• Title/Summary/Keyword: $CcH_2$

Search Result 405, Processing Time 0.027 seconds

Theoretical Calculations of Infrared Bands of CH3+ and CH5+

  • Matin, Mohammad A.;Jang, Joonkyung;Park, Seung Min
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.7
    • /
    • pp.2051-2055
    • /
    • 2013
  • Existing theoretical calculations predict that infrared spectra of the two most fundamental reactive carbo-ions, methyl cation $CH{_3}^+$ with $D_{3h}$ symmetry and protonated methyl cation $CH{_5}^+$ with $C_s(I)$, $C_s(II)$, and $C_{2v}$ symmetries, appear together in the 7-${\mu}m$ region corresponding to the C-H bending modes. Vibrational band profiles of $CH{_3}^+$ and $CH{_5}^+$ have been compared by ab initio calculation methods that use the basis sets of MP2/aug-cc-pVTZ and CCSD(T)/cc-pVTZ. Our results indicate that the bands of rotation-vibration transitions of $CH{_3}^+$ and $CH{_5}^+$ should overlap not only in the 3-${\mu}m$ region corresponding to the C-H stretching modes but also in the 7-${\mu}m$ region corresponding to the C-H bending modes. Five band intensities of $CH{_5}^+$ among fifteen vibrational transitions between 6 and 8 ${\mu}m$ region are stronger than those of the ${\nu}_2$ and ${\nu}_4$ bands in $CH{_3}^+$. Ultimate near degeneracy of the two bending vibrations ${\nu}_2$ and ${\nu}_4$ of $CH{_3}^+$along with the stronger intensities of $CH{_5}^+$ in the three hydrogen scrambling structures may cause extreme complications in the analysis of the high-resolution carbo-ion spectra in the 7-${\mu}m$ region.

High Efficiency FPCB Antenna for the Dual Band Mobile Phone (휴대폰용 2중 대역 고효율 FPCB 안테나)

  • Seo, Sang-Hyuk;Son, Tae-Ho;Jo, Young-Min
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.20 no.11
    • /
    • pp.1194-1200
    • /
    • 2009
  • An internal antenna which has 1 cc volume was implemented on the FPCB(Flexible Printed Circuit Board) for the mobile phone. We increased antenna gain and efficiency by the applying of current direction concept on the antenna pattern for this small antenna. Short antenna length for the GSM band was compensated by the spiral inductor on the FPCB. For broadening bandwidth on GSM band, it's applied 2 spiral inductors. A conductor pattern for the DCS band was positioned perpendicular with the FPCB. Antenna was implemented on FPCB that is dielectric constant 4.4 and thickness 0.05 mm, and FPCB was attached on a carrier dimensioned $L{\times}W{\times}H=30{\times}7{\times}5\;mm$. Measurements showed that max. VSWR 2:1, efficiency 42.49~60.95 % and 47.95~73.21 %, average gain -3.72~-2.15 dBi and -3.19~-1.35 dBi on the GSM and DCS band, respectively. These results are good performances among the small antenna. And the radiation patterns are omnidirectional on the H-plane to both band.

Effects of Bedding Material Composition in Deep Litter Systems on Bedding Characteristics and Growth Performance of Limousin Calves

  • Meng, J.;Shi, F.H.;Meng, Qingxiang;Ren, L.P.;Zhou, Z.M.;Wu, H.;Zhao, L.P.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.28 no.1
    • /
    • pp.143-150
    • /
    • 2015
  • The objective of this study was to evaluate the effects of different litter mixture compositions on bedding system temperature, pH and volatile fatty acid and ammonia-N ($NH_3$-N) content, and the serum physico-chemical parameters and growth indices of calves. Thirty-two Limousin calves ($280{\pm}20kg$) were randomly assigned to four groups (n = 8 for each group) according to the bedding system used: i) control with soil only (CTR); ii) mixture with 50% paddy hulls (PH), 30% saw dusts (SD), 10% peat moss (PM) and 10% corn cobs (CC) (TRT1); iii) mixture with 15% PH, 15% SD, 10% PM, 40% CC, and 20% corn stover (CS) (TRT2); iv) mixture with 30% PH, 10% PM, 40% CC, and 20% CS (TRT3). The litter material combinations of different treatments were based on the cost of bedding system materials in China. The cost of four treatments from low to high: Control$NH_3$-N level (271.83 to 894.72 mg/kg) was lowest for TRT1 (p<0.0001) and highest for TRT2 (p<0.0001). The acetate, propionate and butyrate levels were highest for the control group (p<0.0001). In all the groups, the pH value (6.90 to 9.09) increased at the beginning and later remained stable at below 9.09. The temperature of deep litter increased at the first week and reached the maximum ($42.1^{\circ}C$) on day 38. 3,5,3'-Triiodothyronine ($T_3$) levels in the TRT1 group animals (p<0.0001) were lower than those in the control and TRT2 animals. 3,5,3',5'-Tetraiodothyronine ($T_4$) in the TRT1 group (p = 0.006) was lower than that in the other treatment groups. Cortisol (COR) in the control and TRT1 group was lower (p<0.0001) than that in the TRT2 and TRT3 groups. Corticosterone (CORt) in the control group was higher (p<0.0001) than that in the treatment groups. The findings indicate that the deep litter bedding systems provided better conditions for animal health and growth performance compared with the control system. Furthermore, the litter composition of TRT1 was found to be optimal among the three treatment groups.

A Study on the Synthesis of $Mn_3O_4$ and the Decomposition and Adsorption of $CO_2$ ($Mn_3O_4$의 합성과 $CO_2$ 분해 및 흡착에 관한 연구)

  • Kim Seung-Ho;Park Young-Goo;Ko Jae-Churl
    • Journal of the Korean Institute of Gas
    • /
    • v.4 no.2 s.10
    • /
    • pp.27-32
    • /
    • 2000
  • In this study, $Mn_3O_4$ was synthesized by the different equivalent ratios using solution of $MnCL_2 {\cdot} 4H_2O$ and NaOH. We have investigated the crystal structure and surface area by XRD, BET Method, studied on the decompositon and adsorption of carbon dioxide with synthesized $Mn_3O_4$. As the results, we surveyed that main peak was $Mn_3O_4$, some Peaks were $MnO_2$ and $Mn_5O_8$ The specific surface area was ranged from $13.92m^2/g$ to $32.33m^2/g$. The decomposition of $CO_2$ was observed by the differential equivalent ratios at $450^{\circ}C$. $CO_2$ was well decomposed at equivalent ratio of 0.75. The amount of chemisorption of $CO_2$ was ranged from 2.885 to 19.628cc/g. Optimal equivalent ratio was 1.00 for the chemisorption of $CO_2$.

  • PDF

Physicochemical Properties of Various Blends of Peatmoss and Perlite and the Selection of Rooting Media for Different Growing Seasons (다양한 종류의 피트모스와 펄라이트 혼합에 따른 물리·화학성 변화와 계절별 육묘를 위한 상토 선발)

  • Shim, Chang Yong;Kim, Chang Hyeon;Park, In Sook;Choi, Jong Myung
    • Horticultural Science & Technology
    • /
    • v.34 no.6
    • /
    • pp.886-897
    • /
    • 2016
  • The physical properties of rooting media for the establishment of plugs in a greenhouse are modified according to variations in the greenhouse environment throughout the season. In this study, we established a standard for rooting media for the production of plug seedlings for each growing season (summer, winter and spring fall). Eight types of peatmoss (PM) and 4 types of perlite (PL) commonly used in Korea were collected and blended with the ratio of 7 parts PM to 3 parts PL (v/v) to make 32 different rooting media blends. We determined the total porosity (TP), container capacity (CC), air-filled porosity (AFP), pH, and electrical conductivity (EC) of the 32 media blends, and 6 media blends were selected for seasonal use. We also conducted additional analyses for plant easily available water (EAW), buffering water (BW), cation exchange capacity (CEC), and nutrient contents in the 6 media blends. The TP, CC, and AFP of the 32 media blends ranged from 64.7 to 96.0%, 42.9 to 90.1%, and 1.3 to 27.8%, respectively, indicating that the physical properties were strongly influenced by the type of PM and PL. The pH and EC of the PMs ranged from 2.96 to 3.81 and 0.08 to $0.47dS{\cdot}m^{-1}$, respectively. However, after blending the PM with the PL the pH was raised and the EC was lowered The media blends selected for the summer growing season were Blonde Golden peatmoss (BG) + No. 1 perlite size < 1 mm (PE1) and Latagro 0-10 mm (L1) + No. 2 perlite size 1-2 mm (PE2). These two media blends had 89.8-90.9% of TP, 80.8-81.3% of CC, and 9.0-9.7% of AFP. The media blends selected for the winter growing season were Sfagnumi Turvas (ST) + PE2 and Latagro 20-40 mm (L3) + PE2. These media blends had 79.9-86.7% of TP, 60.4-74.9% of CC, and 11.8-19.6% of AFP. The TP, CC, and AFP of two media blends, BG + No.3 perlite 2-5 mm (PE3) and Orange peatmoss (O) + PE3, selected for the spring and fall growing seasons, respectively, were 85.2-87.3%, 77.9%, and 7.4-9.4%, respectively. The percentage of EAW of the media blends selected for the spring, summer, and winter growing seasons ranged from 24.2-24.9%, 22.0-28.6%, and 18.0-21.8%, respectively, but the percentages of BW were not significantly different among the selected root media blends. The pH, EC, and CEC of the 6 selected media blends ranged from 3.11-3.97, $0.06-0.26dS{\cdot}m^{-1}$, and $97-119meq{\cdot}100g^{-1}$, respectively.

Single Nucleotide Polymorphisms[SNPs] of DNA repair genes; hMLH1, hMSH2 and ATM in Healthy Korean (한국인에서의 DNA repair gene[hMLH1, hMSH2 및 ATM]의 Single Nucleotide Polymorphisms[SNPs]의 빈도)

  • 정현숙;김태연;조윤희;김양지;정해원
    • Environmental Mutagens and Carcinogens
    • /
    • v.23 no.1
    • /
    • pp.16-22
    • /
    • 2003
  • Single nucleotide polymorphisms (SNPs) are alterations in DNA base that occur most frequently throughout the human genome. The SNPs of DNA repair genes, hMLH1, hMSH2 and ATM, among 100 Korean people were analyzed using Dynamic Allele specific Hybridization (DASH) techniques. Mutation at the position of exon 38 (GA) and exon 10 (CG) of ATM gene, mutation at the position of exon 8 (AG), and exon 1 (AG) of hMLH1 gene and exon 14 (AG) of hMSH2 gene were investigated. No mutation at the selected position of ATM gene and hMSH1 gene was found. However, while there was no mutation at the position of exon of hMSH2 gene, mutation was found at the promotion region (CT) with the frequency of 24% CC, 36% CT and 62% TT genotyes. This results might be used as baseline data for research on SNP of Korean population.

  • PDF

SNPs of Excision Repair Cross Complementing Group 5 and Gastric Cancer Risk in Chinese Populations

  • Yang, Wan-Guang;Zhang, Shan-Feng;Chen, Ju-Wu;Li, Li;Wang, Wan-Peng;Zhang, Xie-Fu
    • Asian Pacific Journal of Cancer Prevention
    • /
    • v.13 no.12
    • /
    • pp.6269-6272
    • /
    • 2012
  • We conducted a case-control study to determine the association between several potential SNPs of excision repair cross complementing group 5 (XPG) and gastric cancer susceptibility, and roles of XPG polymorphisms in combination with H.pylori infection in determining risk of gastric cancer. In our study, we collected 337 newly diagnosed gastric cancer cases and 347 health controls. Three SNPs of XPG, rs2296147T>C, rs2094258C>T and rs873601G>A, were genotyped using the Taqman real-time PCR method with a 7900 HT sequence detector system. H. pylori infection was diagnosed by ELISA. By multivariate logistic regression analysis, the rs2296147 CC genotype was associated with a decreased risk of gastric cancer (OR=0.52, 95% CI=0.27-0.97), and rs2094258 TT was associated with elevated risk (OR=2.13, 95% CI=1.22-3.35). Positive H.pylori individuals with rs2094258 TT genotypes demonstrated increased risk of gastric cancer (OR=2.13, 95% CI=1.22-3.35), while rs2296147 CC was associated with lower risk among patients with negative H.pylori (OR=0.45, 95%CI=0.22-0.89). Our findings suggested that XPG polymorphisms might contribute to risk of gastric cancer among Chinese populations, but the effect needs to be further validated by larger sample size studies.

The performance evaluation for H2 reforming of the plate type hydrogen generation system (평판형 수소생산시스템의 수소개질 성능평가)

  • Heo, Su-Bin;Yun, Bong-Seock;Lee, Do-Hyung
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.38 no.6
    • /
    • pp.602-608
    • /
    • 2014
  • Hydrogen energy, a field of low-carbon substitute energy, can be produced by fossile fuel reforming and electrolysis of water etc. We developed 1kW class flat type reformer for PEM Fuel Cells. The PEMFC is highly sensitive to carbon monoxide because CO has detrimental effects on the performance of the fuel cell. Thus, reformed gas supplied to Fuel cell system, which maintained CO concentration below 10ppm. After applying optimum drive condition, reformed gas was measured with gas chromatography and could find out about each experimental condition of $H_2$ and CO concentration. As a results, The 1kW class plate type hydrogen generation system's optimum condition is A/F ratio ${\alpha}=1.3$, STR temperature 1023K, S/C ratio 3, and $PrOx1{\cdot}2$ 30cc/min. It turns out that installation of PrOx 2 stage is more efficient for reducing CO concentration.

Control of broadleaf weeds with 2,4-D in barley field (맥작에 있어서 2,4-D에 의한 광엽잡초 방제에 관한 연구)

  • Ryang H. S.;Jeon J. C.;Kim S. J.
    • Korean journal of applied entomology
    • /
    • v.15 no.4 s.29
    • /
    • pp.185-191
    • /
    • 1976
  • This study was conducted to evaluate the performance of 2,4-D amine salt (2,4-dichlorophenoxy acetic acid) 40EC in broadleaf weeds control under diverse conditions of rate and time of application and soil type in fall barley field. The results obtained were summarized as follows: 1) At the rate of 70cc prod./10a, 2,4-D amine salt treated during the fully tillered stage of barley was effective for the control of most broadleaf weeds without crop injury. 2) The fully tillered stage was a optimun time lot the application of 2,4-D amine salt in fall barley. Earlier(zero-to four-leaf stage) or late. (boot stage to flowering) application than this stage caused a crop injury and resulted in yield reduction. 3) It was possible to safely use 2,4-D amine salt in fall barley regardless of soil types if applied the rate of 70cc prod./10a at the fully tillered stage.

  • PDF

Analysis of Pericardial Fluid in Patients with Cardiac Disease (심장질환환자에서 심막액의 분석)

  • 김종원;황수희
    • Journal of Chest Surgery
    • /
    • v.29 no.12
    • /
    • pp.1354-1359
    • /
    • 1996
  • Few observation have been made on the pericardial pressure and little is known about the composition of he pericardial fluid. So we studied the basic qualitative and quantitative analysis of the pericardial fluid in the patients with cardiac disease either congenital heart diasese(group A) or acquired heart disease(group B). The pressure of the pericardial cavity was measured by the method of open tipped water filled small polyethylene catheter connecting to the standardized monitor, which was introduced into pericardium of the patients who were performed pericardial incision for the heart or pericardial surgery. All of the data was compared to the simultaneously checked hematologic value of the same patient. The mean pressure of the pericardial cavity was 2.4mmHg and the amount of the pericardial fluid was 13cc/m2 of body surface for the group A and 17.7cc for the group B. And the cell count was 138$\pm$l16/1 in group A and 230$\pm$135/1 in group B and the pH was 7.83$\pm$0.40 in group A. 7.80$\pm$0.52 in group B. Pericardial fluid revealed satisfactically significant alkaline pH than plasma. The fundamental electrolyte, Wa+, K+, Cl and glucose were identical to the hematologic values of the same patient, but the protein concentration was 2.Bg/dL for group A and 3.Ig/dL for group B heart disease and those were remarkable low concentration compared to the hematologic value of the same patient. LDH and amylase were identical to the value of the serum of the same patient, but the concentration of LDH of group B was slightly higher than that of the group A.

  • PDF