• Title/Summary/Keyword: $CH_4$ addition

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The Effects of Combustion Products Dilution and Wall Temperature on the Ignition of Methane Fuel (메탄연료의 점화특성에 미치는 연소 생성물 희석 및 벽면온도의 영향)

  • Song, Keum-Mi;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.9-15
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    • 2012
  • The ignition characteristics in a confined axisymmetric coflow $CH_4$ jet were investigated numerically with the Fire Dynamics Simulator(FDS). The $CH_4$ fuel stream was diluted with main combustion product gases, such as $O_2$, $N_2$, CO, $CO_2$, and $H_2O$, and the mixed fuel stream was heated up to the sufficient temperature where a supplying fuel stream can be ignited. For the calculation of chemical reaction in the simulation, a 2-step global finite chemistry model was considered. Boundary condition for confined wall was optimized by investigating the effects of wall temperature on the ignition characteristics of fuel stream. In addition, the effects of composition of diluents in the fuel stream and fuel stream temperature on the ignition of fuel steam were investigated. The ignition characteristics of $CH_4$ stream with diluents were very sensitive to the wall temperature, composition of diluents in the fuel stream and fuel stream temperature.

Emissions of Air Pollutants and Greenhouse Gases from Aircraft Activities at the Gimhae International Airport (김해공항에서 항공기에 의한 대기오염물질과 온실가스의 배출량 산정 및 특성 분석)

  • Song, Sang-Keun;Shon, Zang-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.190-202
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    • 2012
  • Emissions of air pollutants and greenhouse gases (GHGs) by aircraft at the Gimhae International Airport (GIA) were investigated using the Emissions and Dispersion Modeling System (EDMS) version 5.1.3. The number of Landing and Take-Off (LTO) at the GIA for aircraft B737 was dominant, accounting for more than 60% of the total LTOs. For air pollutant emissions, CO was the most dominant pollutant by aircraft, followed by $NO_x$, VOCs, $SO_x$, etc. The emissions of CO, $NO_x$, and VOCs in 2009 (and 2010) at the GIA were 974 (968), 447 (433), 118 (122) ton/yr, respectively. The emissions of GHGs such as $CO_2$, $CH_4$, and $N_2O$ in 2009 (and 2010) were 110,795 (111,114), -0.157 (-0.151), and 1,989 (1,998) ton/yr, respectively. The negative number in $CH_4$ emission represents the consumption of atmospheric $CH_4$ in the engine. In addition, the emissions of most air pollutants (except for $PM_{10}$) and GHGs were estimated to be high in Taxi-Out and Climb-Out modes.

Plant Regeneration from Embryogenic Suspension Culture of Orchardgrass (Dactylis glomerata L.) (오차드그래스의 현탁배양으로부터 부정배 형성과 식물체 재분화)

  • 이효신;권용삼;이병현;원성혜;김기용;조진기
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.20 no.1
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    • pp.7-12
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    • 2000
  • This study was carried out to improve the ability of embryo formation and the efficiency of plant regeneration from suspension cultured cells of seed derived calli of orchardgrass (Dactylis glomerata L.). The frequency of formation of round cell and cell colonies was highest at 50 days after suspension culture in $N_6$ medium supplemented with $4\;g/{\ell}$ casein hydrolysate (CH), $20\;g/{\ell}$ sucrose and $30\;g/{\ell}$ sorbitol. The highest frequency of plant regeneration and somatic embryo formation was obtained from suspension cultured cells of 60 days. Addition of CH ($4\;g/{\ell}$) in suspension culture medium gave the highest frequency of embryo formation (39.6%) and plant regeneration (73.0%).

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Experimental Investigation on the Highly N2-diluted CH4-O2 Flame Stabilization in an Axially Two-section Porous Medium (축방향 2단 다공체 내 N2로 과다 희석된 CH4-O2 화염의 안정화에 관한 실험적 연구)

  • Kim, Seung Gon;Lee, Dae Keun;Noh, Dong-Soon;Ko, Chang-Bog
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.45-46
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    • 2013
  • Stabilization characteristics of highly $N_2$-diluted $CH_4-O_2$ flame in an axially two-section porous inert medium were experimentally investigated for its application to the waste gas scrubber in semiconductor manufacturing processes. The flame behaviors were observed with respect to the fuel and $N_2$ flow rates and the equivalence ratios. As a result, four kinds of flame behaviors such as stable, flashback crossing the interface, blowout and sudden extinction were observed. It was also found that there exists two flame regime divided by a critical fuel flow rate. In addition, the flame stability was discussed based on the $N_2$ index which means the abatement capacity of our combustor in scrubbing the waste gas from the semiconductor processes.

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The Problem of Plato's Space (플라톤의 공간 문제)

  • Kim, Yoon-dong
    • Journal of Korean Philosophical Society
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    • v.145
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    • pp.195-215
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    • 2018
  • Plato said that our cosmos was created from the union of nous and $anank{\bar{e}}$ in Timaeus. In addition to this, 'the third kind', namely $ch{\bar{o}}ra$, exists already with genesis before the birth of the cosmos. Plato explains this $ch{\bar{o}}ra$ with several metaphors. That is, 'receptacle', 'mother', 'gold', 'space', 'place' etc. From Aristotle to contemporary scholars, generally three types of interpretations are presented. First, $ch{\bar{o}}ra$ is a kind of a 'void.' Secondly, $ch{\bar{o}}ra$ is Aristotle's $prot{\bar{e}}$ $hyl{\bar{e}}$. Thirdly, $ch{\bar{o}}ra$ has two aspects of space and matter. I will accept the third opinion. Plato's $ch{\bar{o}}ra$ has both a spatial aspect and material aspect. $Ch{\bar{o}}ra$ is a place that accommodates all sensible things in itself. On the other hand, $ch{\bar{o}}ra$ seems to be a mother who nourishes sensible things like a child. In this, Plato lacks a logical consistency. The research of $ch{\bar{o}}ra$ can not deviate from the limits of $eik{\bar{o}}s$ logos.

The Study of Cyclophosphamide Metabolite $^{15}N$ and $^{17}O$ Phosphoramide Mustards (항암제인 Cyclophosphamide의 중간체인 $^{15}N$$^{17}O$-phosphoramide Mustards의 합성)

  • Koo, Kyo-Im;Ryem, Kon
    • YAKHAK HOEJI
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    • v.38 no.4
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    • pp.455-461
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    • 1994
  • Each nitrogen and oxygen site isotope enriched the cyclophosphamide metabolite phosphoramide mustard was synthesized. Reaction of N,N-bis(2-chloroethyl)phosphoramidic dichloride$[Cl_2P(O)N(CH_2CH_2Cl)_2]$ with benzyl alcohol and ammonia gave N,N-bis(2-chloroethyl)phosphorodiamidic acid phenylmethyl ester $[BzO(H_2N)P(O)N(CH_2CH_2Cl)_2]$. Catalytic hydrogenation of this benzyl ester followed by the addition of cyclohexylamine provided PM. Incorporation of $^{15}NH_3$ into this general scheme gave PM with a $^{15}NH_2$ moiety. Glycine-$^{15}N$ was converted to bis(2-chloroethyl)amine-$^{15}N$ hydrochloride which, in turn, provided for N,N-bis(2-chloroethyl)phosphorodiamidic-$^{15}N$ dichloride. Use of this compound in the general synthetic pathway yielded PM CHA with $^{15}N$ in the mustard moiety. $^{17}O$-Enriched PM was generated through the use of benzyl alcohol-$^{17}O$. To obtain the alcohol, labelled benzaldehyde was made by exchange with $^{17}OH_2$ and was then reduced with sodium borohydride.

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Inhibition of IgM Secretion in Murine B Cell Lymphoma by Hydrogen Peroxide

  • Jang, Eun-Jung;Jo, Sung-Kee;Yoo, Byung-Sun
    • Toxicological Research
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    • v.18 no.4
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    • pp.363-367
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    • 2002
  • Reactive of gen species (ROS) contribute to several cellular function and are involved in the regulation of signal transduction, gene expression, and proliferation. In the present study, we investigated the effect of $H_2O_2$ treatment on IgM secretion in LPS-stimulated murine B Iymphoma, CH12.LX. Cells were treated directly With $H_2O_2$ and stimulated with LPS. $H_2O_2$ treatment during 72 h time period inhibited IgM secretion in LPS-stimulated CH12.LX cells in a dose- and time-dependent manners. After treatment with 50 $\mu\textrm{M}$ $H_2O_2$ during 72 h time period, the level of IgM in LPS-stimulated CH12.LX cells was markedly decreased, whereas cell viability was not significantly changed. Addition of $H_2O_2$ concomitantly with LPS, or 12 h post-LPS stimulation, produced a significant inhibition of IgM secretion, Whereas inhibitory effect of $H_2O_2$ on IgM secretion was not observed when added 24 h after LPS stimulation. These findings suggest that $H_2O_2$ can inhibit the secretion of IgM in LPS-stimulated CH15.LX cells, and may alter the events necessary for terminal B cell differentiation.

Design of CO2 Absorber Mix Tuned for Ripening of Packaged Kimchi (포장 김치의 숙성에 맞춘 CO2 흡수제 배합비율 설계)

  • Jung, Soo Yeon;Lee, Dong Sun;An, Duck Soon
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.1
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    • pp.35-40
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    • 2021
  • Calcium hydroxide (CH) reacts with CO2 to produce moisture, and sodium carbonate (SC) reacts with CO2 in the presence of moisture. Using these different characteristics of these two reactants, a CH/SC mixture of CO2 absorber tuned for kimchi ripening to produce CO2 in a flexible package was selected. A ratio of CH:SC (1:2) in highly gas permeable microporous spunbonded film (Tyvek) sachet was found to be appropriate for delayed and consistent CO2 absorption useful for kimchi package. Addition of superabsorbent polymer (SAP) as moisture buffer was helpful for boosting the consistency of CO2 absorption. In a package of 0.5 kg kimchi at 10℃, the sachet consisting of 0.794 g of CH + 2.276 g of SC + 0.4 g of SAP suppressed its volume expansion and maintained a suitable range of CO2 partial pressure (PCO2) steadily inside. These optimal conditions may vary depending on the type and salinity of kimchi, storage and distribution temperature, and the material and area of the absorber sachet. This study showed a potential of mixture CO2 absorber to be tuned for CO2 producing packaged kimchi for the purpose of keeping consistent PCO2 at tolerable volume expansion.

Kinetics and Mechanism for the Reaction of 4-Nitrophenyl 2-Furoate with Secondary Alicyclic Amines

  • 이종팔;윤지회;엄익환
    • Bulletin of the Korean Chemical Society
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    • v.20 no.7
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    • pp.805-808
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    • 1999
  • Second-order-rate constants (kN) have been measured spectrophotometrically for the reactions of 4-nitrophenyl 2-furoate (1) with a series of secondary alicyclic amines in H2O containing 20 mole % DMSO at 25.0℃. 1 is about 5-8 times more reactive than 4-nitrophenyl benzoate (2), although 1 is expected to be less reactive than 2 based on MO calculations and 13 C NMR study. The Brфnsted-type plots for the aminolysis reactions of 1 and 2 are linear with βnuc values of 0.78 and 0.85, respectively. The replacement of the CH=CH group by an O atom in the acyl moiety (2->1) does not cause any mechanism change. The reaction of piperidine with a series of substituted phenyl 2-furoates gives a linear Hammett plot with a large ρ- value (ρ- = 2.88) when σ- constants are used. The linear Brфnsted and Hammett plots with a large ρ- value suggest that the aminolysis reaction of 1 proceeds via rate-determining break-down of the addition intermediate to the porducts.

Supplementation of Cassava Hay to Replace Concentrate Use in Lactating Holstein Friesian Crossbreds

  • Wanapat, M.;Petlum, A.;Pimpa, O.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.5
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    • pp.600-604
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    • 2000
  • Exp. I, the study was conducted to examine the supplementation levels of cassava hay (CH) in dairy cows. Six multiparous Holstein-Friesian crossbreds were paired and randomly assigned in a change-over design to receive three levels of CH supplement at 0, 0.8 and 1.7 kg DM/hd/d. Concentrate was supplemented at the same level (1:2; concentrate:milk yield) while urea-treated (5%) rice straw was offered on ad libitum basis. The results revealed that supplementation of CH could significantly reduce concentrate use resulting in similar milk yield (12.5, 12.12 and 12.6 kg/hd/d) and significantly enhanced 3.5% FCM (14.21, 15.70, 14.9 kg/d, respectively). Moreover, CH supplementation significantly increased milk fat and milk protein percentages especially at 1.70 kg/hd/d. Concentrate use could be significantly reduced by 27% at 1.7 kg/hd/d CH supplementation. Exp. II, supplementation of cassava hay to replace concentrate use was studied in lactating-Holstein Friesian crossbreds grazed on Ruzi grass. Six multiparous cows in mid-lactating periods were paired and randomly assiged according to a change-over-design to receive three dietary treatments, $T_1=0kg$ cassava hay (CH) in 1:2 concentrate supplementation (CS) to milk yield (MY), $T_2=1.0kg$ DM CH/hd/d in 1:3 CS to MY, $T_3=1.7kg$ DM CH/hd/d in 1:4 CS to MY, respectively. The results were found that milk yield were similar among treatments while protein, lactose and solids-not-fat percentages were highest (p<0.05) in cows receiving CH at 1.0 kgjhd/d. Most significant improvement from CH supplementation was the ability to reduce concentrate use by 42% which could provide a higher income for small-holder dairy farmers. In addition, milk thiocyanate was enhanced from 5.3 to 17.8 ppm (p<0.05) in the control and in the CH supplemented group (1.7 kg/hd/d), respectively. Moreover, CH supplementation could significantly reduce concentrate level for diary feeding thus resulted in more economical return. Cassava hay demonstrated as a potential and high-quality on-farm feed resource especially for dry season feeding in the tropics.