• Title/Summary/Keyword: $CO_2$ evolution rate

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Co-sintering of M2/316L Layers for Fabrication of Graded Composite Structures

  • Firouzdor, V.;Simchi, A.;Kokabi, A.H.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.696-697
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    • 2006
  • This paper presents the densification and microstructure evolution of bilayer components made from 316L stainless steel and M2 High speed steel during co-sintering process. The sintering was carried out at temperatures ranging from $1230-1320^{\circ}C$ in a reducing atmosphere. The addition of boron to 316L was examined in order to increase the densification rate and improve the sintering compatibility between the two layers. It was shown that the mismatch strain bettwen the two layers induces biaxial stresses during sintering, influencing the densification rate. The effect of boron addition was also found to be positive as it improves the bonding between the two layers.

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Effects of Solvent Viscosity on Conformational Dynamics of Heme-pocket in Myoglobin and Hemoglobin

  • Kim, Seong-Heun;Lim, Man-Ho
    • Bulletin of the Korean Chemical Society
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    • v.27 no.11
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    • pp.1825-1831
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    • 2006
  • The influence of solvent viscosity on conformational dynamics of the heme-pocket, a small vacant site near the binding site of myoglobin (Mb) and hemoglobin (Hb), and playing a functionally important role by serving as a station in ligand binding and escape, was studied by probing time-resolved vibrational spectra of CO photodissociated from MbCO and HbCO in $D_2O$, 75 wt% glycerol/$D_2O$, and trehalose at 283 K. Two absorption bands ($B_1$ and $B_2$) of the sample in viscous solvents, arising from CO in the heme pocket, are very similar to those in $D_2O$. Two bands in Mb and Hb under all three solvents exhibit very similar nonexponential spectral evolution ($B_1$ band; blue shifting and broadening, $B_2$ band; narrowing with a negligible shifting), suggesting that in the present experimental time window of 100 ps, the extents of the spectral shift and narrowing is much influenced neither by the viscosity of solvent nor by the quaternary contact of Hb. Spectral evolution can be described by a biexponential function with a fast universal time constant of 0.52 ps and a slow time constant ranging from 13 to 32 ps. For both proteins in all three solvents majority of spectral evolution occurs with the fast universal time constant. The magnitude of the slow rate in the spectral shift of B1 band decreases with increasing solvent viscosity, indicating that it is influenced by global conformational change which is retarded in viscous solvent, thereby serve as a reporter of global conformational change of heme proteins after deligation.

Kinetics of L-Phenylalanine Production by Corynebacterium glutamicum (Corynebacterium glutamicum에 의한 L-Phenylalanine 생산의 동역학적 특성)

  • 김동일
    • KSBB Journal
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    • v.5 no.2
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    • pp.125-131
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    • 1990
  • Microbial production of L-phenylalanine using Corynebacterium glutamicum ATCC 21674, a tyrosine auxotroph resistant to aromatic amino acid analogues, has been studied and kinetic analysis was performed. Even though the strain was reported as a tyrosine auxotroph, it produced tyrosine and was able to grow on the minimal medium where no tyrosine was present. The average specific growth rate at the exponential growth phase was 0.087 hr-1. There was a dissociation of growth from the formation of the product. Linear correlation between biomass production and total CO2 production was obtained. The relationship between CO2 evolution rate and sugar consumption rate was also found to be linear.

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Production of Ethylene and Carbon Dioxide in Apples during CA Stroage (사과의 CA저장 중 에틸렌 및 이산화탄소 생성)

  • 정헌식;최종욱
    • Food Science and Preservation
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    • v.6 no.2
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    • pp.153-160
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    • 1999
  • This study was carried out to investigate the production of C$_2$H$_4$ and CO$_2$, and the change of flesh firmness and peel color in 'Fuji' apples during CA storage. ACC oxidase activity was more inhibited by the low O$_2$ concentration, and the low level of internal C$_2$H$_4$ in apples was maintained under the low O$_2$ conditions during 8 months storage. Especially, the level of internal C$_2$H$_4$ in apples was maintained below 1 ppm during storage under 1% O$_2$+1% CO$_2$ at 0$^{\circ}C$, and not much changed for 7 days in air at 20$^{\circ}C$ after storage. The influence of CO$_2$ on the C$_2$H$_4$ production was dependent on the O$_2$ concentration. Increasing of CO$_2$ concentration with 3% O$_2$ decreased the C$_2$H$_4$ Production during storage, but that with 1% O$_2$increased. Internal C$_2$H$_4$ concentration and the rate of CO$_2$ evolution in apples showed the close correlation. Internal CO$_2$ concentration of apples was positively related to the rate of CO$_2$ evolution and maintained the lower level in 1% O$_2$+1% CO$_2$ than the other conditions during storage but nu different in the increment after storage. The relationship between C$_2$H$_4$ and CO$_2$ production was exhibited in CA and the short-term air stored apples, but not in the long-term air stored apples. Loss of flesh firmness and green color in apples was more less in storage condition retarded effectively the production of C$_2$H$_4$ and CO$_2$.

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The Change of Quality of Fresh Shiitake (Lentinus edodes) in Storage under Controlled Atmosphere Conditions

  • Pujantoro, Lilik;Tohru, Shiga;Kenmoku, Akitsugu
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1993.10a
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    • pp.423-432
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    • 1993
  • The changes of quality of Fresh Shiitake (Lentinus edodes) was studied in this research work by investigating the effect of low $O_2$ content and high $CO_2$ content, well known as CA Treatment in storage, on the respiration rate and PPO Activity that was the main factor in Shiitake quality decay. CA Condition was conducted in 3 research periods that combined the $O_2$content(1%, 5% and 10%) and $CO_2$ content (5%, 10%, 15% and 20%) and air treatment as the control. The lower $O_2$content was the lower respiration rte that was showed in combination the lower respiration rate that was showed in combination of 20% $CO_2$ and 1% $O_2$ (the lowest), and the control air treatment was the highest . Very low $O_2$ content, conversly, did not show a satisfying result to the product.

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The Compost Inoculation Effect on the Cellulose Degradation in Bench-scale Composting of Food Waste and Paper Mixture (음식쓰레기의 실험실 규모 퇴비화에서 셀룰로스 분해에 대한 퇴비 식종효과)

  • Shin, Hang-Sik;Jeong, Yeon-Koo;Hwang, Eung-Ju
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.21-30
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    • 1998
  • The effects of compost inoculation on the degradation of cellulosic fraction in composting of food waste and paper mixture were investigated by bench-scale composting. With the increase of seed inoculation, the time to reach the peaks of temperature, $CO_2$ evolution rate, and ammonia evolution rate was reduced, indicating that seed compost had beneficial effects on the enhanced degradation of organic materials at the early stage of composting. However, the final conversion of organic matters and the loss of ammonia were not affected by the amount of seed compost inoculated. The increasing of seed inoculum also resulted in the higher level of cellulase activity at initial stages and rapid rise to the maximums, suggesting that initial supply of sufficient cellulolytic microorganisms might facilitate the evolution of cellulase activity. The cellulose was degraded substantially during the increasing phase of cellulase activity, while they showed similar values at the end of 20 days composting. As a result, the seed inoculation seemed to be effective to the enhanced evolution of cellulase activity and cellulose degradation at initial stage of composting. But it did not contribute to increase the final degradation of cellulose after the entire composting reaction of 20 days.

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MOLECULAR GAS PROPERTIES UNDER ICM PRESSURE IN THE CLUSTER ENVIRONMENT

  • LEE, BUMHYUN;CHUNG, AEREE
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.491-494
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    • 2015
  • We present 12CO (2-1) data for four spiral galaxies (NGC 4330, NGC 4402, NGC 4522, NGC 4569) in the Virgo cluster that are undergoing different ram pressure stages. The goal is to probe the detailed molecular gas properties under strong intra-cluster medium (ICM) pressure using high-resolution millimeter data taken with the Submillimeter Array (SMA). Combining this with Institut de RadioAstronomie $Millim{\acute{e}}trique$ (IRAM) data, we also study spatially resolved temperature and density distributions of the molecular gas. Comparing with multi-wavelength data (optical, $H\small{I}$, UV, $H{\alpha}$), we discuss how molecular gas properties and star formation activity change when a galaxy experiences $H\small{I}$ stripping. This study suggests that ICM pressure can modify the physical and chemical properties of the molecular gas significantly even if stripping does not take place. We discuss how this affects the star formation rate and galaxy evolution in the cluster environment.

Synthesis of RuO2/h-Co3O4 Electrocatalysts Derived from Hollow ZIF and Their Applications for Oxygen Evolution Reaction (중공 ZIF를 이용한 RuO2/h-Co3O4 촉매의 합성 및 산소 발생 반응으로의 활용)

  • Yoonmo Koo;Youngbin Lee;Kyungmin Im;Jinsoo Kim
    • Applied Chemistry for Engineering
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    • v.34 no.2
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    • pp.180-185
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    • 2023
  • To improve the efficiency of water electrolysis, it is essential to develop an oxygen evolution reaction (OER) electrocatalyst with high performance and long-term stability, accelerating the reaction rate of OER. In this study, a hollow metal-organic framework (MOF)-derived ruthenium-cobalt oxide catalyst was developed to synthesize an efficient OER electrocatalyst. As the synthesized catalyst increases the surface exposure of ruthenium, a low overpotential (386 mV) was observed at a current density of 10 mA/cm2 with a low Tafel slope. It is expected to be able to replace noble metal catalysts by showing higher mass activity and stability than commercial RuO2 catalysts.

Electrical Contact Characteristics of Ag-SnO2 Materials with Increased SnO2 Content

  • Chen, Pengyu;Liu, Wei;Wang, Yaping
    • Journal of Electrical Engineering and Technology
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    • v.12 no.6
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    • pp.2348-2352
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    • 2017
  • The electrical contact characteristics including temperature rise, contact resistance and arc erosion rate of the $Ag-SnO_2$ materials with increased $SnO_2$ content were investigated during the repeated make-and-break operations. The thickness of arcing melting layer reduces by half and the arc erosion rate decreases more than 70% under 10000 times operations at AC 10 A with the $SnO_2$ content increasing from 15 wt.% to 45 wt.%, on one hand, temperature rise and contact resistance increase obviously but could be reduced to the same order of conventional $Ag-SnO_2$ materials by increasing the contact force. The microstructure evolution and the effect of $SnO_2$ on the arc erosion, contact resistance were analyzed.

Light-Dependent Chilling Injury on the Photosynthetic Activities of Cucumber Cotyledons (저온처리한 오이의 자엽에서 광합성 활성의 광의존성 저해)

  • 김현식
    • Journal of Plant Biology
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    • v.36 no.2
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    • pp.133-140
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    • 1993
  • The photosynthetic activities in relation to oxygen evolution rates, quantum yield, CO2 uptake rates and room temperature chlorophyll fluorescence were investigated in cotyledons of cucumber seedlings exposed to low temperature (at 4$^{\circ}C$) for 24 h. Light-chilling caused more inhibition on light-saturated maximum oxygen evolution rates, quantum yield, and CO2 uptake rates than dark-chilling did in the cucumber plant. Light-chilling induced more marked increase in Fo and decrease in (Fv)m/Fm than dark-chilling did in the room temperature chlorophyll induction kinetics. The above results affected by chilling in the light are considered to be associated with the partial damage of the reaction center of PS II and the decreased photosynthetic activities. There occurred a large decrease in qQ with little change in qNP in the light-chilling plant. When light- and dark-chilled plants were recovered at room temperature for 24 h and their chlorophyll fluorescences were induced with light doubling technique, light-chilled plants showed more smaller magnitude and rate of fluorescence relaxation than dark-chilled plants. These suggest that light-chilling might cause some alterations in transthylakoid pH formation, and that photosynthetic apparatus of cucumber cotyledons is more susceptible to light-chilling. In the fast fluorescence induction kinetics, FR was decreased by 60% in the light-chilled plants with reference to $25^{\circ}C$ light-grown plants, while the dark-chilled plants showed a decreased rate of only 20% with reference to $25^{\circ}C$ dark-treated plants for 24 h, indicating that cucumber seedling is very sensitive to chilling stress. So, it is certain that chilling injury to the photosynthetic apparatus is strongly dependent on the presence of light in cucumber seedlings.

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