• Title/Summary/Keyword: $Al_2O_3/Ti$ composites

Search Result 96, Processing Time 0.031 seconds

Effect of Sintering Temperature on Properties of $\beta$-SiC-$ZrB_2$ Composites Manufactured by Pressureless Sintering (상압소결법에 의해 제조한 $\beta$-SiC-$ZrB_2$ 복합체의 특성에 미치는 소결온도의 영향)

  • Ju, Jin-Young;Shin, Yong-Deok
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1436-1438
    • /
    • 2001
  • The $\beta$-SiC + $ZrB_2$ ceramic electroconductive composites were pressureless-sintered and annealed by adding 12wt% $Al_2O_3$ + $Y_2O_3$ (6 : 4wt%) powder as a function of sintering temperature. The relative density showed the highest value of 81.1% at 1900$^{\circ}C$ sintering temperature. The phase analysis of the composites by XRD revealed of $\alpha$-SiC(6H), $TiB_2$, $Al_5Y_2O_{12}$ and $\beta$-SiC(15R). Flexural strength showed the highest value of 230 MPa for composites sintered at 1900$^{\circ}C$. The vicker's hardness and the fracture toughness showed the highest value of increased with increasing sintering temperature and showed the highest of 9.88 GPa and 6.05 $MPa{\cdot}m^{1/2}$ at 1900$^{\circ}C$. The electrical resistivity was measured by the Pauw method from 25$^{\circ}C$ to 700$^{\circ}C$. The electrical resistivity of the composites showed the PTCR (Positive Temperature Coefficient Resistivity).

  • PDF

Effect of TiB$_2$on Properties of SiC Electroconductive Ceramic Composites (SiC 전도성 세라믹 복합체의 특성에 미치는 TiB$_2$의 영향)

  • Sin, Yong-Deok;Park, Mi-Rim;So, Byeong-Mun;Lee, Dong-Mun
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.51 no.4
    • /
    • pp.141-146
    • /
    • 2002
  • The mechanical and electrical properties of the pressureless sintered SiC-TiB$_2$electroconductive ceramic composites were investigated as functions of the transition metal of TiB$_2$. The result of phase analysis for the SiC-TiB$_2$ composites by XRD revealed $\alpha$-SiC(6H), TiB$_2$, and YAG(Al$_{5}$Y$_3$O$_{12}$) crystal phases. The relative density showed the lowest 84.8% for the SiC-TiB$_2$composites added with 39vol.%TiB$_2$. Owing to crack deflection, crack bridging and YAG of fracture toughness mechanism, the fracture toughness showed the highest value of 7.8 MPa.m$^{1}$2/ for composites added with 39vol.%TiB$_2$under a pressureless annealing at room temperature. The electrical resistivity of the SiC-27vol.%TiB$_2$ composites was negative temperature coefficient resistance(NTCR), and the electrical resistivity of the besides SiC-27vol.%TiB$_2$composites was all positive temperature coefficient resistance(PCTR) in the temperature range of $25^{\circ}C$ to $700^{\circ}C$.EX>.

The Strength Properties of Metal Matrix Composites by Binder Additives (금속기복합재료의 바인더 첨가제에 따른 강도 특성)

  • Park, Won-Jo;Huh, Sun-Chul
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.27 no.7
    • /
    • pp.1051-1057
    • /
    • 2003
  • This study is about controlled impurities, which make metal alloys, especially AC4CH alloy that is made by restraining 0.2% Fe and Aluminum to make a matrix material. A metal matrix composite is produced using the squeeze casting method. The first step in the squeeze casting method is to add some organic binder including aluminum borate whisker into the matrix. After the fabrication of a metal matrix composite, each is individually appended to an inanimate binder such as SiO$_2$, Al$_2$O$_3$, and TiO$_2$. Through experiments the mechanical property changes were investigated between the metal matrix composite and AC4CH alloy. This study proves the superiority of the mechanical property of a metal matrix composites over AC4CH according to the previous tests and results that were mentioned above. One excellent property of matrix material composites is the infiltrated TiO$_2$ reinforcement. This material is a good substitute for the existing materials that are used in the development of industries today.

The Strength Properties of Metal Matrix Composites by Binder Additives (금속기복합재료의 바인더 첨가제에 따른 강도 특성)

  • Park, Won-Jo;Lee, Kwang-Young;Huh, Sun-Chul;Choi, Yong-Bum
    • Proceedings of the KSME Conference
    • /
    • 2001.11a
    • /
    • pp.198-203
    • /
    • 2001
  • This study is about controlled impurities, which make metal alloys, especially AC4CH alloy that is made by restraining 0.2% Fe and Aluminum to make a matrix material. A metal matrix composite is produced using the squeeze casting method. The first step in the squeeze casting method is to add some organic binder including aluminum borate whisker into the matrix. After the fabrication of a metal matrix composite, each is individually appended to an inanimate binder such as $SiO_2,\;Al_2O_3$, and $TiO_2$. Through experiments the mechanical property changes were investigated between the metal matrix composite and AC4CH alloy. This study proves the superiority of the mechanical property of a metal matrix composites over AC4CH according to the previous tests and results that were mentioned above. One excellent property of matrix material composites is the infiltrated $TiO_2$ reinforcement. This material is a good substitute for the existing materials that are used in the development of industries today.

  • PDF

Mechanical Properties and Biocompatibility of Ti-Nb-Zr-Mo-CPP Biomaterial Fabricated by Spark Plasma Sintering (스파크플라즈마 소결에 의한 Ti-Nb-Zr-Mo-CPP 생체복합재의 기계적 성질 및 생체적합성)

  • Woo, Kee Do;Kim, Sang Mi;Kim, Dong Gun;Kim, Dae Young;Kang, Dong Soo
    • Korean Journal of Materials Research
    • /
    • v.23 no.2
    • /
    • pp.135-142
    • /
    • 2013
  • The Ti-6Al-4V extra low interstitial (ELI) alloy has been widely used as an orthopedic implant material because of its excellent mechanical properties and biocompatibility. However, it still has many problems, including a high elastic modulus and toxicity of the Al and V elements. Therefore, non-toxic biomaterials with a low elastic modulus need to be developed. A high energy mechanical milling (HEMM) process is introduced to improve the effect of sintering. Rapid sintering of spark plasma sintering (SPS) under pressure was used to make an ultra fine grain of Ti-25 wt.%Nb-7 wt.%Zr-10 wt.%Mo-(10 wt.%CPP) composites with bio-attractive elements for increasing strength. These composites were fabricated by SPS at $1000^{\circ}C$ at 60 MPa using HEMM powders. During the sintering process, $CaTiO_3$, TixOy, and CaO were formed because of the reaction between Ti and CPP. The effects of CPP content on the physical and mechanical properties of the sintered Ti-Nb-Zr-Mo-CPP composites were investigated. The biocompatibility and corrosion resistance of the Ti-Nb-Zr-Mo alloys were improved by the addition of CPP.

Fracture Behavior of Alumina-Titania-Monazite Composites

  • Paek, Yeong-Kyeun;Chung, Tai-Soo
    • Journal of the Korean Ceramic Society
    • /
    • v.42 no.6 s.277
    • /
    • pp.443-447
    • /
    • 2005
  • Fracture behavior was investigated in the $Al_2O_3-TiO_2(3 wt{\%})-LaPO_4(25 wt{\%}$) composite ceramics. To improve the fracture toughness of alumina ceramics, $TiO_2$ and $LaPO_4$ as a second phase were introduced. The samples were made by conventional powder processing method. Green compacts were sintered at $1600^{\circ}C$ for 2 h in air. Fracture toughness was tested using Indentation Strength Bending(ISB) method. From the bending test, enhanced fracture toughness was found in the composite, compared to the pure and $TiO_2$-doped alumina. The main factor of the enhancement of fracture toughness seems to be attributed to the weak interphase role of the $LaPO_4$ as a particulate type.

Electrochemical properties of $TiO_2$/CNTs composite as anode materials for lithium secondary battery system (리튬이차전지용 음극물질 $TiO_2$/CNTs의 전기화학적 특성)

  • Oh, Mi-Hyun;Park, Soo-Gil
    • Proceedings of the KIEE Conference
    • /
    • 2007.07a
    • /
    • pp.1363-1364
    • /
    • 2007
  • The composites such as Sn-CNTs, $SnSb_{0.5}$-CNTs and $CoSb_3$-CNTs have attracted much attention in the past years owing to their good overall properties. In these samples, intermetallic compounds show high specific capacities. Recently, interest in metal oxides such as $Al_{2}O_{3}$, MgO and $TiO_2$ has been largely stimulated by the realization that they can improve the cycling stability of the Li-ion battery electrodes. The reversible capacity of the $TiO_2$/CNTs composite reaches 168 mAh $g^{-1}$ at the first cycle and remains almost constant during long-term cycling. In this study, a nanocomposite of $TiO_2$/CNTs was prepared by sol-gel method and its electrochemical properties as anode materials for Li-ion batteries were studied by galvanostatic cycling, cyclic voltammograms (CV) and electrochemical impedance spectroscopy (EIS).

  • PDF

Applications and Thermal Durability of Aluminium Titanate Ceramics Having High Thermal Shork Resistance

  • Kim, Ik-Jin;Kang, Won-Ho
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 1993.05a
    • /
    • pp.118-119
    • /
    • 1993
  • Aluminium titanate (Al$_2$TiO$_{5}$) as structural ceramics is known as a low thermal exansion, a low thermal conductivity, a low Young's modulus, and excellent thermal shock resistant material. These properities allow for the testing as an insulating material in engines for portliner, piston bottom an turbo charger. However, those composites has low mechanical strength due to the presence of microcracks developed by the large difference in thermal expansion coefficients along crystallographic directions exceed the internal strength of material and its tendency to decompose into $Al_2$O$_3$ and TiO$_2$ at temperature below 130$0^{\circ}C$ limit however the application of aluminium titanate.e.

  • PDF

Properties of Hot Pressed Alumina-Titanium Diboride Particulate Composites

  • Park, Dong-Soo;Han, Byung-Dong
    • The Korean Journal of Ceramics
    • /
    • v.4 no.3
    • /
    • pp.227-230
    • /
    • 1998
  • Alumina($Al_2O_3$)-Titanium Diboride($TiB_2) particulate composites were fabricated by hot pressing of the powder mixture that was prepared from Self-propagating High Temperature Synthesis (SHS) product and commercial powders. Their propeties were examined in order to find feasibility of using SHS for making the high performance ceramic composite. $TiB_2 particles obtained by grinding the SHS product were finer than the commercial powders. Hot pressed sample containing the SHS products exhibited higher strength than the one prepared from the commercial powders.

  • PDF

Fabrication of Fiber-Reinforced Composites by High Pressure Self-Combustion Sintering Method (고압 자전연소 소결법을 이용한 섬유강화 복합체의 제조)

  • 방환철;고철호;임동원;김봉섭;최태현;윤존도
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.5
    • /
    • pp.444-452
    • /
    • 2000
  • Dense composites of titanium matrix and Al2O3 matrix with reinforcements of carbon or titanium carbide fibers were successfully fabricated by high-pressure self-combustion sintering method or combustion reacton under 30 MPa of uniaxial pressure with an aid of external heating in vaccum. It was found that the fibers were uniformly distributed in the matrix, and aligned in a phase perpendicular to the pressure axis. As a moel ratio of Ti/C or reaction time increased, the density of Ti-matrix composite increased Micro pores around fibers could be removed by using clean carbon fibers without sizing agent on their surface. The evolution of carbide fibers from carbon fibers was observed. The composition of the various phases around fibers were analyzed.

  • PDF