• Title/Summary/Keyword: $COP_c$

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Synthesis and Film Properties of Cross-linked Polysulfone with Imide Side Chain (이미드 곁가지로 가교되는 폴리설폰의 합성 및 필름 특성)

  • Lee Eun-Sang;Hong Sung-Kwon;Kim Yong-Seok;Lee Jae-Heung;Kim In-Sun;Won Jong-Chan
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.140-145
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    • 2006
  • The mort commonly available substrate material is glass in the display fibrication process. However, glass is not desirable due to its heaviness and fragility. Recently, plastics such polysulfone (PSF), polyethesulfone (PES), polycarbonate (PC), polyethylene terephthalate (PET) and cyclic olefin polymers (COP) have been investigated to replace glass as a substrate material for display fibrication. Plastic substrates are advantageous in that they are lightweight, huh impart resistance, flexibility, and ability for roll to roll manufacturing process. But many plastics have poor chemical resistance in organic solvent. The chemica resistance is also lequired because they are exposed to solvents for various chemical treatments din the manufacturing process. So, we have an interest in the chemical modification of PSF to improve chemical resistance. We introduced crosslinkable imide moieties using chloromethylation method for the modification of PSF which could be overcome above shortcomings for display substrate based on plastic film. We prepared the cross-linked polysulfone films which were represented chemical resistance in HeOH, THF, DMSO and NMP. The thermal properties were measured by TGA, DSC and TMA. As the results, we have confirmed to enhance of the thermal property. They had low coefficient of thermal expansion (CTE) which decreased to 15% and had increased $T_g\;from\;180^{\circ}C\;to\;252^{\circ}C$. Cross-linked polysulfone films with imide side-chain had good optical properties and chemical resistance so that they could be used as flexible display substrate.

The Analysis of heating performance of heat pump system for agricultural facility using underground air in Jeju area - Focused on the Jeju Area - (제주지역 지하공기를 이용한 농업시설용 히트펌프시스템의 난방 성능 분석 - 제주지역을 중심으로 -)

  • Kang, Youn-Ku;Lim, Tae-Sub
    • KIEAE Journal
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    • v.16 no.6
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    • pp.109-114
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    • 2016
  • Purpose: The underground air is the warm air discharged from the porous volcano bedrock 30-50m underground in Jeju, including excessive humidity. The temperature of the underground air is $15-20^{\circ}C$ throughout the year. In Jeju, the underground air was used for heating greenhouses by supplying into greenhouses directly. This heating method by supplying the underground air into greenhouses directly had several problems. The study was conducted to develop the heat pump system using underground air as heat source for resolving excessive humidity problem of the underground air, adopting the underground air as a farm supporting project by Ministry of Agriculture, Food and Rural Affairs(MAFRA) and saving heating cost for agricultural facilities. Method: 35kW scale(10 RT) heat pump system using underground air installed in a greenhouse of area $330m^2$ in Jeju-Special Self-Governing Province Agricultural Research & Extension Services, Seogwipo-si, Jeju. The inlet and outlet water temperature of the condenser, the evaporator and the thermal storage tank and the underground air temperature and the air temperature in the greenhouse were measured by T type thermocouples. The data were collected and saved in a data logger(MV200, Yokogawa, Japan). Flow rates of water flowing in the condenser, the evaporator and the thermal storage tank were measured by an ultrasonic flow meter(PT868, Panametrics, Norway). The total electric power that consumed by the system was measured by a wattmeter(CW240, Yokogawa, Japan). Heating COP, rejection heat of condenser, extraction heat of evaporator and heating cost were analyzed. Result: The underground air in Jeju was adopted as a farm supporting project by Ministry of Agriculture, Food and Rural Affairs(MAFRA) in 2010. From 2011, the heat pump systems using underground air as a heat source were installed in 12 farms(16.3ha) in Jeju.

A Simulation Study on the Annual Heating Performance of the Seawater-Source Screw Heat Pump (해수열원 스크류 히트펌프의 연간 난방운전 성능 모사)

  • Baik, Young-Jin;Kim, Min-Sung;Chang, Ki-Chang;Lee, Young-Soo;Kim, Hyeon-Ju
    • Journal of the Korean Solar Energy Society
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    • v.32 no.3
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    • pp.88-95
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    • 2012
  • In this study, in order to utilize the seawater as a heat source at Gangneung city near the East Sea in Korea, an annual heating performance of a screw heat pump was simulated. For a simulation, the maximum heating capacity of heat pump was assumed at 3.5 MW. An ambient temperature at Gangneung city was calculated from the TMY2 weather data, while the seawater temperature was calculated from the regression equation based on the measurement by the National Fisheries Research and Development Institute of Korea. The heating load was assumed linearly dependent on the ambient temperature, while the maximum heating load was assumed to appear when the ambient temperature is below $-2.4^{\circ}C$, which is the temperature of TAC 2.5% for heating at Gangneung city. A heat pump performance at full-load was calculated from the regression equation, which involves refrigerant's evaporating and condensing temperatures, based on a commercial screw compressor performance map. A heating supply temperature which determines refrigerant's condensing temperature was assumed linearly dependent on the heating load. A performance degradation due to the part-load operation of heat pump was also considered. Simulation results show that an annual heating coefficient of performance ($COP_H$) of a seawater-source screw heat pump is approximately 2.8 and that it is necessary to improve part-load performance to increase an annual performance of the heat pump.

A Simulation Study on the Annual Heating Performance of the Seawater-Source Screw Heat Pump (해수열원 스크류 히트펌프의 연간 난방운전 성능 시뮬레이션)

  • Baik, Young-Jin;Kim, Min-Sung;Chang, Ki-Chang;Kang, Byung-Chan;Ra, Ho-Sang;Kim, Hyeon-Ju
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.488-493
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    • 2012
  • In this study, in order to utilize the seawater as a heat source at Gangneung city near the East Sea in Korea, an annual heating performance of a screw heat pump was simulated. For a simulation, the maximum heating capacity of heat pump was assumed at 3.5 MW. An ambient temperature at Gangneung city was calculated from the TMY2 weather data, while the seawater temperature was calculated from the regression equation based on the measurement by the National Fisheries Research and Development Institute of Korea. The heating load was assumed linearly dependent on the ambient temperature, while the maximum heating load was assumed to appear when the ambient temperature is below $-2.4^{\circ}C$, which is the temperature of TAC 2.5% for heating at Gangneung city. A heat pump performance at full-load was calculated from the regression equation, which involves refrigerant's evaporating and condensing temperatures, based on a commercial screw compressor performance map. A heating supply temperature which determines refrigerant's condensing temperature was assumed linearly dependent on the heating load. A performance degradation due to the part-load operation of heat pump was also considered. Simulation results show that an annual heating coefficient of performance ($COP_H$) of a seawater-source screw heat pump is approximately 2.8 and that it is necessary to improve part-load performance to increase an annual performance of the heat pump.

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Sizing of Vertical Borehole Heat Exchangers using TRNOPT (TRNOPT를 이용한 수직 지중열교환기 길이 산정 방법에 관한 연구)

  • Park, Seung-Hoon;Lee, Hyun-Soo;Jang, Young-Sung;Kim, Eui-Jong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.10
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    • pp.402-407
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    • 2016
  • Ground-coupled heat pump systems have been widely used, as they are regarded as a renewable energy source and ensure a high annual efficiency. Among the system components, borehole heat exchangers (BHE) play an important role in decreasing the entering water temperature (EWT) to heat pumps in the cooling season, and consequently improve the COP. The optimal sizing of the BHEs is crucial for a successful project. Other than the existing sizing methods, a simulation-based design tool is more applicable for modern complex geothermal systems, and it may also be useful since design and engineering works operate on the same platform. A simulation-based sizing method is proposed in this study using the well-known Duct STorage (DST) model in Trnsys. TRNOPT, the Trnsys optimization tool, is used to search for an optimal value of the length of BHEs under given ground loads and ground properties. The result shows that a maximum EWT of BHEs during a design period (10 years) successfully approaches the design EWT while providing an optimal BHE length. Compared to the existing design tool, very similar lengths are calculated by both methods with a small error of 1.07%.

Performance of Heat Pump System Using Underground Air as Heat Source (지하공기를 이용하는 농업시설용 난방시스템)

  • Kang, Youn-Ku;Ryou, Young-Sun;Kim, Young-Hwa;Sung, Moon-Seok;Kim, Jong-Koo;Jang, Jae-Kyoung;Lee, Hyoung-Mo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.587-589
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    • 2009
  • The districts of underground geologic structure in Jeju island where underground air is distributed are lava cave, pyroclastic, open joint, and crushing zone. Such districts are identified to secure an enough airflow when air ventilation layer is to secure 25-35m in depth. In Jeju, Ground air is used for heating greenhouse and fertilizing natural $CO_2$ gas by suppling directly into greenhouse. But the heating method by suppling ground air into greenhouse directly bring about several problem. The occurrence of disease of the crops by high humidity is worried because the underground air which becomes discharge from underground air layer has over 90% relative humidity. The underground air is inadequate in heating for crops which need high temperature heating such as mangos, Hallbong and mandarin orange because the temperature of it is $15{\sim}18^{\circ}C$. Also There is worry where the ventilation loss becomes larger because the air pressure inside greenhouse is high by supplying underground air directly. In this study the heat pump system using underground air as heat source was developed and heating performance of the system was analysed. Heating COP of the system was 2.5~5.0 and rejecting heat into greenhouse and extracting heat from underground air were 40,000~27,000 kcal/h, 30,000~18,000 kcal/h respectively.

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Design of closed-loop nitrogen Joule-Thomson refrigeration cycle for 67 K with sub-atmospheric device

  • Lee, C.;Lee, J.;Jeong, S.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.1
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    • pp.45-50
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    • 2013
  • Closed-loop J-T (Joule-Thomson) refrigeration cycle is advantageous compared to common open loop $N_2$ decompression system in terms of nitrogen consumption. In this study, two closed-loop pure $N_2$ J-T refrigeration systems with sub-atmospheric device for cooling High Temperature Superconductor (HTS) power cable are investigated. J-T cooling systems include 2-stage compressor, 2-stage precooling cycle, J-T valve and a cold compressor or an auxiliary vacuum pump at the room temperature. The cold compressor and the vacuum pump are installed after the J-T valve to create sub-atmospheric condition. The temperature of 67 K is possible by lowering the pressure up to 24 kPa at the cold part. The optimized hydrocarbon mixed refrigerant (MR) J-T system is applied for precooling stage. The cold head of precooling MR J-T have the temperature from 120 K to 150 K. The various characteristics of cold compressor are invstigated and applied to design parameter of the cold compressor. The Carnot efficiency of cold compressor system is calculated as 16.7% and that of vacuum pump system as 16.4%. The efficiency difference between the cold compressor system and the vacuum pump system is due to difference of enthalpy change at cryogenic temperature, enthalpy change at room temperature and different work load at the pre-cooling cycle. The efficiency of neon-nitrogen MR J-T system is also presented for comparison with the sub-atmospheric devices. These systems have several pros and cons in comparison to typical MR J-T systems such as vacuum line maintainability, system's COP and etc. In this paper, the detailed design of the subcooled $N_2$ J-T systems are examined and some practical issues of the sub-atmospheric devices are discussed.

Type 2 Absorption Cycle to Transport Energy in the Long Distance for District Cooling Application (지역냉방 적용을 위한 LNG냉열 장거리 수송용 제 2종 흡수식 시스템)

  • Cho Young Kyong;Kim Jin-Kyeong;Oh Min Kyu;Kang Yong Tae
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.3
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    • pp.250-255
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    • 2005
  • The objective of this paper is to develop a new energy transport system for district cooling application by using type 2 absorption cycle. Cold energy from the LNG storage system is utilized as the cooling source of the condenser and the rectifier. The pressures of the system, UAs of the evaporator and the desorber, and the inlet temperatures of the refrigerant to each component are considered as the key parameters. The results show that UA of the evaporator is more dominant parameter on COP than that of the desorber and the optimum system pressure for the demand side is estimated as 525 kPa. For the present system, it is recommended that the refrigerant inlet temperature of the evaporator be lower than $4.3^{\circ}C$ for long-distance transportation. It is concluded that the cold energy from the LNG storage system can be effectively applied to the long-distance transportation system for district cooling application with the type 2 absorption cycle. The optimum operation conditions are also predicted from the parametric analysis.

Optimal design of binary current leads cooled by cryogenic refrigerator (극저온 냉동기로 냉각되는 이중전류도입선의 최적설계)

  • Song, S.J.;Chang, H.M.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.4
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    • pp.552-560
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    • 1997
  • Analysis is performed to determine the optimal lengths or cross-sectional areas of refrigerator-cooled current leads that can be applied to the conduction-cooled superconducting systems. The binary current lead is composed of the series combination of a normal metal at the upper(warm) part and a high $T_c$ superconductor(HTS) at the lower(cold) part. The heat conduction toward the cold end of HTS part constitutes a major refrigeration load. In addition, the joint between the parts should be cooled by a refrigerator in order to reduce the load at the low end and maintain the HTS part in a superconducting state. The sum of the work inputs required for the two refrigeration loads needs to be minimized for an optimal operation. In this design, three simple models that depict the refrigeration performance as functions of cooling temperature are developed based on some of the existing refrigerators. By solving one-dimensional conduction equation that take into account the temperature-dependent properties of the materials, the refrigeration works are numerically calculated for various values of the joint temperature and the sizes of two parts. The results show that for given size of HTS, there exist the optimal values for the joint temperature and the size of the normal metal. It is also found that the refrigeration work decreases as the length of HTS increases and that the optimal size of normal metal is quite independent of the size of HTS. For a given length of HTS, there is an optimal cross-sectional area and it increases as the length increases. The dependence of the optimal sizes on the refrigerator models employed are presented for 1kA leads.

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The Comparison of Performance Characteristics in Refrigeration System using $NH_3$ and R22 ($NH_3$와 R22를 사용한 냉동장치의 성능특성 비교)

  • Ha Ok-Nam;Lee Kyu-Tae;Ha Kyung-Soo;Jeong Song-Tae;Kim Jin-Hyun;Hong Seong-In;Yun Kab-Sig;Kim Yang-Hyun;Kwon Il-Wook;Lee Jong-In
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.5
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    • pp.377-383
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    • 2006
  • Recently, production and use of Freon substances are restrained due to destruction of ozone layer and grobal warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study apply the $NH_3$ and R22 to study the performance characteristic from the superheat control and compare the energy efficiency of two refrigerants from the high performance. The condensing pressure of refrigeration system is increased from 1,500 kPa to 1,600 kPa and degree of superheat is increased from 0 to $10^{\circ}C$ at each condensing pressure. As the result of experiment, when comparing the each COP, we knew the $NH_3$ is suitable as the alternative refrigerant of the R22.