• Journal of Environmental Health Sciences
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• v.24 no.2
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• pp.134-144
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• 1998

A comprehensive air quality monitoring was carried out to investigate the criteria concentration of air pollutant in indoor of subway stations of Seoul City. The samples were collected twice per year (the first and the second half of the year) at each sampling point from February to September in 1997. Sampling point of subway stations was ticket office and platform. The measurement of indoor air pollutants such as sulfur dioxide(SO$_2$), nitrogen dioxide(NO$_2$), carbon monoxide(CO), carbon dioxide(CO$_2$), total suspended particulate(TSP) was performed to determine the indoor air quality. Heavy metals(Pb, Cd, Cu, Cr, As, Hg) were also measured together with those air pollutants. The annual average concentration of CO$_2$ and TSP in subway stations were relatively high while those of heavy metals were within 10% of environmental recommended standard concentration in all stations. As results of regression analysis between line and line of air factors, the concentrations of CO, CO$_2$, TSP, Pb, Cd, Cr and Cu were highly correlated, but those of $SO_2, NO_2$ and Hg were not correlated. As results of regression analysis between ticket office and platform, the concentrations of heavy metals such as Cr and Cu were highly correlated. Results of oneway analysis of variance between the first and the second half of the year air factors also indicated that CO, CO$_2$, Cd, Cu, Hg were significant($\alpha$=0.01), respectively. The average contration of total suspended particulate(TSP) in subway line No. 1 was shown high concentration(200 $\mu g/m^3\cdot$ day) level.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.3
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• pp.379-387
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• 2008

The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to evaluate the corrosion characteristics of metal pipes, such as galvanized iron, copper, stainless steel, and carbon steel. When the pH in sand filtered and ozone+GAC treated water was increased with lime and $CO_2$ from 7.5 to 8.0, the concentration of residual chlorine decreased at higher pH and longer reaction time; the concentration of trihalomethane increased. The corrosion rate of coupons with corrosion control using lime and carbon dioxide was showed much smaller than those without corrosion control using pilot-scale simulated distribution system. The galvanized iron was corroded much faster than carbon steel, copper, and stainless steel. Especially, copper and stainless steel coupons were hardly corroded. The galvanized iron and carbon steel coupons with corrosion control were produced the corrosion products less than those without corrosion control by the results of environmental scanning electron microscope(ESEM) and energy dispersive x-ray spectroscopy(EDS) analyses. The galvanized iron coupon with pH and alkalinity adjustment by lime and carbon dioxide was detected about 30 percent of zinc, when the carbon steel was detected about 30 percent of calcium by calcium carbonate products formation. For the results of X-ray diffraction(XRD) analyses, the goethite(${\alpha}$-FeOOH) was identified as primary corrosion product of galvanized iron without corrosion control, while the Zinc oxide(ZnO) was found on corrosion products of galvanized iron coupon with corrosion control as the results of EDS analyses. However, the carbon steel corrosion products regardless of corrosion control were composed predominantly of maghemite(${\gamma}-Fe_2O_3$) and hematite(${\alpha}-Fe_2O_3$).

• International Journal of Railway
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• v.6 no.3
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• pp.90-94
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• 2013

Cement or lime is generally used to improve the strength of soil. However, bacteria were utilized to produce cementation of loose soils in this study. The microo rganism called Bacillus, and $CaCl_2$ was introduced into loose sand and soft silt and $CaCO_3$ in the voids of soil particles were produced, leading to cementation of soil particles. In this study, loose sand and soft silt typically encountered in Korea were bio-treated with 3 types of bacteria concentration. The cementation (or calcite precipitation) in the soil particles induced by the high concentration bacteria treatment was investigated at 7 days after curing. Based on the results of Scanning Electron Microscope (SEM) tests and EDX analyses, high concentration bacteria treatment for loose sand was observed to produce noticeable amount of $CaCO_3$, implying a significant cementation of soil particles. It was observed that higher calcium carbonate depositions were observed in poorly graded distribution as compared to well graded distribution. In addition, effectiveness of biogrouting has also been found to be feasible by bio-treatment without any cementing agent.

• Spatial Information Research
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• v.21 no.5
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• pp.15-22
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• 2013

The purpose of this work is to investigate correlation between $CO_2$ concentration and NDVI (Normalized Difference Vegetation Index) in North East Asia. Geographically weighted regression techniques were used to evaluate the spatial relationships between GOSAT (Greenhouse Observing SATellite) $CO_2$ measurement and MODIS (Moderate Resolution Imaging Spectroradiometer) vegetation index. The results reveals that $CO_2$ concentration to be negatively associated with NDVI. The analysis of Global Morans' I index and Anselin Local Morasn's I showed spatial autocorrelation between the overall spatial pattern of $CO_2$ and NDVI. Ultimately, there were clustered patterns in both data sets. The results show that carbon dioxide concentration shows non-random distribution patterns in relation to NDVI clusters, which proves that intense development activities such as deforestation are influencing carbon dioxide emission across the area of analysis. However, as the concentration of carbon dioxide varies depending on a variety of factors such as artificial sources, plant respiration, and the absorption and discharge of the ocean, follow-up studies are required to evaluate the correlations among more related variables.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.3
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• pp.282-290
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• 2013

A primary air pollutant as an indicator of air quality released from incomplete combustion is Carbon monoxide. A study of the distributions of CO concentration with no heat source in a tunnel model closed at left end side is simulated with a commercial CFD code. The tunnel model is used to investigate the CO concentration distributions at three Reynolds numbers of 990, 1970, and 3290. which are computed by the inlet velocities of 0.3, 0.6 and 1.0 m/s. The CFD predictive approaches can be useful for a better design to analyze the distributions of CO concentrations. In the case of the tunnel model closed at left end side alone, the concentration changes of x/H=-5 and -2.5 have the similar laminar characteristics like the case of the tunnel model closed at both end sides expecially at low values of Reynolds number. Irregular average CO concentration variations at Re=1790 are considered that the transition from laminar to turbulent flow occurs even in three different tunnel models.

• Journal of the Korean Magnetics Society
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• v.16 no.1
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• pp.1-5
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• 2006

The crystallographic properties and cation distribution of oxyspinels ferrite $Co_xFe_{1-x}O_4$ thin films have been explored by X-ray diffraction, vibrating sample magnetometer (VSM), and conversion electron $M\"{o}ssbauer$ spectroscopy (CEMS). Thin films are prepared by sol-gel method. Normal spinel structure is transformed to inverse spinel structure with increasing Co concentration CEMS results indicate that most of $Fe^{3+}$ ions are substituted to $Co^{3+}$ions. Accordingly $Co^{2+}$ ions on octahedral site migrate to tetrahedral site. Magnetic moment is decreased with increasing Co concentration, which means high spin $Fe^{3+}$ ions are replaced by low spin $Co^{3+}$.

• Journal of Soil and Groundwater Environment
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• v.22 no.5
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• pp.30-39
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• 2017

In this study, the predictive toxicity of barley Hordeum vulgare was estimated using a modified terrestrial biotic ligand model (TBLM) to account for the toxic effects of $CuOH^+$ and $CuCO_3(aq)$ generated at pH 7 or higher, and this was compared to that from the original TBLM. At pH values higher than 7, the difference in $EA_{50}\{Cu^{2+}\}$ (half maximal effective activity of $Cu^{2+}$) between the two models increased with increasing pH. As Mg concentration increased from 8.24 to 148 mg/L in the pH range of 5.5 to 8.5, the difference in $EA_{50}\{Cu^{2+}\}$ increased, and it reached its maximum at pH 8. The difference in $EC_{50}[Cu]_T$ (half maximal effective concentration of Cu) between the two models increased as dissolved organic carbon (DOC) concentration increased when pH was above 7. Thus, for soils with alkaline pH, the toxic effect of $CuOH^+$ and $CuCO_3(aq)$ are greater at higher salt and DOC concentrations. The acceptable Cu concentration in soil porewater can be estimated by the modified TBLM through deterministic method at pH levels higher than 7, while combination of TBLM and species sensitivity distribution through the probabilistic method could be utilized at pH levels lower than 7.

• Journal of Environmental Science International
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• v.14 no.11
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• pp.1035-1047
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• 2005

By using hourly $NO_2$ concentration data$(1998\~2000)$ at the Busan Metropolitan City air qualify monitoring sites, characteristics of daily mean value of $NO_2$ concentration was discussed in space and time. The correlation between $NO_2$ concentration and other relating air pollutants was analyzed by using SAS program and meteorological parameters as well. After choosing representative 4 areas, this study used hourly concentration data$(1998\~2000)$ from air quality monitoring sites on $NO_2,\;NO,\;O_3,\;CO,\;SO_2\;and\;PM_{10}$. Typical metropolitan characteristics of two peaks in a day was shown in the variation of $NO_2$ concentration of Busan city.

• Journal of Korean Society for Geospatial Information Science
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• v.21 no.2
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• pp.85-92
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• 2013

This study determined the spatial distribution characteristics of carbon dioxide in Northeast Asia, connecting land coverage and vegetation index that have influence on concentration and distribution of carbon dioxide measured by GOSAT with GIS spatial analysis method. The results visibly showed that the spatial distribution of carbon dioxide had different patterns in dependent on the present status of land use in its surrounding area. Such high concentration of carbon dioxide was formed in developed sites like cities while forest areas showed low concentration of it. We also found that there were relatively high negative(-) correlations between carbon dioxide and vegetation, in statistically significant level. It is expected to be used as a basic data for establishing measures to reduce greenhouse gas in the future.

• Proceeding of Spring/Autumn Annual Conference of KHA
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• 2006.11a
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• pp.316-321
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• 2006

Multiplex use facility emphasized the importance of indoor air environment because many people using that place. People using parking lot of multiplex use facility in little time, but a pollutant of in indoor air menacing user health. This study measure and analyze the CO, $CO_2$ for better air quality of an indoor parking lot in the multiplex user facility. As a result, two-way opened above ground parking lot is higher numerical value of CO, $CO_2$ than an underground parking lot. And a parking lot of square form is higher numerical value of $CO_2$ than a parking lot of rectangle form.