리트용 급결제의 수화 특성에 관한 연구)

  • Shin Jin-Yong;Kim Jae-Young;Hong Ji-Sook;Suh Jeong-Kwon;Rho Jae-Seong
    • Journal of the Korea Concrete Institute
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    • v.17 no.6 s.90
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    • pp.1011-1018
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    • 2005
  • The influence of liquid shotcrete accelerators(alkali aluminate, two types of alkali-free) was investigated. Comparing to the existing alkali aluminate accelerator, new alkali-free accelerator, AF2, shortened initial and final setting of cement system, and after curing for 1 day compressive strength was analogous with others. On the other hand, compressive strength of specimen cured for 12 hour was the highest by the addition of alkali aluminate accelerator, but final strength was the lowest by that. But compressive strengths of AF1, AF2 were similar to Plain up to 28day. Further from XRD(X-Ray Diffractometer) and DSC(Differential Scanning Calorimeter) analyses, we confirmed that setting promoted by alkali aluminate was mainly because of Ca(OH)2(calcium hydroxide), but the accelerating behavior of alkali-free was influenced by the needle-like ettringite$(6CaO{\cdot}Al_2O_3{\cdot}3SO_3{\cdot}32H_2O)$ crystal.

Influence of Compost Recycling and Magnesium Supplement on Physical and Chemical Traits of Animal Manure Compost

  • Lee, Jin-Eui;Kwag, Jung-Hoon;Ra, Chang-Six
    • Journal of Animal Science and Technology
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    • v.52 no.6
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    • pp.513-519
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    • 2010
  • A series of experiments were performed to study the influence of the following parameters on the physical traits and composition of swine manure compost: (1) addition of magnesium (Mg) at a molar ratio of 1.2 with respect to $PO_4$, and (2) reutilization of compost containing $MgNH_4PO_4{\cdot}6H_2O$ (magnesium ammonium phosphate, MAP). Three independent batch tests were conducted for replication: batch test I-control (C) and Mg added (T), batch test II-C, T and compost recycle ($T_{R1}$), and batch test III-C, T and compost recycle ($T_{R2}$). Magnesium addition and compost reutilization had no adverse effect on the degradation of organic matter. Reuse of the compost, however, had a clear effect on the total nitrogen (TN) and total phosphorus (TP) contents in the final compost. Repeated compost reutilization as a bulking material was resulted in composts rich in N and P. Upon adding the Mg supplement to the composting materials, the ortho-phosphate (OP) to TP ratio decreased due to the MAP crystallization reaction. The decrease in the OP/TP ratio and the increase in the TP content of the compost indicate that water-soluble phosphate is converted into a slow-release phosphate by the formation of crystals during composting. X-ray diffraction analysis of the irregular shaped crystals in the compost indicated that they are MAP crystals and that the crystallization of MAP begins immediately after the addition of the Mg supplement. The Mg addition to composting materials and the reutilization of compost as a bulking material would be a practical means to conserve nutrient content.