• 제목/요약/키워드: $2^{nd}$ law of Thermodynamics

검색결과 2건 처리시간 0.019초

고온열 이용 공정의 열역학적 해석 (Thermodynamic Analysis of Thermochemical Process for Water Splitting)

  • 김종원;손현명;이상호;심규성;정광덕
    • 한국수소및신에너지학회논문집
    • /
    • 제13권3호
    • /
    • pp.204-213
    • /
    • 2002
  • In this work, hydrogen production by a 2-step water-spritting thermochemical cycle based on metal oxides redox pairs was investigated on the bases of the thermodynamics and technical feasibility. Also, a 2nd-law analysis performed on the closed cyclic process indicates a maximum exergy conversion efficiency of 7.1% when using a solar cavity-receiver operated at 2300K and air/Fe3O4 molar ratio = 10.

증기의 감온·감압과정에서의 엑서지 손실 및 저감방안 분석 (The Analysis on Exergy Loss and its Reduction Methods in Steam Desuperheating and Depressurizing Process)

  • 이중용;이찬
    • 한국유체기계학회 논문집
    • /
    • 제18권6호
    • /
    • pp.19-26
    • /
    • 2015
  • The present paper presented and applied an exergy analysis method to evaluate the magnitudes and the locations of exergy losses in the conventional desuperheating and depressurizing process of high pressure and temperature steam delivery system. In addition, for the reduction of exergy losses occurred in conventional process, the present study proposed new alternative processes in which the pressure reducing valve and the desuperheater of conventional process are substituted with steam turbine and heat exchanger, and their effects on exergy loss reduction and exergy efficiency improvement are theoretically investigated and compared. From the present analysis results, the total exergy loss caused in conventional desuperheating and depressurizing process accounted for 66.5% of exergy input and 85% of the total exergy loss was due to the mixing between steam and cold water(e.g desuperheating). However, it was shown from the present analysis results that the present alternative processes can additionally reduce exergy loss by maximum 92.7% of the total exergy loss in conventional process, and can also produce additional and useful energy, the electricity of 220.6 kWh and the heat of 54.3 MJ/hr.