• Title/Summary/Keyword: $CO_2$ foam

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Production Process of Foamed Glass by Compressive Shaping (가압성형 방법에 의한 발포유리의 제조공정)

  • Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.239-246
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    • 2013
  • Principle of foamed glass manufacturing process first starts with putting vitreous material powder into a mold. After the foaming calcination, foamed body should be annealed after separation from the mold. For this reason, existing manufacturing process could not be a continuous type process. In this study, in order to develop a continuous production process of foamed glass, the possibility of new foam glass manufacturing process was investigated by foaming calcination of the compact body obtained from compression-molding of vitreous raw materials in stead of using a mold. Through the experimental results of the foaming calcination of the compact body with adding various foaming agents such as $Na_2CO_3$, $CaCO_3$ and petroleum coke, into hydrated soda-lime vitreous raw materials, it was shown that developing a continuous process without using any molds for manufacturing foamed glass would be possible.

Effect of Talc on cell density in foam processing with CO2 (Talc 함유량이 초미세 발포 셀-밀도에 미치는 영향)

  • 이보형;차성운
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1406-1409
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    • 2003
  • There is a great demand for reducing the amount of material used in mass-produced plastics parts, for material cost constitutes a large percentage of the total cost of 60%. It may be noted that the price of plastics is directly rotated to the price of petroleum. Material reduction therefore decreases the amount of oil needed for the manufacture of plastics and thus help conserve this natural resource. Therefore microcellular foaming process(MCPs) was studied for solving this problems alternatively in 1980's at M.I.T Until now in MCPs carbon dioxide gas was mainly used for microcellular foaming. Besides, Talc was used for reducing the price of plastics. Consequently, we must certificate using the Talc in MCPs according to contents of the Talc.

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Development of high-hydrophilic Biofilter for Decentralized Regions and Rural Communities (분산지역의 생활하수 처리를 위한 고친수성 Biofilter 개발)

  • Kwon, Tae-Young;Yoon, Chun-Gyeong;Jung, Kwang-Wook
    • Journal of Korean Society on Water Environment
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    • v.22 no.4
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    • pp.678-686
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    • 2006
  • The feasibility of the high-hydrophilic biofilter was examined for application in rural wastewater treatment in Korea. The intermittent trickling biofiter was developed for wastewater treatment of media and examined instantaneous wetting water and immersional wetting water. Melamin foam absorbed 120 times it's weight in water and maintained wetting status than other materials. These characteristics are improvement for application in rural areas showing large variance of amount of influent. The biofilter process was effective in treating organic pollutants; mean removal efficiencies of $BOD_5$ and TSS were above 80%. The average SS concentrations of effluent was showed below $10mg/L^{-1}$ and meet guidelines in special regions, however, the average concentration of $BOD_5$ was about $20mg/L^{-1}$. The removals of T-N and T-P were relatively less effective and removal efficiencies were below 40%. It might meet the guidelines for T-P because of low levels of influent T-P concentration. However, the T-N concentration were too high and further treatment is required. The effluent concentration of $NH_4-N$ showed a significant reduction rate about 43.8%, but part of $NH_4-N$ was transformed to $NO_2-N$ and $NO_3-N$ inside the biofilter through nitrification process. The effluent concentration of org-P was removed about 78.8% of influent concentration by filtration. Considering stable performance and effective removal of pollutant in wastewater, low maintenance, and cost-effectiveness, the hydrophilic biofilter system was thought to be an effective and feasible alternative for decentralized rural areas.

Influence of Design Variables on Failure Loads of Sandwich Beam (설계변수에 대한 샌드위치 보의 파손하중)

  • Jongman Kim
    • Composites Research
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    • v.16 no.3
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    • pp.18-24
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    • 2003
  • Sandwich structures have been widely used in the applications of vessel industry, where high structural stiffness is required with small addition of weight. It is so significant to think of the effect of the variables in the design process of the sandwich structure for the concentrated loads. This paper describes the influence of design variables, such as core density, core thickness and face thickness ratio, on the strength of sandwich beam. The theoretical failure loads based on the 2-D elasticity theory agree well with the experimental yield or failure loads, which are measured at the three point bending laboratory test using AS4/3501-6 facing and polyurethane foam core sandwich beam. The comparison of those yield or failure loads was also done with the ratio of the top to bottom face thickness. The theoretical optimum condition is obtained by finding the intersection point of failure modes involved, which gives optimum core density of the sandwich beam for strength and stiffness. In the addition, the effect of unequal face thickness for the optimized and off-optimized sandwich beams for the strength was compared with the ratio of loading length to beam length, and the variations of strength and stiffness were discussed with the relative ratio of core to face mass.

Syngas and Hydrogen Production under concentrated solar radiation : Redox system of $ZrO_2$ nano-structure (고온 태양열을 이용한 합성가스 및 수소 생산 : $ZrO_2$ 나노 구조화에 따른 산화/환원 특성)

  • Jang, Jong-Tak;Lee, Jong-Min;Cho, Eun-Su;Yang, Seung-Chan;Yoon, Ki-June;Han, Gui-Young
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.463-469
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    • 2012
  • Solar thermochemical syngas and hydrogen production process bv redox system of metal oxide was performed under direct irradiation of the metal oxide on the SiC ceramic foam device using solar simulator. $CeO_2/ZrO_2$ nanotube has been synthesized by anodic oxidation method. Syngas and hydrogen production process is one of the promising chemical pathway for storage and transportation of solar heat by converting solar energy to chemical energy. The produced syngas had the $H_2/CO$ ratio of 2, which was suitable for methanol synthesis or Fischer-Tropsch synthesis process. After ten cycles of redox reaction, $CeO_2$ was analyzed using XRD pattern and SEM image in order to characterize the physical and chemical change of metal oxide at the high temperature.

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Synthesis of Carbon Nanofibers Based on Resol Type Phenol Resin and Fe(III) Catalysts

  • Hyun, Yu-Ra;Kim, Hae-Sik;Lee, Chang-Seop
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3177-3183
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    • 2012
  • The carbon nanofibers (CNFs) used in this study were synthesized with an iron catalyst and ethylene as a carbon source. A concentration of 30 wt % iron(III) acetylacetonate was dissolved in resol type phenol resin and polyurethane foam was put into the solution. The sample was calendered after being cured at $80^{\circ}C$ in air for 24 h. Stabilization and carbonization of the resol type phenol resin and reduction of the $Fe^{3+}$ were completed in a high-temperature furnace by the following steps: 1) heating to $600^{\circ}C$ at a rate of $10^{\circ}C/min$ with a mixture of $H_2/N_2$ for 4 h to reduce the $Fe^{3+}$ to Fe; 2) heating to $1000^{\circ}C$ in $N_2$ at a rate $10^{\circ}C/min$ for 30 minutes for pyrolysis; 3) synthesizing CNFs in a mixture of 20.1% ethylene and $H_2/N_2$ at $700^{\circ}C$ for 2 h using a CVD process. Finally, the structural characterization of the CNFs was performed by scanning electron microscopy and a synthesis analysis was carried out using energy dispersive spectroscopy and X-ray photoelectron spectroscopy. Specific surface area analysis of the CNFs was also performed by $N_2$-sorption.

Evaluation of an Organic-Inorganic Hybrid Insulation Material using an Inorganic Filler and Polyurethane with a Foaming Condition (무기질 충진재와 폴리우레탄을 활용한 유·무기 복합 단열소재의 발포조건에 따른 특성 평가)

  • Noh, Hyun-Kyung;Song, Hun;Chu, Yong-Sik;Park, Ji-Sun;Lee, Jong-Kyu
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.654-658
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    • 2012
  • In this work, the properties of an organic-inorganic hybrid insulating material using an inorganic filler and polyurethane foam with different foaming conditions were investigated. At weight ratios of polyol and isocyanate of 1 to 1.2 good foaming properties were noted. In addition, an addition of 0.4 g of water, 0.1 g of surfactant, and 0.1 g of catalyst with respect to the composites of polyol at 5 g and isocyanate at 6 g showed the lowest apparent density and thermal conductivity. The pore size was smaller in the organic-inorganic hybrid foaming body with an increase in the $CaCO_3$ addition amount. Moreover, the apparent density and thermal conductivity were increased when the added amount of $CaCO_3$ increased. Increasing the amount of $CaCO_3$ powder is expected to improve the flame retardant capabilities; however, doing this tends to increase the apparent density and thermal conductivity.

Improvement Proposal for the Fire Suppression Systems of Open Parking Lots (개방형주차장의 소방설비 개선 제안)

  • Jeong, Keesin
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.1-8
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    • 2016
  • In cars, the amount of combustibles, such as plastics, textiles, etc., have increased dramatically to improve the fuel efficiency of cars by reducing the gross vehicle weight according to the increases in an oil price and to reduce environmental problems. One or two cars were involved in a parking lot fire prior to the mid-2000 s. On the other hand, there were many parking lot fires where the entire car was destroyed due to increasing the use of plastics. In this study, the quantity of combustibles in a car was 316.2 kg over a total weight 1935 kg. This is 16.34% of total weight and 10 times greater than that three decades earlier. When a sprinkler is installed as a parking lot fire protection system as a substitute for water spray, the water discharge of the sprinkler must maintain the original density of water spray, $20lpm/m^2$. In addition, the use of a hose reel $CO_2$ system at pilotis parking lots must be prohibited because the hose reel $CO_2$ system has no adaptability for a car fire. Instead, this study proposes foam, dry powder, loaded stream systems be used in parking lot fire suppression systems.

Study on the Hatching Characteristics and Diet of the Stick Insect, Baculum elongatum (Phasmida: Phasmatidae) for Artificial Mass Rearing

  • Lee, Jin Gu;Kim, Hee Dong;Kang, Chang Sung;Seo, Ae Gyeong;Lee, Sang Hyun;Park, Young Kyu;Lee, Young Bo
    • International Journal of Industrial Entomology and Biomaterials
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    • v.26 no.1
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    • pp.61-66
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    • 2013
  • Baculum elongatum has several peculiarities such as parthenogenesis, unique external features, changing body color, and dropping oviposition, which makes it a potential economically useful insect. Oviposition was performed by females without fertilization by the sperm of males. The oviposition period was $42.2{\pm}22.7$ days and the number of eggs per female was $109.5{\pm}70.5$ eggs. The hatch rate was 73.3% at $25^{\circ}C$ and 66.7% after low temperature treatment ($8^{\circ}C$ for 60 days). In nature, B. elongatum overwinters as an egg, but it can be assumed from the results that cold temperatures were not required for hatching. The hatch rate was 98.2% in the treatment using floral foam, fermented sawdust, and leaves. The developmental period was $100.9{\pm}4.2$ days for eggs, $55.3{\pm}4.6$ days for nymphs, and $49.7{\pm}16.0$ days for adults. The length of the eggs was $0.33{\pm}0.0$ cm and the lengths of the nymphs were clearly distinguishable according to the instar stage. Clover(Trifolium repens) was an excellent diet as it was similar to the host plant and could be used as an alternative diet. The rate of reaching adulthood for the insects was 66.7% on an artificial diet containing 25% acacia leaves. For sustainable mass rearing of nymphs or adults of B. elongatum, a natural diet could be used such as acacia (Robinia pseudoacacia), white oak (Quercus aliena), chestnut (Castanea crenata var. dulcis), and bush clover (Lespedeza bicolor), or an alternative diet such as clover or artificial diet.

Change of Glass Transition Temperature of PETG Containing Gas (가스를 포함하는 고분자 재료(PETG)의 유리전이온도 변화)

  • Cha, Seong-Un;Yun, Jae-Dong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.4 s.175
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    • pp.824-829
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    • 2000
  • The industries use polymer materials for many purposes because they have many merits. But these materials' costs take up too much proportion in overall cost of products that use these materials as their major material. So it is very economical for polymer industries to reduce these costs. Microcellular foaming process appeared in 1980's to solve this problem and it proved to be quite successful. This process uses inert gases such as CO2, N2. As these gases are dissolved into polymer matrices. many properties are changed. Glass transition temperature is one of these properties. DSC, DMA are devices that measures this temperature, but these are not sufficient to measure the temperature of polymer containing gas. In this paper, we devised a new tester that uses magnetism. We used this device to acquire data of the change of glass transition temperature and made Cha-Yoon model that can predict the change of glass transition temperature. Using this model, the change of this temperature can be estimated as a function of weight gain of gas. Cha-Yoon model proved that Chow's model is inappropriate to predict the change of glass transition temperature of polymer matrices containing gas.