• Journal of the Korea Concrete Institute
• /
• v.29 no.4
• /
• pp.389-397
• /
• 2017

Friedel's salt is an important product of chemical adsorption between cement hydrate and chloride ions because it contains chlorine in its structure. When cement reacts with water in the presence of chloride ions, the $C_3A$ phase, and $C_4AF$ phase react with chloride to produce Friedel's salt. If chloride ions penetrate into concrete from external environments, many calcium aluminate hydrates, including AFm, can bind chloride ions. It is very important, therefore, to investigate the chloride binding isotherm of $C_3A$ phase, $C_4AF$ phase, and AFm phase to gain a better understanding of chloride binding in cementitious materials. Meanwhile, the adsorption isotherm can provide us with the fundamental information for the understanding of adsorption process. The experimental results of the isotherm can supply not only the quantitative knowledge of the cement-Friedel's salt system, but also the mechanism of adsorption and the properties of their interactions. The purpose of this study is to explore the time dependant behaviors of chloride ions adsorption with $C_3A$, $C_4AF$ and AFm phases. The chloride adsorption isotherm was depicted with Langmuir isotherm and the adsorption capacity was low in terms of the stoichiometric point of view. However, the chloride adsorption of AFm phase was depicted with Freundlich isotherm and the value was very low. Since the amount of the adsorption was governed by temperature, the affecting parameters of isotherm were expressed as a function of temperature.

• Journal of the Mineralogical Society of Korea
• /
• v.15 no.3
• /
• pp.161-169
• /
• 2002

high pressure and temperature conditions. However, those results are not consistent with one another, and phase boundary between ilmenite and perovskite phases determined only from the quenching method may be not so reliable at all. Therefore, in-situ high pressure-temperature (hP-T) X-ray diffraction measurements were performed up to 19 GPa and $700^{\circ}C$ in a large volume press apparatus using synchrotron radiation. Experimental results show that perovskite phase is stable at pressures above 16 GPa, and transforms back to $LiNbO_3$phase near 15 CPa at room temperature, and that the perovskite-ilmenite transition is back and forth near 15 CPa at $500^{\circ}C$. LiNbO$_3$phase transforms to ilmenite at 13 CPa and $300^{\circ}C$ and at 10.8 CPa and $400^{\circ}C$, respectively. These data indicate that $LiNbO_3$phase may have a stability region in the hP-T phase diagram and that the perovskite-ilmenite phase boundary would be quite different from that previously reported.

• Korean Journal of Materials Research
• /
• v.5 no.6
• /
• pp.699-705
• /
• 1995

Effect of the grain boundary phases in Si$_3$N$_4$ ceramics on the fracture tonghness has been investigated. The Si$_3$N$_4$-Y$_2$O$_3$-SiO$_2$, (YS) and Si$_3$N$_4$-Y$_2$O$_3$-Al$_2$O$_3$(YA) systems were Can/HIP treated at 1750$^{\circ}C$ and then heat-treated at 1800∼2000$^{\circ}C$. The fracture toughness of the YA system, the grain boundary phase was only glass phase after heat-treatement, was increased. That of the YS system, however, the grain boundary phase was changed from crystalline and glass to glass phase after the heat -treatement above 1900$^{\circ}C$, was abruptly decreased. The reason of the sudden drop of the fracture toughness of the YS system was believed that the change of the grain boundary phases from crystalline and glass to glass phase effected un the fracture behavior.

• Proceedings of the KWS Conference
• /
• 2010.05a
• /
• pp.21-21
• /
• 2010

AISI 316L 용접금속의 크롬/니켈 당량비에 따른 시그마상의 영향을 알아보기 위하여 응고모드가 다른 3종류의 플럭스 코어드 와이어를 제작하였다. AISI 316L 시편에 FCAW 프로세스를 적용한 용접재를 $650^{\circ}C$, $750^{\circ}C$, $850^{\circ}C$, $950^{\circ}C$에서 각 각 1H, 5H, 24H, 72H동안 열처리하였다. 크롬/니켈 당량비가 높을수록 즉, 크롬의 함량이 높아질수록 $\delta$-페라이트 함량은 증가하였으며, $\delta$-페라이트는 고온에서 시그마상으로 변태되었다. $\delta$-페라이트는 $650^{\circ}C$에서 가장 느리게 분해되었으며 $850^{\circ}C$에서 가장 활발히 분해되었다. 용접부의 특성상 크롬과 니켈 등의 합금원소에 의하여 응고온도범위가 넓어져 $950^{\circ}C$에서도 시그마상이 석출되었으며, 5시간 이상 유지 시 구형으로 존재하였다. 충격시험 시 시그마상에 의해 취약해진 inter-dendrite 를 따라 파면이 형성되었으며, $-100^{\circ}C$이하의 극저온에서는 시그마상의 양과 무관하게 충격흡수에너지는 0에 가까워졌다. 하지만 3%미만의 $\delta$-페라이트를 함유하는 AF모드에서 발생한 DDC와 미량의 시그마상은 충격흡수에너지에 결정적인 영향을 미치지 않았다.

• Journal of the Korean Ceramic Society
• /
• v.40 no.1
• /
• pp.87-92
• /
• 2003

$Ti_3AlC_2$was synthesized from TiCx and Al powder as a starting materials at the temperature range between$800^{circ}C;and;1500^{\circ}C$. The vacuum sintering and hot pressing methods were imployed to synthesize$Ti_3AlC_2$. The high purity$Ti_3AlC_2$was synthesized using TiCx and Al powder as starting materials without formation of Ti-Al intermetallic compound and Al-C compound.$Ti_2$AlC and$Ti_3AlC_2$were preferentially synthesized at$800^{\circ}C$and above$1200^{\circ}C$, respectively.$Ti_2$AlC formed at low temperature was transformed to$Ti_3AlC_2$by further reaction with TiC. In this study, the synthesis mechanism for$Ti_3AlC_2$was proposed. The synthesized$Ti_3AlC_2$showed the nano laminating structure consisting of$Ti_3AlC_2$crystal with the thickness of 45~120 nm.

• Korean Journal of Materials Research
• /
• v.9 no.10
• /
• pp.951-955
• /
• 1999

Two-phase Al-21Ti-23Cr alloy containing 20 vol.% $\textrm{Cr}_{2}\textrm{Al}$ as a second phase in the $Ll_2$ matrix is located in the two- phase region of the Al- Ti- Cr phase diagram at $1150^{\circ}C$, while in the three-phase region at $1000^{\circ}C$. Based on this result, the mechanical properties of the A1-21Ti-23Cr alloy were enhanced through the refined precipitation of the third phase in the $Ll_2$ matrix by aging the alloy below $1000^{\circ}C$. It was observed that a several ,m of the third phase precipitated in the $Ll_2$ matrix through aging at $800^{\circ}C$ and $1000^{\circ}C$, but the precipitation was not observed below $600^{\circ}C$. Furthermore, the third phase was more finely precipitated at $800^{\circ}C$ than at $1000^{\circ}C$. Although the third phase precipitated at $800^{\circ}C$ and at $1000^{\circ}C$, the compressive yield strength increased rapidly at $800^{\circ}C$ only. This is probably attributable to the refined precipitation of the third phase in the $Ll_2$ matrix. It is expected that the precipitation of the third phase. which was confirmed to be the TiAlCr phase, improves the mechanical properties by preventing crack propagation in the $Ll_2$ matrix.

• Solar Energy
• /
• v.11 no.3
• /
• pp.53-61
• /
• 1991

In this research, Octacosane($C_{28}H_{58}$) and Sodium Acetate Trihydrate($CH_3COONa{\cdot}3H_2O$) were selected as latent heat storage materials to store off-peak electricity or waste heat of an industrial plant. Experimental analyses were performed in terms of the variation of phase change temperature and latent heat, phase change stability for the long term utilization. The results were as follows. 1. The phase change temperatures of industrial grade Octacosane and Sodium Acetate Trihydrate were $60.7^{\circ}C$ and $57.4^{\circ}C$, the latent heat were 60.6kcal/kg and 51.1kcal/kg respectively. 2. The latent heat quantity of Octacosane was decreased with the increasing number of phase change cycles. It decreased from 60.6kcal/kg to 47.2kcal/kg upto 200 cycles and then no variation was observed after 200 cycles. 3. To prevent the supercooling of Sodium Acetate Trihydrate, the nucleating agent, Sodium Pyrophosphate Decahydrate of 3 wt% was added, and then the supercooling temperature (Tm-Tsc) was decreased from $25.7^{\circ}C$ to $1^{\circ}C$. The phase separation was disappeared by the addition of CMC-Na of 3 wt% as a thickener. It was found that the optimal quantity of nucleating agent and thickener was 4wt% considering the stability of SAT as a latent heat storage material. 4. The phase change temperature of Sodium Acetate Trihydrate($CH_3COONa{\cdot}3H_2O$) was adjusted from 57.4 to $46.2^{\circ}C$ by the addition of UREA. And then the latent heat quantity was decreased from 51.1 to 38.3kcal/kg. 5. When the heat storage capacities between the sensible and latent heat storage materials were analyzed and compared in heating process from 30 to $90^{\circ}C$, the heat storage capacity of Octacosane was 2.45 times larger than water and 12.5 times than granite at $60.7^{\circ}C$, and the heat storage capacity of Sodium Acetate Trihydrate was 2.53 times larger than water and 12.91 times than granite at $57.4^{\circ}C$.

• Journal of the Korean Magnetics Society
• /
• v.27 no.4
• /
• pp.129-134
• /
• 2017

Bulk-type body-centered-tetragonal Fe-Co alloy was synthesised by utilising a conventional alloy preparation technologies, such as melting, solidification, and homogenising treatments, and its magnetic properties were investigated. In the $(Fe_{100-x}Co_x)_{1-y}C_y$ alloy, the composition range, from which single phase body-centered-tetragonal alloy (martensite phase) was obtained, was severely limited: Co content x = 2.5, and C content y = 0.062. Tetragonality(c/a) of the synthesised body-centered-tetragonal $(Fe_{97.5}Co_{2.5})_{0.938}C_{0.062}$ alloy was 1.05. Magnetocrystalline anisotropy constant ($K_1$) of the body-centered-tetragonal $(Fe_{97.5}Co_{2.5})_{0.938}C_{0.062}$ alloy was measured to be $9.8{\times}10^5J/m^3$), which was 3.1 time as high as the pure iron (${\alpha}-Fe$).

• Korean Chemical Engineering Research
• /
• v.53 no.3
• /
• pp.302-308
• /
• 2015

Isothermal vapor liquid equilibria for the binary system of 3-methylpentane with ethylene glycol monopropyl ether ($C_3E_1$) and ethylene glycol isopropyl ether ($iC_3E_1$) were measured at 303.15, 318.15, and 333.15K. In our previous work, phase equilibria for the binary system of $C_3E_1$ mixtures were investigated according to the chain length of alkane, alcohol or those isomer. But in this study, we discussed the different effect of $C_3E_1$ and its isomer, $iC_3E_1$, on the phase equilibria. The measured systems were correlated with a Peng-Robinson equation of state (PR EOS) combined with Wong-Sandler mixing rule for the vapor phase, and NRTL, UNIQUAC, and Wilson activity coefficient models for the liquid phase. All the measured systems showed good agreement with the correlation results. And it was found that the phase equilibria showed very little difference between the $iC_3E_1$ mixture system and the $C_3E_1$ mixture system.

• Applied Chemistry for Engineering
• /
• v.16 no.6
• /
• pp.778-784
• /
• 2005

It has been found that the addition of cosurfactant is necessary in order to expand three phase region containing middle phase microemulsion in ternary systems containing alkyl ethoxylate (AEO) nonionic surfactant, commercial lubricant and water. Phase behavior in the surfactant systems with addition of cosurfactant over a temperature range of 30 to $60^{\circ}C$ showed different trends depending on surfactant, temperature and chain length of alcohol added. For the $C_{12}E_4$ system, addition of n-pentanol and n-hexanol both produced a three phase region over a wide range of temperatures but the middle-phase formed was found to be a $L_3$ or D' phase which would not facilitate solubilization of high molecular weight lubricants. On the other hand, for the $C_{12}E_5$ system, the middle-phase microemulsion was found to be formed with addition of a rather long-chain alcohol such as n-hexanol, n-heptanol, n-octanol, or n-nonanol. The results shown with the addition of cosurfactant was understood in connection with interfacial tension measurements and composition analysis. The inability of the hydrocarbon region of the surfactant films to incorporate the large lubricant molecules and high solubility of a hydrophobic surfactant are thought to be the chief reasons for poor solubilization with D' phase.