• 한국지하수토양환경학회지:지하수토양환경
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• 제24권3호
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• pp.24-35
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• 2019

It is known that ${\delta}^{13}C_{DIC}$ (carbon-13 isotope of dissolved inorganic carbonate (DIC) ions) of water increases when dissolved $CO_2$ degases. However, ${\delta}^{13}C_{DIC}$ could decrease when the pH of water is lower than 5.5 at the early stage of degassing. Laboratory experiments were performed to observe the changes of ${\delta}^{13}C_{DIC}$ as $CO_2$ degassed from three different artificial $CO_2$-rich waters (ACWs) in which the initial pH was 4.9, 5.4, and 6.4, respectively. The pH, alkalinity and ${\delta}^{13}C_{DIC}$ were measured until 240 hours after degassing began and those data were compared with kinetic isotope fractionation calculations. Furthermore, same experiment was conducted with the natural $CO_2$-rich water (pH 4.9) from Daepyeong, Sejong City. As a result of experiments, we could observe the decrease of DIC and increase of pH as the degassing progressed. ACW with an initial pH of 6.4, ${\delta}^{13}C_{DIC}$ kept increasing but, in cases where the initial pH was lower than 5.5, ${\delta}^{13}C_{DIC}$ decreased until 6 hours. After 6 hours ${\delta}^{13}C_{DIC}$ increased within all cases because the $CO_2$ degassing caused pH increase and subsequently the ratio of $HCO_3{^-}$ in solution. In the early stage of $CO_2$ degassing, the laboratory measurements were well matched with the calculations, but after about 48 hours, the experiment results were deviated from the calculations, probably due to the equilibrium interaction with the atmosphere and precipitation of carbonates. The result of this study may be not applicable to all natural environments because the pressure and $CO_2$ concentration in headspace of reaction vessels was not maintained constant as well as the temperature. Nevertheless, this study provides fundamental knowledge on the ${\delta}^{13}C_{DIC}$ evolution during $CO_2$ degassing, and therefore it can be utilized in the studies about carbonated water with low pH and the monitoring of geologic carbon sequestration.

• Carbon letters
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• 제5권2호
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• pp.55-61
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• 2004

Adsorption isotherms of p-nitrophenol from its aqueous solutions on two samples of activated carbon fibres and two samples of granulated activated carbons have been determined in the concentration range 40~800 mg/L (ppm). The surface of these carbons was modified by oxidation with nitric acid and oxygen gas, and by degassing the carbon surface under vacuum at temperatures of $400^{\circ}C$, $650^{\circ}C$ and $950^{\circ}C$. The oxidation of carbon enhances the amount of carbon-oxygen surface groups, while degassing decreases the amount of these surface groups. The adsorption of p-nitrophenol does not depend upon the surface area alone but appears to be influenced by the presence of oxygen groups on the carbon surface. The adsorption decreases on oxidation while the degassing of the carbon surface enhances the adsorption. The decrease in adsorption depends upon the strength of the oxidative treatment being much larger in case of the oxidation with nitric acid, while the decrease in adsorption on degassing depends upon the temperature of degassing. The results show that while the presence of acidic surface groups which are evolved as $CO_2$ on degassing suppress the adsorption of p-nitrophenol, the presence of non acidic surface groups which are evolved as CO on degassing tend to enhance the adsorption. Suitable mechanisms compatible with the results have been presented.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2648-2653
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• 2007

Recently, increasing demand on not only lighter but also extremely mobile battery make micro fuel cell device very attractive alternative. By reducing the size of fuel cell, surface tension becomes dominant factor with minor gravitational effect. Therefore, it is very difficult to detach the $CO_2$ bubble generating on a cathode side in ${\mu}DMFC$ (micro direct methanol fuel cell). The degassing of a $CO_2$ bubble has drawn quite attention especially for ${\mu}DMFC$ due to its considerable effect on overall machine performance. Our attention has been paid to the dynamic behavior of immiscible bubble attached to the one side of the wall on 2D rectangular channel subject to external shear flow. We use Level Contour Reconstruction Method (LCRM) which is simplified version of front tracking method to track the bubble interface motion. Effects of Reynolds number, Weber number, advancing/receding contact angle and property ratio on bubble detachment characteristic has been numerically identified.

• 한국포장학회지
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• 제20권2호
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• pp.35-39
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• 2014

최근 커피시장의 고속 성장과 더불어 커피 포장용 가스배출 밸브(Degassing valve)의 수요도 급격히 증가하고 있다. 가스배출 밸브 주요 제조사(Big maker)로 Goglio사(이탈리아), Bosch사(독일) 및 Wipf사(스위스)가 있는데, 이들이 전세계 가스배출 밸브 포장재 소비량의 80%이상을 공급하고 있다. 국내시장 역시 대부분 수입에 의존하고 있어 수입 대체와 국내 포장산업 활성화를 위해 기술적 차별화와 동시에 선진기업 수준의 품질 성능을 갖춘 가스배출 밸브의 개발이 필요하였다. 따라서, 본 연구에서는 링타입 고무막을 적용하여 중앙 개폐형 가스배출 밸브(SP 밸브)를 개발하였으며, 실험을 통해 열림압력 820~1200 Pa, 닫힘압력 10~50 Pa, 가스 유동율 1.2~1.6 L/min로 Goglio 밸브와 대등한 수준의 품질 성능을 확인할 수 있었다. 또한, 식품용 기구 및 용기 포장 공전에 따른 밸브의 식품용기 품질 적합성을 확인하였으며, 향후 커피 포장용 밸브의 국내외 시장 점유율 확대와 함께 국내 발효식품 포장에 적용함으로써 한식 세계화에 기여할 것으로 기대된다.

• 한국주조공학회지
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• 제20권6호
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• pp.407-418
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• 2000

The effect of various factors on the results of degassing of AC4C aluminum alloy melt by using rotary degasser were investigated. The difference between the effects of nitrogen gases of commercial pure and high purity grades on the degassing results was not significant. The optimum degassing condition was obtained. The effect of holding and degassing temperature was not significant, either. The result of degassing was deteriorated by the modification treatment of eutectic silicon, meanwhile improved by the grain refining. The effect of the latter was stronger than that of the former when the melt was treated simultaneously. The volume fractions of hydrogen porosity of the castings obtained from the molds with water moisture such as natural and green sand molds were much higher than those from the molds without that such as pep-set and $CO_2$ molds.

• 대한치과보철학회지
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• 제27권1호
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• pp.143-179
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• 1989

To observe the bonding behavior of palladium-based alloys to porcelain; 1. Pd-Co binary alloy with the higher cobalt content, 2. Pd-Co binary alloy with the lower cobalt content, 3. Pd-Ag-Sn ternary alloy, 4. Pd-Ag binary alloy, 5. Pd-Cu-Au ternary alloy and 6. Pd-Cu binary alloy were made as 6 groups of experimental alloys. Each group of alloy was divided into 4 sub-groups such as one sub-group that was not degassed and three sub-groups that degassed for 5 minutes, 10 minutes and 15 minutes. On each specimen, weight changes after degassing, morphological changes of oxide layer by changing the degassing time, compositional changes at metal-ceramic interface and bond strength of metal-ceramic measured with planar shear test were observed and compared. The results of the present study allow the following conclusions to be drawn: 1. The alloy showing the greatest bond strength was Pd-Cu alloy without gold and bond strength was decreased by alloying gold to them. 2. Although Pd-Co alloy showed the most prominent oxidation behavior, bond strength of them to porcelain was not greatly high by the formation of porosities at metal-ceramic interfaces. 3. Likewise tin, cobalt formed the peaks on line profiles at metal-ceramic interface, however copper did not exhibit such peaks on line profiles. 4. Mainly, oxide layer on Pd-Co alloy was composed with cobalt, and for Pd-Co alloy with higher cobalt content the rise of bond strength was not significant by increased degassing time. 5. On Pd-Ag alloy not containing tin, during degassing for 15 minutes silver content was increased at metal-ceramic interface. 6. As an oxidized element, tin formed the oxide layers that widen their area by increasing the degassing time, while cobalt and copper showed the morphological changes of particle or crystal on oxide layer.

• 한국포장학회지
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• 제22권2호
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• pp.33-37
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• 2016

주로 커피포장에 사용되던 포장용 One-way 가스배출밸브(아로마 밸브)가 최근 발효건강기능식품이나 전자렌지 조리용 즉석식품 포장 등 다양한 영역으로 적용이 확대되고 있다. 포장 식품의 효과적인 신선도 유지와 보존성 향상을 위해서는 대상 식품에 따른 최적의 가스배출 압력을 유지하는 것이 중요하며, 이를 위해 다양한 개방압력(Open Pressure)을 가진 밸브를 개발할 필요가 있다. 본 연구에서는 국내에서 개발된 링타입 고무막을 이용한 식품 포장용 가스배출 밸브(Degassing Valve)에 대하여 오일의 표면장력, 고무막의 재질특성 및 구조 역학적 특성을 분석하여 개방압력 예측이 가능하도록 수학적 분석 모델을 개발하였다. 직관적으로 보면 오일의 점도가 밸브의 개방압력에 영향을 미칠 것으로 예상되지만, 이론상으로 점도는 유체 내부의 요인에 의한 특성이고, 표면장력은 서로 다른 상태의 계면에서 발생되는 특성이므로 점도와 표면장력은 서로 무관하다. 이에 대해 본 연구의 실험을 통해 오일의 점도가 표면장력과는 무관하고 결과적으로 밸브의 개방압력과도 무관함을 확인할 수 있었으며, 수학적 모델에 의한 이론값이 재료의 실험값과 유사한 경향의 결과를 확인함으로써 제안한 수학적 모델의 유효성을 확인할 수 있었다. 따라서, 이 모델을 통해 포장용 가스 배출 밸브의 압력 설계 및 품질 신뢰성 확보를 위한 유용한 자료로 활용될 수 있을 것으로 기대된다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제29권1호
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• pp.1-9
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• 2024

As part of monitoring technology aimed at verifying the stability of CO₂ geologic storage and mitigating concerns about leakage, a method for measuring the pH and alkalinity of high-pressure fluid samples was established to obtain practical technology. pH measurement for high-pressure samples utilized a high-pressure pH electrode, and alkalinity was measured using the Gran titration method for samples collected with a piston cylinder sampler (PCS). Experimental samples, referencing CO₂-rich water and CO₂ geologic storage studies, were prepared in the laboratory. The PCS controls the piston, preventing CO₂ degassing and maintaining fluid pressure, allowing mixing with KOH to fix dissolved CO₂. Results showed a 6.1% average error in high-pressure pH measurement. PCS use for sample collection maintained pressure, preventing CO₂ degassing. However, PCS-collected sample alkalinity measurements had larger errors than non-PCS measurements, limiting PCS practicality in monitoring field settings. Nevertheless, PCS could find utility in preprocessing for carbon isotope analysis and other applications. This research not only contributes to the field of CCS monitoring but also suggests potential applications in studies related to natural analogs of CCS, CO₂-rock interaction experiments, core flooding experiments, and beyond.

• 대한약학회:학술대회논문집
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• 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.1
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• pp.283.2-283.2
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• 2003

This study established a highly sensitive novel quantification method for detecting felodipine in human plasma using LC-MS/MS. The mobile phase used after degassing was composed of 1 mM ammonium acetate and acetonitrile (20:80, pH 6.0), with flow rate of 200 uL/min. One mL plasma were pipetted into glass tubes and spiked with 0.1 mL of internal standard solution. (omitted)

• 한국지하수토양환경학회지:지하수토양환경
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• 제14권3호
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• pp.1-13
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• 2009

탄산수를 대상으로 알칼리도 및 총 탄소 측정 방법의 타당성을 평가하기 위하여 산중화 적정법, 역적정법, 침전법, NDIR-TC 측정법 등 다양한 측정방법을 적용하였다. 인공적으로 제조한 탄산수(ACW(Artificial $CO_2$-rich Water): pH = 6.3, alkalinity = 68.8 meq/L, $HCO_3^-$ = 2,235 mg/L)의 알칼리도 및 총 탄소를 측정한 결과, 탄산수 제조와 동시에 측정된 시료에서는 상기한 모든 측정방법에서 비교적 정확한 측정값을 얻어내었다. 이때 퍼센트 오차는 0~12% 수준이었으며, 반복측정 분산분석(repeated measure ANOVA)의 사후 분석 결과 각 측정 방법간 차이는 95% 신뢰수준에서 없는 것으로 판정되었다. 또한 이때 정밀도(분산계수)도 4% 이내로 재현성이 높은 측정 방법이라고 할 수 있다. 탄산수와 같이 $CO_2$가 탈기(脫氣: degassing)되는 경우 각 측정 방법의 정도관리를 위하여 24시간, 48시간 동안 $CO_2$를 탈기시킨 후 각 측정 방법을 적용하였다. 그 결과 산중화 적정법과 NDIR-TC 방법으로 측정된 알칼리도는 $CO_2$의 탈기에 상관없이 일정한 값을 유지하고 있었다. 이는 알칼리도의 보존성에 기인한 결과로 해석된다. 반면, 역적정법과 침전법으로부터 구한 알칼리도는 증가하는 것으로 나타났다. 한편 총 탄소 함량은 꾸준히 감소하여 48시간후에는 최대 약 50%의 $CO_2$가 탈기된 것으로 평가되었다. 역적정법과 침전법으로부터 구한 알칼리도가 높아진 이유는 총 탄소 함량이 다른 방법에 비하여 높게 측정되었고, $CO_2$ 탈기를 모델링 한 결과, 측정된 총 탄소 함량에 평형인 pH보다 측정된 pH가 높기 때문이다. 이는 ACW에 잔류한 $CO_2$ 기포의 영향으로 생각된다. $CO_2$ 탈기에 의해 발생한 $CO_2$ 기포는 pH를 낮추지 못하고 알칼리도에 영향을 주지는 않기 때문에 산중화 적정법과 NDIR-TC 측정에서는 분석되지 않지만 역적정과 침전법을 적용하여 총 탄소를 분석할 경우에는 측정값에 포함된다. 따라서 탄산수에서 알칼리도 및 총 탄소의 측정과 해석을 정확하게 하기 위해서는 역적정법이나 침전법을 이용하여 측정한 결과를 비교 검토하는 것이 필요하다. 이 연구의 결과는 탄산수 연구나 $CO_2$ 지중저장에 관련된 연구에 활용될 수 있다. 특히 $CO_2$ 지중저장 연구에 응용될 경우 탈기되지 않는 $CO_2$ 기포의 함량을 반영할 수 있기 때문에 심부 지중의 pH를 보정하거나 $CO_2$의 지중 거동과 $CO_2$ 저장 용량 평가에 응용될 것으로 기대된다. 이 연구를 기반으로 고온 고압 환경에서 직접 총 탄소를 정확하고 편리하게 측정하기 위한 방법을 개발할 예정이다.