• Journal of Electrochemical Science and Technology
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• v.1 no.2
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• pp.75-80
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• 2010

We report Co-tetramethoxyphenylporphyrin on carbon particles (Co-TMPP/C) as a non-Pt catalyst for tri-iodide reduction in dye-sensitized solar cells (DSSCs). The presence of well-dispersed carbon and cobalt source in the catalyst surface is confirmed by transmission electron microscopy, scanning electron microscopy, and energy dispersive X-ray analysis. In the C 1s, Co 2p, and N 1s peaks measured by X-ray photoelectron spectroscopy, the C-N, Co-$N_4$, and N-C are assigned to the component at 285.7, 781.8, and 401 eV, respectively. Especially, the Co-TMPP/C shows improved current density, diffusion coefficient, and charge-transfer resistance in the ${I_3}^-/I^-$ redox reaction compared to conventional catalysts. Furthermore, in the DSSCs performance, the Co-TMPP/C shows increased short circuit current density, higher open circuit voltage, and improved cell efficieny in comparison with Pt/C.

• Korean Journal of Materials Research
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• v.33 no.2
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• pp.29-46
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• 2023

The electrochemical reduction of carbon dioxide (CO₂) to value-added products is a remarkable approach for mitigating CO₂ emissions caused by the excessive consumption of fossil fuels. However, achieving the electrocatalytic reduction of CO₂ still faces some bottlenecks, including the large overpotential, undesirable selectivity, and slow electron transfer kinetics. Various electrocatalysts including metals, metals oxides, alloys, and single-atom catalysts have been widely researched to suppress HER performance, reduce overpotential and enhance the selectivity of CO₂RR over the last few decades. Among them, single-atom catalysts (SACs) have attracted a great deal of interest because of their advantages over traditional electrocatalysts such as maximized atomic utilization, tunable coordination environments and unique electronic structures. Herein, we discuss the mechanisms involved in the electroreduction of CO₂ to carbon monoxide (CO) and the fundamental concepts related to electrocatalysis. Then, we present an overview of recent advances in the design of high-performance noble and non-noble singleatom catalysts for the CO₂ reduction reaction.

• Korean Journal of Agricultural and Forest Meteorology
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• v.16 no.1
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• pp.22-28
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• 2014

This study was conducted to investigate the photosynthetic characters of Populus alba${\times}$glandulosa cuttings in response to elevated $CO_2$ concentration and air temperature for selecting tree species adaptive to climate change. The cuttings were grown in environment controlled growth chambers with two combinations of $CO_2$ concentration and air temperature conditions: (i) $22^{\circ}C$ + $CO_2$ 380 ${\mu}mol$ $mol^{-1}$ (control) and (ii) $27^{\circ}C$ + $CO_2$ 770 ${\mu}mol$ $mol^{-1}$ (elevated) for almost three months. The cuttings under the elevated treatment showed reduced tree height and photosynthetic pigment contents such as chlorophyll and carotenoid. In particular, the elevated treatment resulted in a marked reduction in the chlorophyll a closely associated with $CO_2$ fixative reaction system. Different levels of reduction in photosynthetic characters were found under the elevated treatment. A decrease was noted in photochemical reaction system parameters: net apparent quantum yield (7%) and photosynthetic electron transport rate (14%). Moreover, a significant reduction was obvious in $CO_2$ fixative reaction system parameters: carboxylation efficiency (52%) and ribulose-1,5-bisphosphate(RuBP) regeneration rate (24%). These results suggest that the low level of photosynthetic capacity may be attributed to the decreased $CO_2$ fixative reaction system rather than photochemical reaction system.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.227-234
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• 2004

For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion(CLC) may yield great advantages of savings of energy to $CO_2$ separation and suppressing the effect on environment. In chemical-looping combustor, fuel is oxidized by metal oxide medium (oxygen carrier particle) in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. The purpose of this study is to demonstrate inherent $CO_2$ separation and no NOx emission and to confirm high $CO_2$ selectivity, no side reaction (i.e., carbon deposition, hydrogen generation) by continuous reduction and oxidation experiment in a 50kWtb chemical-looping combustor. NiO/bentonite particle was used as a bed material and $CH_4$ and air were used as reacting gases for reduction and oxidation respectively.

• Journal of Powder Materials
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• v.15 no.2
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• pp.107-113
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• 2008

Ultrafine TiC-5%Co powders were synthesized by spray drying of aqueous solution of TiO$(OH)_2$ slurry and cobalt nitrate, followed by calcination and carbothermal reaction. The oxide powders with carbon powder was reduced and carburized at $900^{\circ}C{\sim}1250^{\circ}C$ under hydrogen atmosphere. During reduction, CO gas was mainly evolved by reducing reaction of oxides. Ultrafine TiC-5%Co powders were easily formed by carbothermal reaction at $1250^{\circ}C$ due to using ultrafine powders as raw materials. The ultrafine WC-TiC-Co alloy prepared by sintering of mixed powder of ultrafine WC-13%Co powder and ultrafine TiC-5%Co powder has higher sintered density and mechanical properties than WC-TiC-Co alloy prepared by commercial WC, TiC and Co powders.

• Korean Chemical Engineering Research
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• v.47 no.1
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• pp.96-104
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• 2009

In order to lower a reaction temperature with high conversions for simultaneous catalytic reduction of NO and $N_2O$ over Pd-Rh supported mixed metal oxide honeycomb catalysts, $H_2$ or CO was utilized as a reductant. When using the reductants, the effects of reaction conditions were examined in NO and $N_2O$ conversions, where reaction temperatures, concentrations of the reductants and oxygen and the concentration ratio of $N_2O$ to NO were varied. In using $H_2$ reductant, larger than 50% of NO and $N_2O$ conversions was observed at the temperatures below $200^{\circ}C$ in absence of $O_2$. In using CO reductant, NO and $N_2O$ conversions increased from the temperatures higher than $200^{\circ}C$ and $300^{\circ}C$, respectively. However, in use of both reductants, NO and $N_2O$ conversions decreased with increasing oxygen concentration. As a result, $H_2$ reductant could reduce simultaneously NO and $N_2O$ at relatively lower reaction temperature than CO. Also, NO and $N_2O$ conversions were less influenced by using $H_2$ reductant than CO one. Concentration ratio between NO and $N_2O$ did not affect their conversions regardless the type of reductants. Pretreatment of the catalyst in $H_2$ was more effective in simultaneous reduction of NO and $N_2O$ at low reaction temperature than that in $O_2$.

• Bulletin of the Korean Chemical Society
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• v.19 no.4
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• pp.417-422
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• 1998

The electrocatalytic reduction of molecular oxygen was investigated with a Co(II)-glyoxal bis(2-hydroxyanil) complex coated-glassy carbon (GC) electrode in aqueous media. The reduction of $O_2$ at the modified electrode was an irreversible and diffusion-controlled reaction. The complex coated-GC electrode demonstrated an excellent electrocatalytic effect for $O_2$ reduction in an acetate buffer solution of pH 3.2. The coated electrode made the $O_2$ reduction potential shift of 60-510 mV in a positive direction compared to the bare GC electrode depending on pH. The Co(II)-glyoxal bis(2-hydroxyanil) coated electrode converted about 51% of the $O_2$ to $H_2O_2$ via a two-electron reduction pathway, with the balance converted to H_2O$.

• Korean Journal of Materials Research
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• v.21 no.6
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• pp.327-333
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• 2011

Nanostructured cobalt materials have recently attracted considerable attention due to their potential applications in high-density data storage, magnetic separation and heterogeneous catalysts. The size as well as the morphology at the nano scale strongly influences the physical and chemical properties of cobalt nano materials. In this study, cobalt nano particles synthesized by a a polyol process, which is a liquid-phase reduction method, were investigated. Cobalt hydroxide ($Co(OH)_2$), as an intermediate reaction product, was synthesized by the reaction between cobalt sulphate heptahydrate ($CoSO_4{\cdot}7H_2O$) used as a precursor and sodium hydroxide (NaOH) dissolved in DI water. As-synthesized $Co(OH)_2$ was washed and filtered several times with DI water, because intermediate reaction products had not only $Co(OH)_2$ but also sodium sulphate ($Na_2SO_4$), as an impurity. Then the cobalt powder was synthesized by diethylene glycol (DEG), as a reduction agent, with various temperatures and times. Polyvinylpyrrolidone (PVP), as a capping agent, was also added to control agglomeration and dispersion of the cobalt nano particles. The optimized synthesis condition was achieved at $220^{\circ}C$ for 4 hours with 0.6 of the PVP/$Co(OH)_2$ molar ratio. Consequently, it was confirmed that the synthesized nano sized cobalt particles had a face centered cubic (fcc) structure and with a size range of 100-200 nm.

• Journal of Electrochemical Science and Technology
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• v.7 no.2
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• pp.91-96
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• 2016

Oxidation behaviours of ash free coal (AFC), carbon, and H₂ fuels were investigated with a coin type molten carbonate fuel cell. Because AFC has no electrical conductivity, its oxidation occurs via gasification to H₂ and CO. An interesting behaviour of mass transfer resistance reduction at higher current density was observed. Since the anode reaction has the positive reaction order of H₂, CO₂ and H₂O, the lack of CO₂ and H₂O from AFC results in a significant mass transfer resistance. However, the anode products of CO₂ and H₂O at higher current densities raise their partial pressure and mitigate the resistance. The addition of CO₂ to AFC reduced the resistance sufficiently, thus the resistance reduction at higher current densities did not appear. Electrochemical impedance results also indicate that the addition of CO₂ reduces mass transfer resistance. Carbon and H₂ fuels without CO₂ and H₂O also show similar behaviour to AFC: mass transfer resistance is diminished by raising current density and adding CO₂.

• Journal of the Korean Chemical Society
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• v.68 no.2
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• pp.87-92
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• 2024

The commercialization of rechargeable metal-air batteries is extremely desirable but designing stable oxygen reduction reaction (ORR) catalysts with non-noble metal still has faced challenges to replace platinum-based catalysts. The nonnoble metal catalysts for ORR were prepared to improve the catalytic performance and stability by the thermal decomposition of ZIF-8 with optimum cobalt loading. The porous carbon was obtained by the calcination of ZIF-8 and different loading amounts of Co nanoparticles were anchored onto porous carbon forming a Co/PC catalyst. Co/PC composite shows a significant increase in the ORR value of current and stability (500 h) due to the good electronic conductive PCN support and optimum cobalt metal loading. The significantly improved catalytic performance is ascribed to the chemical structure, synergistic effects, porous carbon networks, and rich active sites. This method develops a new pathway for a highly active and advantageous catalyst for electrochemical devices.