• Journal of the Korean Ceramic Society
• /
• v.31 no.9
• /
• pp.995-1004
• /
• 1994

Phase relation and microwave dielectric properties of the system BaO.(Nd1-xSmx)2O3.TiO2 (n=4, 5) were studied. With n=5 (1 : 1 : 5), Ba2Ti9O20 and TiO2 formed in case of X$\leq$0.7, and Ba2Ti9O20 and Sm2Ti2O7 formed at X=1.0 as the second phases dispersed in fine-grained orthorhombic matrix phase. With n=4 (1 : 1 : 4). on the contrary, only fine grains of an ortho-rhombic phase were observed irrespective of Nd/Sm ratio. The compositions of these two stable orthorombic phases having distinct lattic constants even with the same Nd/Sm ratio were estimated as 4BaO.5(Nd1-xSmx)2O3.18TiO2 and BaO.(Nd1-xSmx)2O3.4TiO2 with n=5 and n=4 in the system BaO.(Nd1-xSmx)2O3.TiO2, respectively. Consequently the composition BaO.(Nd1-xSmx)2O3.5TiO2 lies in the compatible triangle of 4BaO.5(Nd1-xSmx)2O3.18TiO2 and the second phases mentioned above. The microwave dielectric properties (~4 GHz) of BaO.(Nd1-xSmx)2O3.5TiO2 can be controlled effectively by adjusting Sm content : with increasing X from 0 to 0.7, both dielectric constant and the temperature coefficient of resonant frequency decreased monotonically from 82 to 65 and from 91 (ppm/$^{\circ}C$) to -19(ppm/$^{\circ}C$), respectively, while unloaded Q(Qo) remained constant at about 2,600.

• Journal of the Korean Ceramic Society
• /
• v.41 no.11
• /
• pp.842-850
• /
• 2004

We have investigated on the preparation of BaTiO$_3$ powder at the system of BaO$_2$-TiO$_2$-Reduction ag.-PSCA by SHS. C and Mg were used as reduction agent, and NaCl was used as PSCA (Particle Size Control Agent). The effects of the various reduction agent and its concentration, particle size control agent, reaction mixture mass on the product in the preparation of BaTiO$_3$ powder at the optimum system by SHS were investigated. The optimum conditions for reaction system and composition were BaO$_2$+TiO$_2$+0.11 Mg +0.2C+0.75NaCl in the As atmosphere. NaCl as PSCA showed the effect of controlling the particle size of product as well as the combustion temperature. The particle size of BaTiO$_3$ synthesized at the optimum condition was about 0.5 ${\mu}{\textrm}{m}$. And as the mixture mass for the reaction was increased, the more stable combustion wave appeared. We have conducted the sintering experiment at the temperature of 130$0^{\circ}C$, the time of 2 h and the atmosphere of air to measure the dielectric properties of BaTiO$_3$ synthesised in this work, and the sample sintered in this condition showed 2,290 of dielectric constant at 10$0^{\circ}C$ and 13,890 at curie point (129$^{\circ}C$).

• Korean Journal of Crystallography
• /
• v.10 no.1
• /
• pp.56-65
• /
• 1999

수열법을 이용하여 미세한 BaTiO3 분말을 합성하였다. Ti원으로 두 종류의 TiO2 gel을 사용하였으며 그 크기와 모양을 BaTiO3 합성에 주는 영향을 고찰하였다. 구형의 단분산 TiO2 gel을 사용하여 Ba(NO3)2 수용액에서 수열 합성한 BaTiO3 분말은 입자크기도 균일하였으며 응집이 일어나지 않아않았다. 비교적 낮은 pH에서 구형 TiO2 gel을 사용하여 합성한 BaTiO3 분말은 구형을 그대로 유지하였지만 높은 pH에서 합성한 BaTiO3 분말은 그 구형이 분해되었다. KOH양이 많아지고, 합성시간이 길어짐에 따라 합성된 BaTiO3 분말의 크기는 커졌으며 그 c/a 값도 증가하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.05c
• /
• pp.127-130
• /
• 2001

The $BaTiO_3+xNb_2O_5$(x=6, 8, 10wt%) ceramics were prepared by conventional mixed oxide method. The structural properties of the $BaTiO_3+Nb_2O_5$ ceramics with the sintering temperature and addition of $Nb_2O_5$ were investigated by XRD and SEM. Increasing the sintering temperature, the $2{\theta}$ value of BT(110) peak was shifted to the lower degree and intensity of the $Ba_6Ti_2Nb_8O_{30}$ (133) peak was increased. Increasing the addition of $Nb_2O_5$, the intensity of $BaTiNb_4O_{13}$ (201) peak was decreased and $Ba_6Ti_2Nb_8O_{30}$ (133) peak was increased. The grain size of the $BaTiO_3+Nb_2O_5$ ceramics sintered at $1500^{\circ}C$ were almost uniform.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
• /
• 2004.05a
• /
• pp.57-59
• /
• 2004

The melting temperature and critical temperature (Tc) of YBa$_2$Cu$_3$Ox with deferent content impurities of PbO and BaPbO$_3$ were studied. When the PbO was used as addition in YBa$_2$Cu$_3$Ox, although the melting point could be reduced, the superconductivity (the transition wide, ΔTc) became poor. From the XRD pattern of the sintered mixture of YBa$_2$Cu$_3$Ox and PbO it was known that there is a reaction between YBa$_2$Cu$_3$Ox and PbO, and the product is BaPbO$_3$. In the process of the reaction the superconducting phase of YBa$_2$Cu$_3$Ox was decreased and in the sample BaPbO$_3$became the main phase. Therefore the superconductivity was reduced. BaPbO$_3$was chosen as the impurity for the comparative study. The single phase BaPbO$_3$was synthesized by the simple way from both mixtures of BaPbO$_3$and PbO, BaPbO$_3$and PbO$_2$. Deferent contents of BaPbO$_3$(10%, 20%, 30%) were added in the YBa$_2$Cu$_3$Ox. By the phase analysis in the XRD patterns it was proved that there were not reactions between YBa$_2$Cu$_3$Ox and BaPbO$_3$. When BaPbO$_3$was used as impurity in YBa$_2$Cu$_3$Ox the superconductivity was much better than PbO as impurity in YBa$_2$Cu$_3$Ox But the melting point of YBa$_2$Cu$_3$Ox with BaPbO$_3$could not be found when the temperature was lower than 1000 $^{\circ}C$ in the DTA measurement.

• Journal of the Korean Magnetics Society
• /
• v.16 no.6
• /
• pp.283-286
• /
• 2006

We have studied the role of ${\alpha}-Al_{2}O_{3}$ buffer layer as a diffusion barrier in the Ba-ferrite/$SiO_{2}$ magnetic thin films for high-density recording media. In the interface of amorphous Ba-ferrite $(1900-{\AA}-thick)/SiO_{2}$ thin film during annealing, the interfacial diffusion started to occur at ${\sim}700^{\circ}C$. As the annealing temperature increased up to $800^{\circ}C$, the interfacial diffusion abruptly proceeded resulting in the high interface roughness and the deterioration of the magnetic properties. In order to control the interfacial diffusion at the high temperature, we introduced ${\alpha}-Al_{2}O_{3}$ buffer layer ($110-{\AA}-thick$) in the interface of Ba-ferrite/$SiO_{2}$ thin film. During the annealing of Ba-ferrite/${\alpha}-Al_{2}O_{3}/SiO_{2}$ thin film even at ${\sim}800^{\circ}C$, the interface was very smooth. The magnetic properties, such as saturation magnetization and intrinsic coercivity, were also enhanced, due to the inhibition of interfacial diffusion by the ${\alpha}-Al_{2}O_{3}$ buffer layer. Our study suggests that the ${\alpha}-Al_{2}O_{3}$ buffer layer act as a useful interfacial diffusion barrier in the Ba-ferrite/$SiO_{2}$ magnetic thin films.

• Journal of the Korean Ceramic Society
• /
• v.26 no.4
• /
• pp.493-498
• /
• 1989

High purity, submicron BaTiO3 powder was prepared by a hydrothermal technique using Ba(OH)2.8H2O, TiCl4 and NH4OH as starting raw materials. The submicron BaTiO3 powder was synthesized at 130~23$0^{\circ}C$ for 2.5h to yield highly crystalline particles with a narrow particle distribution. The mole ratio of Ba(OH)2.8H2O/TiO(OH)2 was 1.5. It is possible to obtain BaTiO3 with Ba : Ti=1.00$\pm$0/01. The samples densified well at 13$25^{\circ}C$, showing a uniform and fine grain structure. The grain size ranged between 0.3 and 0.5${\mu}{\textrm}{m}$. The products obtained by hydrothermal treatment at various temperatures from 130 to 23$0^{\circ}C$ were characterized by XRD, DTA, BET and SEM etc.

• Journal of the Korean Ceramic Society
• /
• v.24 no.1
• /
• pp.41-46
• /
• 1987

When barium titanate was synthesized in soild-solid reaction the abnormal expansion occurred from 900$^{\circ}C$ to 1100$^{\circ}C$. The equi-molecular mixture of BaCO3 and TiO2 was sintered from 800$^{\circ}C$ to 1300$^{\circ}C$ on the condition of air, vacuum and CO2 atmosphere. After that the specimens were tested closely with XRD, Dilatometer, SEM and EDS. The result indicated that; 1. The crystal phase which was concerned with expansion of BaTiO3 was Ba2TiO4 as the intermediate crystal phase. 2. The formation of Ba2TiO4 was affected by the firing atmosphere. 3. The expansion occurred when BaTiO3 changed to Ba2TiO4 and pore also expanded by the expansion of BaTiO3 body just as the model of expansion.

• Korean Journal of Plant Tissue Culture
• /
• v.27 no.2
• /
• pp.101-107
• /
• 2000

The explants of yacon (Polymnia sonchifolia Poeppig & Endlicher) were cultured to invest th8e dedifferentiation condition, and formative callus from leaf was cultured to find the regeneration and micro-crown bud formation. Basal MS medium was more effective to form callus than 1/2 MS and B$_{5}$ medium. Calli formations from leaf, petiole and lateral bud were more effective on MS medium supplemented with 1.0, 2.0 mg/L 2,4-D and 0.2, 0.4 mg/L kinetin or BA than 1.0, 2.0 mg/L NAA and 0.2, 0.4 mg/L kinetin or BA. Formative callus from leaf was proliferated about 70% on medium supplemented with 1.0 mg/L BA. When callus was proliferated, 63% regeneration rate was shown on medium supplemented with 1.0, 2.0 mg/L BA in case of subculture for 3~4 months but was not shown on medium supplemented with 1.0, 2.0 mg/L kinetin. Micro-crown bud formed as addition of BA at 3~4 months after callus culture and then was obtained many at 5~6 months, it was most formed about 82% on medium supplemented with 5 mg/L BA. Rate of micro-crown bud formation was increased as more over 5 mg/L BA concentration, when this time, however, shoot had thick leaves and short internodes, and then withered before long, Micro-crown bud was formed about 88.0% on medium supplemented with 5% sucrose, that was more increased 28% than with 3% sucrose. The buds of crown bud between harvested in field and formed in vitro were difference only in size, but both were similar in shape according to histological view.

• Journal of the Speleological Society of Korea
• /
• no.78
• /
• pp.17-22
• /
• 2007

The melting temperature and critical temperature (Tc) of $YBa_2Cu_3O_x$ with deferent content impurities of PbO and $BaPbO_3$ were studied. When the PbO was used as addition in $YBa_2Cu_3O_x$, although the melting point could be reduced, the superconductivity (the transition wide, ${\Delta}T_c$) became poor. From the XRD pattern of the sintered mixture of $YBa_2Cu_3O_x$ and PbO it was known that there is a reaction between $YBa_2Cu_3O_x$ and PbO, and the product is $BaPbO_3$. In the process of the reaction the superconducting phase of $YBa_2Cu_3O_x$ was decreased and in the sample $BaPbO_3$ became the main phase. Therefore the superconductivity was reduced. $BaPbO_3$ was chosen as the impurity for the comparative study. The single phase $BaPbO_3$ was synthesized by the simple way from both mixtures of $BaCO_3$ and PbO, $BaCO_3$ and $PbO_2$. Deferent contents of $BaPbO_3$ (10%, 20%, 30%) were added in the $YBa_2Cu_3O_x$. By the phase analysis in the XRD patterns it was proved that there were not reactions between $YBa_2Cu_3O_x$ and $BaPbO_3$. When $BaPbO_3$ was used as impurity in $YBa_2Cu_3O_x$ the superconductivity was much better than PbO as impurity in $YBa_2Cu_3O_x$. But the melting point of $YBa_2Cu_3O_x$ with $BaPbO_3$ could not be found when the temperature was lower than $1000^{\circ}C$ in the DTA measurement.