• Title/Summary/Keyword: $CO_2$ utilization

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Prediction of Transport Properties for Transportation of Captured CO2. 1. Viscosity (수송조건 내 포집 이산화탄소의 전달물성 예측. 1.점성)

  • Lee, Won Jun;Yun, Rin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.4
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    • pp.195-201
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    • 2017
  • In this study, the viscosity of a $CO_2-gas$ mixture was investigated for the transportation of the captured $CO_2-gas$ in pipelines and for the designing of a thermal system, both of which involve the utilization of the $CO_2-gas$ mixture. The viscosities of the $CO_2-gas$ mixture, $CO_2+CH_4$, $CO_2+H_2S$, and $CO_2+N_2$ were predicted using three different models as follows : Chung, TRAPP, and REFPROP. The predictability values of the models were validated by comparing the estimated results with the experiment data for the $CO_2+CH_4$ and $CO_2+N_2$ under high-density conditions. The Chung model showed 2.41%, which is the lowest mean deviation of the prediction among the model. Based on the Chung model, the mixture mole fractions were changed from 0.9, 0.95, and 0.97, the mixture pressure was ranged from 80 bar to 120 bar by 10 bar, and the mixture temperature was varied from 310 K to 400 K by 10 K to observe the effects of the parameters on the mixture viscosity. Considering the high mole fraction of the $CO_2$ in the mixture, a significant variation of the mixture viscosity was observed close to the pseudo-critical temperature, and the viscosity for the $CO_2+H_2S$ mixture shows the highest values compared with those of the $CO_2+CH_4$ and $CO_2+N_2$.

A Review on Nanostructured Carbon Nitrides for CO2 Capture (Carbon Nitrides 나노구조체를 이용한 CO2 포집 연구의 최신동향)

  • Ha, Seongjin;Lee, Dongki;Jin, Wenji;Park, Dae-Hwan
    • Ceramist
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    • v.22 no.3
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    • pp.316-327
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    • 2019
  • Carbon nitride has drawn broad interdisciplinary attention in diverse fields such as catalyst, energy storage, gas adsorption, biomedical sensing and even imaging. Intensive studies on carbon dioxide (CO2) capture using carbon nitride materials with various nanostructures have been reported since it is needed to actively remove CO2 from the atmosphere against climate change. This is mainly due to its tunable structural features, excellent physicochemical properties, and basic surface functionalities based on the presence of a large number of -NH or -NH2 groups so that the nanostructured carbon nitrides are considered as suitable materials for CO2 capture for future utilization as well. In this review, we summarize and highlight the recent progress in synthesis strategies of carbon nitride nanomaterials. Their superior CO2 adsorption capabilities are also discussed with the structural and textural features. An outlook on possible further advances in carbon nitride is also included.

Synthesis of Cement Raw Materials by Melting of Industiral Wastes(II) (폐기물의 용융처리에 의한 시멘트 원료의 합성(II))

  • Hwang, Y.;Sohn, Y. U.;Chung, H. S.;Lee, H. K.;Park, H. S.
    • Resources Recycling
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    • v.6 no.1
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    • pp.29-34
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    • 1997
  • The feasibility of using the industrial inorganic waste materials such as l~mestone sludge. Soundly sand. coal fly 'ash, and chemical glasses as a raw material for cement clinker by melting treatmeut was iovestigated. The slag wh~ch is obtained from thc melts of the mixtnres of waste materials is composed of P-C,S(ZCaO - SIOJ and C,AS(ZCaO . AI,O, . SiO,) phases. The effect of melting tempcrabre, coaling condition and CIS ratio on the fo~mation of P-C,S phasc was examed. In order to obtain thc P-CiS phase which is useful in thc utilhtion as a clinkcr malcrid, it B found that sudl considerations as low melting temperature as possible of the wastc mixhire, quenching the melts and law CIS ratio of the mlxhlre are necessary.

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Technology of syngas production and utilization by waste gasification (폐기물 가스화를 통한 합성가스 생산 및 활용 기술)

  • Gu, Jae-Hoi;Yoo, Young-Don;Lee, Hyup-Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.633-636
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    • 2007
  • 국내에서 발생되는 폐기물을 이용하여 가스화에 의해 생산되는 합성가스의 생산 및 활용기술에 대해 고찰하였다. 폐기물 가스화에 의해 생산되는 합성가스의 조성은 CO, $H_2$를 주성분으로 하며 부분산화 조건에 $CO_2$가 함께 생산된다. 생산된 합성가스는 CO $20{\sim}35$%, $H_{2}$ $20{\sim}35$% 정도의 조성으로 나타나며 발생량은 $1,365{\sim}2,125$ $Nm^3/hr$로 나타났다. 이러한 합성가스는 스팀생산, 전력생산 및 DME, SNG, 메탄올, 수소와 같은 고부가가치의 화학원료를 생산할 수 있다.

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Development of Hybrid Induction Heating System for Laser Printer

  • Chae Young-Min;Kwon Joong-Gi;Han Sang-Yong;Sung Hwan-Ho
    • Journal of Power Electronics
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    • v.6 no.2
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    • pp.178-185
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    • 2006
  • Recently, the demand for the development of high quality and high-speed laser printers and efficient power utilization has required. Among complicated electro-mechanic devices in laser printers, the toner-fusing unit consumes above 90[%] of all electrical energy needed for printing devices. Therefore, the development of a more effective energy-saving toner fusing process becomes a significant task in great demand. Generally, there are several ways to implement a fusing unit. Among them this paper presents a new induction heating method. The proposed induction heating method enables the increase of coupling coefficient between heating coil and heat roller which also increases total energy transfer efficiency. Therefore, the proposed IH (Induction Heating) inverter system provides very fast W.U.T. (Warm UP Time) as well as higher efficiency. Through experimental results, the proposed control system is verified.

An Analysis on the $CO_2$ Reduction and Sequestration Technology using the AHP (AHP를 이용한 $CO_2$ 저감 및 처리기술 분석)

  • 이덕기;최상진;박수억;하영진;이정태
    • Journal of Energy Engineering
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    • v.13 no.3
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    • pp.219-227
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    • 2004
  • World have been encouraged to develop technologies that contribute to CO$_2$ emission reduction for many years. Those technologies can be categorized into capture, storage or sequestration, utilization, etc. There have been lots of efforts, in Korea, to develop the technology as well. In this paper, the impact factors of the technologies, especially in CDRS (Carbon Dioxide Reduction & Sequestration Center), were selected and were weighed by SMM (Storing Models Method) and AHP (Analytic Hierarchy Process) in order to evaluate the four representative areas of the technologies.

Solvent Extraction of Cobalt Chloride from Strong Hydrochloric Acid Solutions by Alamine336 (진한 염산용액에서 Alamine336에 의한 염화코발트의 용매추출)

  • Lee, Man-seung;Lee, Jin-Young
    • Korean Journal of Metals and Materials
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    • v.46 no.4
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    • pp.227-232
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    • 2008
  • Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02- 1.75 M, and [HCl ] : 5 - 10 M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. $Co^{2+}+2Cl^{-}+R_3NHCl_{org}=CoCl_3\;R_3NH_{org}$, $K_{ex}=2.21$ The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.

Thermodynamic Evaluation of Sulfate-Roasting Process for the Vanadium Extraction from Korean VTM Ore (국내부존 VTM으로부터 바나듐 회수를 위한 황화배소 공정의 열역학적 평가)

  • Kim, Youngjae;Choi, Kyungsob;Park, Hyunsik;Chung, Kyeong Woo
    • Resources Recycling
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    • v.31 no.2
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    • pp.49-55
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    • 2022
  • In the present study, the thermodynamic evaluation of the sulfate-roasting process was conducted to extract vanadium from the Korean vanadium titano-magnetite ore. The leaching efficiency of vanadium and other impurities was analyzed for varying roasting temperatures and addition of Na2SO4. In the case of sulfate roasting, the roasting temperature was 200 ℃ higher than that previously observed Na2CO3 roasting. However, the higher leaching efficiency of vanadium and lower leaching efficiency of other impurities, such as aluminum and silicon, were observed. The high selectivity for the extraction of vanadium in sulfate roasting would result from the reaction mechanism between SO2 gas and vanadium concentrate.

Studies on the Utilization of Chestnut Bur(2) - Utilization of Chestnut Bur Powder as Glue Extender for Plywood Adhesion - (밤송이 이용(利用)에 관(關)한 연구(硏究)(2) - 밤송이 분말(粉末)의 합판접착용(合板接着用) 증량제(增量劑)로의 이용(利用) -)

  • Kong, Young-To;Kim, Jae-Kwang;Ahn, Byung-Hwan;Jo, Jae-Myeong;Kang, Young-Mu
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.4
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    • pp.64-68
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    • 1987
  • To develope the utilities of the chestnut bur, which is wasted after harvesting chestnut in farmhouses, the feasibilities of adhesion(urea resin) extenders of the powder for plywood were examined. These experiments were implemented on experimental scale at Forestry Research Institute(Seoul) and on a plywood mill scale at Eugon Industrial Co LTD(Inchon) for more reliable data. In this paper, it was proved that the chestnut bur powder caused to rise the glue viscosity but the chaff powder to down reversely. The most effective mixing ratio were wheat flour 5kg, chaff powder: 5kg and chestnut bur powder. 5kg per 100kg of urea resin. At this condition, the viscosity were most appropriate (1,320 2,230 cps) for glue spreading operations, and the dry shear strengthes were most adequate(10.7-13.2kg/$cm^2$), wood failure ratio 82-88%). The chestnut bur powder, can be utilized for plywood adhesion extenders without any change of present process lines in plywwod mills.

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Screening of Spray-Dried K2CO3-Based Solid Sorbents using Various Support Materials for CO2 Capture

  • Eom, Tae Hyoung;Lee, Joong Beom;Baek, Jeom In;Ryub, Chong Kul;Rhee, Young Woo
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.115-120
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    • 2015
  • $K_2CO_3$-based dry regenerable sorbents were prepared by spray-drying techniques to improve mass produced $K_2CO_3-Al_2O_3$ sorbents (KEP-CO2P, hereafter), and then tested for their $CO_2$ sorption capacity by a $2,000Nm^3/h$ (0.5 MWe) $CO_2$ capture pilot plant built for Unit 3 of the Hadong thermal power station in 2010. Each of the sample sorbents contained 35 wt.% $K_2CO_3$ as the active materials with various support materials such as $TiO_2$, MgO, Zeolite 13X, $Al_2O_3$, $SiO_2$ and hydrotalcite (HTC). Their physical properties and reactivity were tested to evaluate their applicability to a fluidized-bed or fast transport-bed $CO_2$ capture process. The $CO_2$ sorption capacity and percentage utilization of $K_2CO_3$-MgO based sorbent, Sorb-KM2, was $8.6g-CO_2/100g$-sorbents and 90%, respectively, along with good mechanical strength for fluidized-bed application. Sorbs-KM2 and KT were almost completely regenerated at $140^{\circ}C$. No degradation of Sorb-KM by $SO_2$ added as a pollutant in flue gas was observed during a cycle test.