• 한국응용과학기술학회지
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• 제22권3호
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• pp.250-256
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• 2005

This study was aimed to investigate treatment feasibility of leachate from D landfill that is located in gyr대ungbuk. From the analytical results of leachate, organic and nonbiodegradable matters were contained in high concentration. Thus chemical treatment was introduced to degrade nonbiodegradable matters in pre or post biological process. Two types of Fenton oxidation were adapted in this study. The first one is pre treatment process before biological treatment. The second one is post treatment process after biological treatment. The optimal conditions of both treatment methods were investigated as follows. In case of pre treatment process, the optimal conditions appeared in $Fe^{+2}/H_2O_2$(mmol/mmol): 0.1, $H_2O_2/CODcr$(mg/mg): 27.0, pH: 3 and reaction time: 2hrs. On the other hand, in case of post treatment process, the optimal conditions appeared in $Fe^{2+}$(mmol/mmol): 0.14, $H_2O_2/COD_{cr}$(mg/mg): 57.4, pH: 3 and reaction time: 1.25hrs. In the above optimal conditions, high COD removal was obtained in pre and post treatment process. Also it can expect that Fenton oxidation converted nonbiodegradable matters into biodegradable matters.

• 한국환경보건학회지
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• 제27권4호
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• pp.63-71
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• 2001

PM 2.5/ samples were measured at two sites, Hadan(suburban site) and Anrak (roadside site) in Busan area. PM 2.5/ sampling was performed for 24-hour intervals by the FH9.5 particulate sampler. Aerosol samples were collected on PTFE filter. A total of 60 particulate samples were collected, dad samples were measured for Particulate mass concentration, metallic elements (Cr, Mn, Ni. Cu. Se, Fe, Pb, and Zn) and waer-soluble elements (C $l^{[-10]}$ , N $O_{3}$$^{[-10]}$ ,S $O_{4}$$^{2-}$, N $H_{4}$$^{+}$, $Ca_{2}$$^{+}$, $Mg_{2}$$^{+}$ and $^{+}$.Mass concentration in Hadan ranged 24.23~57.12 $\mu\textrm{g}$/㎥ and 60.22~72.12 $\mu\textrm{g}$/㎥m Yellow Sand Events. Major cations in Hadan and Anrak site is N $H_{4}$$^{+}$and N $a^{+}$ respectively. SO42$^{[-10]}$ was the abundant specie in the PM 2.5 fraction for Hadan site an dAnrak site. Hadan site showed igher concentration in S $O_{4}$$^{2.1}$ and N $H_{4}$ $^{+}$ In Anrak site the concentration of S $O_{4}$/sip 2-/and N $a^{+}$ was higher than other ions Prominent metallic elements were Fe and Pb in two sites. Principal component analysis showed that main source of PM 2.5 aerosol particles was non-metal related source which was resulted in relating elements as Cr, Ni, and Pb at Hadan site, Anrak site also has resulted PM2.5 aerosol paricles source, which was related its element like Zn, and Ni,. The SAS package analysis also showed that long-range transport effect at Hadan area due to Yellow Sand Event by the prevailing weaterlies.ling weaterlies.

• 전기화학회지
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• 제8권4호
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• pp.172-176
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• 2005

차세대 5V급 양극활물질로 각광받고 있는 $LiNi_{0.5}Mn_{1.5}O_4$는 기존의 $LiMn_2O_4$ spinel 물질의 $Mn^{3+}$을 $Ni^{2+}$으로 치환하여 5V 영역에서 $Ni^{2+}/Ni^{4+}$ 산화/환원 반응이 가능하게 한 물질이다. 기존의 $LiMn_2O_4$는 낮은 초기 용량과 충 방전에 따른 빠른 용량감소를 보이는 단점을 가지고 있어 이 문제를 극복하기 위해 Mn의 일부를 다른 금속으로 치환하여 $LiM_yMn_{2-y}O_4$ (M=Cr, Al, Ni, Fe, Co, Cu, Ca)을 만드는 방법이 활발히 연구되고 있다. 본 연구에서는 기계 화학적 합성법을 이용하여 합성한 $LiNi_{0.5}Mn_{1.5}O_4$의 전기화학적 특성에 대해 연구하였다. 이 물질은 기존의 $LiMn_2O_4$보다 에너지 밀도가 높으며 저가 및 친환경성 등으로 앞으로 HEV 등에서 그 활용성이 크게 기대된다. 볼밀을 이용하여 여러가지 조건(출발물질 조건, 볼밀조건, 열처리조건 등)에서 $LiNi_{0.5}Mn_{1.5}O_4$을 합성한 결과 기계화학적 방법으로는 $Ni^{2+}$가 $Mn^{3+}$를 완전히 치환하지 못하여 $4.0{\sim}4.1V$의 전압에서 $Mn^{3+}/Mn^{4+}$의 산화/환원과 관련된 peak가 발생하였다. Ni 원료 물질로써 수산화 물질을 사용하고 열처리 온도를 $800^{\circ}C$로 하였을 때 최상의 성능을 나타내었다.

• Nuclear Engineering and Technology
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• 제54권3호
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• pp.984-990
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• 2022

Corrosion release behavior of Alloy 690 in high-temperature water was investigated under the conditions of injected Zn concentrations of 0 ppb, 10 ppb and 50 ppb. A protective oxide film composed of Zn(Fe_xCr_1-x)₂O₄ and Cr₂O₃ was formed with Zn injection, resulting in a better corrosion resistance. In comparison with the Zn-free condition, the corrosion release rate under the Zn-injection conditions was smaller. The corrosion release inhibiting factors were 1.7 and 1.9 under the conditions of 10 ppb and 50 ppb Zn-injection respectively. A foreseen application of the corrosion and corrosion release rates has been proposed and discussed.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제1권1호
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• pp.1-9
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• 1997

We investigated the depth profiles of heavy metals in the surface sediments at Heedong reservoir in Pusan. Sampling was done at the intervals of 50 m of drift along the water channel into the reservoir. All samples were analyzed with an ICP-AES. We determined the content of Zn, Pb, Cd, Mn, Cu, Cr, and Fe. The overall mean content of these heavy metals were observed to $(2.9\pm1.2){\times}10^{-3},\;(1.3\pm0.7){\times}10^{-3},$ $(1.9\pm2.1){\times}10^{-4},$ $(2.3\pm1.1){\times}10^{-2},\;(1.6\pm1.0){\times}10^{-3},\;and\;(4.5\pm2.6){\times}10^{-4}$ ppm/ppmFe, respectively excluding iron data. Mean contents of Cu show an increasing trend toward the surface of sediments, while those of Cd show a decreasing trend, and those of Pb and Cr are relatively stable. Comparing with the contents of heavy metals in soils at two sites of Kumjeong mountain, enrichment factors of heavy metals in the surface sediments were determined. Among heavy metals we investigated, copper showed the largest value of enrichment factor. Considering the maximum content of heavy metals in the surface sediment, the values of enrichment factors of Cu, Cd and Cr were significant, which were 22, 8.1 and 4.0, respectively. In leaching experiment, it appeared that Pb, Cd, Cr, and Fe in sediments were hardly leached out into water, We also examined the effect of pH on the content of heavy metals.

• Corrosion Science and Technology
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• 제7권2호
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• pp.119-124
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• 2008

Steel is generally not corrosion resistant to water with formation of non protective rusts on its surface. Rusts are composed of iron oxides such as $Fe_3O_4$, $\alpha-$, $\beta-$, $\gamma-$and ${\delta}-FeOOH$. However, steel, particularly weathering steel containing small amounts of Cu, Ni and Cr etc., shows good corrosion resistance against rural, industrial or marine environment. Its corrosion rate is exceedingly small as compared with that of carbon steel. According to the exposure test results undertaken in outdoor environments, the atmospheric corrosion rate for weathering steel is only 1 mm for a century. Atmospheric corrosion for steels proceeds under alternate dry and wet conditions. Dry condition is encountered on steel surface on fine or cloudy days, and wet condition is on rainy or snowy days. The reason why weathering steel shows superior atmospheric corrosion resistance is due to formation of corrosion protective rusts on its surface under very thin water layer. The protective rusts are usually composed of two layer rusts; the upper layer is ${\gamma}-FeOOH$ termed as lepidocrocite, and inner layer is nano-particle ${\alpha}-FeOOH$ termed as goethite. This paper is aimed at elucidating the atmospheric corrosion mechanism for steel in comparison with corrosion in bulky water environment by use of empirical data.The summary is as follows: 1. No corrosion protective rusts are formed on steel in bulky water. 2. Atmospheric corrosion for steel is the corrosion under wetting and drying conditions. Corrosion and passivation occur alternately on steel surface. Steel, particularly weathering steel with small amounts of alloying elements such as Cu, Ni and Cr etc. enhances forming corrosion protective rusts by passivation.

• 한국분말재료학회지
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• 제24권4호
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• pp.292-297
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• 2017

A metallic oxide layer of a heat-resistant element contributes to the high-temperature oxidation resistance by delaying the oxidation and has a positive effect on the increase in electrical resistivity. In this study, green compacts of Fecralloy powder mixed with amorphous and crystalline silica are oxidized at $950^{\circ}C$ for up to 210 h in order to evaluate the effect of metal oxide on the oxidation and electrical resistivity. The weight change ratio increases as per a parabolic law, and the increase is larger than that observed for Fecralloy owing to the formation of Fe-Si, Fe-Cr composite oxide, and $Al_2O_3$ upon the addition of Si oxide. Si oxides promote the formation of $Al_2O_3$ and Cr oxide at the grain boundary, and obstruct neck formation and the growth of Fecralloy particles to ensure stable electrical resistivity.

• 자원환경지질
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• 제25권4호
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• pp.435-446
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• 1992

REE, major and trace elements analyses of the Jurassic Daebo granite and Cretaceous Bulguksa granite were carried out to interpet their petrogenesis and relationships between petrogenesis and tectonics. Analytical results are summarized as follows. (1) $SiO_2$ content of the Bulguksa granite (aver. 74.6%) are significantly higher than those of the Daebo granite (aver. 68.1%). Major elements of $TiO_2$, $Al_2O_3$, $P_2O_5$, CaO, MgO, Total FeO, and trace elements of Co, V and Sr are negatively correlated with $SiO_2$. Incompatible elements such as Ba, Sr, Y, Zr and HREE are contained differently in the Bulguksa granites distributed in between Okchon folded belt and Kyongsang sedimentary basin. (2) Trace element abundances show a good discrimination between two goups of granitic rocks. Ba, Sr and V are enriched in Daebo granites, while Zn and Cr are depleted in them. (3) Jurassic granites have quite different Eu anomalies and REE patterns from those of Cretaceous granites: Large negative Eu anomaly in the former and mild or absent Eu anomaly in the latter. The large Eu negative of Cretaceous granitic rocks are interpreted as a differentiated product of fractional crystallization of granitic magma from the upper mantle. Meanwhile, the Daebo plutonic rocks was resulted from the partial melting of subcrustal material or crustal contamination during ascending granitic magma from the mantle. Senario of igneous activities of Mesozoic age in South Korea was proposed based on Kula-Pacific ridge subduction model.

• Bulletin of the Korean Chemical Society
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• 제32권9호
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• pp.3281-3289
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• 2011

The materials composed of the 3d series transition metals are introduced into the hydrocarbon steam-reforming reaction in order to enhance the $H_2$ production and abruptly depress the catalytic deactivation resulting from the strong sintering between the Ni component and the ${\gamma}-Al_2O_3$ support. The conventional impregnation method is used to synthesize the Ni/3d series metal/${\gamma}-Al_2O_3$ materials through the sequentially loading Ni source and the 3d series metal (Ti, V, Cr, Mn, Fe, Co, Cu, and Zn) sources onto the ${\gamma}-Al_2O_3$ support. The Mnloaded material exhibits a significantly higher reforming reactivity than the conventional Ni/${\gamma}-Al_2O_3$ and the other Ni/3d series metal/${\gamma}-Al_2O_3$ materials. Particularly the addition of Mn selectively improves the $H_2$ product selectivity by eliminating the formation of $CH_4$ and CO. The $H_2$ production is maximized at a value of 95% over Ni(0.3)/Mn(0.3)/${\gamma}-Al_2O_4$(1.0) with a butane conversion of 100% above $750^{\circ}C$ for up to 55 h.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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• pp.207-207
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• 2003

최근 광촉매 재료로 각광받고 있는 TiO$_2$는 band gap 에너지가 3.0-3.2eV로 자외선 영역과 일부 가시광선 영역에서 활성을 갖는 것으로 알려져 있다. 따라서 용액 중에 결정화 및 안정화 되어있는 TiO$_2$의 band gap 에너지를 낮춘다면 가시광 영역의 광반응을 얻을 수 있다. 이에 본 연구는 G. Sato등이 제안한 방법으로 TiO$_2$ sol을 제조할 때 band gap 에너지를 낮추고자 천이 금속원소를 첨가하여 복합 및 담지된 TiO$_2$계 복합 sol을 합성하고자 하였다 출발원료는 TiC1$_4$를 가수분해하여 제조한 TiOCl$_2$에 천이금속원소인 V, Cr, Fe, Ni, Nb 등의 chloride 화합물을 첨가하여 중화 및 세척과정을 거친 후, 과산화수소수에 용해하여 전구체 용액인 titania peroxo용액을 제조하였다 제조된 전구체 용액은 온도와 시간을 변수로 각각 열처리하여 TiO$_2$계 복합 sol을 합성하였다. 제조된 시편은 X-선 회절 분석, 투과전자현미경, particle size analyzer, ζ-potential analyzer 및 UV-VIS Spectrometer 통을 이용하여 천이금속 첨가에 따른 TiO$_2$계 복합 sol의 형성과정과 특성변화를 관찰하였다.