• Journal of Environmental Science International
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• v.20 no.12
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• pp.1617-1624
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• 2011

Caustic (NaOH) solution is used to remove $H_2S$ from hydrocarbon streams in petroleum refining industry, gradually being, so called, spent sulfidic caustic (SSC) which has high levels of $H_2S$ and alkalinity. Thus, SSC can be used as an electron donor and a buffering agent for autotrophic denitrification. As SSC, however, contains some non-biodegradable organics, air stripping was conducted to remove the non-biodegradable organics. As a result, over 93 % of the non-biodegradable organics was removed within 30 min of aeration. Then, $Na_2S_2O_3{\cdot}5H_2O$, methanol and organic matters, which are produced from a biodiesel production plant, were added to reform the air-stripped SSC and their products being referred to new sulfidic caustics (NSCs) I, II and III, respectively. Thereafter, to investigate the effect of these products on the removal of COD and TN, these products were injected to a biological nitrogen removal (BNR) process, resulting in additional 44 % TN removal without noticeable increase in the effluent COD level. Therefore, it can be said that the BNR process is a promising option to treat NSC as demonstrated in this study whose results can be useful for developing resource recovery technologies.

• Journal of Forest and Environmental Science
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• v.30 no.1
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• pp.1-14
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• 2014

Timber harvest in natural forests and its implications on carbon sequestration were investigated in the Southwestern Nigeria. Data on timber harvest from forest estates for a 3-year period were collected from the official record of States' Forestry Department. The data registered the species, volume and number of timbers exploited during the study period. The data were analyzed accordingly for rate of timber harvest and carbon value of the exploited timbers using existing biomass functions. Values were compared for significant differences among states using one way analysis of variance. The results showed that the most exploited logs, in terms of volume and number of trees, have the highest amount of carbon removal. There was a variation in type of timber species being exploited from each state. The total number of harvested trees from Oyo, Ondo, Ogun, Ekiti and Osun were estimated at 100,205; 111,789; 753; 15,884 and 18,153 respectively. Total quantity of carbon removed for the 3-year period stood at 2.3 million metric tons, and this translated to 8.4 million metric tons of $CO_2$. The annual carbon and $CO_2$ removal therefore were estimated at 760,120.73 tons and 2.8 million tons/ year respectively. There were significant differences (p<0.05) in the amount of $CO_2$ removed from the five states. Based on our result, we inferred that there is increasing pressure on economic tree species and it is plausible that they are becoming scarce from the forests in Southwestern Nigeria.. If the present rate of log removal is not controlled, forests could become carbon source rather than carbon sink and the on biological conservation, wood availability and climate change may turn out grave. For the forest to perform its environmental role as carbon sink, urgent conservation measures and logging policies are needed to be put in place.

• Applied Chemistry for Engineering
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• v.22 no.3
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• pp.332-335
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• 2011

As our interests in eco-friendly materials have been significantly increased, the utilization of porous zeolite concrete that has structural functionality and permeability has been increased. In this paper, the mixture of porous concrete and zeolite, which can be used as multirole boulders, was investigated for the suitability of an environment-friendly product by evaluating of the water purification ability. The contamination removal rates of BOD, TOC, T-N, and T-P in stagnant water tank were 70.6, 67.0, 57.7, and 50.6%, respectively. Also for the non-point source pollution with the inflow and the outflow, the removal rates of Zn, Pb, BOD, and COD were 99.9, 90.0, 69.2, and 33.5%, respectively. The performance of the heavy metal contamination removal for the porous zeolite showed better than that of stagnant system. Therefore, it is expected that the installation of the porous zeolite concrete can play a role as an eco-friendly products by its high contamination removal.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.533-536
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• 2009

The gasification technology is a very flexible and versatile technology to produce a wide variety products such as electricity, steam, hydrogen, Fisher-Tropsch(FT) diesels, Dimethyl Ether(DME), methanol and SNG(Synthetic Natural Gas) with near-zero pollutant emissions. Gasification converts coal and other low-grade feedstocks such as biomass, wastes, residual oil, petroleum coke, etc. to a very clean and usable syngas. Syngas is produced from gasifier including CO, $H_2$, $CO_2$, $N_2$, particulates and smaller quantities of $CH_4$, $NH_3$, $H_2S$, COS and etc. After removing pollutants, syngas can be variously used in energy and environment fields. The pilot-scale coal gasification system has been operated since 1994 at Ajou University in Suwon, Korea. The pilot-scale gasification facility consists of the coal gasifier, the hot gas filtering system, and the acid gas removal (AGR) system. The acid gas such as $H_2S$ and COS is removed in the AGR system before generating electricity by gas engine and producing chemicals like Di-methyl Ether(DME) in the catalytic reactor. The designed operation temperature and pressure of the $H_2S$ removal system are below $50^{\circ}C$ and 8 kg/$cm^2$. The iron chelate solution is used as an absorbent. $H_2S$ is removed below 0.1 ppm in the H2S removal system.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.9
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• pp.913-917
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• 2008

Since the difficulty of analysis at low concentration and the uncertainty of the removal mechanism for Nitrosodimethylamine (NDMA) have been reported, this study has detected extremely low concentration $^{14}$C-NDMA using the LSC(Liquid Scintillation Counter) and tested NDMA removal by Powdered Activated Carbon(PAC). The results showed the highest correlation over 99% when samples were measured with the mixture ratio of sample to scintillation liquid of 10 : 10 and at the detection time of 10 min. For $^{14}$C-NDMA removal by the PACs(S-A(Sigma-Aldrich co.) and Dj(Daejung co.)) raging from 50$\sim$10,000 mg/L, $^{14}$C-NDMA was removed over 90% by adsorption treatment. In addition, S-A showed twice greater adsorption capacity than that of Dj. However, the required PAC amount for $^{14}$C-NDMA removal was higher than that of other amine compounds.

• Journal of Environmental Science International
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• v.4 no.1
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• pp.41-52
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• 1995

The effects of reaction temperature, SO2 and CO2 concentration in an air gas stream, particle sizes of limestone on the reactivity and capacity of SO2 removal have been determined in a thermogravimetric analyser(TGA). The apparent reaction order of sulfation reaction of pre-calcined lime(CaO) with respect to SO2 is found to be close to unity. The apparent activation energies are found to be 17,000 kcal/kmol for sulfation of pre-calcined lime and 19,500 kcal/kmol for direct sulfation of limestone(CaCO3). The initial sulfation reaction rate of pre-calcined lime increases with increasing temperature, whereas the sulfur capture capacity exhibits a maximum value at 90$0^{\circ}C$. In direct sulfation of limestone, sulfation reactivity and sulfur capature capacity of sorbent increase with increasing temperature and decreasing CO2 concentration in a gas bulk stream. The main pare of pre-calcined lime is shifted to the larger pore sizes and pore volume decreases with increasing sulfation time and temperature. The surface area of lime decreases with increasing calcination temperature under an air atmosphere, whereas is yearly constant under a CO2(5, 10%) atmosphere in a gas stream.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.571-572
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• 2006

Tungsten CMP needs interconnect of semiconductor device ULSI chip and metal plug formation, CMP technology is essential indispensable method for local planarization. This Slurry development also for tungsten CMP is important, slurry of metal wiring material that is used present is depending real condition abroad. It is target that this research makes slurry of efficiency that overmatch slurry that is such than existing because focus and use colloidal silica by abrasive particle to internal production technology development. Compared selectivity of slurry that is developed with competitor slurry using 8" tungsten wafer and 8" oxide wafer in this experiment. And removal rate measures about density change of $H_2O_2$ and Fe particle. Also, corrosion potential and current density measure about Fe ion and Fe particle. As a result, selectivity find 83:1, and expressed similar removal rate and corrosion potential and current density value comparing with competitor slurry.

• Clean Technology
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• v.23 no.3
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• pp.237-247
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• 2017

In the dimethyl ether (DME) synthesis and separation process, over 8% by mole of $CO_2$ is fed to the DME synthesis reactor which lowers DME productivity. Therefore, this work focused on the removal of $CO_2$ using three kinds of processes with physical absorbents by comparing the utility consumption through computer simulation of each process. Among the processes selected for comparison are Rectisol$^{(R)}$ process using methanol, Purisol$^{(R)}$ process using n-methyl pyrrolidone (NMP), and SelexolTM process using dimethyl ethers of polyethylene glycol (DEPG) as a solvent. As a result of this study, it was concluded that Purisol$^{(R)}$ process consumes the least energy followed by SelexolTM process. Therefore, it is considered that Purisol$^{(R)}$ process is the most suitable method to absorb $CO_2$ contained in the feed of DME synthesis reactor.

• Korean Chemical Engineering Research
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• v.47 no.5
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• pp.646-650
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• 2009

Hydrocarbon gases generated from the gasification of waste could be converted into $CO_2$ and $H_2$ using reforming catalysts and then $CO_2$ was selectively adsorbed and removed to obtain pure hydrogen. To optimize adsorption efficiency for $CO_2$ removal, $Na_2CO_3$ was supported on nanoporous alumina and the efficiency was compared with commercial alumina(Degussa). Nanoporous adsorbents formed more uniform pores and larger surface area compared to adsorbents using commercial alumina. The increase of $Na_2CO_3$ loading improved adsorption of $CO_2$. Finally, the highest adsorption capacity per unit mass of $Na_2CO_3$ could be achieved when the loading of $Na_2CO_3$ reached up to 20wt%. When the content of $Na_2CO_3$ increased above 20 wt%, it aggregated on the surface, and the pore volume was decreased. Used adsorbents could be recycled by the thermal treatment.

• Journal of The Korean Society of Agricultural Engineers
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• v.56 no.6
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• pp.85-91
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• 2014

In this study, the water quality purification of new medias which were NPS media, hyugato, mineral stone, charcoal for applying soil media of Integrated Management Practices (IMPs) of Low Impact Development (LID) were evaluated. The influent concentrations of COD, T-N, and T-P were 117.8 mg/L, 17.1 mg/L, and 2.062 mg/L, respectively. The infiltration capacities of NPS media, hyugoto, mineral stone, charcoal, and gravel were $7.1{\times}10m/s$, $7.3{\times}10^{-5}m/s$, $7.9{\times}10^{-5}m/s$, $6.0{\times}10^{-5}m/s$, respectively. All media meet criteria of infiltration capacity as surface soil layer at IMPs which is over $1.0{\times}10^{-5}m/s$. Maximum removal rates of COD, T-N, and T-P occurred at Charcoal with 98 % of COD removal rate, NPS with 78 % of T-N removal rate, and hyugato with 75 % fo T-P removal rate, respectively. For more high removal efficiency of all water quality item, the mixed media which is 4.5(NPS media): 1(charcoal) : 4.5 (hyugato) as volume ratio was evaluated. The infiltration capacity of mixed media was $7.9{\times}10^{-5}m/s$ and met the criteria of infiltration as surface soil layer. The water quality removal efficiencies of mixed media were very high with showing 70 % for COD, 85 % for T-N, and 71 % for T-P. The mixed media could purify the water quality of surface runoff and was recommended to used at the LID site of ground water quality problem.