• Journal of the Korean Chemical Society
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• v.28 no.2
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• pp.95-101
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• 1984

Aquation reaction kinetics of $[Cr(en)_2Cl_2]^+$complex was carried by the electric conductivity method. Its temperature range was $15^{\circ}C$ to $30^{\circ}C$ and pressure was varied up to 2,000 bars. The reaction rate was increased with increasing temperature, but was reversed to increasing pressure. The activation volume(${\Delta}V^{\neq}$) was increased with increasing temperature and decreased with increasing pressure. At $25^{\circ}C$ and 1 bar it was fairly small positive value, $1.82cm^2/mole$. Activation entropy change(${\Delta}S^{\neq}$) $was calculated as small negative value,-9.019 eu, at $25^{\circ}C$ and 1bar. Referring to the thermodynamic parameters, it was estimated that aquation reaction was proceeded by the interchange-dissociation(Id) mechanism.

• Journal of Biosystems Engineering
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• v.10 no.2
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• pp.1-11
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• 1985

A double pipe grain heater using engine exhaust gas as a heat source was developed. The performance of the grain heater was examined with soybeans as a test material experimentally and numerically using a mathematical model constructed. The following conclusions were drawn: 1. The modified screw conveyor used in the grain heater has a characteristic of decreasing capacity with increasing speed at speeds above 60 rpm. Operation with speeds below 60 rpm is recommended. 2. Heating soybeans by the heater at soybean flow rate up to 100 kg/hr, inlet temperature of the exhaust gas to the heater are recommended as above $400^{\circ}C$, $300^{\circ}C$, and $200^{\circ}C$ roughly for a 2, 5, and 10 kW engine, respectively. 3. Temperature increments of soybean by the heater at soybean flow rates ranged from 25 to 100 kg/hr are in the ranges of $6^{\circ}C-35^{\circ}C$, $15^{\circ}C-88^{\circ}C$, and $15^{\circ}C-140^{\circ}C$ with exhaust gas from a 2, 5, and 10 kW engine, respectively, at an exhaust temperature of $500^{\circ}C$. 4. Thermal efficiency of the heater at soybean flow rates ranged from 25 to 100 kg/hr are in the ranges of 35-37%, 28-34%, and 20-29% with exhaust gas from a 2, 5, and 10 kW engine, respectively. 5. The grain heater can be used to heat the other grain, also, without any bad effect from the exhaust gas used as a heat source.

• Electrical & Electronic Materials
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• v.1 no.3
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• pp.235-242
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• 1988

본 논문에서는 X선장치용 절연유의 X선 조사에 의한 전기전도 현상을 이해하기 위해서 X선량(1.2*$10^{4}$R), 인가시간, 분위기(공기, N$_{2}$가스, 진공), 전계 등의 특성과 전극 재료와 갭길이 의존성을 시료의 온도 30-100.deg.C 범위에서 도전전류를 측정하였다. 도전전류는 X선 미조사 절연유 보다는 저온 및 저전계 영역의 조사된 절연유에서 증가되었으나 고온과 고전계 영역에서는 구별되지 않았다. 이들 결과는 저온 및 저전계에서는 X선 조사에 의한 해리 및 이온화 작용에 의해 하전항체가 증가되고 있음을 생각할 수 있으며 X선장치 설계 및 취급 관리에 있어 적당한 자료로 제시할 수가 있겠다.

• Microbiology and Biotechnology Letters
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• v.26 no.4
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• pp.275-282
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• 1998

To investigate the increased acid tolerance of a acid-resistant mutant Leuconostoc paramesenteroides P-100 improved as a kimchi starter, proton permeability, ATPase acitivity, glycolysis activity, $Mg^2$sup +/ releasement, and membrane fatty acid composition were studied and comprised with its wild type Leuconostoc paramesenteroides Pw. In the proton permeability experiment, the maximum values of the average half time (t$\_$1/2/) of pH equilibration through the cell membrane of the Pw and the P-100 were about 6.4 min and 7.8 min in 150 mM KCI solution, respectively. In the 3% NaCl solution, the t$\_$1/2/ values of the Pw and the P-100 were 5.5 min and 6.9 min, respectively. The values and pHs of maximal specific activities of ATPase originated from the Pw and the P-100 were 0.5 unit/mg protein and 0.78 unit/mg protein at pH 6.0, respectively. The result of pH dependence of glycolysis showed that the P-100 had higher activities than that of Pw except at pH 7.0. The releases of magnesium from the Pw and the P-100 were observed about 54.5% and 23.2% at pH 4.0 after 2 hours, respectively. The results of comparison of membrane fatty acid composition of the Pw with the P-100 showed that C$\_$8:0/, C$\_$9:0/, C$\_$10:0/, C$\_$11:0/, C$\_$18:0/, and C$\_$19:0,cyclo/ were major different fatty acids between two strains and the content of C$\_$18:1/, and C$\_$19:0,cyclo/ were 2.8%, N.D (not detected) in the Pw and 0.4%, 2.3% in the P-100. These results indicated that acid tolerance of the P-100 was significantly improved in comparison with its wild type Pw.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.31 no.1
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• pp.56-61
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• 1986

Germination and seedling elongation of maize (Dekalb XL 72B), and soybeans (Williams) were measured at two temperatures (15 and 35$^{\circ}C$), three soil water potentials (-1.50, -0.5, and -0.05 MPa), and four polyethy-lene glycol 8000 (PEG) levels (0, 20, 30, and 50 percent). Twenty conditioned seeds of each cultivar were treated with 0.2% thiram and planted 2 cm deep in sterilized Mexico silt loam soil which was subsequently compacted to a bulk density of 1.20 g/㎤. Seedling moisture content, dry weight, and length were measured for each treatment combination. Osmoconditioning with PEG showed little effect at high temperature or low soil water potential conditions. Soybeans had higher seedling moisture content than corn and both crops in-creased moisture uptake as soil water potential and temperature increased. Seedling length of corn was longer than soybeans at 35$^{\circ}C$ but shorter at 15$^{\circ}C$. Seedling dry weight of corn decreased at 35$^{\circ}C$ and that of soybeans decreased as soil water potential increased.

• Journal of the Korean Chemical Society
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• v.29 no.1
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• pp.9-14
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• 1985

The solubilities of i-propyl bromide in nitrobenzene have been measured at 10$^{\circ}$, 19$^{\circ}$ and 25$^{\circ}C$ in the presence and absence of gallium bromide. In the presence of gallium bromide, 1 : 1 complex, i-C$_3$H$_7Br{\cdot}GaBr_3$ is formed in the solution. The instability constant K of the complex formation was evaluated from the following equilibrium equation: i-C$_3$H$_7Br{\cdot}GaBr_3$ ${\rightleftharpoons}$ i-C$_3$H$_7$Br + $\frac{1}{2}$$Ga_2Br_6$. The change of enthalpy, free energy and entropy for the dissociation of the complex were also calculated. From these result, it seems that the stabilities of the complex formation, gallium bromide with alkyl bromide, are directly related with those of the carbonium ions of alkyl bromide.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.189.2-189.2
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• 2011

매립가스(LFG)는 약 50v/v% 이상의 메탄가스로 이루어져 있어 LFG의 자원화 사업은 국내 신 재생에너지를 이용한 발전사업 중 태양광사업 다음으로 활발히 진행되고 있다. LFG의 대표적인 활용기술로는 가스엔진, 가스터빈 및 증기터빈을 이용한 발전과 중질가스 및 고질가스 형태의 연료로 생산하는 방식 등이 있으며 이러한 분야에 매립지가스를 적용하기 위해서는 장치 부식의 주 원인이 되는 황화수소 가스의 제거가 반드시 이루어져야 한다. 본 연구에서는 황화수소 제거를 위해 하이드레이트와 마찬가지로 동공을 형성하여 가스의 포집과 저장이 가능한 하이드로퀴논(HQ)을 이용하고자 한다. HQ은 $0^{\circ}C$ 부근에서 해리되는 하이드레이트와 달리 상온에서 고체 형태로 구조를 유지할 수 있어 가스의 포집 및 저장에 용이한 장점이 있다. 메탄, 이산화탄소, 황화수소 혼합가스에서 황화수소 90% 이상 제거를 목적으로 HQ와 반응시켜 동공 내에 이들 가스의 포집여부를 확인하였다.

• Applied Chemistry for Engineering
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• v.3 no.2
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• pp.256-265
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• 1992

The kinetics for the oxidative coupling of methane over NaCl(30wt%)/ZnO(60wt%)/${\alpha}-Al_2O_3$ catalyst was investigated, and then the active oxygen species were discussed. The conversion rate of methane was measured at the atmospheric pressure with various combinations of partial pressure of methane and oxygen at temperature range of $650^{\circ}C{\sim}750^{\circ}C$, at conversions less than with 10%. These rate data were then used to verify the proposed Langmuir-Hinshelwood kinetic equation. The rate limiting step appeared to be the formation of the methyl radicals by the reactin of the adsorbed methane and the adsorbed oxygen, which were adsorbed on the different active sites of the catalyst. The activation energy of the methyl radical formation was estimated to be ca. 39 kcal/mol. From the kinetic studies, the oxygen species respolsible for the formation of methyl radicals was proposed to be diatomic oxygen such as $O{_2}{^{2-}}$ or $O_2{^-}$ on the surface.

• Microbiology and Biotechnology Letters
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• v.26 no.2
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• pp.102-109
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• 1998

To investigate the increased acid tolerance of a acid-resistant mutant Leuconostoc mesenteroides M-100 improved as a kimchi starter, proton permeability, ATPase acitivity, glycolysis activity, $Mg^{2+}$ releasement, and membrane fatty acid composition were studied and comprised with its wild type Leuconostoc mesenteroides Mw. In the proton permeability experiment, the mininum values of the average half time ($t_{1/2}$) of pH equilibration through the cell membrane of the Mw and the M-100 were about 8.6 min and 9.2 min in 150 mM KCI solution, respectivily. In the 3% NaCl solution, the $t_{1/2}$ values of the Mw and the M-100 were 6min and 8.6 min, respectivily. The values and pHs of maximal specific activities of ATPase originated from the Mw and the M-100 were 0.6U at pH 5.5 and 0.8U at pH 5.5, respectivily. The result of pH dependence of glycolysis showed that the M-100 had higher activities than that of Mw except at pH 5.0. The releases of magnesium from the Mw and the M-100 were observed about 36.5% and 13% at pH 4.0 after 2 hours, respectivily. The results of comparison of membrane fatty acid composition of the Mw with the M-100 showed that $C_{12}$, $C_{14}$, $C_{18:1}$, and $C_{19:0cyclo}$ were major different fatty acids between two strains and the content of $C_{18:1}$, and $C_{19:0cyclo}$ were 23.4%, 10.2% in the Mw and 15.1%, 12.2% in the M-100. These results indicated that acid tolerance of the M-100 was significantly improved in comparison with its wild type Mw.

• Journal of the Korean Chemical Society
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• v.27 no.3
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• pp.178-182
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• 1983

The conductances of sodium, potassium, ammonium, tetramethylammonium, and tetraethylammonium iodides, picrates(Pic) of sodium and potassium, and tetrabutylammonium tetraphenyl-boride have been measured in ethylene carbonate-acetone mixtures at $25{\circ}C$. The limiting equivalent conductances of the electolytes were computed by Fuoss-Kraus equation and the order was $(C_4H_9)_4NB(ph)_4 at any composition of the mixtures. The dissociation constants of the salts showed that the mixtures are good ionizing solvents for the salts. The order of limiting ionic equivalent conductance, $Na^+, is consistent with exactly the reverse order found for solvation number. Effective solvated radii calibrated by the Nightingale method showed that picrate ion seems to be unsolvated and that iodide ion seems to be solvated to some extent in the mixtures.