• Title/Summary/Keyword: $BaSO_4$

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Preparation of Ferroelectric Barium Titanate Fine Particles by Hydrothermal Method and Their Dielectric Properties -Variation of Dielectric Properties and Phase Transition by Heat Treatment- (강유전성 티탄산바륨 극미립자의 수열합성과 그 유전특성 - 열처리에 의한 상전이 및 유전 특성 변화 -)

  • Um, Myeong-Heon;Lee, Jin-Sik;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.817-821
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    • 1998
  • $BaTiO_3$ particles were prepared using $Ba(OH)_2{\cdot}8H_2O$ and $Ti(OC_2H_5)O_4$ by the hydrothermal method and their characteristics treated at the various temperatures have been investigated. This prepared $BaTiO_3$ powder includes a very small amount of $H_2O$ and $OH^-$. By increasing the treated temperature from $200^{\circ}C$ to $1000^{\circ}C$, the mean particle size was accordingly increased from $0.022{\mu}m$ to $0.072{\mu}m$ and the tetrogonality(c/a)was increased from 1.02 to 1.2 so that the phase transition to tetroganal takes place. $BaTiO_3$ sintered at $1250^{\circ}C$ after heat treatment at $400^{\circ}C$ for 3 hrs showed a specific dielectric constant of 8120 and surface activation energy was 9680 kcal/mol.

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Adsorption Effect of Heavy Metals (Zn, Ni, Cd, Cu) in Aqueous Solution Using Bottom Ash of Biomass Power Plant (바이오매스 발전소 저회를 활용한 수용액 내 중금속(Zn, Ni, Cd, Cu) 흡착 효과)

  • So-Hui Kim;Seung-Gyu Lee;Jin-Ju Yun;Jae-Hyuk Park;Se-Won Kang;Ju-Sik Cho
    • Korean Journal of Environmental Agriculture
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    • v.41 no.4
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    • pp.252-260
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    • 2022
  • BACKGROUND: The number of biomass power plants is increasing around the world and the amount of wastes from power plants is expected to increase. But the bottom ash (BA) is not recycled and has been dumped in landfill. This study was conducted to find out functional groups of BA and adsorption rate of heavy metals on BA. METHODS AND RESULTS: The BA was dried in oven at 105℃ for 24 hours, and characterized by analyzing the chemistry, functional group, and surface area. The adsorption rates of heavy metals on BA were evaluated by different concentration, time, and pH. As a result, the adsorption amount of the heavy metals was high in the order of Zn> Cu> Cd> Ni and the removal rates of Zn, Cu, Cd, and Ni by BA was 49.75, 30.20, 32.46, and 36.10%, respectively. Also, the maximum adsorption capacity of BA was different by the heavy metal in the environmental conditions, and it was suggested that the isotherms for Zn, Ni, Cd, and Cu were adequate to Langmuir model. CONCLUSION(S): It is suggested that it would be effective to remove heavy metals in aqueous solution by using BA from biomass power plants in South Korea.

Flux Pinning Enhancement in $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_{2}Cu_{3}O_y$ Oxides by Zone Melt Growth Process

  • Kim So-Jung
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.6
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    • pp.251-256
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    • 2005
  • Directionally melt-textured high $T_c\;(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_{2}Cu_{3}O_y$ [(YNS)-123] superconductor was systematically investigated by the zone melt growth process in air. A sample prepared by this method showed well-textured microstructure, and $(Y_{0.5}Nd_{0.25}Sm_{0.25})_{2}BaCuO_5$[(YNS)211] inclusions were uniformly dispersed in large $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_{2}Cu_{3}O_y$ [(YNS)123] matrix. High irreversibility field and magnetization hysteresis loop of the zone melt-textured (YNS)-123 sample exhibited the enhanced flux pinning, compared with $YBa_{2}Cu_{3}O_y$ (Y-123) sample without RE(rare earth). Critical current density of (YNS)-123 sample was $2.5{\times}10^4\;A/cm^2$ at 2 T and 77 K.

Effect of Saline Soil and Crop Growth with Bottom Ash from Biomass Power Plant Based Wood Pellet (우드펠릿 기반 바이오매스 발전소로부터 배출된 저회를 활용한 염류토양 및 작물성장에 미치는 영향)

  • So-Hui Kim;Seung-Gyu Lee;Jin-Ju Yun;Jae-Hyuk Park;Se-Won Kang;Ju-Sik Cho
    • Korean Journal of Environmental Agriculture
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    • v.41 no.4
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    • pp.310-317
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    • 2022
  • BACKGROUND: The salt in soil interrupts crop growth. Therefore, water resources are used to remove any salt found in the soil. However, water resources have been reduced by global warming; thus, a new study is required into reducing the salt in soil. Recently, the bottom ash (BA) of a biomass power plant was found to be similar to biochar. Hence, it can be used to remove heavy metals and wastewater through the adsorption characteristics of BA. The objective of this study was to evaluate the improvement effects on crop growth in saline soil containing the BA from biomass power plants. METHODS AND RESULTS: The effect on crop growth in the saline soil supplemented with BA was studied with the crop-planted pots, which were packed by reclaimed greenhouse soils collected from Byolyang, Suncheon. The BA application level was 25, 50, 100, 200, and 400 kg/10a (referred as BA25, BA50, BA100, BA200, and BA400, respectively). The BA increased the fresh weights of the leaf and root, while nitrogen uptake increased by approximately 24-102% and 54-77%, respectively for the lead and root. The phosphorous uptake increased by 38%, although only in the leaf of the lettuce. In the case of soil, BA increased water content, pH, EC, CEC, and NH4+ and the SAR of the soil decreased by 5-15%. The bottom ash increased the contents of Ca2+ and Mg2+, and fixed the amount of Na+. CONCLUSION(S): It was confirmed the bottom ash of a biomass power plant, based on wood pellets, improved crop growth, and increased the nutrient uptake of crops in saline soil. In addition, bottom ash, which has a wide range of porosity and high values of pH and EC, improved properties of the saline soil. However, the BA has a large amount of B, As, and heavy metals. Finally, it may require a study on the safety and contamination of heavy metals contained in the bottom ash, which would be applied in soil for a long time.

Fabrication of Inkjet-printed and Non-sintered $BaTiO_3$ Dielectric Film

  • Lim, Jong-Woo;Kim, Ji-Hoon;Kim, Hyo-Tea;Yoon, Young-Joon;Yoon, Ho-Gyu;Kim, Jong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.80-80
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    • 2009
  • $BaTiO_3$ has high permittivity so that has been applied to dielectric and insulator materials in 3D system-level package integration. In order to achieve excellent performance of device, the $BaTiO_3$ layer should be highly dense. In this study, $BaTiO_3$ thick films were prepared by the inkjet printing method using 4 vol.% $BaTiO_3$ colloidal inks and cured at $28^{\circ}C$ for 5 h after infiltration of polymer resin for non-sintered process using 3 vol.% cyanate ester emulsion ink. From the obtained results. packing density was determined to be improved by overlapping rabbit ears which were generated by coffee ring effect. We also calculated the packing densities of the films and correlated these packing densities to the measured permittivity of the films.

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In vivo Comet Assay on Flounder and Clam Exposed to BaP and TBT (BaP 및 TBT에 노출된 넙치와 개조개의 in vivo Comet assay)

  • Kim, So-Jung;Chung, Young-Jae;Lee, Taek-Kyun
    • Ocean and Polar Research
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    • v.33 no.2
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    • pp.127-133
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    • 2011
  • The comet assay, also called single-cell electrophoresis (SCGE) assay, is a potential sensitive monitoring tool for DNA damage in cells. The primary objective of this study was to use comet assay to ascertain if the blood cells of flounder (Pleuronichthys olivaceus) and muscle cells of clam (Saxidomus purpurata) are suitable for genotoxicity screening. This was achieved by initially exposing blood and muscle cells under in vitro conditions to the reference genotoxin hydrogen peroxide ($H_2O_2$); strong correlation between $H_2O_2$ concentration and comet values were found. Subsequently, the identification of DNA damage in isolated cells from flounder and clam was performed under in vivo exposure to benzo(a)pyrene (BaP) and tributyltin (TBT). Flounder and clam were exposed to different concentrations (1, 10, 50, 100 ${\mu}g/L$) of BaP or TBT for 4 days. Regardless of treated chemicals, blood cells of flounder were more prone to DNA breakage compared to muscle cells of clam. In conclusion, in vivo genotoxicity of BaP and TBT can be biomonitored using the comet assay. This study suggests that flounder and clam do show potential as mediums for monitoring genotoxic damage by comet assay.

Preparation and Magnetic Properties of Acicular Ba-Ferrite Powder

  • Lee, Hak-Dong;Nam, Joong-Hee;Oh, Jae-Hee
    • Journal of Magnetics
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    • v.5 no.2
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    • pp.40-43
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    • 2000
  • Acicular $\alpha-FeOOH\; and\; Ba(OH)_2\cdot8H_2O$ are starting materials in this study. This paper presents the characteristics of the contents of citric acid and heating condition for preparing acicular barium ferrite powder. They control particle shape, crystalline phase, magnetic properties of acicular barium ferrite powder So the effects of the contents of citric acid and heating condition are studied. The experimental condition for starting materials were 800~1000$\circ C$ in firing and 0~40 wt% citric acid, respectively, Ba-ferrite particles fired at the range of 800 $\circ C$to 900 $\circ C$ were maintained as acicular particle shape, but there were mixed particles of acicular and round shape after fired at 950 $\circ C$. Ba-ferrite powder of the single phase was obtained in firing at 900~1000$\circ C$ and with 20 wt.% citric acid. There were unreacted phase of $\alpha-Fe_2O_3 \;and \; BaFe_2O_4$ phases as a second phase in case of sintering at below 850 $\circ C$. Acicular barium ferrite powder of single phase was also produced in firing at 900 $\circ C$ with 20 wt.% citric acid. The saturation magnetization of single phase of acicular $BaFe_12O_19$powder was about 51 emu/g and coercivity was about 4200 Oe.

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Filtration Performance in MSBR (Membrane-Coupled Sequencing Batch Reactor) using a Membrane for Both Filtration and Aeration (막결합형 연속회분식 생물반응조에서 여과 및 공기공급용으로 분리막을 사용할 때 공기공급이 막여과 성능에 미치는 영향)

  • Ryu, Kwan-Young;Park, Pyung-Kyu;Lee, Chung-Hak
    • Journal of Korean Society on Water Environment
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    • v.21 no.4
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    • pp.337-346
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    • 2005
  • An MSBR using a membrane for not only filtration but also aeration (MA-MSBR) was designed to reduce membrane fouling and to enhance water quality, and compared with an MSBR using a membrane for only filtration (BA-MSBR). COD removal efficiency of the MA-MSBR was similar to that of the BA-MSBR, but membrane performance of the MA-MSBR was better than that of the BA-MSBR. The MA-MSBR had more small particles in mixed liquor, so the specific cake resistance of flocs in the MA-MSBR was higher than that in the BA-MSBR. However, in the aerobic reaction step of the MA-MSBR, air went through membrane pores and out of the membrane surface, so cake layers on the membrane surface and a portion of organics adsorbed on membrane pores could be removed periodically. Therefore, cake resistance, $R_c$, and fouling resistance by adsorption and blocking, $R_f$, for the MA-MSBR increased more slowly than those for the BA-MSBR. Additionally, in order to compare the energy efficiency for two MSBRs, oxygen transfer efficiency and power to supply air into the reactor by a membrane module and a bubble stone diffuser were measured using deionized water. From these measurements, the transferred oxygen amount per unit energy was calculated, resulting that of MA-MSBR was slightly higher than that of BA-MSBR.

Clinical Course of Transferred Patients for Operation Under the Impression of Biliary Atresia (담도폐쇄증 의심하에 수술을 위해 전원된 환자의 임상 경과 분석)

  • Jung, Poong-Man;Lee, Jong-In
    • Advances in pediatric surgery
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    • v.7 no.2
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    • pp.95-104
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    • 2001
  • Biliary atresia (BA) is very difficult to distinguish from neonatal hepatitis (NH) and its prognosis depends on the age at the time of Kasai operation. Therefore early differentiation between these two conditions is very important. Although various clinical and laboratory tests have been reported to differentiate between them, they are still of limited value. From 1980 to 1999, forty-five infants were referred to our pediatric surgical unit for operation for suspected BA. Eight patients underwent Kasai operation immediately because of late diagnosis. These were excluded from the study. The clinical history, physical findings. radiologic and laboratory examinations of 37 cases were analyzed retrospectively. The average age of BA (n=20) was $55.1{\pm}16.7$ days, and that of NH (n=17) was $55.8{\pm}15.6$ days. The sex ratio of BA was 13:7, and that of NH was 14:3. All the patients had obstructive jaundice and acholic stool except 4 BA and 6 NH patients. Acholic stool with yellow component was more frequent in NH. Onset of jaundice was within 2 weeks after birth in 85 % of BA, and in 65% of NH. The onset of acholic stool was within 2 weeks after birth in 60 % of BA, and in 23.5 % of NH. The duration of jaundice and acholic stool of BA were $50.9{\pm}16.6$ days and $41.3{\pm}18.4$ days and those of NH were $40.1{\pm}23.1$ days and $26.6{\pm}25.4$ days respectively. The ultrasonogram and hepatobiliary scan were useful, but not a definitively reliable method for the differentiation of these two diseases. There was no difference in laboratory data. Seventeen cases had NH among 45 referred cases for Kasai operation with the clinical impression of BA, and 4 cases of 17 NH cases needed to be explored to rule out BA. In conclusion. false positive rate of clinical impression of BA was 37.8 %. and negative exploration rate was 8.9 %, Therefore. careful clinical observation for 1-2 weeks by an experienced pediatric surgeon was very important to avoid unnecessary operation to rule out NH up to the age of 8 - 10 weeks. so long as the stool had yellow component.

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Growth Characteristics and Grain Quality of Naked Barley Infected by Barley Yellow Mosaic Virus (보리호위위병(BaYMV)이병에 따른 쌀보리 품종의 생육특성 및 품질)

  • 이중호;김양길;서재환;박종철;최재성;김수동
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.6
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    • pp.501-505
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    • 2003
  • The growth characteristics and damage of naked barley infected with barley yellow mosaic virus (BaYMV) were investigated between resistant and susceptible varieties in habitual field plot of BaYMV BaYMV of the barley plants with typical disease symptom were identified by enzyme linked immunosorbent assay (ELISA) test. The visual degree (0-9) based on disease symptoms of BaYMV was different as 9 and 1 between susceptible variety Baegdong and resistant variety Naehanssalbori, respectively. Susceptible variety, Baegdong showed significant damage in culm length, number of kernel per spike and tiller per square meter but not in 1,000 kernel weight, so these results caused yield reduction to only 80% comparing to the control. Seed germination did not affected by BaYMV infection both in susceptible and resistant variety. In grain quality test, abortive grain yale and crude protein content were significantly increased compared to the control. The relationships between BaYMV infection and growth characteristics showed the negative correlations in culm length, number of tiller, 1000 kernel weight and yield, but it showed the positive correlation in crude protein contents. These results implied that BaYMV can affect not only barley growth and yield but grain quality.