• 공업화학
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• 제30권3호
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• pp.324-330
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• 2019

Petal-like nickel cobaltite ($NiCo_2O_4$)/reduced graphene oxide (rGO) composites with different $rGO-to-NiCo_2O_4$ weight ratios were synthesized using a simple hydrothermal method and subsequent thermal treatment. In the $NiCo_2O_4/rGO$ composite, the $NiCo_2O_4$ 3-dimensional nanomaterials contributed to the improvement of electrochemical properties of the final composite material by preventing the restacking of the rGO sheet and securing ion movement passages. The composite structure was examined by field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and Fourier-transform infrared (FT-IR) spectroscopy. The FE-SEM and TEM images showed that petal-like $NiCo_2O_4$ was supported on the rGO surface. Cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) were used for the electrochemical analysis of composites. Among the prepared composites, $0.075g\;rGO/NiCo_2O_4$ composite showed the highest specific capacitance of $1,755Fg^{-1}$ at a current density of $2Ag^{-1}$. The cycle performance and rate capability of the composite material were higher than those of using the single $NiCo_2O_4$ material. These nano-structured composites could be regarded as valuable electrode materials for supercapacitors that require superior performance.

• Design & Manufacturing
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• 제17권3호
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• pp.61-66
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• 2023

In this study, we developed a simulation methodology for a technology that rapidly cools molds by directly spraying them with CO₂ in its liquefied gaseous state. Initially, a simulation verification process was conducted using ANSYS Fluent's heat transfer analysis based on temperature values measured in prior research experiments, ensuring a comparable temperature could be calculated. Subsequently, the validated analysis method was employed to evaluate design factors that exert the most significant influence on cooling. An evaluation was conducted based on three factors: part thickness, mold thickness, and the melting temperature of material. Using a full factorial design approach, a total of 27 analyses were completed and subsequently calculated through analysis of means. The impact assessment was carried out based on the temperature values at the product's core. The results indicated that the thickness of the mold had the highest influence, while the melting temperature of material had the least.

• Korean Chemical Engineering Research
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• 제49권2호
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• pp.244-249
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• 2011

연소 후 $CO_{2}$ 포집기술이 적용된 500 MWe 석탄화력발전소의 경제성평가를 수행하고 $CO_{2}$ 저감비용(Cost of $CO_{2}$ avoided)을 산출하였다. 본 연구에서 고려된 $CO_{2}$ 포집기술은 이미 상업적으로 적용이 가능하고, 기존의 화력발전에 적용이 용이한 화학 흡수법을 기초로 하였으며 투자비용 산출을 위해 IEA Greenhouse Gas R&D Programme에서 제시하는 데이터를 활용하였다. 또한 $CO_{2}$ 포집공정 중 가장 많은 발전효율 저하를 가져오는 재열기(리보일러)에 투입되는 열에너지(재생에너지)를 대상으로 민감도분석을 수행하고 각각의 경우에서의 $CO_{2}$ 저감비용을 산출하였다. 분석결과 $CO_{2}$ 포집공정에 적용될 흡수제로 MEA(모노에탄올아민)가 사용되고 재생탑에서 필요한 재생에너지가 3.31 GJ/ton$CO_{2}$ 인 경우 발전효율은 $CO_{2}$ 포집설비 설치 전의 41.0에서 31.6%로 9.4% 감소하고 이때의 $CO_{2}$ 저감비용은 43.3 $/ton$CO_{2}$ 로 산출되었다. 그러나, 흡수제 재생에너지를 변수로 한 민감도분석에서 재생에너지가 2.0 GJ/ton$CO_{2}$로 낮아질 경우 $CO_{2}$ 저감비용은 36.7 $/ton$CO_{2}$까지 낮아질 것으로 분석되었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.156-156
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• 2008

Single crystal of $In_2S_3$ and $In_2S_3:Co^{2+}$ were grown successfully with a good quality by the CTR(Chemical Transport Reaction)method. XRD analysis showed that the grown In2S3 and $In_2S_3:Co^{2+}$ single crystals were cubic structure. The optical absorption spectra of $In_2S_3:Co^{2+}$ single crystal showed impurity absorption peaks due to cobalt impurity. These impurity absorption pesks were assigned to the ligand transition between the split energy levels of $Co^{2+}$ ions with $T_d$ symmetry of these semiconductor host lattice.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.242-245
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• 2008

In the power generation industry, various efforts are needed to cope with tightening regulation on carbon dioxide emission. Integrated gasification combined cycle (IGCC) is a relatively environment friendly power generation method using coal. Moreover, pre-combustion $CO_2$ removal is possible in the IGCC system. Therefore, much effort is being made to develop advanced IGCC systems. However, removal of $CO_2$ may affect the system performance and operation through reduction of fuel gas supplied to the gas turbine. This study predicts system performance change due to $CO_2$ capture by pre-combustion process from the normal IGCC performance without $CO_2$ capture and presents results of design parametric analysis.

• 한국세라믹학회지
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• 제42권9호
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• pp.602-606
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• 2005

[ $LiCoO_{2}$ ] is the most common cathode electrode materials in Lithium-ion batteries. $LiCo_{0.97}Mg_{0.03}O_2$ was synthesized by the solid-state reaction method. We investigated crystal structures, electrical conductivities and electrochemical properties. The crystal structure of $LiCo_{0.97}Mg_{0.03}O_2$ was analyzed by X-ray powder diffraction and Rietveld refinement. The material showed a single phase of a layered structure with the space group R-3m. The lattice parameter(a, c) of $LiCo_{0.97}Mg_{0.03}O_2$ was larger than that of $LiCoO_2$. The electrical conductivity of sintered samples was measured by the Van der Pauw method. The electrical conductivities of $LiCoO_2$ and $LiCo_{0.97}Mg_{0.03}O_2$ were $2.11{\times}10^{-4}\;S/cm$ and $2.41{\times}10^{-1}\;S/cm$ at room temperature, respectively. On the basis of the Hall effect analysis, the increase in electrical conductivities of $LiCo_{0.97}Mg_{0.03}O_2$ is believed due to the increased carrier concentrations, while the carrier mobility was almost invariant. The electrochemical performance was investigated by coin cell test. $LiCo_{0.97}Mg_{0.03}O_2$ showed improved cycling performance as compared with $LiCoO_2$.

• 대한조선학회 특별논문집
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• 대한조선학회 2005년도 특별논문집
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• pp.38-43
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• 2005

The present study is concerned with the numerical analysis of the sloshing impact pressure of the Liquefied Natural Gas (LNG) carriers in rough sea. The reliable predictions of the both random tank motions in irregular waves and violent fluid flow in the LNG tanks are required for practical sloshing analysis procedure of LNG carriers. The three-dimensional numerical model adopting SOLA-VOF scheme is used to predict violent free surface movements of LNG tank in irregular motions. For accurate input motion of tank, a three-dimensional panel method program called SSMP (Samsung Ship Motion Program) is applied for seakeeping analysis. Comparison studies of sloshing analysis are carried out for No.2 tank of 138K and 205K LNG carriers to verify the safety of the LNG containment system of the proposed 205K large LNG carrier.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 추계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.37-39
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• 2004

This study investigates the characteristic analysis of Line-start Permanent Magnet Synchronous Motor considering PWM Inverter. The effects of the PWM inverter on machine characteristic are analyzed by using direct co-simulation of Matlab Simulink and Flux2D. Validity of analysis method is confirmed by the analysis result of Sin-wave power Model.

• 에너지공학
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• 제13권3호
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• pp.219-227
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• 2004

본 연구에서는 기후변화에 따른 온실가스 감축을 위해 추진되고 있는 이산화탄소 저감 및 처리기술개발의 성과제고를 위해 개발기술들을 대상으로 기술개발 동향 및 향후 발생될 여러 가지 영향요인(impact factor)을 발굴하여 분석하였다. 이를 위해 평점법(Scoring Models Method, SMM)과 분석적계층과정(Analytic Hierarchy Process, AHP)을 이용하여 $CO_2$저감 및 처리기술에 대한 분석을 수행하였으며 평가요인별 중요도의 계량적 제시와 함께 각각의 기술들에 대한 평가요인별 우선순위를 제시하였다.

• International Journal of Fluid Machinery and Systems
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• 제2권3호
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• pp.197-205
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• 2009

Since large-scale commercial wind turbine generator systems such as MW-class wind turbines are becoming widely operated, the vibration and distortion of the blade are becoming larger and larger. Therefore the soft structure design instead of the solid-design is one of the important concepts to reduce the structural load and the cost of the wind turbine rotors. The objectives of the study are development of the fluid-structure coupled analysis code and evaluation of soft rotor-blade design to reduce the unsteady structural blade load. In this paper, fluid-structure coupled analysis for the HAWT rotor blade is performed by free wake panel method coupled with hinge-spring blade model for the flapwise blade motion. In the model, the continuous deflection of the rotor blade is represented by flapping angle of the hinge with one degree of freedom. The calculation results are evaluated by comparison with the database of the NREL unsteady aerodynamic experiment. In the analysis the unsteady flapwise moments in yawed inflow conditions are compared for the blades with different flapwise eigen frequencies.