• Title/Summary/Keyword: $CO_2$-cut

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Characterizations of Copoly(ester imide)s with New 2,7-Dihydroxynaphthalene Bis(trimellitate anhydride) (새로운 2,7-Dihydroxynaphthalene Bis(trimellitate anhydride) 무수물을 이용한 폴리(에스터 이미드) 공중합체의 특성)

  • Ju, Jieun;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.632-639
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    • 2014
  • 2,7-Dihydroxynaphthalene bis(trimellitate anhydride) (2,7-TA) was synthesized from trimellitic anhydride chloride and 2,7-dihydroxynaphthalene. Copolyimides (Co-PI) containing ester group were synthesized from 2,7-TA, pxylylenediamine, and 2,2'-bis(trifluoromethyl)benzidine (TFB). The Co-PI films were obtained from poly(amic acid) by solution casting through thermal imidization on a glass plate. The thermal property, gas permeation, and optical transparency of the Co-PI films with various TFB monomer contents were investigated. These Co-PIs could be solution-cast into a flexible and tough film. The cast Co-PI films exhibited high optical transparency with a cut-off wavelength of 370~395 nm in UV-vis. absorption and a low yellow index value of 3.55~7.63. The thermal property of Co-PI films increased linearly with increasing TFB content. However, the oxygen permeation and optical transparency of the Co-PI films was found to worsen with increasing TFB content.

Angiotensin I-Converting Enzyme Inhibitory Activity of the ${\kappa}-Casein$ Fragments Hydrolysated by Chymosin, Pepsin, and Trypsin (${\kappa}-Casein$의 Chymosin, Pepsin 및 Trypsin 가수분해물에 대한 안지오텐신 변환효소 저해효과의 탐색)

  • Oh, Se-Jong;Kim, Sae-Hun;Kim, Sang-Kyo;Baek, Young-Jin;Cho, Kyung-Hyun
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1316-1318
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    • 1997
  • The isolated ${\kappa}-Casein$ on gel permeation chromatography was hydrolyzed by chymosin, trypsin, and pepsin. The 3% TCA soluble portion of the hydrolysates were dialyzed on the angiotensin-I converting enzyme (ACE) inhibition rate (%,) and inhibitory activity $(IC_{50})$ were determined. The trypsin hydrolysate exhibited the highest ACE inhibition rate while the chymosin hydrolysation showed the lowest activity. The hydrolysate was dialyzed using dialysis membrane with various molecular cut-offs, and $IC_{50}$ was determined. As the pore size of the dialysis tubing increased, the ACE inhibitory activity decreased.

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The ionization energy and lattice parameters of Co- and Ce-doped cubic zirconia (YSZ) single crystal (Co와 Ce를 첨가한 큐빅지르코니아(YSZ) 단결정의 이온화에너지 및 격자상수)

  • Seok, Jeong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.4
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    • pp.159-163
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    • 2010
  • Co-(0.5 mol%) and Ce-(0~0.3 mol%) doped cubic zirconia ($ZrO_2:Y_2O_3$=64:36 mol%) single crystals grown by a skull melting method were heat-treated in $N_2$ at $1200^{\circ}C$ for 3 hrs. The brown-colored as-grown single crystals were changed into either green or blue color after the heat treatment. Before and after the heat treatment, the YSZ (yttriastabilized zirconia) single crystals were cut for wafer form (${\phi}7mm{\times}t2mm$) and round brilliant cut ($\phi$ 12 mm). The optical and structural properties were examined by UV-VIS spectrophotometer and X-ray diffraction. Absorption by $Ce^{3+}(^2F_{5/2},\;_{7/2}(4f){\rightarrow}^2T_g(5d^1)),\;Co^{2+}(^4A_2(^4F){\rightarrow}^4T_1(^4F)$ or $^4T_1(^4P))$ and $Co^{3+}$, change of ionization energy and lattice parameter were confirmed.

Effects of Calcinations Temperature on the Electrochemical Properties of Li[Ni0.6Co0.2Mn0.2]O2 Lithium-ion Cathode Materials (리튬 이차전지용 양극활물질 Li[Ni0.6Co0.2Mn0.2]O2의 소성 온도가 전기화학적 특성에 미치는 영향)

  • Yoo, Gi-Won;Jeon, Hyo-Jin;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.16 no.2
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    • pp.59-64
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    • 2013
  • Using $Na_2CO_3$ and $MeSO_4$ (Me = Ni, Co and Mn) as starting materials, the precursor of $[Ni_{0.6}Co_{0.2}Mn_{0.2}]CO_3$ has been synthesized by carbonate co-precipitation. The precursor was mixed with $Li_2CO_3$, and calcined at 750, 850, and$950^{\circ}C$ in air. Effect of calcinations temperature on characteristics of $Li[Ni_{0.6}Co_{0.2}Mn_{0.2}]O_2$ cathode materials was investigated. The structure and characteristics of $Li[Ni_{0.6}Co_{0.2}Mn_{0.2}]O_2$ were determined by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and electrochemical measurements. The X-ray diffraction (XRD) results show that the intensity ratio of $I_{(003)}/I_{(104)}$ increased and the R-factor ratio decreased with the increase of calcinations temperature. And Scanning electron microscopy (SEM) result show that the primary particle size increased. Especially, the $Li[Ni_{0.6}Co_{0.2}Mn_{0.2}]O_2$ calcined at $950^{\circ}C$ for 24 H shows excellent electrochemical performances with reversible specific capacity of $165.3mAhg^{-1}$ [cut-off voltage 2.5~4.3 V, 0.1 C($17mAhg^{-1}$)] and good capacity retention of 95.4% after 50th charge/discharge cycles[cut-off voltage 2.5~4.3 V, 1 C($170mAhg^{-1}$)].

A Study on Reduction of Energy and CO2 Emission by Using Regenerative Energy of Electric Vehicle (전동차 회생 에너지활용에 따른 에너지 및 CO2 절감 분석에 관한 연구)

  • Kim, Chul-Sub;An, Cheon-Heon;Lee, Byung-Song;Lee, Hi-Sung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.9
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    • pp.85-96
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    • 2010
  • The recent environmental protection trend requires more strict energy saving, therefore every transportation system should reduce energy consumption to the minimum value. High-efficiency operation system, energy saving and $CO_2$ emissions shall be addressed as important issues in railway system. These issues are the most essential factors of railway, compared to major public transportation system. Recently, saving energy in the electric railway system has been studied. The efficient use of regenerated energy is considered to save energy. Namely, Using regenerative energy is that to store the energy generated during braking and discharge it again when a vehicle accelerates. Reusing energy stores and discharges energy, consequently enables a complete exchange of energy between vehicles, even if they are not braking and accelerating at precisely the same time, as is most frequently the case in everyday service. This paper analyzes effects of energy saving and $CO_2$-cut by using regenerative energy of electric vehicles.

Color-change for ligand field of cobalt doped yttria stabilized cubic zirconia (YSZ) single crystal (Cobalt가 첨가된 이트리아 안정화 큐빅지르코니아(YSZ) 단결정의 리간드장에 따른 색상변화)

  • Seok, Jeong-Won;Choi, Jong-Koen
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.1
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    • pp.35-40
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    • 2007
  • Cobalt ($Co^{2+}$) doped yttria stabilized cubic zirconia (YSZ, $Y_2O_3\;:\;25{\sim}50wt%$) single crystals grown by a skull melting method were heat-treated in $N_2\;at\;1000^{\circ}C$ for 5 hrs. The reddish brown single crystals were changed into either violet or blue color, respectively. Before and after heat treatment, the Co-doped YSZ crystals cut for wafers (${\phi}6.5{\times}t\;2mm$) and round brilliant (${\phi}10mm$). The optical and structural properties were examined by UV-VIS spectrophotometer and XRD. These results are analyzed absorption by $Co^{2+}\;(^4A_2(^4F)\to{^4P})\;and\;Co^{3+}$, change of energy gap and lattice parameter.

Separation and Purification of Bio Gas by Hollow Fiber Gas Separation Membrane Module (중공사형 기체분리막 모듈을 이용한 바이오가스의 분리 및 정제)

  • Koh, Hyung-Chul;Ha, Seong-Yong;Woo, Seung-Moon;Nam, Sang-Yong;Lee, Byung-Seong;Lee, Chung-Seop;Choi, Whee-Moon
    • Membrane Journal
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    • v.21 no.2
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    • pp.177-192
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    • 2011
  • Hollow fiber membrane using CTA polymers were prepared by the phase separation method for the separation and purification of biogas and the hollow fiber gas separation membrane modules with the effective surface area of 0.17 $m^2$ were prepared. The pure gas permeation properties of membrane modules for methane, oxygen and carbon dioxide were measured. The permeance of $CO_2$ and $CH_4$were 0.46 GPU and 18.52 GPU, respectively, therefore, the high $CO_2$/$CH_4$ selectivity of 40.4 was obtained. The separation and purification test for 4 different simulated mixed gases were carried out after the pure gas test and the gas concentration and flux of the permeate at the various stage-cut were measured from the 1 stage, 2 stage, and 3 stage cascade of membrane modules. In the 1 stage test, the concentration of $CH_4$ increased as the increase of the stage-cut, while the $CH_4$ recovery efficiency ratio decreased. In the 2 stage test, the $CH_4$ recovery efficiency ratio increased compared to the 1 stage. The 3 stage test was employed to reduce the loss of $CH_4$ in biogas and the result showed less than 5% of $CH_4$ recovery loss.

Quality Changes of Fresh-Cut Tumeric by Packaging Methods during Storage (포장방법에 따른 세절 생울금의 저장 중 품질 변화)

  • Kim, Dong-Hoo;Han, Jin-Soo;Woo, In-Bong;Jung, Jun-Jae;Park, Si-Woo;Heo, Kyung-Chel;Ha, Ju-hyeung;Yoon, Chan-Suk
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.3
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    • pp.151-162
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    • 2017
  • The purpose of this study was to investigate the quality change of fresh-cut tumeric (Curcuma Longa Linne) according to packaging method during storage time. The fresh-cut tumeric were packaged in three different methods : degassing valve packaging (DVP), $CO_2$ gas absorber packaging (CAP) and micro-perforated packaging (MPP). After the samples were packaged, they were stored for 15 days at 4 and $23^{\circ}C$ respectively. The following parameters were observed to indicate the quality changes of the samples: weight loss, CIE $L^*a^*b^*$ colour difference, variation of gas composition inside the package, curcumin contents and changes in hardness of fresh-cut tumeric. DVP did not effectively release $CO_2$ gas to the outside. MPP was suitable to release $CO_2$ gas. However, MPP showed very fast browning and erosion, because a large amount of oxygen was introduced through the perforated hole on the film. CAP was most effective packaging method to inhibit browning, to prevent expansion of the packaging by $CO_2$ gas and to minimize weight loss of fresh-cut tumeric.

Dose Effect of Phytosanitary Irradiation on the Postharvest Quality of Cut Flowers

  • Kwon, Song;Kwon, Hye Jin;Ryu, Ju Hyun;Kim, Yu Ri
    • Journal of People, Plants, and Environment
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    • v.23 no.2
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    • pp.171-178
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    • 2020
  • The present study was conducted to determine the effects of electron beam irradiation on the postharvest quality of cut flowers. Cut flowers were irradiated with electron beam at 100, 200, 400, 600, 800, 1,000, and 2,000 Gy with a 10 MeV linear electron beam accelerator to evaluate their irradiation tolerance. Postharvest quality was determined by monitoring fresh weight loss, flower longevity, flower diameter, flowering rate, visual quality of flowers and leaves, and chlorophyll content. Cut flowers showed a radiation-induced damage with increasing the irradiation dose. Flower longevity and fresh weight of cut flowers decreased when the irradiation dose was increased. Flower bud opening was also inhibited in a dose-dependent manner. The effective irradiation doses for 10% reduction of postharvest quality (ED10) values were 144.4, 451.6, and 841.2 Gy in the 'Medusa' lily, 'Montezuma' carnation, and 'Rosina White' eustoma, respectively. Although tolerance of cut flowers to electron beam irradiation vary according to species, cultivars, or maturity stage conditions, it is conceivable that 'Montezuma' carnation and 'Rosina White' eustoma could be tolerated and maintained overall postharvest quality up to 400 Gy, the generic irradiation dose approved by the Animal and Plant Health Inspection Service (APHIS) and the International Plant Protection Convention (IPPC) for postharvest phytosanitary treatments.

Study on Dose Rate on the Surface of Cask Packed with Activated Cut-off Pieces from Decommissioned Nuclear Power Plant

  • Park, Kwang Soo;Kim, Hae Woong;Sohn, Hee Dong;Kim, Nam Kyun;Lee, Chung Kyu;Lee, Yun;Lee, Ji Hoon;Hwang, Young Hwan;Lee, Mi Hyun;Lee, Dong Kyu;Jung, Duk Woon
    • Journal of Radiation Protection and Research
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    • v.45 no.4
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    • pp.178-186
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    • 2020
  • Background: Reactor pressure vessel (RV) with internals (RVI) are activated structures by neutron irradiation and volume contaminated wastes. Thus, to develop safe and optimized disposal plan for them at a disposal site, it is important to perform exact activation calculation and evaluate the dose rate on the surface of casks which contain cut-off pieces. Materials and Methods: RV and RVI are subjected to neutron activation calculation via Monte Carlo methodology with MCNP6 and ORIGEN-S program-neutron flux, isotopic specific activity, and gamma spectrum calculation on each component of RV and RVI, and dose rate evaluation with MCNP6. Results and Discussion: Through neutron activation analysis, dose rate is evaluated for the casks containing cut-off pieces produced from decommissioned RV and RVI. For RV cut-off ones, the highest value of dose rate on the surface of cask is 6.97 × 10-1 mSv/hr and 2 m from it is 3.03 × 10-2 mSv/hr. For RVI cut-off ones, on the surface of it is 0.166 × 10-1 mSv/hr and 2 m from it is 1.04 × 10-1 mSv/hr. Dose rates for various RV and RVI cut-off pieces distributed lower than the limit except the one of 2 m from the cask surface of RVI. It needs to adjust contents in cask which carries highly radioactive components in order to decrease thickness of cask. Conclusion: Two types of casks are considered in this paper: box type for very-low-level waste (VLLW) as well as low-level waste (LLW) and cylinder type for intermediate-level waste (ILW). The results will contribute to the development of optimal loading plans for RV and RVI cut-off pieces during the decommissioning of nuclear power plant that can be used to prepare radioactive waste disposal plans for the different types of wastes-ILW, LLW, and VLLW.