• Title/Summary/Keyword: $COD_{cr}$

Search Result 332, Processing Time 0.031 seconds

A Study on Proper Fenton Oxidation Conditions for Pretreatment of Livestock Wastewater (축산폐수 전처리를 위한 펜톤산화 적정조건에 관한 연구)

  • Kim, Jong Oh;Jeong, Seong Uk
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.13 no.4
    • /
    • pp.107-117
    • /
    • 2005
  • The objective of this study was to investigate the proper operation conditions of fenton oxidation such as initial pH, $H_2O_2/Fe^{2+}$ ratio, $H_2O_2/Fe^{2+}$ dosage amount, and neutralizing agent for pretreatment of the livestock wastewater. Fenton oxidation reagents were reacted with the livestock wastewater for 2 hours at 120 rpm and the settling was performed for 2 hours using jar-tester apparatus under the different experimental conditions. And then the supernatant was sampled and measured for the residual $H_2O_2$, $COD_{Cr}$, and SS. The results are as follows; optimum initial pH=4, optimum $H_2O_2/Fe^{2+}$ ratio=10:1, optimum $H_2O_2/Fe^{2+}$ dosage amount=5,000/500 mg/L and $Ca(OH)_2$ as proper neutralizing agent. The removal efficiency of $COD_{Cr}$ and SS were 43% and 84% under those optimal fenton oxidation conditions.

  • PDF

A Study on Removal of Organics, Nitrogen and Phoschorus of Domestic Wastewater in Pilot-Scale Upflow Packed Bed Column Reactor (Pilot 규모의 상향류식 충전탑 반응기를 이용한 생활오수의 유기물 및 질소, 인 처리에 관한 연구)

  • Seon, Yong-Ho
    • KSBB Journal
    • /
    • v.22 no.4
    • /
    • pp.191-196
    • /
    • 2007
  • This study used biofilm process, which needs simple operation, maintenance and smaller facility area than conventional activated sludge process with the small plant operation, in the treatment of increasing sewage with the rapid industrial growth. The reactor used in this study consists of one anaerobic and one aerobic chamber filled with waste ceramic and waste vinyl as media and the treated sewage was from restaurant source. The experiment was scaled up from lab. to pilot scale and lasted for about 100 days. We focused on the removal efficiency of organics, nitrogen and phosphorus with constant HRT and continuous aeration. The removal efficiency of $BOD_5$ and SS were 94.33% and 87.77% respectively, which was a satisfaction level. However the removal efficiency of $COD_{Cr}$ was 81.46% somewhat below the desired level of 90%, and that of T-N and T-P showed 71.92% and 21.10% respectively, that was below the expected value. The removal efficiency of $COD_{Cr}$ and T-N in the pilot scale was about 10% low compared with the lab.-scale.

Study on the Removal of Fluorescent Whitening Agent for Paper-mill Wastewater Reuse using the Submerged Membrane Bioreactor(SMBR) with Ozone Oxidation Process (제지폐수 재이용을 위한 침지형 생물막 여과와 오존산화공정(SMBR-Ozone Oxidation Process)에 의한 형광증백제 제거에 관한 연구)

  • Choi, Jang-Seung;Shin, Dong-Hun;Ryu, Seung-Han;Lee, Jae-Hun;Ryu, Jae-Young;Shin, Won-Sik;Lee, Seul-Ki;Park, Min-Soo;Lee, Sang Oh
    • Textile Coloration and Finishing
    • /
    • v.30 no.1
    • /
    • pp.51-61
    • /
    • 2018
  • In this study, effluent water was produced through Submerged Membrane Bio-Reactor(SMBR) process, which is a simple system and decomposes organic matter contained in wastewater with biological treatment process and performs solid-liquid separation, Especially, ozone oxidation treatment process is applied to effluent water containing fluorescent whitening agent, which is a trace pollutant which is not removed by biological treatment, and influences the quality of reused water. The concentration of $COD_{Cr}$ in the SMBR was $449.3mg/{\ell}-COD_{Cr}$, and the concentration of permeate water was $100.3mg/{\ell}-COD_{Cr}$. The removal efficiency was about 70.1%. The amount of ozone required for the removal of the fluorescent whitening agent in the permeated water in SMBR was $6.67g-O_3/min$, and the amount of ozone required to remove $COD_{Mn}$ relative to the permeate water was calculated to remove $0.997mg-COD_{Mn}$ for 1mg of $O_3$.

Biological Treatment of Dyeing Wastewater Using Jet Loop Reactor with Activated Carton Supports (활성탄 담체가 포함된 Jet-Loop Reactor를 이용한 종합염색폐수처리)

  • 조무환;박종탁;이길호;류원률
    • KSBB Journal
    • /
    • v.17 no.3
    • /
    • pp.241-246
    • /
    • 2002
  • Today, many problems of dye-processing wastewaters were raised due to industry of dyeing and textiles. It is difficult to treat them perfectly because they contain many poorly degradable matters, such as surfactants, ethylene glycol, polyvinyl alcohol, and so on. To improve the performances of conventional physicochemical treatment and activated sludge process, new systems of combining jet-loop reactor (JLR) with physicochemical treatment were developed. Volumetric oxygen transfer coefficient ($k_{L}a$) of JLR was significantly larger than that of air-lift reactor. Also, for the effective treatment of dye-processing wastewater, JLR with active carbon supports (JLRAS) were investigated. Removal efficiency of BOD, $COD_{Mn}$, $COD_{Cr} and color were found as 99, 86, 84, 83%, respectively, when HRT was 8 hrs. And performance of JLRAS was rapidly restored after step change of $COD_{Mn}$ loading late. The optimal coagulant and dosage of second physicochemical treatment after JLRAS were polyferric sulfate and 130 mg/L, respectively, when removal efficiencies of $COD_{Mn} and color were 85 and 73%, respectively. In conclusion, this system enables the reduction of operation cost, and the effective removal of many organics.

Estimating of Pollutant Load at Paddy Field Area (광역논에서의 오염물질 부하량 산정)

  • Kim, Byoung-Hee;Yoon, Chun-Gyeong;Hwang, Ha-Sun
    • Proceedings of the Korean Society of Agricultural Engineers Conference
    • /
    • 2001.10a
    • /
    • pp.509-512
    • /
    • 2001
  • In this study, pollutant load from paddy field was estimated by regression equation from 5 to 8 in 2001. During study period, total rainfall was 511.3mm and runoff discharge was 968.71mm. Regression equation between flow rate(m3/s) and pollutant loading rate(g/s) is exponential relationship. For site 1, coefficient of determination (R2) for $COD_{cr}$, T-P, T-N were 0.7068, 0.8441, 0.6806 respectively and site 2, 0.9369, 0.8855, 0.4262 respectively. Considering unit loads, Jun was the highest valus as 13.85 $COD_{c}kg/km2/day$, 0.24 T-Pkg/km2/day, 1.22 T-Nkg/km2/day. Until study period, total $COD_{cr}$ load estimated regression equation is 19.32kg/km2/day and, T-P, T-N were 0.264, 1.88 respectively

  • PDF

Effects of Domestic Wastewater Treatment used Biofilm-Electrode Reactor(BER) (生物膜 電極反應機를 이용한 廚房廢水 처리 효과)

  • Noh, Hyun-Woong;Yoon, Oh-Sub
    • Journal of Environmental Health Sciences
    • /
    • v.23 no.1
    • /
    • pp.43-49
    • /
    • 1997
  • This study was aimed to estimate removal efficiency(%) of BER(Biofilm-Electrode Reactor) and A.S(Activated Sludge) treatments. When were analyzed COD$_{Cr}$, NH$_3$-N and T-P by current density and reaction time, the results were as follows : 1) In BER treatment, the removal efficiency of COD$_{Cr}$ in domestic wastewater was 79-86% when current density was 2.39 mA/dm$2$(15mA)-3.98 mA/dm$^2$(25mA) and reaction time was 48 hr. 2) Removal efficiency of NH$_3$-N was 71-73% when current density was 2.39-3.98 mA/dm$^2$ and reaction time 48 hr. 3) When the reaction time was 48 hr removal efficiency(%) of BER treatment for COD$_{Cr}$, NH$_3$-N and T-P were more excellent than A.S. treatment. And then we prospect that was because activated microorganism colonies attached in biofilm on surface of electrode pannel. Therefore, In order to derive BER treatment efficiency(%) should establish optimum conditions of pH, temp., reaction time, current density and biochemical and electrochemical states.

  • PDF

Pollutant Concentrations at Experimental Paddy Plots during Irrigation Season (관개기 시험구 논에서의 오염물질의 농도특성)

  • Cho, Jae-Won;Kim, Jin-Soo;Oh, Kwang-Young;Oh, Seung-Young
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.48 no.3
    • /
    • pp.97-106
    • /
    • 2006
  • The pollutant concentrations at experimental paddy plots with three (excessive, standard, reduced) different fertilization rates were investigated during 2001-2002 irrigation seasons. Mean concentrations of pollutants in ponded water were not significantly different among three experimental plots, but the T-N concentrations in percolated water significantly depended on fertilization rates. The T-N, T-P and $COD_{Cr}$, concentrations in ponded water during early irrigation season (late May to mid-June) were much higher than those during later irrigation season likely due to fertilization and low uptake by young rice crops. The T-N concentrations decreased but the concentrations of T-P and $COD_{Cr}$, increased three days after tillering fertilization. The removal rates of T-N by paddy plots were $0.13-0.16g/m^2{\cdot}d$ for an excessive fertilization plot, $0.08-0.25g/m^2{\cdot}d$ for a standard fertilization plot, and $0.03-0.34g/m^2{\cdot}d$ for a reduced fertilization plot three days after tillering fertilization. On the other hand, T-P and $COD_{Cr}$, were released three days after tillering fertilization.

Solid Separation and Flotation Characteristics of Livestock Wastewater Using DAF Process (DAF 공정을 이용한 축산폐수의 고형물 분리와 부상특성)

  • Kang, Byong-Jun;Yoo, Seung-Joon;Lee, Se-il;Kwak, Dong-Heui
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.22 no.3
    • /
    • pp.359-366
    • /
    • 2008
  • The series of experiments under the various conditions were carried out to evaluate the feasibility of dissolved air flotation (DAF) as an alternative of conventional gravity sedimentation (CGS) and to investigate the decrease of the loadings following to biological wastewater treatment processes in livestock wastewater system. On the basis of the experiment result between CGS and DAF processes, for the other water quality criteria as well as suspended solid the removal efficiency of DAF process was about 20~25 % better than CGS process on average. In addition, the particle removal efficiency of DAF process became higher in proportion as the increase of air to solid (A/S) ratio and the general wastewater treatment efficiency of DAF process was enough to meet the requirement of loading decrease to following biological process even at low A/S ratio range. Though DAF process is widely known as an solid separation unit, there was not the notable relationship between particle separation efficiency and several pollutant removal efficiencies like $COD_{Cr}$ and nutrients (T-N, T-P). Assume that the $COD_{Cr}$ was removed as the fraction of particle separation in this experiment, the removal efficiency of T-N and T-P were sensitive to removal efficiency of $COD_{Cr}$, especially.

Refractory Textile Wastewater Treatment Using Cell-Immobilized Polyethylene glycol Media (PEG 포괄고정화담체를 이용한 난분해성 염색폐수 처리)

  • Han, Duk-Gyu;Cho, Young-Jin;Bae, Woo-Keun;Hwang, Byung-Ho;Lee, Yong-Woo
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.3
    • /
    • pp.345-350
    • /
    • 2006
  • This study investigated the removal of recalcitrant organics in dyeing wastewater using a fluidized bed reactor(FBR) that contained cell-immobilized pellets. The pellets were manufactured and condensing the gel phase by mixing PEG-polymer and cells to form micro-porous PEG-polymer pellets whose size were ${\Phi}\;4mm{\times}H\;4mm$ on average. An industrial activated sludge without any pre-adaptation was used for the cell immobilization because it gave an equivalent removal efficiency to a pre-adapted sludges. The feed was obtained from an effluent of a biological treatment plant, which contained $SCOD_{Cr}$ of 330 mg/L and $SBOD_5$ of 20 mg/L. The $SCOD_{Cr}$ removal efficiency was over 45% and the effluent $COD_{Mn}$ concentration was less than 100 mg/L at HRTs from 6 to 24 hrs. The optimum HRT in the FBR was determined as 12 hrs considering the removal efficiency and cost. When a raw wastewater containing 768 mg/L of $COD_{Cr}$ was fed to the FBR, the effluent $COD_{Cr}$ concentration increased only slightly, giving a 70% of $COD_{Cr}$ removal or a 97% of $BCOD_5$ removal. This indicated that the FBR had an excellent capability of biodegradable organics removal also. In conclusion, the FBR could be applied to textile wastewater treatment in place of an activated sludge process.