• 제목/요약/키워드: $C^{*}$-Integral

검색결과 658건 처리시간 0.024초

결합공간과 반결합공간 (제2보). $H_2O_2$$C_2H_6$의 Internal Rotation Barrier의 원천적 요인 (Bonding and Antibonding Regions (II). Origin of Barriers to Internal Rotation of $H_2O_2$ and $C_2H_6$)

  • 김호징;이덕환
    • 대한화학회지
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    • 제23권1호
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    • pp.20-29
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    • 1979
  • 과산화수소와 에탄의 integral rotation barrier의 원천적 요인을 결합 공간과 반결합 공간의 개념을 이용하여 연구하였다. internal rotation barrier는, 중심 원자의 존재로 인하여 천이밀도가 중심 원자가 없을 때보다 더 많이 반결합 공간으로 쏠림에 기인 함을 밝혔다. 이러한 천이밀도의 쏠림은 강한 O-H (또는 C-H) 결합에 의하여 내부 회전에 따른 전자밀도의 변화가 적어지는 것으로 설명할 수 있음을 보였다.

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Equilibrium Geometries of the Neutral and Ionic Clusters of $Ag_7$, $Ag_8$, and $Ag_9$ Studied by Intermediate Neglect of Differential Overlap Method

  • 유창현;선호성
    • Bulletin of the Korean Chemical Society
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    • 제21권10호
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    • pp.953-954
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    • 2000
  • The equilibrium geometrical structures of silver atom clusters at their electronic ground states have been theo-retically determined by using the nonrelativistic semiempirical INDO/1 method. The clusters investigated are Agn, Agn+, and Agn- (n = 7 , 8, 9). In order to find the most stable structure, i.e., the global minimum in energy hypersurface, geometry optimization and energy calculation processes have been repeatedly performed for all the possible graphical models by changing the bond parameters (resonance integral values). The heptamers are pentagonal bipyramidal-Ag7(D5h), Ag7+ (D5h), Ag7- (D5h); the octamers are pentagonal bipyramidal with one atom capped-Ag8(D2d), Ag8+ (Cs), Ag8- (D2d); the nonamers are pentagonal bipyramidal with two atoms capped -Ag9(C2v), Ag9+ (C2v), Ag9- (C2v). Our structures are in good agreement with those by ab initio calculations ex-cept for the anionic Ag9- cluster. And it is noted that the INDO/1 method can accurately predict the Ag cluster geometries when a proper set of bond parameters is used.

화력 발전용 고압 로터강의 정하중 및 변동하중하의 고온 크립 균열전파 특성에 관한 연구 (A Study on the High Temperature Creep Crack Growth Properties for Steam Turbine Rotor Steel under Static and Cyclic Loading Condition)

  • 오세규;정순억
    • 한국해양공학회지
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    • 제5권2호
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    • pp.207-207
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    • 1991
  • The crack length measurements by electrical potential(EP) method for 1% Cr-Mo-V and 12%Cr steel of 0.5T-CT specimen were performed at $500^{\circ}C, 600^{\circ}C 700^{\circ}C$, and an applicability of stress intensity factor($K_I$), net section stress($\sigma_{net}$), $C^*$-ingegral and $C_t$ parameter was studied to measure creep crack growth rate(da/dt) with side groove and without side groove under static and cyclic loading condition. The experimental result could be summarized as follows: 1) Crack measurement by EP method was available and coincided with the Johnson,s analytical equation. 2) da/dt by $K_I$ and $\sigma_{net}$ was not adequate because of the wide scatter band according to load and temperature, but $C^*$-integral, except for transition region, was adequate. 3) $C_t$ parameter showed the best fitted line through total creep region without relating with both temperature and load condition. 4) Under the cyclic loading condition, $C_t$ parameter was proper to extimate da/dt. And it was shown that da/dt for 1% Cr-Mo V steel under the static condition(R=1) was 1.16 times faster than the case under cyclic loading(R=0), and for 12% Cr steel, 1.43 times.

화력 발전용 고압 로터강의 정하중 및 변동하중하의 고온 크립 균열전파 특성에 관한 연구 (A Study on the High Temperature Creep Crack Growth Properties for Steam Turbine Rotor Steel under Static and Cyclic Loading Condition)

  • 오세규;정순억
    • 한국해양공학회지
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    • 제5권2호
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    • pp.67-75
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    • 1991
  • The crack length measurements by electrical potential(EP) method for 1% Cr-Mo-V and 12%Cr steel of 0.5T-CT specimen were performed at $500^{\circ}C, 600^{\circ}C 700^{\circ}C$, and an applicability of stress intensity factor($K_I$), net section stress($\sigma_{net}$), $C^*$-ingegral and $C_t$ parameter was studied to measure creep crack growth rate(da/dt) with side groove and without side groove under static and cyclic loading condition. The experimental result could be summarized as follows: 1) Crack measurement by EP method was available and coincided with the Johnson, s analytical equation. 2) da/dt by $K_I$ and $\sigma_{net}$ was not adequate because of the wide scatter band according to load and temperature, but $C^*$-integral, except for transition region, was adequate. 3) $C_t$ parameter showed the best fitted line through total creep region without relating with both temperature and load condition. 4) Under the cyclic loading condition, $C_t$ parameter was proper to extimate da/dt. And it was shown that da/dt for 1% Cr-Mo V steel under the static condition(R=1) was 1.16 times faster than the case under cyclic loading(R=0), and for 12% Cr steel, 1.43 times.

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동해 울릉분지 퇴적물에서 유기탄소 순환 (Organic Carbon Cycling in Ulleung Basin Sediments, East Sea)

  • 이태희;김동선;김부근;최동림
    • Ocean and Polar Research
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    • 제32권2호
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    • pp.145-156
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    • 2010
  • This study investigated organic carbon fluxes in Ulleung Basin sediments, East Sea based on a chamber experiment and geochemical analyses. At depths greater than 2,000 m, Ulleung Basin sediments have high organic carbon contents (over 2.0%). Apparent sedimentation rates (ASR) calculated from excess $^{210}Pb$ activity distribution, varied from 0.036 to $0.047\;cm\;yr^{-1}$. The mass accumulation rates (MAR) calculated from porosity, grain density (GD), and ASR, ranged from 131 to $184\;g\;m^{-2}\;yr^{-1}$. These results were in agreement with sediment trap results obtained at a water depth of 2100 m. Input fluxes of organic carbon varied from 7.89 to $11.08\;gC\;m^{-2}\;yr^{-1}$ at the basin sediments, with an average of $9.56\;gC\;m^{-2}\;yr^{-1}$. Below a sediment depth of 15cm, burial fluxes of organic carbon ranged from 2.02 to $3.10\;gC\;m^{-2}\;yr^{-1}$. Within the basin sediments, regenerated fluxes of organic carbon estimated with oxygen consumption rate, varied from 6.22 to $6.90\;gC\;m^{-2}\;yr^{-1}$. However, the regenerated fluxes of organic carbon calculated by subtracting burial flux from input flux, varied from 5.87 to $7.98\;gC\;m^{-2}\;yr^{-1}$. Respectively, the proportions of the input flux, regenerated flux, and burial flux to the primary production ($233.6\;gC\;m^{-2}\;yr^{-1}$) in the Ulleung Basin were about 4.1%, 3.0%, and 1.1%. These proportions were extraordinarily higher than the average of world open ocean. Based upon these results, the Ulleung Basin might play an integral role in the deposition and removal of organic carbon.

노트북 열발생에 따른 열해석에 관한 융합연구 (A Convergent Investigation on the Thermal Analysis due to Heat Generation of Laptop)

  • 최계광;조재웅
    • 한국융합학회논문지
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    • 제11권11호
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    • pp.189-194
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    • 2020
  • 본 연구에서는 노트북의 Model A,B,C에 대한 열응력 해석을 통하여 열에 대한 내구성을 고찰하였다. Model A는 일체형으로서 열을 받는 자판 부분이 가장 뜨겁고 열 받는 곳과 거리가 먼 모니터 부분이 가장 온도가 낮은 것을 보였다. Model B와 Model C에서는 열을 받는 자판부분만 모델링 하였기 때문에 전체적으로 뜨거워지는 것을 알 수가 있다. Model A의 경우는 노트북 자판의 두께가 더 두껍지만 변형이 제일 많이 나타났고 Model C는 두께가 가장 얇으면서도 응력과 변형이 가장 작게 나타났다. Model B의 경우는 응력이 제일 많았지만 변형은 비교적 적게 나타났다. 본 연구에서의 열해석 결과를 이용함으로서 내구성이 있는 노트북의 효율적인 최신 설계를 할 수 있다고 사료된다. 본 연구 결과를 노트북에 적용함으로서 열에 대한 노트북의 내구성을 평가할 수 있고 그 결과가 강성있는 노트북의 설계와 미적인 융합이 될 수 있다고 보인다.

2관능성 에폭시/생분해성 폴리부틸렌 숙시네이트 블렌드의 유변학적 특성 및 경화거동에 관한 연구 (Studies on Rheological Properties and Cure Behaviors of Difunctional Epoxy/Biodegradable Poly(butylene succinate) Blends)

  • 박수진;김승학;이재락;민병각
    • Composites Research
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    • 제15권6호
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    • pp.8-15
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    • 2002
  • 본 실험에서는 2관능성 에폭시 수지(2EP)와 생분해성 poly(butylene succinate)(PBS) 블렌드의 유변학적 특성, 경화거동, 열안정성 그리고 기계적 특성을 살펴보았다. 유변학적 특성은 레오미터를 이용하여 등온 조건 하에서 검토하였고, 겔화시간과 경화 온도를 이용한 Arrhenius 방정식을 적용하여 가교 활성화 에너지($\textrm{E}_c$)를 구하였다. $\textrm{E}_c$는 2EP에 대한 PBS의 비율이 10 wt%로 증가함에 따라 증가하였다. DSC 측정 결과, 경화 활성화 에너지($\textrm{E}_a$)는 $\textrm{E}_c$와 유사만 경향을 나타내었는데 이는 2EP와 PBS 사이의 분자상호작용이 증가하였기 때문으로 사료된다. 그리고 열안정성과 관련하이 분해 활성화에너지($\textrm{E}_t$)는 Horowitz-Metzger식을 이용한 적분법을 사용하여 구하였는데 PBS 10 wt%에서 증가하였다. 그리고 20 wt% PBS일 때 가장 높은 임계응력세기 인자를 보이는데, 이는 2EP/PBS 블렌드 시스템의 파괴인성이 증가하였기 때문으로 사료된다.

Quantitative Assessment the Relationship between p21 rs1059234 Polymorphism and Cancer Risk

  • Huang, Yong-Sheng;Fan, Qian-Qian;Li, Chuang;Nie, Meng;Quan, Hong-Yang;Wang, Lin
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권10호
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    • pp.4435-4438
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    • 2015
  • p21 is a cyclin-dependent kinase inhibitor, which can arrest cell proliferation and serve as a tumor suppressor. Though many studies were published to assess the relationship between p21 rs1059234 polymorphism and various cancer risks, there was no definite conclusion on this association. To derive a more precise quantitative assessment of the relationship, a large scale meta-analysis of 5,963 cases and 8,405 controls from 16 eligible published case-control studies was performed. Our analysis suggested that rs1059234 was not associated with the integral cancer risk for both dominant model [(T/T+C/T) vs C/C, OR=1.00, 95% CI: 0.84-1.18] and recessive model [T/T vs (C/C+C/T), OR=1.03, 95% CI: 0.93-1.15)]. However, further stratified analysis showed rs1059234 was greatly associated with the risk of squamous cell carcinoma of head and neck (SCCHN). Thus, larger scale primary studies are still required to further evaluate the interaction of p21 rs1059234 polymorphism and cancer risk in specific cancer subtypes.

색상기반 주목연산자를 이용한 정규화된 얼굴요소영역 추출 (Normalized Region Extraction of Facial Features by Using Hue-Based Attention Operator)

  • 정의정;김종화;전준형;최흥문
    • 한국통신학회논문지
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    • 제29권6C호
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    • pp.815-823
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    • 2004
  • 색상(hue) 기반 주목연산자와 조합누적투영함수(combinational integral projection function: CIPF)를 제안하여 조명변화에 강건하게 정규화된 얼굴요소영역을 추출하였다. 살색 필터를 도입하여 얼굴후보영역들을 추출하고, 거기에 색상과 대칭성에 기반한 주목연산자를 적용하여 조명변화에 강건하게 두 눈의 위치를 정확히 검출할 수 있도록 하였으며, 색상기반 눈 분산 필터로 눈을 검증하여 얼굴영역을 확인하였다. 또한, 색상과 밝기 성분을 조합한 조합누적투영함수를 사용하여 두 눈의 위치를 기준으로 조명변화나 수염의 존재유무에 둔감하게 눈썹 및 입의 수직위치를 구하고, 이를 바탕으로 정규화된 얼굴영역 및 그 요소영역을 추출하였다. AR 얼굴 데이터베이스[8]에 제안한 색상기반 주목연산자를 적용한 결과 기존 명도기반 주목연산자에 비해 약 39.3%의 눈 검출 성능향상을 보임으로써 조명방향 변화에 강건하게 정규화된 얼굴 및 그 요소영역을 일관성 있게 추출할 수 있음을 확인하였다.

Effect of Night Interruption with Mist and Shade Cooling Systems on Subsequent Growth and Flowering of Cymbidium 'Red Fire' and 'Yokihi'

  • Kim, Yoon Jin;Kim, Ki Sun
    • 원예과학기술지
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    • 제32권6호
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    • pp.753-761
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    • 2014
  • Growth and flowering of Cymbidium 'Red Fire' and 'Yokihi' plants were examined in a greenhouse with cooling systems in summer, and with night interruption (NI) lighting in winter as a forcing culture system. The greenhouse was divided into two sections with separate cooling controls during the summer season. One section was cooled by a mist system (mist), while the other section was cooled by a shade screen (shade). During the winter, the greenhouse was redivided into three sections within each cooling system. Plants were grown with NI either at a low light intensity of $3-7{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$(LNI) or a high l ight intensity of $120{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$(HNI) u sing h igh-pressure sodium l amps during the 22:00-02:00 HR. The control plants were grown under 9 h short-day condition. NI for 16 weeks and cooling for 9 weeks were employed twice during the 2 years of the experimental period. The air temperature was approximately $2^{\circ}C$ lower in the mist than in the shade and the relative humidity was 80 ${\pm}5%$ in the mist compared to $55{\pm}5%$ in the shade. The daily light integral in the mist section was 48% higher than in the shade section. The time from initial planting to flowering pseudobulb emergence decreased with both LNI and HNI for both cultivars, regardless of the cooling treatments. Under NI conditions, however, between 60% and 1 00% of plants of both cultivars flowered in the mist, whereas no or 20% of 'Red Fire' or 'Yokihi' plants, respectively, flowered in the shade treatment over 2 years. Plants grown under the mist had bigger pseudobulbs than those grown in the shade under both NI treatments. These results show that commercial use of NI in winter and a mist cooling system in summer would decrease crop production time to 2 years and increase profits in Cymbidium forcing culture.