• Journal of the Korean Magnetic Resonance Society
• /
• v.14 no.2
• /
• pp.76-87
• /
• 2010

The structural phase transition of $Cs_2MnCl_4{\cdot}2H_2O$ single crystals was investigated by determining the $^{133}Cs$ spin-lattice relaxation time $T_1$. The number of resonance lines in the $^{133}Cs$ spectrum changes from seven to one near 375 K, which means that above 375 K the Cs sites are symmetric. Further, the $T_1$ of the $^{133}Cs$ nucleus undergoes a significant change near 375 K, which coincides with the change in the splitting of the $^{133}Cs$ resonance lines. The change in $T_1$ near $T_C$ is related to the loss of $H_2O$, and means that the forms of the octahedra of water molecules surrounding $Cs^+$ are disrupted.