• 제목/요약/키워드: $C_2O_2H_4$

검색결과 5,476건 처리시간 0.037초

Analysis of the first core of the Indonesian multipurpose research reactor RSG-GAS using the Serpent Monte Carlo code and the ENDF/B-VIII.0 nuclear data library

  • Hartanto, Donny;Liem, Peng Hong
    • Nuclear Engineering and Technology
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    • 제52권12호
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    • pp.2725-2732
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    • 2020
  • This paper presents the neutronics benchmark analysis of the first core of the Indonesian multipurpose research reactor RSG-GAS (Reaktor Serba Guna G.A. Siwabessy) calculated by the Serpent Monte Carlo code and the newly released ENDF/B-VIII.0 nuclear data library. RSG-GAS is a 30 MWth pool-type material testing research reactor loaded with plate-type low-enriched uranium fuel using light water as a coolant and moderator and beryllium as a reflector. Two groups of critical benchmark problems are derived on the basis of the criticality and control rod calibration experiments of the first core of RSG-GAS. The calculated results, such as the neutron effective multiplication factor (k) value and the control rod worth are compared with the experimental data. Moreover, additional calculated results, including the neutron spectra in the core, fission rate distribution, burnup calculation, sensitivity coefficients, and kinetics parameters of the first core will be compared with the previous nuclear data libraries (interlibrary comparison) such as ENDF/B-VII.1 and JENDL-4.0. The C/E values of ENDF/B-VIII.0 tend to be slightly higher compared with other nuclear data libraries. Furthermore, the neutron reaction cross-sections of 16O, 9Be, 235U, 238U, and S(𝛼,𝛽) of 1H in H2O from ENDF/B-VIII.0 have substantial updates; hence, the k sensitivities against these cross-section changes are relatively higher than other isotopes in RSG-GAS. Other important neutronics parameters such as kinetics parameters, control rod worth, and fission rate distribution are similar and consistent among the nuclear data libraries.

크라온에테르를 이용한 탈륨(I) 이온 선택성 전극 (Tallium(I) Ion-Selective Electrodes Based on Crown Ethers)

  • 김성민;정성욱;김진은;김재상
    • 대한화학회지
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    • 제37권8호
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    • pp.773-778
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    • 1993
  • Tl$^+$이온 센서로서 크라운 에테르 B15C5와 DB18C6를 중성운반체로 한 PVC 액체막 이온 선택성 전극을 제작하였다. 막용매로는 DOA, NPPE 및 NPOE를 사용하였으며 친유성 염, KTClPB의 농도를 변화시킨 여러가지 조성의 막을 시험하였다. B15C5와 DB18C6 막 전극의 감응전위는 농도범위, 10$^{-1}$∼10$^{-5}$M에서 직선으로 나타났으며 최대 기울기는 전극에 따라서 40∼55 mV/decade였다. 선택계수는 분리용액법으로 결정하였으며 알카리금속 이온, 알칼리토금속 이온 및 일부 전이금속 이온에 대하여 좋은 선택성을 나타냈다. 제작된 액체막 전극은 Ph > 3 에서 안정한 감응전위를 보였다.

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주년공급을 위한 풋땅콩 냉동가공기술 개발 (Development of Frozen Vegetable Groundnut Product for Year-round Supply)

  • 손영구;황종진;김선림;허한순;박장환;김석동;이춘기
    • 한국식품저장유통학회지
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    • 제5권4호
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    • pp.326-330
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    • 1998
  • 풋땅콩의 고유특성을 유지하고 영양성분의 손실과 변패에 의한 상품성 하락을 방지하면서 장기간 안전하게 저장할 수 있는 풋땅콩 냉동가공제품을 개발하기 위하여 건조용 땅콩의 일반수확기보다 20-30일 정도 이른 9월 10일경에 조기 수확한 대풍땅콩, 대광땅콩 및 신대광땅콩을 10$0^{\circ}C$ 수증기로 5분간 쪄서 효소를 불활성화 시키고 방냉한 후 0.08mm P.V.D.C 필름봉지에 감압밀봉포장 하고 -7$0^{\circ}C$의 초저온냉동고에 24시간동안 급속동결시킨 후 다시 -2$0^{\circ}C$의 일반냉동저장고에 옮겨 2개월간 저장 후 그 품질특성을 조사하였다. 냉동풋땅콩은 건조땅콩에 비하여 수분함량이 30% 이상 높고, 경도가 낮아 조직이 유연하며 유리당을 0.12-0.36% 함유하여 물성과 맛이 좋았다. 저장 중 내피의 수용성 탄닌이 불용화되어 껍질채 먹을 수 있고, 건조땅콩보다 산가가 1/5 수준으로 낮았으며 식미에 있어서도 공시 3품종 모두 보통 이상으로 나타나 고품질 대중건강식품으로 활용될 수 있을것으로 판단되었다.

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Fabrication of Artificial Sea Urchin Structure for Light Harvesting Device Applications

  • Yeo, Chan-Il;Kwon, Ji-Hye;Kim, Joon-Beom;Lee, Yong-Tak
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.380-381
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    • 2012
  • Bioinspired sea urchin-like structures were fabricated on silicon by inductively coupled plasma (ICP) etching using lens-like shape hexagonally patterned photoresist (PR) patterns and subsequent metal-assisted chemical etching (MaCE) [1]. The lens-like shape PR patterns with a diameter of 2 ${\mu}m$ were formed by conventional lithography method followed by thermal reflow process of PR patterns on a hotplate at $170^{\circ}C$ for 40 s. ICP etching process was carried out in an SF6 plasma ambient using an optimum etching conditions such as radio-frequency power of 50 W, ICP power of 25 W, SF6 flow rate of 30 sccm, process pressure of 10 mTorr, and etching time of 150 s in order to produce micron structure with tapered etch profile. 15 nm thick Ag film was evaporated on the samples using e-beam evaporator with a deposition rate of 0.05 nm/s. To form Ag nanoparticles (NPs), the samples were thermally treated (thermally dewetted) in a rapid thermal annealing system at $500^{\circ}C$ for 1 min in a nitrogen environment. The Ag thickness and thermal dewetting conditions were carefully chosen to obtain isolated Ag NPs. To fabricate needle-like nanostructures on both the micron structure (i.e., sea urchin-like structures) and flat surface of silicon, MaCE process, which is based on the strong catalytic activity of metal, was performed in a chemical etchant (HNO3: HF: H2O = 4: 1: 20) using Ag NPs at room temperature for 1 min. Finally, the residual Ag NPs were removed by immersion in a HNO3 solution. The fabricated structures after each process steps are shown in figure 1. It is well-known that the hierarchical micro- and nanostructures have efficient light harvesting properties [2-3]. Therefore, this fabrication technique for production of sea urchin-like structures is applicable to improve the performance of light harvesting devices.

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Neuroprotective Effects of Phlorotannin-Rich Extract from Brown Seaweed Ecklonia cava on Neuronal PC-12 and SH-SY5Y Cells with Oxidative Stress

  • Nho, Jin Ah;Shin, Yong Sub;Jeong, Ha-Ram;Cho, Suengmok;Heo, Ho Jin;Kim, Gun Hee;Kim, Dae-Ok
    • Journal of Microbiology and Biotechnology
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    • 제30권3호
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    • pp.359-367
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    • 2020
  • Neurodegenerative disorders in the elderly are characterized by gradual loss of memory and cognitive function. Oxidative stress caused by reactive oxygen species is associated with progressive neuronal cell damage and death in Alzheimer's disease, one of the most common neurodegenerative disorders. An edible brown seaweed, Ecklonia cava, contains a variety of biologically active compounds such as phlorotannins. In this study, we comparatively evaluated the total phenolic content, antioxidant capacity, and neuroprotective effects of the phlorotannin-rich extract from E. cava (PEEC). The total phenolic content of PEEC and dieckol was 810.8 mg gallic acid equivalents (GAE)/g and 996.6 mg GAE/g, respectively. Antioxidant capacity of PEEC was 1,233.8 mg vitamin C equivalents (VCE)/g and 392.1 mg VCE/g determined using ABTS and DPPH assays, respectively, while those of dieckol were 2,238.4 mg VCE/g and 817.7 mg VCE/g. High-performance liquid chromatography results revealed 48.08 ± 0.67 mg dieckol/g of PEEC. PEEC had neuroprotective effects in pheochromocytoma (PC-12) and human neuroblastoma (SH-SY5Y) cells against H2O2- and AAPH-induced oxidative damage, partly due to reduced intracellular oxidative stress. PEEC treatment inhibited acetylcholinesterase and butyrylcholinesterase in a dose-dependent manner. Taken together, these findings suggest that PEEC is a good source of antioxidants and neuroprotective materials.

내음성 지표식물 개발을 위한 애기나리의 생육환경분석 (Analysis on the Growth Environment of Disporum smilacinum A. GRAY for Development of Shade-tolerance Groundcover Plant)

  • 이기철;박슬기
    • 한국조경학회지
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    • 제19권2호
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    • pp.65-74
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    • 1991
  • The purpose of this study was to find the basic application of Disporum genus in landscape-arc-hitectual space. Environment of native site (Daeducksan, Piseulsan) and growth characteristics of experiment plot were investigated and analyzed in this study. The results of this study were as follows; 1. In the case of environment of native site, the relative light intensity was about 10% and distribution of species were primarily north slope. Gradient of Daeducksan and Piseulsan were 10$^{\circ}$, 18$^{\circ}$ Soil textures was Lic both and field capacity of Daeducksan and Piseulsan were 69%, 73.5%. The soil pH of Daeducksan and Piseulsan were 6.1 and 5.8. The both content of organic matter and C.E.C. were high markedly. The P2O5 content of Daeducksan showed high but total nitrogen showed nearly the same level when comparing with the common dry field condition. 2. In tree layer, Daeducksan composed of broadleaved forest of 80% involving Quercus variabilis, and Piseulsan composed of coniferous forest of 80% involving Pinus densiflora on the other hand. Daeducksan, therefore, was more appearance species than Piseulsan in herbaceous layer. 3. Result in ANOVA Test, significance followed with light intensity was recognized in plant height, leaf width, leaf length, leaf thick and No. of leaf, while in the case of soil was not. Plant height was longest in 1% and leaf width, leaf length was largest in 25%. Therefore ornamental value of leaf was the very best in 25%. 4. Result in correlation coefficient analysis, plant height was correlated leaf width, leaf length. The longer plant height, the smaller leaf width, leaf length. In relative light intensity of 1%, flower was hardly expected because of the more shade, the less flower. Disporum smilacinum is expected great use as ground covers in the shades of tall-building or hdavy woods.

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Influence of 2-bromo-α-ergocryptine on Plasma Prolactin, Oestradiol-17β and Progesterone Levels in Domestic Hen

  • Reddy, I.J.;David, C.G.;Singh, Khub
    • Asian-Australasian Journal of Animal Sciences
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    • 제15권8호
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    • pp.1103-1109
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    • 2002
  • This study investigated the effect of 2-bromo-$\alpha$-ergocryptine (anti prolactin agent) on plasma levels of prolactin, oestradiol-17$\beta$ and progesterone in domestic hen during the active period of lay. Fifty healthy female White Leghorn birds were administered with anti prolactin agent (2-bromo-$\alpha$-ergocryptine, Sigma-USA., methane sulphonate salt, $C_{32}H_{40}BrN_5O_5.CH_4SO_3$) subcutaneously @100$\mu$g/kg body weight at weekly intervals from 17th to 36th week of age. Another group of fifty birds as controls were given placebo in place of bromocriptine. The level of prolactin remained lower in treated birds than in the control birds from 19 to 36 weeks of age. Level of prolactin even in the control group was found to decrease during the peak production period. Oestradiol-$17{\beta}$ and progesterone concentration in treated birds were significantly (p<0.01) higher than the controls during the treatment. Egg production, is positively correlated with oestradiol-$17{\beta}$ (r=0.02; r=0.67) and progesterone (r=0.49; r=0.90) in control and treated groups respectively where as prolactin level is positively correlated with egg production in the control birds (r=0.07). Prolactin levels were negatively correlated with egg production (r=-0.55) in treated birds; and oestradiol-$17{\beta}$ (r =-0.71; r=-0.53) and progesterone (r=-0.22; r=-0.27) respectively in control and treated groups. The total number of pause days during the treatment period decreased significantly (p<0.01) in the treated group compared to the control group. The reduction in pause days in treated group resulted in 1.76% increase in egg production over that in control group. The increase in egg laying days and the total egg production were found to be significant (p<0.01). These results indicate that a lower level of prolactin in circulatory blood enhances egg production in the domestic hen.

우리밀 Ethanol-Acetic Acid 추출물에 함유된 대식세포의 식작용 활성 증강 물질의 분리.정제 (Purification of Macrophage Phagocytic Activity-Enhancing Component from Ethanol-Acetic Acid Extract of Korean Wheat)

  • 최면;김선률;김종대;이상영;김현숙
    • 한국식품영양과학회지
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    • 제29권2호
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    • pp.312-315
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    • 2000
  • 본 연구에서는 우리밀로부터 대식세포 식작용 활성화시키는 물질을 탐색하는 과정에서 고분밀의 EA 추출물이 가장 높은 식작용 활성 증강효과를 보임을 알았고, EA 추출물을 정성한 후 순수 분리 정제하여 대식세포 활성 증강효과를 나타내는 단일 물질을 찾고자 하였다. TLC 방법을 이용하여 ASW와 고분밀의 EA 추출물을 정성한 결과 약 5개 정도의 band를 확인한 후, column chromatography를 이용하여 EA 추출물을 분획하였다. 1차 column chromatography만으로는 single fractionation이 어려워 분획물을 fraction A, B, C, D로 분류하여 식작용 활성 증강효과를 측정하였다. 대분류된 각 fraction의 식작용 활성 증강효과를 측정한 결과 고분밀의 fraction b가 대부분의 활성을 가진 분획으로 사료되었다. 2차 column chromatography를 통해 fraction b만응 분리 하였으며, 구조결정 실험과 동물실험을 추가로 시행하여 fraction b의 효과를 입증할 것이다.

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Effects of vacuum and high-oxygen modified atmosphere packaging on physico-chemical and microbiological properties of minced water buffalo meat

  • Jaberi, Rahimeh;Kaban, Guzin;Kaya, Mukerrem
    • Asian-Australasian Journal of Animal Sciences
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    • 제32권3호
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    • pp.421-429
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    • 2019
  • Objective: In this study, the effects of vacuum (VP) and high-oxygen modified atmosphere ($80%\;O_2+20%\;CO_2$) packaging (HiOx-MAP) on physico-chemical and microbiological properties of minced water buffalo meat were investigated. Methods: After minced meat preparation, samples were packaged under VP and HiOx-MAP and stored at $2^{\circ}C{\pm}0.5^{\circ}C$ for 14 days. Samples taken on certain days were subjected to total aerobic mesophilic bacteria, total aerobic psychrotrophic bacteria, lactic acid bacteria, Pseudomonas, Enterobacteriaceae and yeast-mold counts as well as pH, color ($L^*$, $a^*$, and $b^*$) and thiobarbituric acid reactive substances (TBARS) analyses. Results: In minced water buffalo meat packaged under HiOx-MAP, TBARS value exceeded 1 mg malondialdehyde/kg on the 4th day of the storage. In VP samples, TBARS value remained close to initial TBARS value during storage. According to the findings, $a^*$ value was determined to be high in the HiOx-MAP samples within initial days of the storage. However, no significant changes in $a^*$ value were observed in VP samples during storage. In contrast, the mean value of $L^*$ was detected as higher in HiOx-MAP sample than VP samples. The count of psychrotrophic bacteria increased more than that of mesophilic bacteria during storage. The growth of Enterobacteriaceae and Pseudomonas was delayed in both the packaging methods. However, lactic acid bacteria exhibited more growth in VP samples compared to MAP samples. Conclusion: The lipid oxidation proceeded faster than expected in minced water buffalo meat packed with HiOx-MAP method. This situation adversely affected the $a^*$ value. On the other hand, similar microbiological results were obtained in both packing methods.

항돌연변이원성 Lactobacillus plantarum KLAB21에 의한 복숭아 주스의 젖산발효 특성 (Characteristics of Lactic Acid Fermentation of Peach Juice by Lactobacillus plantarum KLAB21 Possessing Antimutagenic Effects)

  • 이용호;최상원;박희동
    • 한국식품저장유통학회지
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    • 제15권3호
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    • pp.469-476
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    • 2008
  • 복숭아를 원료로 하여 항돌연변이원성이 강한 것으로 알려진 L. plantaum KLAB21 균주에 의한 젖산발효 주스의 제조 가능성과 젖산발효 특성을 조사하였다. 젖산발효에 미치는 온도의 효과를 조사한 결과 $37^{\circ}C$에서 25, 30, $40^{\circ}C$에서 보다 더욱 높은 생균수의 증가와 적정산도를 나타내었다. 살균하지 않은 복숭아 주스보다는 저온에서 살균한 주스가 젖산발효에 더욱 적합한 것으로 나타났다. 또한 L. plantaum KLAB21 균주 단독발효의 경우가 L. plantaum KLAB21 및 L. mesenteroides 두 균주의 혼합발효 경우보다 젖산발효가 큰 차이는 없었으나 다소 양호하였다. 발효시간에 따른 젖산발효 특성을 조사한 결과 발효 3일 동안에 대부분의 환원당이 소모되었으며 발효 3일 후 9.2 log cfu/mL로서 가장 높은 생균수를 나타낸 후 발효가 진행되면서 생균수는 오히려 감소하여 5일 후에는 8.4 log cfu/mL을 나타내었다. 발효 중 적정산도는 초기에 급격히 증가하였으나 점차 증가폭이 둔해졌으며 발효 5일 후의 적정산도는 1.98%이었다. pH는 발효가 진행되면서 초기 3.9에서부터 발효 5일 후에는 3.1까지 감소하였다. 발효 주스의 유기산 조성은 발효 전 복숭아 주스에서는 전혀 검출되지 않았던 젖산이 1.236.1mg%로 전체 유기산의 약 56.6%를 차지하여 가장 높았으며 발효 전 검출되지 않았던 갈락투론산은 발효 후 840.5mg%로서 전체 유기산의 38.5%를 차지하였다. 또한 92.3mg%의 사과산과 소량의 구연산 및 초산이 검출되었다. S. enterica serovar Typhimurium TA100을 사용하여 발효 주스 원심분리 상징액 $100\;{\mu}L$의 항돌연변이 활성을 조사한 결과 MNNG(N-methyl-N'-nitro-N-nitrosoguanidine)에 대하여 97.7%, NPD(4-nitro-O-phenylenediamine)에 대하여는 58.3%의 활성을 나타내었다.