• Title/Summary/Keyword: $C^{*}$-Integral

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Bonding and Antibonding Regions (II). Origin of Barriers to Internal Rotation of $H_2O_2$ and $C_2H_6$ (결합공간과 반결합공간 (제2보). $H_2O_2$$C_2H_6$의 Internal Rotation Barrier의 원천적 요인)

  • Kim Hojing;Lee Duckhwan
    • Journal of the Korean Chemical Society
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    • v.23 no.1
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    • pp.20-29
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    • 1979
  • The origin of barriers to internal rotation of hydrogen peroxide and ethane is investigated by using the concept of Bonding and Antibonding Regions. The strong bond formations between the axial and end atoms on the same side make the real charge densities in these molecules less dependent on conformations than those in the hypothetical molecules having no axial atoms. Thus, the existence of the axial atoms should induce the migration of the transition density from the Bonding region to the Antibonding region. Barrier to internal rotation can be understood in terms of this migration of the transition density to such an extent that the change in nuclear-nuclear repulsion energy becomes the dominating part of the total perturbation energy.

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Equilibrium Geometries of the Neutral and Ionic Clusters of $Ag_7$, $Ag_8$, and $Ag_9$ Studied by Intermediate Neglect of Differential Overlap Method

  • Yu, Chang Hyeon;Seon, Ho Seong
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.953-954
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    • 2000
  • The equilibrium geometrical structures of silver atom clusters at their electronic ground states have been theo-retically determined by using the nonrelativistic semiempirical INDO/1 method. The clusters investigated are Agn, Agn+, and Agn- (n = 7 , 8, 9). In order to find the most stable structure, i.e., the global minimum in energy hypersurface, geometry optimization and energy calculation processes have been repeatedly performed for all the possible graphical models by changing the bond parameters (resonance integral values). The heptamers are pentagonal bipyramidal-Ag7(D5h), Ag7+ (D5h), Ag7- (D5h); the octamers are pentagonal bipyramidal with one atom capped-Ag8(D2d), Ag8+ (Cs), Ag8- (D2d); the nonamers are pentagonal bipyramidal with two atoms capped -Ag9(C2v), Ag9+ (C2v), Ag9- (C2v). Our structures are in good agreement with those by ab initio calculations ex-cept for the anionic Ag9- cluster. And it is noted that the INDO/1 method can accurately predict the Ag cluster geometries when a proper set of bond parameters is used.

A Study on the High Temperature Creep Crack Growth Properties for Steam Turbine Rotor Steel under Static and Cyclic Loading Condition (화력 발전용 고압 로터강의 정하중 및 변동하중하의 고온 크립 균열전파 특성에 관한 연구)

  • O, Se-Gyu;Jeong, Sun-Eok
    • Journal of Ocean Engineering and Technology
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    • v.5 no.2
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    • pp.207-207
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    • 1991
  • The crack length measurements by electrical potential(EP) method for 1% Cr-Mo-V and 12%Cr steel of 0.5T-CT specimen were performed at $500^{\circ}C, 600^{\circ}C 700^{\circ}C$, and an applicability of stress intensity factor($K_I$), net section stress($\sigma_{net}$), $C^*$-ingegral and $C_t$ parameter was studied to measure creep crack growth rate(da/dt) with side groove and without side groove under static and cyclic loading condition. The experimental result could be summarized as follows: 1) Crack measurement by EP method was available and coincided with the Johnson,s analytical equation. 2) da/dt by $K_I$ and $\sigma_{net}$ was not adequate because of the wide scatter band according to load and temperature, but $C^*$-integral, except for transition region, was adequate. 3) $C_t$ parameter showed the best fitted line through total creep region without relating with both temperature and load condition. 4) Under the cyclic loading condition, $C_t$ parameter was proper to extimate da/dt. And it was shown that da/dt for 1% Cr-Mo V steel under the static condition(R=1) was 1.16 times faster than the case under cyclic loading(R=0), and for 12% Cr steel, 1.43 times.

A Study on the High Temperature Creep Crack Growth Properties for Steam Turbine Rotor Steel under Static and Cyclic Loading Condition (화력 발전용 고압 로터강의 정하중 및 변동하중하의 고온 크립 균열전파 특성에 관한 연구)

  • O, Se-Gyu;Jeong, Sun-Eok
    • Journal of Ocean Engineering and Technology
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    • v.5 no.2
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    • pp.67-75
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    • 1991
  • The crack length measurements by electrical potential(EP) method for 1% Cr-Mo-V and 12%Cr steel of 0.5T-CT specimen were performed at $500^{\circ}C, 600^{\circ}C 700^{\circ}C$, and an applicability of stress intensity factor($K_I$), net section stress($\sigma_{net}$), $C^*$-ingegral and $C_t$ parameter was studied to measure creep crack growth rate(da/dt) with side groove and without side groove under static and cyclic loading condition. The experimental result could be summarized as follows: 1) Crack measurement by EP method was available and coincided with the Johnson, s analytical equation. 2) da/dt by $K_I$ and $\sigma_{net}$ was not adequate because of the wide scatter band according to load and temperature, but $C^*$-integral, except for transition region, was adequate. 3) $C_t$ parameter showed the best fitted line through total creep region without relating with both temperature and load condition. 4) Under the cyclic loading condition, $C_t$ parameter was proper to extimate da/dt. And it was shown that da/dt for 1% Cr-Mo V steel under the static condition(R=1) was 1.16 times faster than the case under cyclic loading(R=0), and for 12% Cr steel, 1.43 times.

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Organic Carbon Cycling in Ulleung Basin Sediments, East Sea (동해 울릉분지 퇴적물에서 유기탄소 순환)

  • Lee, Tae-Hee;Kim, Dong-Seon;Khim, Boo-Keun;Choi, Dong-Lim
    • Ocean and Polar Research
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    • v.32 no.2
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    • pp.145-156
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    • 2010
  • This study investigated organic carbon fluxes in Ulleung Basin sediments, East Sea based on a chamber experiment and geochemical analyses. At depths greater than 2,000 m, Ulleung Basin sediments have high organic carbon contents (over 2.0%). Apparent sedimentation rates (ASR) calculated from excess $^{210}Pb$ activity distribution, varied from 0.036 to $0.047\;cm\;yr^{-1}$. The mass accumulation rates (MAR) calculated from porosity, grain density (GD), and ASR, ranged from 131 to $184\;g\;m^{-2}\;yr^{-1}$. These results were in agreement with sediment trap results obtained at a water depth of 2100 m. Input fluxes of organic carbon varied from 7.89 to $11.08\;gC\;m^{-2}\;yr^{-1}$ at the basin sediments, with an average of $9.56\;gC\;m^{-2}\;yr^{-1}$. Below a sediment depth of 15cm, burial fluxes of organic carbon ranged from 2.02 to $3.10\;gC\;m^{-2}\;yr^{-1}$. Within the basin sediments, regenerated fluxes of organic carbon estimated with oxygen consumption rate, varied from 6.22 to $6.90\;gC\;m^{-2}\;yr^{-1}$. However, the regenerated fluxes of organic carbon calculated by subtracting burial flux from input flux, varied from 5.87 to $7.98\;gC\;m^{-2}\;yr^{-1}$. Respectively, the proportions of the input flux, regenerated flux, and burial flux to the primary production ($233.6\;gC\;m^{-2}\;yr^{-1}$) in the Ulleung Basin were about 4.1%, 3.0%, and 1.1%. These proportions were extraordinarily higher than the average of world open ocean. Based upon these results, the Ulleung Basin might play an integral role in the deposition and removal of organic carbon.

A Convergent Investigation on the Thermal Analysis due to Heat Generation of Laptop (노트북 열발생에 따른 열해석에 관한 융합연구)

  • Choi, Kye-Kwang;Cho, Jae-Ung
    • Journal of the Korea Convergence Society
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    • v.11 no.11
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    • pp.189-194
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    • 2020
  • In this study, the durability on heat was considered through the thermal stress analyses on models A, B, and C of laptops. Model A is an integral part, indicating that the heated keyboard showed the highest temperature and the monitor part far from the heated one showed the coldest. In models B and C, only the heated keyboard parts are modeled, so it can be seen that they get hot overall. In the case of model A, the thickness of the laptop keyboard was thicker, but there were the most deformations, while model C had the thinnest thickness with the smallest stress and deformation. Model B had the highest stress but relatively little deformation. It is considered that the result of thermal analysis in this study can be used to make the latest efficient design of durable laptop. The durability of laptop against the heat can be evaluated by applying this study result to the laptop. And it is seen that the result can be the design of laptop with strength and the aesthetic convergence.

Studies on Rheological Properties and Cure Behaviors of Difunctional Epoxy/Biodegradable Poly(butylene succinate) Blends (2관능성 에폭시/생분해성 폴리부틸렌 숙시네이트 블렌드의 유변학적 특성 및 경화거동에 관한 연구)

  • 박수진;김승학;이재락;민병각
    • Composites Research
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    • v.15 no.6
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    • pp.8-15
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    • 2002
  • In this work, the effect of biodegradable poly(butylene succinate)(PBS) in difunctional epoxy(21:P) resin was investigated in terms of rheological properties, cure kinetics, thermal stabilities, and mechanical interfacial properties. Rheological properties of the blend system were measured under isothermal condition using a rheometer. Cross-linking activation energies($\textrm{E}_c$) were determined from the Arrhenius equation based on gel time and curing temperature. The $\textrm{E}_c$ was increased in the presence of 10 wt% PBS as compared with neat 2EP. From the DSC results of the blends, the cure activation energies($\textrm{E}_a$) showed a similar behavior with $\textrm{E}_c$ due to the increased intermolecular interaction between 2EP and PBS. The decomposed activation energies($\textrm{E}_t$) for the thermal stability derived from the integral method of Horowitz-Metzger equation, were also increased in 10 wt% PBS. In addition, 20 wt% PBS showed the highest critical stress intensity factor($\textrm{E}_{IC}$). which was explained by increasing the fracture toughness of the 2EP/PBS blend systems.

Quantitative Assessment the Relationship between p21 rs1059234 Polymorphism and Cancer Risk

  • Huang, Yong-Sheng;Fan, Qian-Qian;Li, Chuang;Nie, Meng;Quan, Hong-Yang;Wang, Lin
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.10
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    • pp.4435-4438
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    • 2015
  • p21 is a cyclin-dependent kinase inhibitor, which can arrest cell proliferation and serve as a tumor suppressor. Though many studies were published to assess the relationship between p21 rs1059234 polymorphism and various cancer risks, there was no definite conclusion on this association. To derive a more precise quantitative assessment of the relationship, a large scale meta-analysis of 5,963 cases and 8,405 controls from 16 eligible published case-control studies was performed. Our analysis suggested that rs1059234 was not associated with the integral cancer risk for both dominant model [(T/T+C/T) vs C/C, OR=1.00, 95% CI: 0.84-1.18] and recessive model [T/T vs (C/C+C/T), OR=1.03, 95% CI: 0.93-1.15)]. However, further stratified analysis showed rs1059234 was greatly associated with the risk of squamous cell carcinoma of head and neck (SCCHN). Thus, larger scale primary studies are still required to further evaluate the interaction of p21 rs1059234 polymorphism and cancer risk in specific cancer subtypes.

Normalized Region Extraction of Facial Features by Using Hue-Based Attention Operator (색상기반 주목연산자를 이용한 정규화된 얼굴요소영역 추출)

  • 정의정;김종화;전준형;최흥문
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.6C
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    • pp.815-823
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    • 2004
  • A hue-based attention operator and a combinational integral projection function(CIPF) are proposed to extract the normalized regions of face and facial features robustly against illumination variation. The face candidate regions are efficiently detected by using skin color filter, and the eyes are located accurately nil robustly against illumination variation by applying the proposed hue- and symmetry-based attention operator to the face candidate regions. And the faces are confirmed by verifying the eyes with the color-based eye variance filter. The proposed CIPF, which combines the weighted hue and intensity, is applied to detect the accurate vertical locations of the eyebrows and the mouth under illumination variations and the existence of mustache. The global face and its local feature regions are exactly located and normalized based on these accurate geometrical information. Experimental results on the AR face database[8] show that the proposed eye detection method yields better detection rate by about 39.3% than the conventional gray GST-based method. As a result, the normalized facial features can be extracted robustly and consistently based on the exact eye location under illumination variations.

Effect of Night Interruption with Mist and Shade Cooling Systems on Subsequent Growth and Flowering of Cymbidium 'Red Fire' and 'Yokihi'

  • Kim, Yoon Jin;Kim, Ki Sun
    • Horticultural Science & Technology
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    • v.32 no.6
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    • pp.753-761
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    • 2014
  • Growth and flowering of Cymbidium 'Red Fire' and 'Yokihi' plants were examined in a greenhouse with cooling systems in summer, and with night interruption (NI) lighting in winter as a forcing culture system. The greenhouse was divided into two sections with separate cooling controls during the summer season. One section was cooled by a mist system (mist), while the other section was cooled by a shade screen (shade). During the winter, the greenhouse was redivided into three sections within each cooling system. Plants were grown with NI either at a low light intensity of $3-7{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$(LNI) or a high l ight intensity of $120{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$(HNI) u sing h igh-pressure sodium l amps during the 22:00-02:00 HR. The control plants were grown under 9 h short-day condition. NI for 16 weeks and cooling for 9 weeks were employed twice during the 2 years of the experimental period. The air temperature was approximately $2^{\circ}C$ lower in the mist than in the shade and the relative humidity was 80 ${\pm}5%$ in the mist compared to $55{\pm}5%$ in the shade. The daily light integral in the mist section was 48% higher than in the shade section. The time from initial planting to flowering pseudobulb emergence decreased with both LNI and HNI for both cultivars, regardless of the cooling treatments. Under NI conditions, however, between 60% and 1 00% of plants of both cultivars flowered in the mist, whereas no or 20% of 'Red Fire' or 'Yokihi' plants, respectively, flowered in the shade treatment over 2 years. Plants grown under the mist had bigger pseudobulbs than those grown in the shade under both NI treatments. These results show that commercial use of NI in winter and a mist cooling system in summer would decrease crop production time to 2 years and increase profits in Cymbidium forcing culture.