• Bulletin of the Korean Chemical Society
• /
• 제28권10호
• /
• pp.1763-1770
• /
• 2007

Strong solid acid catalysts, NiO/Al2O3-TiO2/WO3 for ethylene dimerization were prepared by the addition of Al2O3 and the modification with WO3. The acid sites and acid strength were increased by the inductive effect of WO3 species bonded to the surface of catalysts. The larger the dispersed WO3 amount, the higher both the acidity and catalytic activity for ethylene dimerization. The addition of Al2O3 to TiO2 up to 5 mol% enhanced acidity and catalytic activity gradually due to the interaction between Al2O3 and TiO2 and consequent formation of Al-O-Ti bond.

• 연구논문집
• /
• 통권26호
• /
• pp.103-112
• /
• 1996

$Al_2O_3/SiC$ Hybrid-Composite이 일반적인 분말공정에 의하여 제조되었다. 소결시 $\gamma-Al_2O_3에서 $\alpha-Al_2O_3$로의 전이에 seed역할을 하는 $\alpha-Al_2O_3의 첨가는 균일한 미세구조를 발달시켜 강도의 증진을 가져왔다. nano size의 SiC의 첨가는 $Al_2O_3$의 소결성과 입성장에 영향을 미쳐 파괴강도의 증진을 가져왔다. $Al_2O_3/SiC$ nano-Composite에 SiC plates의 첨가는 파괴강도의 감소를 가져왔지만, 상대적으로 파괴인성은 증진되었다. SiC plates에 nitride (BN, $Si_3N_4$ 코팅을 할 경우 crack deflection을 더욱 유발하여 파괴인성이 증진되었다.

• 조명전기설비학회논문지
• /
• 제24권4호
• /
• pp.140-148
• /
• 2010

단사정 $ZrO_2(ZrO_2(m))$ 또는 $Y_2O_3$를 5.35[wt%] 첨가한 정방정 $ZrO_2(ZrO_2(t))$를 $Al_2O_3$에 첨가하여 물리적 및 전기전도도의 영향을 연구하였다. $ZrO_2$(m)과 $ZrO_2$(t)의 첨가는 $Al_2O_3$의 소결밀도를 증가시켰다. $ZrO_2$(t)의 첨가함에 따라 비커스 경도 또한 증가했으며, 그 량이 20[wt%]에서 최대가 되었다. 시편의 경도는 소결 밀도에 의존함을 알 수 있었다. $Al_2O_3-ZrO_2$계의 경도는 $ZrO_2$(t)의 첨가에 의해 개선되었고, $ZrO_2$(m)의 첨가가 $ZrO_2$(t)의 첨가보다 $Al_2O_3-ZrO_2$계의 열충격 특성에는 더 많은 영향을 받음을 알 수 있었다. 15[wt%] 이상의 $ZrO_2$(t) 첨가에서 인가전압이 증가 함에 따라 점차로 전기전도도가 증가 하였으나, $ZrO_2$(m)의 첨가에서는 영향이 없었다.

• 한국세라믹학회지
• /
• 제32권1호
• /
• pp.106-112
• /
• 1995

In order to examine the effect of CuO and Al2O3 addition on the electrical conductivity of ZnO, both Al2O3 (0, 1, 2, 5, 10at.%) and CuO (1, 5at.%) were added to ZnO. Al2O3 addition (~2at.% Al) increased the total electrical conductivity of ZnO which was already decreased by CuO doping effect Above solid solubility of Al (~2at.%), ZnAl2O4 formed and the total electrical conductivity decreased due to the decrease of sintered density. Impedance measurements were used to know the reason and degree of contribution of three resistive elements, ZnO grain, ZnO/CuO, and ZnO/ZnO grain boundaries, to the total electrical conductivity changed.

• 한국세라믹학회지
• /
• 제38권12호
• /
• pp.1123-1131
• /
• 2001

재활용 $Al_2$O$_3$분말인 구조재료용 $Al_2$O$_3$세라믹스의 분쇄분말과 폐Al$_2$O$_3$흡착제의 첨가량과 입경에 따른 재생 $Al_2$O$_3$세라믹스의 소결특성을 조사하였다. 1,$650^{\circ}C$에서 5시간 소결한 순수 $Al_2$O$_3$시편을 급랭하여 분쇄한 -40과 +40$\mu$m의 $Al_2$O$_3$분말과 폐Al$_2$O$_3$흡착제를 순수한 $Al_2$O$_3$분말에 10~50wt% 첨가한 후, 재소결하여 재생 $Al_2$O$_3$세라믹스를 제조하였다. 재활용 $Al_2$O$_3$분말의 첨가량과 입경에 관계없이 소결온도가 증가함에 따라 시편의 밀도와 3점곡강도는 증가하였으나, 동일 소결온도에서는 재활용 $Al_2$O$_3$분말의 첨가량이 증가함에 따라 밀도와 3점곡강도는 감소하였다. ~30wt%의 $Al_2$O$_3$분쇄분말(-40$\mu$m), ~20wt%의 $Al_2$O$_3$분쇄분말(+40$\mu$m) 및 10wt%의 폐Al$_2$O$_3$흡착제를 첨가한 시편의 3점곡강도는 200MPa 이상이었다. 재생 $Al_2$O$_3$시편의 치밀화를 위하여 5~20wt%의 폐유리분말을 첨가하여 1200~1$650^{\circ}C$에서 5시간 소결한 시편은 폐유리분말의 첨가량이 증가함에 따라 최대 밀도와 3점곡강도를 나타내는 온도는 감소하였으나, 140$0^{\circ}C$이상에서는 페유리분말을 첨가하지 않은 시편에 비하여 밀도와 3점곡강도가 감소하여 재생 $Al_2$O$_3$세라믹스의 소결성 향상에는 기여하지 못하였다.

• 대한전자공학회논문지
• /
• 제27권6호
• /
• pp.886-894
• /
• 1990

Sinterbility, microstructure, mechenical and electrical properties of yttriastabilized zirkconiz (92 mole % ZrO2 + 8 mole % Y2O3) doped with 0.5 mole % SiO2 and 0-2.O mole% Al2O3 were studied as a functin of Al2O3 addition. Sintered density increased with increasing Al2O3 addition up to o.5 mole%but decreased up to 1.0mole% Al2O3. Vickers hardness is proportional to sintered density. The specimen added 0.5mole% Al2O3 and 0.5mole% SiO2 exhibited a maximum conductivity. And the specimen added 0.5 mole % Al2O3 and 0.5 mole% SiO2 was measured a maximum electromotive force for a characteristics of oxyzen partial pressure.

• 한국전기전자재료학회논문지
• /
• 제22권5호
• /
• pp.397-404
• /
• 2009

Effects of ceramic filler types and dose on the low temperature sintering and dielectric properties of ceramic/$CaO-Al_2O_3-SiO_2$ (CAS) glass composites were investigated. All of the specimens were sintered at $850{\sim}900^{\circ}C$ for 2 h, which conditions are required by the low-temperature co-firing ceramic (LTCC) technology. Ceramic fillers of $CaCO_3$, $Al_2O_3$, $CaCO_3-Al_2O_3$ mixture, and $CaCO_3-Al_2O_3$ compound ($CaAl_2O_4$), respectively, were used. The addition of $Al_2O_3$ yielded the crystalline phase of alumina, which was associated with the inhibition of sintering, while, $CaCO_3$ resulted in no apparent crystalline phase but the swelling was significant. The additions of $CaCO_3-Al_2O_3$ mixture and $CaAl_2O_4$, respectively, yielded the crystalline phases of alumina and anorthite, and the sintering properties of both composites increased with the increase of filler addition and the sintering temperature. In addition, the $CaAl_2O_4$/CAS glass composite, sintered at $900^{\circ}C$, demonstrated good microwave dielectric properties. In overall, all the investigated fillers of 10 wt% addition, except $CaCO_3$, yielded reasonable sintering (relative density, over 93 %) and low dielectric constant (less than 5.5), demonstrating the feasibility of the investigated composites for the application of the LTCC substrate materials.

• 한국세라믹학회지
• /
• 제27권4호
• /
• pp.465-472
• /
• 1990

The effects of Al2O3 and Cr2O3 addition on the mechanical properties and microstructures of Y-TZP ceramics obtained by co-precipitation method of ZrO2＋3m/o Y2O3, following pressureless sintering at 150$0^{\circ}C$ for 2h were investigated. The addition of Al2O3 and Cr2O3 improved the Y-TZP sinterability and the Al2O3 addition showed the better effect on Y-TZP sintering than that of the Cr2O3 addition. The density and microstructure had the better effect on the bending strength of specimen more than stressinduced phase transformation (SIPT) of ZrO2 from tetragonal to monoclinic phase. The hardness of the specimens was found to be depend on the relative density and the fracture toughness of Y-TZP was found to rely on the amount of SIPT. The grian size of Cr2O3-doped Y-TZP was observed to be relatively smaller and had a narrower distribution than that of Al2O3-doped Y-TZP. If decomposition reaction of Cr2O3 can be controlled at high temperatures, it is anticipated that the mechanical properties of Y-TZP can be much improved by the Cr2O3 addition.

• 한국세라믹학회지
• /
• 제45권12호
• /
• pp.827-831
• /
• 2008

Spark plasma sintering (SPS) of AlN ceramics were carried out with ${Y_2}{O_3}$ as sintering additive at a sintering temperature $1,550{\sim}1,700^{\circ}C$. The effect of ${Y_2}{O_3}$ addition on sintering behavior and thermal conductivity of AlN ceramics was studied. ${Y_2}{O_3}$ added AlN showed higher densification rate than pure AlN noticeably, but the formation of yttrium aluminates phases by the solid-state reaction of ${Y_2}{O_3}$ and ${Al_2}{O_3}$ existed on AlN surface could delay the densification during the sintering process. The thermal conductivity of AlN specimens was promoted by the addition of ${Y_2}{O_3}$ up to 3 wt% in spite of the formation of YAG secondary phase in AlN grain boundaries because ${Y_2}{O_3}$ addition could reduced the oxygen contents in AlN lattice which is primary factor of thermal conductivity. However, the thermal conductivity rather decreased over 3 wt% addition because an immoderate formation of YAG phases in grain boundary could decrease thermal conductivity by a phonon scattering surpassing the contribution of ${Y_2}{O_3}$ addition.

• 한국세라믹학회지
• /
• 제34권4호
• /
• pp.406-412
• /
• 1997

Al2O3/SiC hybrid-composite has been fabricated by the conventional powder process. The addition of $\alpha$-Al2O3 as seed particles in the transformation of ${\gamma}$-Al2O3 to $\alpha$-Al2O3 provided a homogeneity of the microstructure. The grain growth of Al2O3 are significantly surpressed by the addition of nano-size SiC particles. Dislocation were produced due to the difference of thermal expansion coefficient between Al2O3 and SiC and piled up on SiC particles in Al2O3 matrix, resulting in transgranular fracture. The high fracture strength of the composite was contributed to the grain refinement and the transgranular fracture mode. The addition of SiC platelets to Al2O3/SiC nano-composite decreased the fracture strength, but increased the fracture toughness. Coated SiC platelets with nitrides such as BN and Si3N4 enhanced fracture toughness much more than non-coated SiC platelets by enhancing crack deflection.