• Title/Summary/Keyword: ${NO_3}-N$

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NO Removal Characteristics in $N_2$ for a Dielectric Barrier Discharge Reactor with the Variation of a Discharge Gap (유전체 장벽 방전 반응기에서 방전 간극의 변화에 따른 질소 분위기하의 NO 제거 특성)

  • 차민석;이재옥;신완호;송영훈;김석준
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.407-408
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    • 2000
  • 유전체 장벽 방전 반응기 (Dielectric Barrier Discharge (DBD) Reactor)를 이용한 비열 플라즈마(Non-thermal plasma) 공정에서 NO 제거 특성을 실험적으로 연구하였다. 질소 분위기에서 전자에 의한 NO 의 제거는 $N_2$ + e $\longrightarrow$ N + N + e 반응에 의한 질소의 전자충돌해리 (electron-impact dissociation)와 이 반응에 의하여 생성된 질소원자에 의한 NO 의 환원반응 N + NO $\longrightarrow$ $N_2$ + O 으로 설명될 수 있으며, 이로 인하여 $O_2$$H_2O$ 의 첨가에 따른 부산물(O, $O_3$, OH 등)에 의한 산화반응이 주로 일어나는 경우 (XO + NO $\longrightarrow$ X + NO$_2$) 와는 달리 NO 제거에 소모된 에너지를 평가하기에 용이한 장점이 있다(Penetrante et al., 1995). (중략)

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Effects of Persicaria thunbergii on Nitrogen Retention and Loss in Wetland Microcosms (습지 미소생태계에서 질소 보유와 제거에 대한 고마리 ( Persicaria thunbergii ) 의 효과)

  • Woo, Yeun-Kyung;Eun-Jin Park;Dowon Lee;Kye Song Lee
    • The Korean Journal of Ecology
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    • v.19 no.2
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    • pp.179-189
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    • 1996
  • Growth and nitrogen retention of Persicaria thunbergii were investigated in the wetland microcosms which contained the plants growing on soil bed. Nitrogen solution was supplied to the microcosms with the same amount of $NH_4^{+}-N\; and\; NO_3^{-}-N$ at the rates of 0.00, 0.78, 1.57, 3.14g $N{\cdot}m^{-2}{\cdor}wk^{-1}$ from May 1 to August 31, 1995. The solution was detained for 5 days to react with soil and plant and then allowed to leach. The contents of NH_4^{+}-N\;and\; NO_3^{-}-N$ in the leachate, total Kjeldahl nitrogen, plant biomass, and soil characteristics were determined. Nitrogen retained by plant was estimated as the increment of TKN in plant biomass. The addition of 0.78 and 1.57g $N{\cdot}m^{-2}{\cdot}wk^{-1}$ resulted in significant increase of plant biomass. However, plant growth was inhibited when nitrogen was added at the rate of 3.14g $N{\cdot}m^{-2}{\cdot}wk^{-1}$. Overall, the plant biomass was positively correlated with the amount of nitrogen retained by plant and soil system. The amounts of $NO_3^{-}-N$ leached from the microcosms were 5~10 times higher than those of $NH_4^{+}-N$. While total nitrogen added ranged from 143.2 to 576.5g $N/m^2$, total leaching loss of inorganic nitrogen and nitrogen retained by plant was as little as 1.04~22.71g $N/m^2$, and 5.46~12.91g $N/m^2$, respectively. Then, the plant seemed to contribute to KDICical and microbial immobilization of nitrogen in the soil. Finally, it is suggested that a large portion of nitrogen added was lost into the air by denitrification and volatilizaton, and / or leached in organic forms.

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Nitrate Removal Rate in Reed Wetland Cells of a Pond-Wetland Stream Water Treatment System (하천수정화 연못-습지 시스템의 갈대 습지셀 초기 질산성질소 제거)

  • Yang, Hong-Mo
    • Korean Journal of Environmental Agriculture
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    • v.21 no.4
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    • pp.274-278
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    • 2002
  • Nitrate removal rate in three wetland cells was examined. The acreage of each cell was 150 $m^2$. They were a part of a stream water treatment demonstration system which was composed of two ponds and six wetland cells. Earth works far the pond-wetland system were finished from April 2000 to May 2000 and reeds were planted in the three cells in May 2001. Waters of Sinyang Stream flowing into Kohung Esturiane Lake located southern coastal area of Korean Peninsula were pumped into a primary pont Effluents from a secondary pond were funneled into the three cells. Volumes and water quality of inflow and outflow were analyzed from July 2001 through December 2001. Inflow and outflow averaged 20 $m^3/d$ and 19.3 $m^3/d$, respectively. Hydraulic retention time was 1.5 days. Average influent and effluent nitrate concentration was 2.30 mg/L, 1.75 mg/L, respectively. Nitrate removal rate in the three cells averaged 80.9 $mg/m^2/day$. Seasonal changes of nitrate retention rates were closely related to those of wetland temperatures. Full growth of reeds within a few years can develope litter-soil substrates beneficial to the denitrification of nitrate, which may lead to increases of the nitrate retention rates.

Effects of Various Nitrogen Compounds for the Growth of Barley Roots and Transaminase Activity (대맥근(大麥根)의 생장(生長)과 Transaminase의 활성(活性)에 미치는 몇 가지 질소화합물(窒素化合物)의 영향(影響))

  • Kim, K.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.3 no.1
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    • pp.43-48
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    • 1970
  • In order to investigate the inter-relation with the growth of the barley root and GOT and GPT activities the growth of root and GOT, GPT activities were measured those which have been supplied various nitrogen compounds ($NO_3-N$, $NH_4-N$, Urea, and Amino acid). The results obtained are summarized as follows: 1. Growth of barley root supplied with $NH_4-N$ is generally increased in length and weight compared with that of the root fertilized by $NH_4-N$. 2. The above-mentioned root with $NH_4-N$ is not only decreased in its weight and length but also is apt to inhibited its growth, in compared with the root provided with $NO_3-N$. 3. The activities of GOT and GPT for the root fertilized by $NH_4-N$, the badly grown root is generally increased, while of the root supplied with $NO_3-N$ is decreased compared with that of the root fertilized by $NH_4-N$. 4. The activities of GOT and GPT for the root provided with amino acid known as the considerable growth inhibiting compound for rice is generally decreased, while that of the badly known-grown root is increased. 5. The activities of GOT and GPT in the supernatant fraction of the barley is for the most part, high and low in the mitocondrial fraction.

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Denitrification of the wastewater containing nitrate by various hydrogen donor addition (각종 수소공여체의 첨가에 의한 $NO_3^--N$ 함유 폐수의 탈질)

  • Kim, Hyeong-Seok;Eun, Jong-Keug;Park, Seung-Cho
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.229-237
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the NO3--N removal efficiency by various hydrogen donor addition, determination of optimum COD/$NO_3^--N$ ratio and characteristics of granular sludge.

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Evaluation and Application of QUAL2E and QUAL2K Models in Anyang Stream (안양천에서 QUAL2E와 QUAL2K 모델의 적용 및 평가)

  • Jung, Sung-Soo;Kim, Kyung-Sub
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.5
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    • pp.544-551
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    • 2008
  • QUAL2K enhanced QUAL2E and applied in real fields efficiently incorporates denitrification process, sediment-water interaction process, bottom algae and detritus. Also, the CBOD of QUAL2K is divided into two real parts, one is slow CBOD(sCBOD) and another is fast CBOD(fCBOD). The simulation results of QUAL2E and QUAL2K models in Anyang Stream were compared and analyzed in water quality constituents of DO, BOD, Org-N, NH$_3$-N, NO$_3$-N, Org-P, Dis-P and Chl-a respectively. The similar results were shown in Org-N, NH$_3$-N, Org-P and Chl-a both QUAL2K and QUAL2E models. But the different results were revealed in DO, BOD, Dis-P and NO$_3$-N by the influence of new incorporating processes. DO was shown relatively low values in the effect of bottom algae. BOD which is influenced by particulate organic matter was revealed high values. NO$_3$-N was closed to the real values by the two processes of denitrification and sediment-water interaction. To evaluate the running results of QUAL2K and QUAL2E models, a simple statistical analysis was conducted. According to the statistical analysis, QUAL2K represented less relative error and coefficient of variation than QUAL2E in almost all of constituents. It was found that QUAL2K, which simulates the water quality more realistically, can be applied to control and manage the water problems of river or river-run reservoir effectively.

A Study on Release Characteristics of Lake Sediments under Oxic and Anoxic Conditions (호수 퇴적물의 호기 및 혐기조건에서의 용출 특성에 대한 연구)

  • Yoon, Mi-Hae;Hyun, Jun-Taek;Huh, Nam-Soo;Kwon, Sung-Hyun;Cho, Dae-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.1003-1012
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    • 2007
  • In this study, we analyzed the release differences for some critical pollution compounds according to the surrounding conditions in order to predict water quality due to the sedimental releases and the release characteristics at different sedimental locations in Lake Leewon, in Tae-An area. COD, nitrogens and phosphates were analyzed using the standard methods for water quality, based on high chloride ion concentration(greater than 2,000 ppm). For COD, the release rate increased in the anoxic basin but almost the same in the oxic basin. For $NH_3$-N, the release rate decreased in the oxic basin as you go A through C point meanwhile, for $NO_3$-N and T-N, the tendency was reversed because of nitrification of them. In the anoxic basin, the release rates of $NH_3$-N and $NO_3$-N went up with A through C path. However, the release rate of T-N was found to decrease. Also, for $PO_4$-P and T-P, the release rates in the oxic basin were lowest at B point mainly because the phosphates were at less released in the highly $O_2$ concentrated environment. In the anoxic reactor, $PO_4$-P was released similarly regardless of the sampling points. In summary, the release rates in the oxic reactor were greater than those in the anoxic reactor for COD and $NO_3$-N. For the other components, the anoxic basin generated the higher release rates.

Studies on the Modelling of Controlled Environment in Leaf Vegetable Crops (엽채류의 환경제어 모델 연구 I. 야온 및 양액내 $\textrm{NO}_3\;^-$: $\textrm{NH}_4\;^+$비가 백경채 및 탑채의 생육에 미치는 영향)

  • 박권우;신영주;이용범
    • Journal of Bio-Environment Control
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    • v.1 no.1
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    • pp.21-27
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    • 1992
  • The effects of different night temperatures and NO$_3$$^{[-10]}$ : NH$_4$$^{+}$ ratios in nutrient solution on the growth and quality of Chinese white cabbage(B. chinensis L. var. chinensis) and Chinese flat cabbage(B. chinensis L. var. rosularis) were studied. The results were summarized as follows. 1. Fresh weight was increased higher in night temperature 15$^{\circ}C$ than 5, 1$0^{\circ}C$, but content of vitamin C and dry weight ratio were increased as night temperature was lower. 2, The growth of Chinese white cabbage and Chinese flat cabbage was bad extremely in NO$_3$$^{[-10]}$ : NH$_4$$^{+}$(0 : 8), and the others were little different 3. In nutrient solution, the higher NO$_3$$^{[-10]}$ -N concentration was, the more content of vitamin C, and the higher NH$_4$$^{+}$-N concentration was, the more dry weight ratio.ratio.

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Water Quality Level Model Using the Discriminant Analysis for the Small Streams of Rural Area in the Han River Watersheds (판별분석을 이용한 한강권역 농업용 하천수의 수질등급모형)

  • Choi, Chul-Mann;Lee, Jong-Sik;Cho, Nam-Jun;Ryu, Hui-Yong;Park, Seong-Jin;Kim, Jin-Ho;Yun, Sun-Gang;Lee, Jeong-Taek
    • Korean Journal of Environmental Agriculture
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    • v.27 no.2
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    • pp.105-110
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    • 2008
  • The main purpose of this work is the development of water quality level model using the data such as DO, EC, BOD, $COD_{Cr},\;NH_3-N,\;NO_3-N,\;PO_4-P$, T-N, T-P, and SS in 88 agricultural streams of the Han river watersheds. To grant water quality level for each parameters, it divided into 20% respectively in the order of water quality level. On the basis of the lowest water quality level, water quality of streams was assigned. As the result, number of stream corresponding to Level Ⅰ was 0, Level II was 1 stream, Level III was 3 streams, Level IV was 22 streams, and Level V was 62 streams. By standardized canonical discriminant function coefficient, $NO_3-N$ was the highest in 0.427 at the discriminant power. According to discriminant function for water quality level, it was equal to $-4.648+3.246{\times}[NO_3-N],\;-5.084+3.456{\times}[NO_3-N],\;-4.298+3.067{\times}[NO_3-N],\;and\;-7.369+4.396{\times}[NO_3-N]$ from Level II to Level V, respectively. As a result of test at real data of the Han river watersheds in 2007, the suitability of water quality level model was high to 88.4%.

Sanitary Chemical Conditions of Farmwaters in Choongcheongnam and Kangwon Province According to Spring and Summer (충청남도 및 강원도 목장지역 목장용수의 춘하절간 위생화학적 변화)

  • 이강문;박석기;이용욱
    • Journal of Food Hygiene and Safety
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    • v.9 no.4
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    • pp.229-235
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    • 1994
  • It is very important to investigate the sanitary chemical conditions of farmwaters used for cattle breeding in the dairy farms. For this purpose we examined pH, KMnO4 consumption, total hardness, chloride, sulfate, NH3-N, NO3-N, fluoride, lead, iron, manganese, cadmium, copper, zinc and chrome in the farmwaters sampled 2 times(spring and summer)in Choongcheongnam and Kangwon Province. The pH of farmwaters in Choongcheongnam and Kangwon Province was 6.49$\pm$0.09, 6.70$\pm$0.06, total hardness 90.21$\pm$7.07, 64.53$\pm$6.38 mg/ι, consumption of KMnO4 4.13$\pm$0.62, 4.34$\pm$0.26mg/ι, NO3-N 6.51$\pm$0.55, 3.61$\pm$0.58 mg/ι, chloride ion 20.51$\pm$1.99, 5.41$\pm$1.36 mg/ι and sulfate ion 6.61$\pm$1.02, 7.28$\pm$1.30 mg/ι, respectively. But NH3-N was scarcely detected. Fluoride, iron, lead, cadmium, zinc, manganese and chrome were not detected from the tested farmwaters. There was high significance between each other in total hardness, NO3-N, chloride ion and sulfate ion. There was regional and seasonal significance in only NO3-N but only regional significance in total hardness and chloride ion.

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